Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “temperature extremes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 793 records · Page 44

Shifts in Evapotranspiration Components During Heatwaves Alter Surface Cooling

Heatwave events significantly alter ecosystem water and energy balance and are often accompanied by extreme surface temperatures. Understanding how surface temperatures during such events are regulated by soil evaporation (E) and vegetation transpiration (T) remains limited due to challenges in partitioning total evapotranspiration (ET). Here, high-frequency turbulence methods are used to partition observed ET at 32 National Ecological Observatory Network sites across the contiguous United States. Heatwaves were defined as at least three consecutive days with daily maximum air temperature exceeding the site-specific 90th percentile of the 2019–2021 record. Across 268 identified events, the T/ET ratio decreased by 32% ± 16% relative to the non-heatwave baseline of 0.65, with greater reductions at lower biomass sites. The T/ET ratio was typically suppressed below non-heatwave conditions during the early and middle stages of the heatwave (first two-thirds of event duration), but was on average higher than non-heatwave baseline levels during late stages (final third) due to extremely low soil evaporation. Of the studied heatwaves, 71% of these had surface temperatures above 38°C in their late stage; however, heatwaves sustaining higher evaporation fluxes (upper tertile of observed fluxes) during the late stage were associated with relative surface temperature anomalies that were on average 45% lower than those of heatwaves with lower evaporation fluxes (lower tertile). The commensurate surface cooling induced by higher transpiration was only 2% during heatwaves, suggesting that transpiration has a limited ability to mitigate extreme surface temperatures. This study allows for improved prediction of ecosystem feedbacks under extreme thermal stress.

54 ENVIRONMENTAL SCIENCES↗

Tailoring sub-3.3 Å ultramicropores in advanced carbon molecular sieve membranes for blue hydrogen production

Carbon molecular sieve (CMS) membranes prepared by carbonization of polymers containing strongly size-sieving ultramicropores are attractive for high-temperature gas separations. However, polymers need to be carbonized at extremely high temperatures (900° to 1200°C) to achieve sub-3.3 Å ultramicroporous channels for H 2 /CO 2 separation, which makes them brittle and impractical for industrial applications. Here, we demonstrate that polymers can be first doped with thermolabile cross-linkers before low-temperature carbonization to retain the polymer processability and achieve superior H 2 /CO 2 separation properties. Specifically, polybenzimidazole (PBI) is cross-linked with pyrophosphoric acid (PPA) via H bonding and proton transfer before carbonization at ≤600°C. The synergistic PPA doping and subsequent carbonization of PBI increase H 2 permeability from 27 to 140 Barrer and H 2 /CO 2 selectivity from 15 to 58 at 150°C, superior to state-of-the-art polymeric materials and surpassing Robeson’s upper bound. This study provides a facile and effective way to tailor subnanopore size and porosity in CMS membranes with desirable molecular sieving ability.

42 ENGINEERING↗

Emission Spectral Measurements in the Plenum of an Arc Jet Wind Tunnel

Arc jet wind tunnel facilities are used to evaluate thermal protection system materials for re-entry vehicles. The high speed, high temperature flowfield generated by the arc jet can simulate the extreme aerodynamic heating environment experienced during re-entry so that the survivability of heat shield materials and performance of various designs options can be tested. Although the re-entry heating environment can be approximated in the arc jet facility, the flowfield only partially simulates the actual re-entry flight conditions. Reynolds numbers are not matched so that surface shear stress distributions and mass transfer rates due to ablation or other mechanisms are not modeled correctly. Unlike flight conditions the arc freestream air is in non-equilibrium because of the rapid expansion that occurs in the supersonic nozzle. To properly study the actual re-entry flow environment, computational fluid dynamics, computational chemistry and radiation models must be used. Arc jet tunnel tests serve to validate these models. To perform accurate simulations inlet and boundary-conditions are needed, which come from measurements of the flowfield. The present study is concerned with measurements in the plenum region of an arc heater. In the past, conditions in the arc heater flowfield have been predicted using simulations since conventional measurement techniques could not be used in the harsh extremely high temperature environment. The present study is part of a recent push to utilize optical techniques to help better characterize the arc jet flowfields. Emission measurements have been made in the shock layer and the constrictor section of the arc heater to determine temperatures and species number densities. LIF measurements have been made in the free stream to determine temperature and velocity.

