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At least 793 records · Page 44

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NASA NTRS1986

Fluidized-bed reactor modeling for production of silicon by silane pyrolysis

An ideal backmixed reactor model (CSTR) and a fluidized bed bubbling reactor model (FBBR) were developed for silane pyrolysis. Silane decomposition is assumed to occur via two pathways: homogeneous decomposition and heterogeneous chemical vapor deposition (CVD). Both models account for homogeneous and heterogeneous silane decomposition, homogeneous nucleation, coagulation and growth by diffusion of fines, scavenging of fines by large particles, elutriation of fines and CVD growth of large seed particles. At present the models do not account for attrition. The preliminary comparison of the model predictions with experimental results shows reasonable agreement. The CSTR model with no adjustable parameter yields a lower bound on fines formed and upper estimate on production rates. The FBBR model overpredicts the formation of fines but could be matched to experimental data by adjusting the unkown jet emulsion exchange efficients. The models clearly indicate that in order to suppress the formation of fines (smoke) good gas-solid contacting in the grid region must be achieved and the formation of the bubbles suppressed.

Dudukovic, M. P.↗

NASA NTRS1986

Solar flare neon and solar cosmic ray fluxes in the past using gas-rich meteorites

Methods were developed earlier to deduce the composition of solar flare neon and to determine the solar cosmic ray proton fluxes in the past using etched lunar samples and at present, these techniques are extended to gas rich meteorites. By considering high temperature Ne data points for Pantar, Fayetteville and other gas rich meteorites and by applying the three component Ne-decomposition methods, the solar cosmic ray and galactic cosmic ray produced spallation Ne components from the trapped SF-Ne was resolved. Using appropiate SCR and GCR production rates, in the case of Pantar, for example, a GCR exposure age of 2 m.y. was estimated for Pantar-Dark while Pantar-Light yielded a GCR age of approx. 3 m.y. However the SCR exposure age of Pantar-Dark is two orders of magnitude higher than the average surface exposure ages of lunar soils. The possibility of higher proton fluxes in the past is discussed.

Nautiyal, C. M.↗

NASA NTRS1986

Optical, radio, and infrared observations of compact H II regions. V - The Hourglass in M8

Multiwavelength observations of the inner core of the M8 Hourglass region are presented, including VLA interferometric maps, 2-4 micron and 8-13 micron spectroscopy, photometric mapping in the K (2.2 micron) and L (3.45 micron) bands and in the 3.28 micron dust-emission feature, optical CCD imaging, and optical and infrared polarimetry. The compact H II region is excited by the O7 V star Herschel 36, and its apparent bipolar structure at optical wavelengths may be due to variable line-of-sight extinction and scattered light. Standard reddening laws are not applicable in the Hourglass region. A power law extinction lambda exp -0.78 yields consistent agreement between ultraviolet, optical, and infrared extinction estimates and suggests that one component of the total grain distribution is on the average larger than that found in the interstellar medium. The spatial distribution of the 3.28 micron dust-emission feature shows that the feature emission is associated with the boundary layer in the H II region/molecular cloud interface. The observations favor models in which feature emission comes from small refractory grains rather than from fluorescence or thermal emission from volatile mantles.

Woodward, C. E.↗

NASA NTRS1986

Theoretical analysis of isotope effects on ozone formation in oxygen photochemistry

In situ measurements of stratospheric ozone and laboratory studies of ozone production in electric discharge through oxygen have shown previously that ozone containing heavy isotopes of oxygen (O-17, O-18) may be formed preferentially. In order to assess the relevance of thee latter experiment to the stratospheric measurements, detailed understanding of the effect of isotopic substitution on the O3 formation reaction O + O2 + M yields O3 + M and on the O atom exchange reaction O + O2 + O yields O2 + O is necessary. In this work, an estimate of the effect of isotopic substitution on the recombination rate is made by us of approximate dynamical theories and statistical mechanics. The results indicate the possibility of isotope effects on the O + O2 recombination rate of the order of several percent at stratospheric temperatures. In general, recombination reactions involving heavy (mass 49, 50) O3 formation are found to be slower than the reaction leading to normal (mass 48) O3 formation. The calculated isotope effects are sufficiently small that the uncertainties in the model input and the approximations in the dynamical theories will probably make the quantitative nature of these results subject to considerable uncertainty. This isotope effect should not be observable in the atmosphere given the precision of the current measurements but may be crucial in the understanding of the laboratory experiments, where observed enhancements are only of the order of several percent. Possible reasons for this discrepancy between the observed enhancement and predicted depletion are presented.

