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NASA NTRS2001

Paleoenvironmental History of JoCo Marsh, Jamaica Bay, New York

Sediment cores from JoCo Marsh, located in Jamaica Bay, NY were analyzed for plant macrofossil and foraminifera records. These records reflect changes in vegetation, sea level, climate and human intervention. Better understanding of past environmental changes provides information for future preservation and protection of the estuary. A 2.81 m core was retrieved from JoCo, a high marsh area located on the eastern side of Jamaica Bay. The lithology of the core differs from high levels of sand, with small amounts of clay, in the bottom 0.8 meters, to salt marsh peat in the upper 2 meters of the core. Basal wood in the sand was dated to about 2060 yr BP. Elphidium foraminifera dominate the basal sands, along with Scirpus seeds, wood, and charcoal. These sands include fish scales which are tentatively identified as killifish, suggesting shallow pools. The transition to marsh peat is dominated by sedge seeds, and declines in charcoal. The peat appears to be dominated by salt marsh grasses. At 2 m the foraminifera change to include mainly Trochammina species and other undifferentiated agglutinates. The upper portion of the core is dominated by Salicornia seeds along with Trochammina and Miliammina or Quinqueloculia. The history of this marsh will be integrated with other records of marsh environmental change along the US eastern seaboard.

Liberman, Louisa↗

NASA NTRS1995

Exopaleontology at The Pathfinder Landing Site

The Mars Pathfinder Mission is a Discovery Class mission that will place a small lander and rover on the surface of Mars in July of 1997. It is primarily a technology demonstration to test the feasibility of a direct entry-delivery system, but carries a nominal scientific payload that includes rover-lander and instrumentation for limited mineralogical analysis. The nominal landing site was selected by the Pathfinder Team under the leadership of Dr. Matthew Golombek (JPL) based input from 60 participants at a Landing Site Workshop held last Spring at the Lunar Planetary Institute in Houston. The mission constraints for the landing site were 0-30 deg. N latitude, and below the 0.0 elevation datum. Over 20 landing sites were proposed and a nominal site was selected on southern Chryse Planitia near the terminae of the Ares and Tui outflow channels. In part, the decision to land at this location was based on the opportunity to sample a potentially large number lithologies in a small area (the rover will have a range of a few tens of meters from the lander). The purpose here is to review the general geological context of the landing site and the rationale for Exobiology's recommendation of the Ares site given at the workshop last spring. Because Ares and Tui Valles are sourced within terranes that may have originated by thermokarst processes, hydrothermal processes could have operated there for some time. Hydrothermal systems are presently regarded as important sites for a fossil record on Mars. Models for the formation of the outflow channels suggest that thermal spring sinters and associated aqueous mineral deposits, high priority targets for Mars Exopaleontology, could have formed in association with thermokarst processes and subsequently been delivered to the landing site in large quantities during the periodic cataclysmic outflows that created the channels.

Farmer, Jack D.↗

NASA NTRS2002

Kinetics of Melting and Dissolution in Lunar Materials

An understanding of the petrogenesis of lunar magmas, particularly mare basalts and the parent magmas to the Mg-rich suite, remains an unfulfilled goal. The fact is not surprising given the complexity of the problem. On the Moon, the source region for lunar magmas is not primitive mantle but rather a series of cumulate rocks that vary widely in both minerology and major and minor element contents. The stratigraphy of the cumulate mantle is not likely to be very regular given that the culumate pile is formed initially in an unstable configuration and subsequent thermal and compositional heterogeneities on a number of length scales. These lithologic heterogeneities, the large range of pressures and temperatures over which melts are generated on the Moon, and the close juxtaposition of cumulate rock with widely varying solidii introduce significant complications to the nature of the melting relations that control melt generation. These factors, coupled with the likelihood that polybaric fractional melting of varying efficiencies ultimately control the composition of planetary progress, are ample reasons why the lunar magmas remain the enigma they are. To make progress, phase equilibria studies must be coupled with a detailed understanding of the time scales and the dynamics of crystal and melt reequilibration processes.

