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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Ice in Comet Bowell

Results of observations of the reflected light in the 1-5 micron region of the spectrum from the Comet Bowell are presented as part of the attempt to directly detect the presence of frozen volatiles in the nucleus of a comet. A deep absorption at 3.25 microns is detected in Comet Bowell which is due to the presence of H2O ice. While other volatile ices have absorption features near 3 microns, it is shown that only H2O ice is a plausible identification at the heliocentric distance of Comet Bowell during the observations (3.4 AU) since only H2O grains are stable enough to have produced the observed absorption. The implications of these findings for models of cometary nuclei are examined.

Campins, H.↗
NASA NTRS1983

Loss of water from Venus. I - Hydrodynamic escape of hydrogen

A one-dimensional photochemical-dynamic model is used to study hydrodynamic loss of hydrogen from a primitive, water-rich atmosphere on Venus. The escape flux is calculated as a function of the H2O mixing ratio at the atmospheric cold trap. The cold trap mixing ratio is then related in an approximate fashion to the H2O concentration in the lower atmosphere. Hydrodynamic escape should have been the dominant loss process for hydroogen when the H2O mass mixing ratio in the lower atmosphere exceeded approximately 0.1. The escape rate would have depended upon the magnitude of the solar ultraviolet flux and the atmospheric EUV heating efficiency and, to a lesser extent, on the O2 content of the atmosphere. The time required for Venus to have lost the bulk of a terrestrial ocean of water is on the order of a billion years. Deuterium would have been swept away along with hydrogen if the escape rate was high enough, but some D/H enrichment should have occurred as the escape rate slowed down.

Kasting, J. F.↗
NASA NTRS1983

Remote sensing of tropospheric gases and aerosols with airborne DIAL system

The multipurpose airborne DIAL system developed at NASA Langley Research Center is characterized, and the published results of tropospheric O3, H2O, and aerosol-backscatter remote-sensing experiments performed in 1980 and 1981 are summarized. The system comprises two tunable dye lasers pumped by frequency-doubled Nd:YAG lasers, dielectric-coated steering optics, a 36-cm-diameter Cassegrain receiver telescope, gateable photomultiplier tubes, and a minicomputer data-processing unit for real-time calculation of gas concentrations and backscattering profiles. The transmitted energy of the 100-microsec-separated dye-laser pulses is 40, 80, or 50 mJ/pulse at around 300, 600, or 720-nm wavelength, respectively. Good agreement was found between DIAL-remote-sensed and in-situ H2O and O3 profiles of the lower troposphere and O3 profiles of the tropopause region, and the usefulness of DIAL backscattering measurements in the study of boundary-layer and tropospheric dynamics is demonstrated. The feasibility of DIAL sensing of power-plant or urban plume SO2, of urban-area (or rural-area column-content) NO2, and of temperature and H2O (simultaneously using a third laser) has been suggested by simulation studies.

Browell, E. V.↗
NASA NTRS1984

Shock vaporization and the accretion of the icy satellites of Jupiter and Saturn

The role of impact vaporization acting during the formation of the Jovian and Saturnian satellites is examined in an attempt to explain the observed density in terms of composition of these rock and ice objects. A hypothesis is examined which states that the smaller satellites of Saturn having mean densities in the 1.1 to 1.4 Mg/cu m range represent primordial accreted planetesimal condensates formed in the proto-Jovian and Saturnian accretionary planetary discs. These densities are in the range expected for water-ice/silicate mixtures constrained in the solar values of O/Si and O/Mg atomic ratios. It is demonstrated that if the large satellites accreted from the same group of planetesimals which formed the small Saturnian satellites impact vaporization of water upon accretion in a porous regolith, at low H2O partial pressure, can account for the increase in mean planetesimal density from 1.6 Mg/cu m (43% H2O + 57% silicate) to a mean planetary density of 1.9 Mg/cu m for Ganymedean-sized water silicate objects. If impact volatilization of initially porous planetesimals is assumed, it can be demonstrated starting with planetesimals composed of 54% H2O and 40% silicate partial devolatilization upon accretion will yield a Ganymede-sized planet, having a radius of 2600 km and a density of 1.85 kg/cu m, similar to that of Ganymede, Callisto, and Titan.