Kaye, J. A.↗

NASA NTRS1986

Precision of vertical position estimates from very long baseline interferometry

It is found that the precision of VLBI measurements of vertical crustal motions is limited by errors in the modeling of the propagation delay through the earth's neutral atmosphere, and by errors in finding the orientation of a fixed crust coordinate system in the VLBI reference frame. The repeatability of baseline length measurements study indicates a vertical position precision of about 8 cm, averaged over 13 sites and 4.5 years of data, while the repeatability of vertical position estimates for a Richmond, FL site is found to yield a precision of about 7 cm for 42 observations made over an 11-month period. An overall precision of 8 cm for a 24-hour VLBI observing session is obtained, and the effects of earth orientation parameter errors is contingent on the distances between the VLBI sites.

Herring, T. A.↗

NASA NTRS1987

On the 1A1 - 3B1 separation in CH2 and SiH2

The 1A1 - 3B1 separation in CH2 and SiH2 has been computed using extended basis sets and CASSCF/SOCI wave functions. Using theoretical estimates for the effects of zero-point vibration yields T(0) values of 8.9 and -20.9 kcal/mol respectively, in excellent agreement with the experimental values of 9.02 and -21.0 kcal/mol. A corollary to the small zero-point vibrational contribution to the separation is that the symmetric stretching fundamental in CH2(3B1) must be near 3100/cm, much less than a recently suggested value of around 3400/cm. An accurate Te value for SiH2 establishes the ionization potential of the 1A1 state as 9.15 eV, the higher of two recent experimental values.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1994

The propagation of spark-produced N waves through turbulence

A model experiment was designed and built to simulate the propagation of sonic booms through atmospheric turbulence. The setup of the model experiment is described briefly. Measurements of the N waves after they propagated across the turbulent velocity field reveal the same waveform distortion and change in rise time as for sonic booms. The data from the model experiment is used to test sonic boom models. Some models yield predictions for the waveform distortion, while others give estimates of the rise time of the sonic booms. A new theoretical model for the propagation of plane N waves through a turbulent medium is described.

Lipkens, Bart↗

NASA NTRS1994

Calibration of the TOPEX altimeter using a GPS buoy

The use of a spar buoy equipped with a Global Positioning System (GPS) antenna to calibrate the height measurement of the TOPEX radar altimeter is described. In order to determine the height of the GPS antenna phase center above the ocean surface, the buoy was also equipped with instrumentation to measure the instantaneous location of the waterline, and tilt of the bouy from vertical. The experiment was conducted off the California coast near the Texaco offshore oil platform, Harvest, during cycle 34 of the TOPEX/POSEIDON observational period. GPS solutions were computed for the bouy position using two different software packages, K&RS and GIPSY-OASIS II. These solutions were combined with estimates of the waterline location on the bouy to yield the height of the ocean surface. The ocean surface height in an absolute coordinate system combined with knowledge of the spacecraft height from tracking data provides a computed altimeter range measurement. By comparing this computed value to the actual altimeter measurement, the altimeter bias can be calibrated. The altimeter height bias obtained with the buoy using K&RS was -14.6 +/- 4 cm, while with GIPSY-OASIS II it was -13.1 +/- 4 cm. These are 0.1 cm and 1.6 cm different from the -14.7 +/- 4 cm result obtained for this flight overflight with the tide gauge instruments located on Platform Harvest.

Born, G. H.↗

NASA NTRS1995

Biological processes and optical measurements near the sea surface: Some issues relevant to remote sensing

The advent of remote sensing, the develpmemt of new optical instrumentation, and the associated advances in hydrological optics have transformed oceanography; it is now feasible to describe ocean-scale biogeochemical dynamcis from satellite observations, verified and complemented by measurements from optical sensors on profilers, moorings, and drifters. Only near-surface observations are common to both remote sensing and in situ observation, so it is critical to understand processes in the upper euphotic zone. Unfortunately, the biological principles that must be used to interpret optical variability near the sea surface are weaker than we would like, because relatively few experiments and analyses have examined bio-optical relationships under high irradiance characteristic of the upper optical depth. Special consideration of this stratum is justified, because there is good evidence that bio-optical relationships are altered near the surface; (1) the fluorescence yield from chlorophyll declines, leading to bias in the estimation of pigment from fluorometry; (2) the modeled relationship between solar-stimulated fluorecence and photosynthesis seems to deviate significantly from that presented for the lower euphotic zone; and (3) carbon-specific and cellular attenuation cross sections of phytoplankton change substantially during exposures to bright light. Even the measurement of primary productivity is problematic near the sea surface, because vertical mixing is not simulated and artifactual inhibition of photosynthesis can result. These problems can be addressed by focusing more sampling effort, experimental simulation, and analytical consideration on the upper optical depth, and by shortening timescales for the measurement of marine photosynthesis. Special efforts to study near-surface processes are justified, because new bio-optical algorithms will require quantitaitve descriptions of the responses of phytoplankton to bright light.

