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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Polyenamines for Films, Coatings, and Adhesives

Easy process makes polymers with good mechanical properties. Synthesis involves Michael-type addition polymerization of two diacetylenic diketones, with various aromatic diamines in m-cresol at 60 to 130 degrees C. Technique provides synthetic route to high-molecular-weight polyenamines with moderate thermal stability and good mechanical properties. Polyenamines produced exhibit potential for use as films, coatings, adhesives, molding compounds, and composite matrices.

Hergenrother, Paul M.↗
NASA NTRS1987

Colorless Polyimide Films for Thermal-Control Coatings

Series of six essentially colorless aromatic polyimide films synthesized and characterized with objective of obtaining maximum optical transparency for applications in space; optical transparency requirement for high-performance polymeric films used in second-surface mirror coatings on thermal-control systems. Films remain more transparent than commercial film after ultraviolet and electron irradiation. Increased transparency and enhanced solubility of optically transparent polyimides makes them viable candidates for use in thermal-control coatings.

St. Clair, Anne K.↗
NASA NTRS1986

Environmentally stable polymers and coatings for space application: CH-5, supplement 10

High molecular weight, randomly coupled poly(imide siloxane) soluble block copolymers were synthesized from bis(amino propyl) polydimethylsiloxane equilibrates of various molecular weights, aromatic metalinked diamines, and 3,3'-4,4'-benzophenone tetracarboxylic dianhydride (BTDA). Two synthetic procedures were successfully used to synthesize the poly(amic acid siloxane) intermediates. For both synthetic procedures, a cosolvent system was employed to achieve complete solvation of all components throughout the polymerization. Physical property characterization is continuing.

Sykes, G.↗
NASA NTRS1986

Polyimides containing oxyethylene units. Part 4: Polymerization of dianhydrides containing ether linkages

The development of new composite resins for various aerospace applications is attempted. Although it is highly desirable that these polymers be soluble in order to facilitate processing, they must display considerable solvent-resistance in use. A recent approach has involved the synthesis of a new series of polyimides containing flexible linkages. The polymers were prepared by the polymerization of aromatic dianhydrides with diamines containing oxyethylene linkages. For example, the polymerization of 3,3',4,4'-benzophenonetetracarboxylic dianhydride (BTDA) with 1,2-bis(4-aminophenoxy)ethane (1a) and bis2-(4-aminophenoxy)ethylether (lb), afforded highly crystalline polyimides that were completely insoluble. However, a polyimide that was amorphous and soluble was obtained from the polymerization of BTDA and an isomer of lb, i.e., bis2-(3-aminophenoxy)ethyl ether (4b). In an attempt to obtain a soluble, amorphous polyimide that could be annealed into a crysalline state, block copolymers of 1b and 4b and BTDA were prepared. Copolymers containing less than 20 weight % 1b were soluble in organic solvents. However, these polymers did not crystallize when heated above their Tg's. Copolymers containing higher levels of 1b were semicrystalline and insoluble. The polymerization of the diamines containing oxyethylene linkages with 4,4'-oxydiphthalic anhydride (ODPA) and a new dianhydride, i.e., 4,4'-oxyethyleneoxyethyleneoxydiphthalic anhydride (OEDA) was investigated. It was postulated that the use of these more flexible dianhydrides would result in more processable polyimides.

Harris, F. W.↗
NASA NTRS1986

Interplanetary and interstellar dust

Several processed polycyclic aromatic hydrocarbons (PAH) samples were produced to date. The Raman spectra and D/H ratios of these samples will be studied in the near future. A manuscript was sent to Icarus which gives a detailed discussion of the possibility of using solar flare tracks in interplanetary dust particles (IDPs) to determine a cometary vs. asteroidal source of the IDPs. The technique looks promising and a program was started to measure the large number of IDP track density necessary to address the issue of the source(s) of the dust. The results could potentially tell a great deal about comets and/or asteroids.

