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(PrSb)2PdSb crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one antimony molecule, one palladium molecule, and two PrSb clusters. In each PrSb cluster, Pr3+ is bonded in a single-bond geometry to one Sb+2.67- atom. The Pr–Sb bond length is 2.73 Å. Sb+2.67- is bonded in a single-bond geometry to one Pr3+ atom.
(HfSi)2CuSi crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one copper molecule, one silicon molecule, and two HfSi clusters. In each HfSi cluster, Hf is bonded in a single-bond geometry to one Si atom. The Hf–Si bond length is 2.31 Å. Si is bonded in a single-bond geometry to one Hf atom.
RbK2As is Cyanogen Chloride-like structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of two rubidium molecules and two K2As clusters. In each K2As cluster, K1+ is bonded in a single-bond geometry to one As3- atom. The K–As bond length is 3.16 Å. As3- is bonded in a linear geometry to two equivalent K1+ atoms.
(HfAs)2CuSi is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one copper molecule, one silicon molecule, and two HfAs clusters. In each HfAs cluster, Hf4+ is bonded in a single-bond geometry to one As3- atom. The Hf–As bond length is 2.31 Å. As3- is bonded in a single-bond geometry to one Hf4+ atom.
(HoSb)2CuSb crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one antimony molecule, one copper molecule, and two HoSb clusters. In each HoSb cluster, Ho3+ is bonded in a single-bond geometry to one Sb+2.33- atom. The Ho–Sb bond length is 2.62 Å. Sb+2.33- is bonded in a single-bond geometry to one Ho3+ atom.
(TbTe)2Te crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one telloy molecule and two TbTe clusters. In each TbTe cluster, Tb3+ is bonded in a single-bond geometry to one Te2- atom. The Tb–Te bond length is 2.64 Å. Te2- is bonded in a single-bond geometry to one Tb3+ atom.
LiNi2As is Cyanogen Chloride-like structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of two lithium molecules and two Ni2As clusters. In each Ni2As cluster, Ni1+ is bonded in a single-bond geometry to one As3- atom. The Ni–As bond length is 2.09 Å. As3- is bonded in a linear geometry to two equivalent Ni1+ atoms.
(H2)2HClO4 crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of eight hydrogen molecules and four HClO4 clusters. In each HClO4 cluster, H is bonded in a single-bond geometry to one O atom. The H–O bond length is 0.99 Å. There are four inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.43 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.43 Å. In the third O site, O is bonded in a distorted water-like geometry to one H and one Cl atom. The O–Cl bond length is 1.67 Å. In the fourth O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.43 Å. Cl is bonded in a tetrahedral geometry to four O atoms.
(ThAs)2As crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one arsenic molecule and two ThAs clusters. In each ThAs cluster, Th4+ is bonded in a single-bond geometry to one As+2.67- atom. The Th–As bond length is 2.48 Å. As+2.67- is bonded in a single-bond geometry to one Th4+ atom.
(PrSb)2PdSb crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one antimony molecule, one palladium molecule, and two PrSb clusters. In each PrSb cluster, Pr3+ is bonded in a single-bond geometry to one Sb+2.67- atom. The Pr–Sb bond length is 2.72 Å. Sb+2.67- is bonded in a single-bond geometry to one Pr3+ atom.
(DySb)2CuSb crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one antimony molecule, one copper molecule, and two DySb clusters. In each DySb cluster, Dy3+ is bonded in a single-bond geometry to one Sb+2.33- atom. The Dy–Sb bond length is 2.65 Å. Sb+2.33- is bonded in a single-bond geometry to one Dy3+ atom.
(Ta2N)2(N2)3(Br)20 crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of six ammonia molecules, twenty hydrobromic acid molecules, and two Ta2N clusters. In each Ta2N cluster, Ta5+ is bonded in a single-bond geometry to one N3- atom. The Ta–N bond length is 1.89 Å. N3- is bonded in a linear geometry to two equivalent Ta5+ atoms.
Tb(IrB)2 crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of four terbium molecules and eight IrB clusters. In each IrB cluster, Ir is bonded in a single-bond geometry to one B atom. The Ir–B bond length is 1.78 Å. B is bonded in a single-bond geometry to one Ir atom.
(ISr)4H2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one hydrogen molecule and two ISr clusters. In each ISr cluster, Sr is bonded in a single-bond geometry to one I atom. The Sr–I bond length is 2.93 Å. I is bonded in a single-bond geometry to one Sr atom.
HgSO3N2SO3 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight ammonia molecules, four sulfur trioxide molecules, and four HgSO3 clusters. In each HgSO3 cluster, Hg2+ is bonded in a single-bond geometry to one O2- atom. The Hg–O bond length is 3.01 Å. S2+ is bonded in a trigonal planar geometry to three O2- atoms. There is two shorter (1.44 Å) and one longer (1.45 Å) S–O bond length. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one S2+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one Hg2+ and one S2+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one S2+ atom.
(TmSb)2AgSb crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one antimony molecule, one silver molecule, and two TmSb clusters. In each TmSb cluster, Tm3+ is bonded in a single-bond geometry to one Sb+2.33- atom. The Tm–Sb bond length is 2.61 Å. Sb+2.33- is bonded in a single-bond geometry to one Tm3+ atom.
(LuTe)2Te crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one tellurium molecule and two LuTe clusters. In each LuTe cluster, Lu3+ is bonded in a single-bond geometry to one Te2- atom. The Lu–Te bond length is 2.62 Å. Te2- is bonded in a single-bond geometry to one Lu3+ atom.
(Nb2N)2(N2)3(Br)20 crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of six ammonia molecules, twenty hydrobromic acid molecules, and two Nb2N clusters. In each Nb2N cluster, Nb5+ is bonded in a single-bond geometry to one N3- atom. The Nb–N bond length is 1.88 Å. N3- is bonded in a linear geometry to two equivalent Nb5+ atoms.