Ahrens, T. J.↗
NASA NTRS1984

Self-deactivation of water vapor - Role of the dimer

A phenomenological multiple-relaxation theory of the deactivation rate constant for the nu-2 (1 - 0) bending mode of water vapor is presented which incorporates the role not only of the excited monomer but also of the bound molecular complex, in particular the dimer. The deactivation takes place by means of three parallel processes: (1) collisional deexcitation of the excited monomer, (2) a two-step reaction involving association and spontaneous redissociation of an H2O collision complex, and (3) spontaneous dissociation of the stably bound H2O dimer. Oxygen, but not nitrogen or argon, serves as an effective chaperon for the formation of the activated complex. This observation explains the impurity dependence of the self-deactivation rate constant of water vapor. Analysis of an ultrasonic absorption peak based on the third process yields values for the standard entropy and enthalpy of dissociation of the stably bound H2O dimer.

Zuckerwar, A. J.↗
NASA NTRS1986

Development of a high-altitude airborne dial system: The Lidar Atmospheric Sensing Experiment (LASE)

The ability of a Differential Absorption Lidar (DIAL) system to measure vertical profiles of H2O in the lower atmosphere was demonstrated both in ground-based and airborne experiments. In these experiments, tunable lasers were used that required real-time experimenter control to locate and lock onto the atmospheric H2O absorption line for the DIAL measurements. The Lidar Atmospheric Sensing Experiment (LASE) is the first step in a long-range effort to develop and demonstrate an autonomous DIAL system for airborne and spaceborne flight experiments. The LASE instrument is being developed to measure H2O, aerosol, and cloud profiles from a high-altitude ER-2 (extended range U-2) aircraft. The science of the LASE program, the LASE system design, and the expected measurement capability of the system are discussed.

Browell, E. V.↗
NASA NTRS1986

An all-purpose computer program for lidar simulations and reduction of lidar data

A general computer program was written for the dual purpose of simulating lidar returm signals and extracting H2O vapor and temperature (T) profiles from actual lidar returns. This program will be used to retrieve H2O vapor and T profiles from data obtained with the University of Maryland ground-based lidar systems. The program is designed to simulate and to analyze lidar returns from a monostatic system for two cases: when the output laser pulse is monochromatic, and when the pulse has a known wavelength spectrum. The simulation part of the program has several model H2O vapor, T, and aerosol profiles which can be combined to form different model atmospheres. The simulation program also permits the testing of different methods of numerical filtering to suppress noise, and testing the accuracy of different methods of numerical integration.

Braun, C.↗
NASA NTRS1986

Ground-based observation of Comet Halley

Approximately five hundred Fabry-Perot scans of H2O+, H alpha, and (OI) emissions from comets Halley, Hartley-Good, and Thiele were obtained at Kitt Peak in November, December and January. The analysis of the data is in a very early stage, but preliminary results were obtained on the production rate Q(H) of hydrogen, Q(D) of metastable oxygen, and Q(H2O) of water. The rate Q(H) varied with heliocentric distance R as R to the power -3.5 + or - 0.5. The rate Q(D) varied as R to the power -4.8 + or - 0.1. The ratio of Q(H2O) to Q(D) was 15 + or - 5.

Scherb, F.↗
NASA NTRS1986

Calculations of electric currents in Europa

Electrical currents should flow in the Galilean satellite, Europa, because it is located in Jupiter's corotating magnetosphere. The possible magnitudes of these currents are calculated by assuming that Europa is a differentiated body consisting of an outer H2O layer and a silicate core. Two types of models are considered here: one in which the water is completely frozen and a second in which there is an intermediate liquid layer. For the transverse electric mode (eddy currents), the calculated current density in a liquid layer is approximately 10 to the -5/Am. For the transverse magnetic mode (unipolar generator), the calculated current density in the liquid is severely constrained by the ice layer to a range of only 10 to the -10 to -11th power/ Am, for a total H2O thickness of 100 km, provided that neither layer is less than 4 km thick. The current density is less for a completely frozen H2O layer. If transient cracks were to appear in the ice layer, thereby exposing liquid, the calculated current density could rise to a range of 10 to the -6 to 10 to the -5/Am, depending on layer thicknesses, which would require an exposed area of 10 to the -9 to 10 to the -8 of the Europa surface. The corresponding total current of 2.3x10 to the 5th power A could in 1 yr. electrolyze 7x10 to the 5th power kg of water (and more if the cells were in series), and thereby store up to 10 the 8th power J of energy, but it is not clear how electrolysis can take place in the absence of suitable electrodes. Electrical heating would be significant only if the ice-layer thickness were on the order of 1 m, such as might occur if an exposed liquid surface were to freeze over; the heating under this condition could hinder the thickening of the ice layer.