Sandford, S.↗
NASA NTRS1986

Resolution of the 7.7 micrometers emission feature in NGC 7027

The unidentified infrared (UIR) features are a group of emission bands observed in a variety of objects, which can be characterized as having moderate density gas (densities from 1000 to 1,000,000/cu.cm.) and a nearby ultraviolet source. The origin of the features is still uncertain, but the current evidence points to Polycyclic Aromatic Hydrocarbons (PAHs) as the source of the UIR features. Problems with identifying PAHs as the source of the UIR features are discussed.

Bregman, J. D.↗
NASA NTRS1986

IRAS surface brightness maps of visible reflection nebulae: Evidence for non-equilibrium infrared emission

Surface brightness maps at 12, 25, 60, and 100 microns of 16 visible reflection nebulae were extracted from the Infrared Astronomy Satellite (IRAS) database. The maps were produced by coadding IRAS survey scans over areas centered on the illuminating stars, and have spatial resolutions of 0.9' x 4' at 12 and 25 microns, 1.8' x 4.5' at 60 microns, and 3.6' x 5' at 100 microns. Extended emission in the four IRAS bandpasses was detected in fourteen of the reflection nebulae. The IRAS data were used to measure the flux of the infrared emission associated with each source. The energy distributions show that the 12 micron flux is greater than the 25 micron flux in 11 of the nebulae, and the peak flux occurs in the 60 or 100 micron bandpass in all 16 nebular. The 60 and 100 micron flux can be approximated by blackbodies with temperatures between 30 and 50 K, consistent with temperatures expected from extrapolation of greybody fits to the 60 and 100 micron data. The excess 12 and 25 micron emission is attributed to a nonequilibrium process such as emission from thermal fluctuations of very small grains excited by single ultraviolet photons, or emission from polycyclic aromatic hydrocarbons (PAHs) excited by ultraviolet radiation. The common features of the energy distributions of the 16 reflection nebulae, also seen in the reflection nebulae associated with the Pleiades, suggest that PAHs or very small grains may be found in most reflection nebulae.

Castelaz, M. W.↗
NASA NTRS1986

Infrared absorption and emission characteristics of interstellar PAHs

The mid-infrared interstellar emission spectrum with features at 3.28, 6.2, 7.7, 8.7 and 11.3 microns is discussed in terms of the Polycyclic Aromatic Hydrocarbon (PAH) hypothesis, which is based on the suggestive, but inconclusive comparison between the interstellar emission spectrum with the infrared absorption and Raman spectra of a few PAHs. The fundamental vibrations of PAHs and PAH-like species which determine the IR and Raman properties are discussed. Interstellar IR band emission is due to relaxation from highly vibrationally excited PAHs excited by ultraviolet photons. The excitation/emission process is described and the IR fluorescence from one PAH, chrysene, is traced. Generally, there is sufficient energy to populate several vibrational levels in each mode. Molecular vibrational potentials are anharmonic and emission from these higher levels will fall at lower frequencies and produce weak features to the red of the stronger fundamentals. This process is also described and can account for some spectroscopic details of the interstellar emission spectra previously unexplained. Analysis of the interstellar spectrum shows that PAHs contain between 20 and 30 carbon atoms are responsible for the emission.

Barker, J. R.↗
NASA NTRS1987

Process for preparing phthalocyanine polymer from imide containing bisphthalonitrile

Imide-linked bisphthalonitrile compounds are prepared by combining a dicyano aromatic diamine and an organic dianhydride to produce an amic acid linked bisphthalonitrile compound. The amic acid linked bisphthalonitrile compound is dehydrocyclized to produce the imide-linked bisphthalonitrile compounds. The imide-linked bisphthalonitrile compounds may be polymerized to produce a phythalocyanine polymer by heating the imide-linked bisphthalonitrile compound, either alone or in the presence of a metal powder or a metal salt. These compounds are useful in the coating, laminating and molding arts. The polymers are useful in composite matrix resins where increased fire resistance, toughness and resistance to moisture are required, particularly as secondary structures in aircraft and spacecraft.

