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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Water–NaCl–organic ternary mixtures evaluated with hydrates salt concentrations to reveal general phenomenon of the one-for-one molar displacement of NaCl by organic solutes as well as implications on solvent driven water treatments.
Methanotrophic bacteria utilize methane monooxygenase (MMO) to carry out the first step in metabolizing methane. The soluble enzymes employ a hydroxylase component (sMMOH) with a nonheme diiron active site that activates O 2 and generates a powerful oxidant capable of converting methane to methanol. It is proposed that the diiron(II) center in the reduced enzyme reacts with O 2 to generate a diferric-peroxo intermediate called P that then undergoes O–O cleavage to convert into a diiron(IV) derivative called Q, which carries out methane hydroxylation. Most (but not all) of the spectroscopic data of Q accumulated by various groups to date favor the presence of an Fe IV 2 (μ-O) 2 unit with a diamond core. The Que lab has had a long-term interest in making synthetic analogs of iron enzyme intermediates. To this end, the first crystal structure of a complex with a Fe III Fe IV (μ-O) 2 diamond core was reported in 1999, which exhibited an Fe∙∙∙Fe distance of 2.683(1) Å. Now more than 20 years later, a complex with an Fe IV 2 (μ-O) 2 diamond core has been synthesized in sufficient purity to allow diffraction-quality crystals to be grown. Finally, its crystal structure has been solved, revealing an Fe∙∙∙Fe distance of 2.711(4) Å for comparison with structural data for related complexes with lower iron oxidation states.
This work shows the integration of reductive lignin depolymerization and microbial funneling with Novosphingobium aromaticivorans to produce 2-pyrone-4,6-dicarboxylic acid (PDC) in a lignocellulosic biorefinery.
This work describes successful radiochemical labeling and subsequent in vivo evaluation of radiolanthanide-tagged versions of lanmodulin (LanM), a lathanide-binding protein.
Bond dissociation energetics underpin the thermodynamics of chemical transformations where bonds are broken or formed and can also be used to predict reaction rates and selectivities.
Calculated interface between Li 2 O and Li 2 O 2 surfaces showing the extent of disorder at the interface. Such interfaces are probably present in the new solid-state Li–air battery described here and contribute to the discharge and charge mechanisms.
Triggering one-electron redox processes during palladium catalysis holds the potential to unlock new reaction mechanisms and synthetic methods not previously accessible in the typical two-electron reaction manifolds that dominate palladium catalysis.
Various zinc anodes with increasing calcium zincate (0%, 30%, 70%, 100%) were cycled at 50% theoretical Zn utilization to investigate cycle life and estimated cost. Failure mechanisms of majority 70% Zn/30% CaZn anodes are compared with pure CaZn.
The physics issues involved in scaling from sub ignition to high gain fast ignition are discussed. Successful point designs must collimate the electrons and minimize the stand off distance to avoid multi mega-joule ignition energies. Collimating B field configurations are identified and some initial designs are explored.
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Abstract not provided
The ability to achieve resolution that is better than the instrument resolution (i.e., superresolution) is well known in optics, where it has been extensively studied. Unfortunately, there are only a handful of theoretical studies concerning superresolution of particle spectrometers, even though experimentalists are familiar with the enhancement of resolution that is achievable when appropriate methods of data analysis are used, such as maximum entropy and Bayesian methods. Knowledge of the superresolution factor is in many cases important. For example, in applications of neutron spectrometry to fusion diagnostics, the temperature of a burning plasma is an important physical parameter which may be inferred from the width of the peak of the neutron energy spectrum, and the ability to determine this width depends on the superresolution factor. Kosarev has derived an absolute limit for resolution enhancement using arguments based on a well known theorem of Shannon. Most calculations of superresolution factors in the literature, however, are based on the assumption of Gaussian, translationally invariant response functions and therefore not directly applicable to neutron spectrometers which typically have response functions not satisfying these requirements. In this work, we develop a procedure that allows us to overcome these difficulties and we derive estimates of superresolution for liquid scintillator spectrometers of a type commonly used for neutron measurements. Theoretical superresolution factors are compared to experimental results.
A study of the {eta}{sup '{yields}{eta}{pi}{pi}} Dalitz plot distribution is presented in this talk. The size of the branching ratio is properly understood within U(3) Chiral Perturbation Theory and Resonance Chiral Theory, in the framework of the 1/N{sub C} expansion. Nonetheless, unitarity effects must be incorporated in order to achieve an appropriate description of the Dalitz slope parameters. After taking the final state interactions into account, our predictions become now in agreement with the available experimental measurements, although some clear differences show up with respect to previous theoretical estimates.
The connection between effective-actions and generalizations of Nambu-Jona-Lasinio models is discussed. We suggest the possibility of creation in the early Universe of stable domains of radius a few kilometers wide. Such domains should appear dark to an external observer. The insulation of the domains from the outer world, a consequence of the joint role played by gravity and the existence of two orthogonal Fock spaces could have allowed them to survive untill present days.
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When used at facilities like OMEGA and the NIF, CR-39 is exposed to high vacuum environments before and after irradiation by charged particles and neutrons. Using an electrostatic linear accelerator at MIT, studies have been conducted to investigate the effects of high vacuum exposure on the sensitivity of CR-39 to fusion protons in the {approx}1-9 MeV energy range. High vacuum conditions, of order 10{sup -5} Torr, experienced by CR-39 samples at these facilities were emulated. It is shown that vacuum exposure times longer than {approx}16 h before proton irradiation result in a decrease in proton sensitivity, whereas no effect was observed for up to 67 h of vacuum exposure after proton irradiation. CR-39 sensitivity curves are presented for samples with prolonged exposure to high vacuum before and after proton irradiation.
The application of neutral beams to future power plant devices (DEMO) is dependent on achieving significantly improved electrical efficiency and the most promising route to achieving this is by implementing a photoneutralizer in place of the traditional gas neutralizer. A corollary of this innovation would be a significant reduction in the background gas density through which the beam is transported between the accelerator and the neutralizer. This background gas is responsible for the space charge neutralization of the beam, enabling distances of several metres to be traversed without significant beam expansion. This work investigates the sensitivity of a D{sup -} beam to reduced levels of space charge compensation for energies from 100 keV to 1.5 MeV, representative of a scaled prototype experiment, commissioning and full energy operation. A beam transport code, following the evolution of the phase space ellipse, is employed to investigate the effect of space charge on the beam optics. This shows that the higher energy beams are insensitive to large degrees of under compensation, unlike the lower energies. The probable degree of compensation at low gas density is then investigated through a simple, two component beam-plasma model that allows the potential to be negative. The degree of under-compensation is dependent on the positive plasma ion energy, one source of which is dissociation of the gas by the beam. The subsequent space charge state of the beam is shown to depend upon the relative times for equilibration of the dissociation energy and ionization by the beam ions.
A new concept of lower hybrid antenna for current drive has been proposed for ITER [Bibet et al, Nuclear Fusion 1995]: the Passive Active Multijunction (PAM) antenna that relies on a periodic combination of active and passive waveguides. An actively cooled PAM antenna at 3.7 GHz has been recently installed on the tokamak Tore Supra. The paper summarizes the comprehensive experimental characterization of the linear coupling properties of the PAM antenna to the Tore Supra plasmas. These experimental results are systematically compared with the linear wave coupling theory via the linear ALOHA code. Good agreement between experimental results and ALOHA have been obtained. The detailed validation of the coupling modelling is an important step toward the validation of the PAM concept in view of further optimizing the electromagnetic properties of the future ITER antenna.