Cullen, John J.↗

NASA NTRS1997

A Microwave Technique for Mapping Ice Temperature in the Arctic Seasonal Sea Ice Zone

A technique for deriving ice temperature in the Arctic seasonal sea ice zone from passive microwave radiances has been developed. The algorithm operates on brightness temperatures derived from the Special Sensor Microwave/Imager (SSM/I) and uses ice concentration and type from a previously developed thin ice algorithm to estimate the surface emissivity. Comparisons of the microwave derived temperatures with estimates derived from infrared imagery of the Bering Strait yield a correlation coefficient of 0.93 and an RMS difference of 2.1 K when coastal and cloud contaminated pixels are removed. SSM/I temperatures were also compared with a time series of air temperature observations from Gambell on St. Lawrence Island and from Point Barrow, AK weather stations. These comparisons indicate that the relationship between the air temperature and the ice temperature depends on ice type.

St.Germain, Karen M.↗

NASA NTRS2002

Upper-Stratospheric Ozone Trends 1979-1998

Extensive analyses of ozone observations between 1978 and 1998 measured by Dobson Umkehr, Stratospheric Aerosol and Gas Experiment (SAGE) I and II, and Solar Backscattered Ultraviolet (SBUV) and (SBUV)/2 indicate continued significant ozone decline throughout the extratropical upper stratosphere from 30-45 km altitude. The maximum annual linear decline of -0.8 +/- 0.2 %/yr(2sigma) occurs at 40 km and is well described in terms of a linear decline modulated by the 11-year solar variation. The minimum decline of -0.110.1% yr-1(2o) occurs at 25 km in midlatitudes, with remarkable symmetry between the Northern and Southern Hemispheres at 40 km altitude. Midlatitude upper-stratospheric zonal trends exhibit significant seasonal variation (+/- 30% in the Northern Hemisphere, +/- 40% in the Southern Hemisphere) with the most negative trends of -1.2%/yr occurring in the winter. Significant seasonal trends of -0.7 to -0.9%/yr occur at 40 km in the tropics between April and September. Subjecting the statistical models used to calculate the ozone trends to intercomparison tests on a variety of common data sets yields results that indicate the standard deviation between trends estimated by 10 different statistical models is less than 0.1%/yr in the annual-mean trend for SAGE data and less than 0.2%/yr in the most demanding conditions (seasons with irregular, sparse data) [World Meteorological Organization (WMO), 1998]. These consistent trend results between statistical models together with extensive consistency between the independent measurement-system trend observations by Dobson Umkehr, SAGE I and II, and SBUV and SBUV/2 provide a high degree of confidence in the accuracy of the declining ozone amounts reported here. Additional details of ozone trend results from 1978 to 1996 (2 years shorter than reported here) along with lower-stratospheric and tropospheric ozone trends, extensive intercomparisons to assess relative instrument drifts, and retrieval algorithm details are given by WMO [1998].

Newchurch, M. J.↗

NASA NTRS1991

The timing of alkali metasomatism in paleosols

We have measured the concentrations of rubidium and strontium and 87Sr/86Sr values of whole-rock samples from three paleosols of different ages. The oldest of the three weathering horizons, the 2,760 Ma Mt. Roe #1 paleosol in the Fortescue Group of Western Australia, experienced addition of Rb, and probably Sr, at 2,168 +/- 10 Ma. The intermediate paleosol, developed on the Hekpoort Basalt in South Africa, is estimated to have formed at 2,200 Ma, and yields a Rb-Sr isochron age of 1,925 +/- 32 Ma. The youngest of the three paleosols, developed on the Ongeluk basalt in Griqualand West, South Africa ca. 1,900 Ma, yielded a Rb-Sr age of 1,257 +/- 11 Ma. The Rb-Sr systematics of all three paleosols were reset during post-weathering metasomatism related to local or regional thermal disturbances. The Rb-Sr systematics of the paleosols were not subsequently disturbed. The near-complete removal of the alkali and alkaline earth elements from these paleosols during weathering made them particularly susceptible to resetting of their Rb-Sr systematics. Paleosols of this type are therefore sensitive indicators of the timing of thermal disturbances.

NASA Discipline Number 52-20↗

NASA NTRS2008

Mars Sample Return: The Value of Depth Profiles

Sample return from Mars offers the promise of data from Martian materials that have previously only been available from meteorites. Return of carefully selected samples may yield more information about the history of water and possible habitability through Martian history. Here we propose that samples collected from Mars should include depth profiles of material across the interface between weathered material on the surface of Mars into unweathered parent rock material. Such profiles have the potential to yield chemical kinetic data that can be used to estimate the duration of water and information about potential habitats on Mars.