Achar, Bappalige N.↗
NASA NTRS1986

The hydrogen coverage of interstellar PAHs

The rate at which the CH bond in interstellar Polycyclic Aromatic Hydrocarbons (PAHs) rupture due to the absorption of a UV photon has been calculated. The results show that small PAHs (less than or equal to 25 carbon atoms) are expected to be partially dehydrogenated in regions with intense UV fields, while large PAHs (greater than or equal to 25 atoms) are expected to be completely hydrogenated in those regions. Because estimate of the carbon content of interstellar PAHs lie in the range of 20 to 25 carbon atoms, dehydrogenation is probably not very important. Because of the absence of other emission features besides the 11.3 micrometer feature in ground-based 8 to 13 micrometer spectra, it has been suggested that interstellar PAHs are partially dehydrogenated. However, IRAS 8 to 22 micrometer spectra of most sources that show strong 7.7 and 11.2 micrometer emission features also show a plateau of emission extending from about 11.3 to 14 micrometer. Like the 11.3 micrometer feature, this new feature is attributed to the CH out of plane bending mode in PAHs. This new feature shows that interstellar PAHs are not as dehydrogenated as estimated from ground-based 8 to 13 micrometer spectra. It also constrains the molecular structure of interstellar PAHs. In particular, it seems that very condensed PAHs, such as coronene and circumcoronene, dominate the interstellar PAH mixture as expected from stability arguments.

Barker, J. R.↗
NASA NTRS1987

Preparation of B-trichloroborazine

The present invention relates to a method of preparing B-trichloroborazine. Generally, the method includes the combination of gaseous boron trichloride in an anhydrous aprotic organic solvent followed by addition of excess gaseous ammonia at ambient temperature or below. The reaction mixture is heated to about 100 to 140 C followed by cooling, removal of the solid ammonium chloride at ambient temperature, distillation of the solvent under vacuum if necessary at a temperature of up to about 112 C, and recovery of the B-trichloroborazine. Solvents include toluene, benzene, xylene, chlorinated hydrocarbons, chlorinated aromatic compounds, or mixtures thereof. Toluene is a preferred solvent. The process provides a convenient synthesis of a material which often decomposes on standing. B-trichloroborazine is useful in a number of chemical reactions, and particularly in the formation of high temperature inorganic polymers and polymer precursors.

Riccitiello, Salvatore R.↗
NASA NTRS1987

Kinetics and mechanisms of some atomic oxygen reactions

Mechanisms and kinetics of some reactions of the ground state of oxygen atoms, O(3P), are briefly summarized. Attention is given to reactions of oxygen atoms with several different types of organic and inorganic compounds such as alkanes, alkenes, alkynes, aromatics, and some oxygen, nitrogen, halogen and sulfur derivatives of these compounds. References to some recent compilations and critical evaluations of reaction rate constants are given.

Cvetanovic, R. J.↗
NASA NTRS1987

Potential energy surfaces for atomic oxygen reactions: Formation of singlet and triplet biradicals as primary reaction products with unsaturated organic molecules

The experimental study of the interaction of atomic oxygen with organic polymer films under LEO conditions has been hampered by the inability to conduct detailed experiments in situ. As a result, studies of the mechanism of oxygen atom reactions have relied on laboratory O-atom sources that do not fully reproduce the orbital environment. For example, it is well established that only ground electronic state O atoms are present at LEO, yet most ground-based sources are known to produce singlet O atoms and molecules and ions in addition to O(3P). Engineers should not rely on such facilities unless it can be demonstrated either that these different O species are inert or that they react in the same fashion as ground state atoms. Ab initio quantum chemical calculations have been aimed at elucidating the biradical intermediates formed during the electrophilic addition of ground and excited-state O atoms to carbon-carbon double bonds in small olefins and aromatic molecules. These biradicals are critical intermediates in any possible insertion, addition and elimination reaction mechanisms. Through these calculations, we will be able to comment on the relative importance of these pathways for O(3P) and O(1D) reactions. The reactions of O atoms with ethylene and benzene are used to illustrate the important features of the mechanisms of atomic oxygen reaction with unsaturated organic compounds and polymeric materials.