Donohue, Jim↗

Methyl bromide: ocean sources, ocean sinks, and climate sensitivity

The oceans play an important role in the geochemical cycle of methyl bromide (CH3Br), the major carrier of O3-destroying bromine to the stratosphere. The quantity of CH3Br produced annually in seawater is comparable to the amount entering the atmosphere each year from natural and anthropogenic sources. The production mechanism is unknown but may be biological. Most of this CH3Br is consumed in situ by hydrolysis or reaction with chloride. The size of the fraction which escapes to the atmosphere is poorly constrained; measurements in seawater and the atmosphere have been used to justify both a large oceanic CH3Br flux to the atmosphere and a small net ocean sink. Since the consumption reactions are extremely temperature-sensitive, small temperature variations have large effects on the CH3Br concentration in seawater, and therefore on the exchange between the atmosphere and the ocean. The net CH3Br flux is also sensitive to variations in the rate of CH3Br production. We have quantified these effects using a simple steady state mass balance model. When CH3Br production rates are linearly scaled with seawater chlorophyll content, this model reproduces the latitudinal variations in marine CH3Br concentrations observed in the east Pacific Ocean by Singh et al. [1983] and by Lobert et al. [1995]. The apparent correlation of CH3Br production with primary production explains the discrepancies between the two observational studies, strengthening recent suggestions that the open ocean is a small net sink for atmospheric CH3Br, rather than a large net source. The Southern Ocean is implicated as a possible large net source of CH3Br to the atmosphere. Since our model indicates that both the direction and magnitude of CH3Br exchange between the atmosphere and ocean are extremely sensitive to temperature and marine productivity, and since the rate of CH3Br production in the oceans is comparable to the rate at which this compound is introduced to the atmosphere, even small perturbations to temperature or productivity can modify atmospheric CH3Br. Therefore atmospheric CH3Br should be sensitive to climate conditions. Our modeling indicates that climate-induced CH3Br variations can be larger than those resulting from small (+/- 25%) changes in the anthropogenic source, assuming that this source comprises less than half of all inputs. Future measurements of marine CH3Br, temperature, and primary production should be combined with such models to determine the relationship between marine biological activity and CH3Br production. Better understanding of the biological term is especially important to assess the importance of non-anthropogenic sources to stratospheric ozone loss and the sensitivity of these sources to global climate change.

NASA Discipline Exobiology↗

High-Entropy Borides under Extreme Environment of Pressures and Temperatures

The high-entropy transition metal borides containing a random distribution of five or more constituent metallic elements offer novel opportunities in designing materials that show crystalline phase stability, high strength, and thermal oxidation resistance under extreme conditions. We present a comprehensive theoretical and experimental investigation of prototypical high-entropy boride (HEB) materials such as (Hf, Mo, Nb, Ta, Ti)B2 and (Hf, Mo, Nb, Ta, Zr)B2 under extreme environments of pressures and temperatures. The theoretical tools include modeling elastic properties by special quasi-random structures that predict a bulk modulus of 288 GPa and a shear modulus of 215 GPa at ambient conditions. HEB samples were synthesized under high pressures and high temperatures and studied to 9.5 GPa and 2273 K in a large-volume pressure cell. The thermal equation of state measurement yielded a bulk modulus of 276 GPa, in excellent agreement with theory. The measured compressive yield strength by radial X-ray diffraction technique in a diamond anvil cell was 28 GPa at a pressure of 65 GPa, which is a significant fraction of the shear modulus at high pressures. The high compressive strength and phase stability of this material under high pressures and high temperatures make it an ideal candidate for application as a structural material in nuclear and aerospace fields.