Hausrath, E. M.↗

NASA NTRS2008

Evaluation of Ares-I Control System Robustness to Uncertain Aerodynamics and Flex Dynamics

This paper discusses the application of robust control theory to evaluate robustness of the Ares-I control systems. Three techniques for estimating upper and lower bounds of uncertain parameters which yield stable closed-loop response are used here: (1) Monte Carlo analysis, (2) mu analysis, and (3) characteristic frequency response analysis. All three methods are used to evaluate stability envelopes of the Ares-I control systems with uncertain aerodynamics and flex dynamics. The results show that characteristic frequency response analysis is the most effective of these methods for assessing robustness.

Jang, Jiann-Woei↗

NASA NTRS1997

Balance Velocities for the Greenland Ice Sheet

We present a map of balance velocities for the Greenland ice sheet. The resolution of the DEM, which was derived from the radar altimetery data, yields far greater detail than in earlier balance velocity estimates for Greenland.

Greenland↗

NASA NTRS2021

Optimizing GRACE/GRACE-FO Data and A priori Hydrological Knowledge for Improved Global Terrestial Water Storage Component Estimates

The comprehensive information of global terrestrial water storage (TWS) components (soil moisture, groundwater, snow, surface water) is essential for effective assessment of water resource availability, climate variation, and disaster mitigation measures. Observational data provided by the Gravity Recovery And Climate Experiment (GRACE) and GRACE Follow-On satellite missions offer global TWS variation (ΔTWS) in terms of an integrated water column. However, GRACE spatial resolution is relatively coarse (i.e., 3°), and the vertically integrated value cannot be separated into ΔTWS components directly. This study demonstrates the feasibility to estimate ΔTWS components at any desired spatial-vertical resolution by effectively maintaining the native resolution of the employed hydrological knowledge. It utilizes a least-squares with constraints (LSC) approach to rigorously incorporate GRACE and GRACE-FO data and a priori hydrological knowledge, with the aim to improve global ΔTWS components’ accuracy and spatial resolution. The 3°×3° GRACE mascon derived ΔTWS data is disaggregated into the 0.5°×0.5° anomalous soil moisture storage (ΔSMS), groundwater storage (ΔGWS), snow water equivalent (ΔSWE), and surface water storage (ΔSWS) based on the covariance information obtained from the Community Atmosphere Biosphere Land Exchange (CABLE) and the PCRaster Global Water Balance (PCR-GLOBWB) models. Evaluation with different ground measurements and satellite products between 2002 and 2019 exhibits significantly improved accuracy in all individual ΔTWS components. This improvement is of particular note in ΔGWS and ΔSWS, where the LSC approach increases the globally averaged correlation values by approximately 0.13 and 0.05, respectively. Reliable prior knowledge leads to a more accurate ΔTWS component estimate, and the use of ensemble-mean knowledge yields the best result.

GRACE↗

NASA NTRS1995

Estimation of penetration of forest canopies by Interferometric SAR measurements

In contrast to traditional Synthetic Aperture Radar (SAR), an Interferometric SAR (INSAR) yields two additional measurements: the phase difference and the correlation between the two interferometric channels. The phase difference has been used to estimate topographic height. For homogeneous surfaces, the correlation depends on the system signal-to-noise (SNR) ratio, the interferometer parameters, and the local slope. In the presence of volume scattering, such as that encountered in vegetation canopies, the correlation between the two channels is also dependent on the degree of penetration of the radiation into the scattering medium. In this paper, we propose a method for removing system and slope effects in order to obtain the decorrelation due to penetration alone. The sensitivities and accuracy of the proposed method are determined by Monte Carlo experiments, and we show that the proposed technique has sufficient sensitivity to provide penetration measurements for airborne SAR systems. Next, we provide a theoretical model to estimate the degree of penetration in a way which is independent of the details of the scattering medium. We also present a model for the correlation from non-homogeneous layers. We assess the sensitivity of the proposed inversion technique to these inhomogeneous situations. Finally, we present a comparison of the interferometric results against in situ data obtained by an airborne laser profilometer which provides a direct measurement of tree height and an estimate of the vegetation density profile in the forested areas around Mt. Adams, WA.

Rodriguez, Ernesto↗

NASA NTRS1995

Estimation of Penetration of Forest Canopies by Interferometric SAR Measurements

In contrast to traditional Synthetic Aperture Radar (SAR), and Interferometric SAR (INSAR) yields two additional measurements: the phase difference and the correlation between the two interferometric channels. The phase difference has been used to estimate topographic height. A method is proposed for removing system and slope effects. A model is provided to estimate the degree of radiation penetration.

Forestry↗