Colburn, D. S.↗
NASA NTRS1987

Lidar measurements from space for tropospheric chemistry investigations: Summary of workshop overview presentation

Over the past decade, NASA has played a lead role in defining the scientific objectives and technology requirements for spaceborne lidar investigations of the atmosphere. An assessment of the potential for conducting lidar measurements from space for investigations that pertain specifically to tropospheric chemistry is presented. A description of potential lidar measurement techniques is given, and the scientific requirements for tropospheric chemistry are reviewed. The current status of airborne lidar measurements of aerosols, O3, and H2O is discussed, and a brief description of the evolution of lidar technology to space is given. Also, the measurement of tropospheric gases with a spaceborne lidar system is evaluated for a wide range of gas species. From this general assessment, it appears feasible to measure aerosols, H2O, O3, NH3, CO, CH4, NO2, atmospheric pressure and temperature, and wind with a lidar from space provided that the appropriate laser and receiver technology is available. For the mid-1990's, it is expected that lidar technology will be available for the measurement of aerosols, H2O, and O3 from a space platform.

Browell, Edward V.↗
NASA NTRS1986

Velocity-resolved observations of water in comet Halley

High-resolution observations of H2O in comet Halley are presented. The positions and widths of the H2O emission line profiles are indicative of the coma's velocity field characteristics. Spectral line shape changes are used to infer temporal variations in the kinematic properties of the outflow. The results suggest that H2O is released into the coma by way of multiple jets.

Larson, Harold P.↗
NASA NTRS1986

The water vapour budget of the stratosphere studied using LIMS and SAMS satellite data

Monthly zonal mean observations of H2O and CH4 made by the limb infrared monitor of the stratosphere and the stratospheric and mesospheric sounder instruments on Nimbus 7 have been used to investigate whether the H2O mixing ratios in the stratosphere are consistent with a source via the oxidation of CH4. While both sets of data show considerable seasonally varying structure, total hydrogen (neglecting molecular hydrogen) is relatively featureless with a mean value over the stratosphere of 6.0 + or - 0.35 ppmm(1sigma) for the five-month period studied. The uniformity of the total hydrogen fields points to the validity of the CH4 oxidation hypothesis. The derived fields of total hydrogen are used to deduce a mean H2O mixing ratio for air as it enters the stratosphere of 2.7 + or - 0.35 ppmv (1sigma) from which a desiccation temperature may be deduced.

Jones, R. L.↗
NASA NTRS1986

Infrared heating of Comet Halleys atmosphere

The warm circumnuclear dust in the inner cometary coma reradiates in the IR in the wavelength range of the ground state rotational band of the dominant atmospheric molecule H2O. However, the interaction of this radiation with H2O has hitherto not been taken into account in cometary atmospheric models. Here, an earlier two-phase, multifluid model of the dusty atmosphere is extended by including this effect. Although this IR radiation initially pumps the rotational levels of H2O, frequent intermolecular collisions in the inner coma transfer this energy from rotational modes to translational modes. As a result the temperature in the innermost coma no longer decreases to about 10 K, as predicted by the earlier models, but reaches a minimum of only about 120 K.

Marconi, M. L.↗
NASA NTRS1986

Current status of the prebiotic synthesis of small molecules

Experiments designed to simulate conditions on the primitive earth and to demonstrate how the organic compounds that made up the first living organisms were synthesized are described. Simulated atmospheres with CH4, N2, NH3, and H2O were found to be most effective for synthesis of small prebiotic molecules, although atmospheres with H2, CO, N2, and H2O, and with H2, CO2, N2, and H2O also give good yields of organic compounds provided the H2/CO and H2/CO2 ratios are above 1 and 2, respectively. The spark discharge (which is a good source of HCN) and UV light are also important. Reasonable prebiotic syntheses were worked out for the amino acids that occur in proteins (with the exception of lysine, arginine, and histidine), and for purines, pyrimidines, sugars, and nicotinic acid. Many of the molecules that have been produced in these simulated primitive-earth experiments are found in carbonaceous chondrites.