36 MATERIALS SCIENCE↗

Lithium Ion Batteries for Mars Exploration Missions

The upcoming NASA's missions aimed at exploring our Planetary system require batteries that can operate at extreme operating temperatures, with high specific energy and energy densities. Conventional aerospace rechargeable battery systems are inadequate to meet the demands.

extreme↗

Extreme Environment Simulation - Current and New Capabilities to Simulate Venus and Other Planetary Bodies

Science, technology, and planetary mission communities have a growing interest in components and systems that are capable of working in extreme (high) temperature and pressure conditions. Terrestrial applications range from scientific research, aerospace, defense, automotive systems, energy storage and power distribution, deep mining and others. As the target environments get increasingly extreme, capabilities to develop and test the sensors and systems designed to operate in such environments will be required. An application of particular importance to the planetary science community is the ability for a robotic lander to survive on the Venus surface where pressures are nearly 100 times that of Earth and temperatures approach 500C. The scientific importance and relevance of Venus missions are stated in the current Planetary Decadal Survey. Further, several missions to Venus were proposed in the most recent Discovery call. Despite this interest, the ability to accurately simulate Venus conditions at a scale that can test and validate instruments and spacecraft systems and accurately simulate the Venus atmosphere has been lacking. This paper discusses and compares the capabilities that are known to exist within and outside the United States to simulate the extreme environmental conditions found in terrestrial or planetary surfaces including the Venus atmosphere and surface. The paper then focuses on discussing the recent additional capability found in the NASA Glenn Extreme Environment Rig (GEER). The GEER, located at the NASA Glenn Research Center in Cleveland, Ohio, is designed to simulate not only the temperature and pressure extremes described, but can also accurately reproduce the atmospheric compositions of bodies in the solar system including those with acidic and hazardous elements. GEER capabilities and characteristics are described along with operational considerations relevant to potential users. The paper presents initial operating results and concludes with a sampling of investigations or tests that have been requested or expected.

Extreme Environment↗

Fiber optic photoelastic pressure sensor for high temperature gases

A novel fiber optic pressure sensor based on the photoelastic effects has been developed for extremely high temperature gases. At temperatures varying from 25 to 650 C, the sensor experiences no change in the peak pressure of the transfer function and only a 10 percent drop in dynamic range. Refinement of the sensor has resulted in an optoelectronic interface and processor software which can calculate pressure values within 1 percent of full scale at any temperature within the full calibrated temperature range.

Wesson, Laurence N.↗

Modeling electron temperature profiles in the pedestal with simple formulas for ETG transport

Abstract This paper reports on the refinement (building on (Hatch D.R. et al 2022 Phys. Plasmas 29 062501)) and application of simple formulas for electron heat transport from electron temperature gradient (ETG) driven turbulence in the pedestal. The formulas are improved by (1) improving the parameterization for certain key parameters and (2) carefully accounting for the impact of geometry and shaping in the underlying gyrokinetic simulation database. Comparisons with nonlinear gyrokinetic simulations of ETG transport in the MAST pedestal demonstrate the model’s applicability to spherical tokamaks in addition to standard aspect ratio tokamaks. We identify bounds for model applicability: the model is accurate in the steep gradient region, where the ETG turbulence is largely slab-like, but accuracy decreases as the temperature gradient becomes weaker in the pedestal top. We use the formula to model the electron temperature profile in the pedestal for four experimental scenarios while extensively varying input parameters to represent uncertainties. In all cases, the predicted electron temperature profile exhibits extreme sensitivity to separatrix temperature and density, which has implications for core-edge integration. The model reproduces the electron temperature profile for high η e = L n e / L T e scenarios but not for low η e scenarios in which microtearing modes (MTMs) have been identified. We develop a proof-of-concept model for MTM transport and explore the relative roles of ETG and MTM in setting the electron temperature profile.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Wyandotte Integrated Renewable Energy Strategy (WIRES 2) (Final Technical Report)