Jaffe, Richard L.↗
NASA NTRS1987

Preparation of bis(4-(3,4 dimethylene pyrrolidyl) phenyl) methane as a high temperature reactive oligomer

A major goal in the field of high temperature polymers was to prepare aromatic polyimides that can be easily fabricated with the required thermal and physical properties for aerospace applications. Recent research was directed to achieve polyimides that are: soluable in a common organic solvent; melt-processable; and thermally curable without the evolution of volatile by-products. A monomer, N-phenyl 3,4-dimethylene pyrrolidine, that can be modified to form a bis (exocyclodiene) I for the preparation of polyimides by the Diels-Alder process was developed. Preparation of high temperature polymeric materials by Diels-Alder polymerization that will maintain their integrity and toughness during long exposure time at elevated temperature is sought.

Ottenbrite, Raphael M.↗
NASA NTRS1986

Characterization of crystalline LARC-TPI powder

LARC-TPI, a linear aromatic polyimide, developed by NASA Langley Research Center in the late 1970's had thermoplastic character, but its melt-flow properties were much lower than those of conventional thermoplastics. An imidized version of the LARC-TPI molding powder was submitted to NASA-Langley for evaluation. The initial broad melt of this material occurs in the 270 C range and reorders to higher melting forms, depending on the physical and thermal treatments. Rheological characterization of this polymer shows it to have a very low melt viscosity, which increases as the melted specie transforms to other crystalline forms with higher melting temperatures.

Burks, Harold D.↗
NASA NTRS1986

Syntheses and thermal stabilities of polyamides from 2,2'-bithiophene-5,5'-dicarbonyl dichloride and diamines

The properties of 12 polymers derived from 2,2'-bithiophene-5,5'-dicarbonyl dichloride are analyzed. The solution and interfacial polymerizations of 2,2'-bithiophene-5,5'-dicarbonyl dichloride are described. It is observed that due to high glass transition temperatures and the lack of flexibility of the polyamide of 2,2'-bithiophene-5,5'-dicarbonyl dichloride most of the polymers failed to fabricate into fibers or films. The data reveal that the polyamides formed from terphenyl ether form a tough, heat-pressed film; the polyamides made from aromatic diamides show great thermal stability; and the polyamides derived from aliphatic or benzylic diamides display no thermal stability.

Barber, Patrick G.↗
NASA NTRS1987

Hydrogenated amorphous carbon (a:C-H) in the planetary nebula NGC 7027

A spectroscopic identification of the infrared continuum radiation is proposed for the planetary nebula NGC 7027. Hydrogenated amorphous carbon (a:C-H) is shown to account for the undulating spectrum between 5 and 15 microns. The unidentified infrared emission bands lie at the peaks in the a:C-H spectrum, pointing to their association with a carbon polymorph, possibly a:C-H or polycyclic aromatic hydrocarbon molecules. Except for atomic emission lines, all the infrared emission from NGC 7027 comes from one or another polymorph of carbon.

Goebel, John H.↗
NASA NTRS1987

The IR emission features - Emission from PAH molecules and amorphous carbon particles

Given the current understanding of polycyclic aromatic hydrocarbons (PAHs), the spectroscopic data suggest that are at least two components which contribute to the interstellar emission spectrum: (1) free molecule-sized PAHs producing the narrow features and (2) amorphous carbon particles (which are primarily composed of an irregular 'lattice' of PAHs) contributing to the broad underlying components. An exact treatment of the IR fluorescence from highly vibrationally excited large molecules demonstrates that species containing between 20 and 30 carbon atoms are responsible for the narrow features, although the spectra match more closely with the spectra of amorphous carbon particles. It is concluded that, since little is known about the spectroscopic properties of free PAHs and PAH clusters, much laboratory work is required along with an observational program focusing on the spatial characteristics of the spectra.

Allamandola, L. J.↗