Miller, Stanley L.↗
NASA NTRS1987

Corotation lag limit on mass-loss rate from Io

Considering rapid escape of H2O from Io during an early hot evolutionary epoch, an H2O plasma torus is constructed by balancing dissociation and ionization products against centrifugally driven diffusion, including for the first time the effects of corotation lag resulting from mass loading. Two fundamental limits are found as the mass injection rate increases: (1) an 'ignition' limit of 1.1 x 10 to the 6th kg/s, beyond which the torus cannot ionize itself and photoionization dominates; and (2) the ultimate mass loading limit of 1.3 x 10 to the 7th kg/s, which occurs when neutrals newly created by charge exchange and recombination cannot leave the torus, thereby bringing magnetospherically driven transport to a halt. Connecting this limit with the variations of Io's temperature in its early evolution epoch gives an estimate of the upper limit on the total mass loss from Io, about 3.0 x 10 to the 20th kg (for high-opacity nebula) and about 8.9 x 10 to the 20th kg (for low-opacity nebula). These limits correspond to eroding 8 km and 22 km of H2O from the surface. It is concluded that compared to the other Galilean satellites, Io was created basically dry.

Huang, T. S.↗
NASA NTRS1987

Coloration and darkening of methane clathrate and other ices by charged particle irradiation - Applications to the outer solar system

The results of laboratory experiments simulating the irradiation of hydrocarbon-H2O or hydrocarbon-H2O/NH3 clathrates by charged particles in the outer solar system are reported. Ices produced by condensing and boiling liquid CH4 on an H2O frost surface at 100 K or by cocondensing frosts from gaseous mixtures were exposed to coronal-discharge electron irradiation at 77 K, and the spectral properties of the irradiated surfaces were determined. Significant darkening of the initially white ices was observed at doses of 1 Gerg/sq cm, corresponding to 8-500 yrs of irradiation by Uranian magnetospheric electrons on the surfaces of the principal Uranian satellites, or to total destruction of CH4 in the upper 1 mm of the satellite surfaces after 0.05-3.0 Myr. It is estimated that 10 m or more of icy satellite or comet surfaces would be radiation-hardened to a CH4-free ice-tholin mixture over 4 Gyr.

Thompson, W. Reid↗
NASA NTRS1988

Abundances in Comet Halley at the time of the spacecraft encounters

Spectrophotometric observations of Comet Halley obtained in March 1986 at the time of the spacecraft encounters with the comet are described, and the column densities derived from the integrated emission band fluxes are presented. The scale lengths are determined from the spatial profiles of the observed species. Production rates are derived and the parent identities and abundance ratios of the studied species are discussed. The data indicate that the abundance of the primordial condensate NH3 comprises about 0.2 percent of the total volatile fraction of the comet nucleus. The ratio of production rates Q(NH2)/Q(H2O) = 0.003 indicates that Q(NH3)/Q(H2O) is roughly 0.3 percent, which is nearly 10 times lower than the value determined from Giotto ion mass spectrometer data. The production rate Q(CH)/Q(H2O) of 0.007 and the CH spatial profile indicate that CH cannot derive entirely from direct photodissociation of CH4.

Wyckoff, Susan↗
NASA NTRS1988

The circumstellar water fountains of IRAS 16342-3814 - A very high velocity bipolar outflow

Maser emission from OH and H2O is observed to be present over an exceptionally wide range of velocities in the cold, stellar infrared source IRAS 16342-3814. OH emission at 1612, 1665, and 1667 MHz spans 130 km/s, a range far larger than in any other known OH/IR star. The H2O emission features appear as two widely separated doublets with a full velocity spread of 259 km/s. Several lines of evidence point to the conclusion that IRAS 16342-3814 is an evolved star with a bipolar outflow, related to objects such as OH 231.8 + 4.2 and M1 - 92. The H2O masers are interpreted as streams or clumps of molecular gas forced out the polar axes by, or as part of, a wind from an accretion disk, while the OH masers appear to arise from lower velocity material at intermediate latitudes.

Likkel, Lauren↗