Wyandotte Municipal Services (WMS), a Michigan Municipal Utility offering electric generation, transmission & distribution, water filtration & distribution and Broadband/Video sought to deploy a set of renewable energy projects for their Electric Utility that contributed to reducing the City’s environmental and energy impact, provided examples that would encourage businesses and citizens to adopt cleaner energy practices and help WMS meet the required renewable energy standards of the State of Michigan (10% in 2015, 15% in 2021). WMS generates and delivers roughly 280,000 megawatt hours (MWh) of electricity annually to more than 10,000 homes and 1,000 businesses within the City of Wyandotte. The Wyandotte Integrated Renewable Energy Strategy – WIRES 2 resulted in deployment of a set of community-scale micro-wind turbines, evaluation and installation of energy-efficient and low-maintenance light-emitting diode (LED) street lights and park lights in highly visible locations in the City and expansion of the geothermal heating and cooling district that already included residential geothermal systems, to include larger scale business/institutional systems at the Utility’s largest electric customer and at the City Library. Finally, WMS identified the need for job training in energy efficiency and renewable energy technologies to further develop a local skilled workforce in these areas. Partially funded by the grant, the wind turbine project provides a benchmark for WMS, local businesses and residents in the evaluation of utility-scale wind v. micro-wind in an urban environment as a renewable energy strategy. Also partially funded by the grant, the LED project benefited the City of Wyandotte by reducing load on the electric system for the public utility but also reduced City costs for streetlighting, parking lot lighting and park lighting without a compromise in security. The project also resulted in a visual success that has led to additional approvals for non-Grant related LED lighting installations resulting in further reduction in the electric load in the City. Commercial Geothermal installations resulted in the Utility being able to eliminate steam customers who formerly utilized the byproduct of steam from WMS electric production. Due to the reduction in natural gas prices and the overall reduction in market purchased power, it was no longer feasible for WMS to operate its Power Plant as a base load plant and to only operate on a market dispatch philosophy when market prices dictated that WMS could produce electricity cheaper than the market purchase price. This has resulted in fewer operating days for the WMS Power Plant, resulting in less environmental impact. WMS has now completely exited the steam business and the ability to offer a geothermal option to two (2) former steam customers (BASF-Wyandotte and the Bacon Memorial Library) allowed for that. In addition, peak loads have been shaved for these two (2) large customers due to the consistent temperature offered by geothermal heating and cooling, reducing the swings associated with thermostat changes caused by outside temperature changes during extreme high and low temperatures. Finally, energy efficiency and renewable energy college-level classes at Wayne County Community College allowed a group of interested students to pursue studies in those technologies through grant provided tuition, books and course materials. This effort provided a foundation of potential future employees not only for WMS but other energy efficiency/renewable energy employers such as Franklin Energy, a partner with WMS in energy optimization efforts with Wyandotte businesses.

17 WIND ENERGY↗

Fractionation of Lignin for Selective Shape Memory Effects at Elevated Temperatures

We report a facile approach to control the shape memory effects and thermomechanical characteristics of a lignin-based multiphase polymer. Solvent fractionation of a syringylpropane-rich technical organosolv lignin resulted in selective lignin structures having excellent thermal stability coupled with high stiffness and melt-flow resistance. The fractionated lignins were reacted with rubber in melt-phase to form partially networked elastomer enabling selective programmability of the material shape either at 70 °C, a temperature that is high enough for rubbery matrix materials, or at an extremely high temperature, 150 °C. Utilizing appropriate functionalities in fractionated lignins, tunable shape fixity with high strain and stress recovery, particularly high-stress tolerance were maintained. Detailed studies of lignin structures and chemistries were correlated to molecular rigidity, morphology, and stress relaxation, as well as shape memory effects of the materials. The fractionation of lignin enabled enrichment of specific lignin properties for efficient shape memory effects that broaden the materials’ application window. Electron microscopy, melt-rheology, dynamic mechanical analysis and ultra-small angle neutron scattering were conducted to establish morphology of acrylonitrile butadiene rubber (NBR)-lignin elastomers from solvent fractionated lignins.

36 MATERIALS SCIENCE↗

Heating rate controller for thermally stimulated conductivity and thermoluminescence measurements.

A temperature controller is described which enables the temperature of a sample mounted on a cold finger to be varied linearly with time. Heating rates between 0.5 and 10 K/min can be achieved for temperatures between 90 and 300 K. Provision for terminating the sample heating at any temperature between these extremes is available. The temperature can be held at the terminating temperature or be reduced to the starting temperature in a matter of minutes. The controller has been used for thermally stimulated conductivity measurements and should be useful for thermoluminescence measurements as well.

Manning, E. G.↗

Hexagonal Boron Nitride Reinforced Multifunctional Well Cement for Extreme Conditions

The overarching objective of this project was to provide a system approach for developing the next generation of well cementing with remarkable multifunctional, high performance characteristics including mechanical, thermal, rheological and durability properties to prevent offshore spill and leakage at extreme high temperature, high pressure (HTHP) and corrosive conditions. Building on our scientifically illustrated principles, the objective of Phase I was to develop and tune our current proof-of-concept hexagonal boron-nitride (hBN)/cement composite to offer the best hybrid nanostructure, and optimum slurry formulation and rheological properties in environments with a variety of extreme conditions including high temperature, high pressure, and high acidity. This phase also focused on testing the actual barrier efficiency and performance of our new cement formulation against gas/liquid leakage at HT, and/or corrosive conditions. The objective of Phase 2 was product validation (meeting API/EPA standards), cost/risk analysis, and scale-up to facilitate integration for primary well cementing with no/minimal modification.

02 PETROLEUM↗

Properties of optics at high temperature and their measurement, a study

Bibliography lists, the sources containing emissivity and absorptivity data on materials at extremely high temperatures. The experimental techniques, equipment and efforts of the experimenters to characterize the materials used and methods to evaluate the errors are given in the sources in this bibliography.

Gates, D. W.↗

High temperature solid lubricants: When and where to use them

The state of the art of solid lubrication for moderate to extremely high temperature lubrication (to 1600 F) is reviewed. Lubricating characteristics, stability in various environments, and relevant machine design considerations are discussed. Lubricating materials discussed include the layer lattice compounds: MoS2, WS2, graphite and graphite fluoride, the high temperature polyimide polymer, and calcium fluoride based coating and composites. The scope of the information includes results from wear testers, ball bearing, and journal bearings.

Sliney, H. E.↗

Analytical, Numerical, and Experimental Investigation on a Non-Contact Method for the Measurements of Creep Properties of Ultra-High-Temperature Materials

Responsive access to space requires re-use of components such as rocket nozzles that operate at extremely high temperatures. For such applications, new ultra-hightemperature materials that can operate over 2,000 C are required. At the temperatures higher than the fifty percent of the melting temperature, the characterization of creep properties is indispensable. Since conventional methods for the measurement of creep is limited below 1,700 C, a new technique that can be applied at higher temperatures is strongly demanded. This research develops a non-contact method for the measurement of creep at the temperatures over 2,300 C. Using the electrostatic levitator in NASA MSFC, a spherical sample was rotated to cause creep deformation by centrifugal acceleration. The deforming sample was captured with a digital camera and analyzed to measure creep deformation. Numerical and analytical analyses have also been conducted to compare the experimental results. Analytical, numerical, and experimental results showed a good agreement with one another.

Lee, Jonghyun↗

Electric Vehicle and Charging Infrastructure Assessment in Cold-Weather Climates: A Case Study of Fairbanks, Alaska

The purpose of this report is to determine the effects that extreme cold temperatures have on electric vehicles (EVs) and electric vehicle supply equipment (EVSE). The adoption of EVs in extreme cold weather presents challenges that require careful analysis of efficiency and charging infrastructure. This report, "Electric Vehicle and Charging Infrastructure Assessment in Cold-Weather Climates: A Case Study of Fairbanks, Alaska," explores how EVs and EVSE perform in temperatures as low as -40 degrees C (-40 degrees F), focusing on real-world data from Teslas in Alaskan winter conditions. The findings indicate that EVs can successfully function in extreme cold, though efficiency is significantly affected. Vehicles stored in heated environments outperformed those stored outdoors, with efficiency dropping by up to 69% for outdoor storage. Despite these challenges, none of the vehicles experienced failures that prevented travel. Storing EVs indoors led to benefits such as faster preconditioning and improved efficiency, while charging in extreme cold, though slower, remained functional. Ultimately, the report concludes that with proper precautions and best practices, EVs are viable transportation solutions in cold climates. Investing in enclosed, heated storage is recommended to maximize efficiency and minimize battery strain. As advancements in battery chemistry and thermal management progress, EV adoption in extreme climates is expected to become even more feasible.

33 ADVANCED PROPULSION SYSTEMS↗