Hess, Paul C.↗

NASA NTRS2003

Investigating Surface Mineralogy, Alteration Processes, and Biomarkers on Mars Using Laser Raman Spectroscopy

Despite a wealth of information from past and ongoing missions to Mars, the capability to determine the mineralogy of surface materials and to connect mineralogy with lithologic characteristics that are diagnostic of the environment in which those materials formed remains inadequate. The 2003 Mars Exploration Rovers (MER) will carry a Mini-TES and a Mossbauer spectrometer, which will provide some detailed mineralogy information. For general characterization of minerals and/or biogenic phases (reduced carbon, PAHs, etc) on the surface of Mars, we have been developing a miniaturized laser Raman spectrometer for in situ analyses -- the Mars Microbeam Raman Spectrometer, MMRS. We are also developing strategies to use Raman spectroscopy as a stand-alone technique and to be used synergistically with other in situ analysis methods in future planetary missions. Through studies of Martian meteorites and terrestrial analogs, we are gaining experience of what compositional and structural information can be obtained on key mineral groups using in-situ Raman measurements. We are developing methods for determining mineral proportions in rocks or soils and identifying rock types from sets of closely spaced, rapidly acquired spectra. We are studying how weathering and alteration affect the Raman and luminescence features of minerals and rocks, and we are investigating the Raman characteristics of biogenic organisms and their remains. These studies form the scientific basis for in-situ planetary Raman spectroscopy, and they are being done in parallel with instrument development towards a flight version of the MMRS.

Alian Wang↗

NASA NTRS2002

Russian-US Partnership to Study the 23-km-diameter El'gygtgyn Impact Crater, Northeast Russia

El'gygytgyn crater, located within Eastern Siberia, is a Pliocene-aged (3.6 Ma), well-preserved impact crater with a rim diameter of roughly 23 km. The target rocks are a coherent assemblage of crystalline rocks ranging from andesite to basalt. At the time of impact the region was forested and the Arctic Ocean was nearly ice-free. A 15-km lake fills the center of the feature and water depths are approximately 175 m. Evidence of shock metamorphism, -- including coesite, fused mineral glasses, and planar deformation features in quartz -- has been reported. This feature is one of the youngest and best preserved complex craters on Earth. Because of its remote Arctic setting, however, El gygytgyn crater remains poorly investigated. The objectives of this three-year project are to establish and maintain a research partnership between scientists from Russia and the United States interested in the El gygytgyn crater. The principal institutions in the U.S. will be the Geophysical Institute, University of Alaska Fairbanks and the University of Massachusetts Amherst. The principal institution in Russia will be the North East Interdisciplinary Scientific Research Institute (NEISRI), which is the Far-East Branch of the Russian Academy of Science. Three science tasks are identified for the exchange program: (1) Evaluate impactite samples collected during previous field excursions for evidence of and level of shock deformation. (2) Build a high-resolution digital elevation model for the crater and its surroundings using interferometric synthetic aperture radar techniques on JERS-1, ERS-1, ERS-2, and/or RadarSat range-doppler data. (3) Gather all existing surface data available from Russian and U.S. institutions (DEM, remote sensing image data, field-based lithological and sample maps, and existing geophysical data) and assemble into a Geographic Information Systems database.

Sharpton, Virgil L.↗

NASA NTRS2003

A Search for Impact Debris in the Pliocene Age Sirius Group, Transantarctic Mountains

The Sirius Group is a mixed sequence of interbedded diamictite and mudstone of Pliocene age found at scattered locations along the length of the Transantarctic Mountains. Sirius Group rocks are usually considered tillites, but contain some very "un-tillite" elements. Within section and from site to site, Sirius Group rocks vary considerably in terms of texture and relative abundance of clast lithologies, recording a history that includes shifting influences of glacial, lacustrine, fluvial and wetland processes. The colorful heritage of the Sirius Group has generated a lot of interest due to its potential as a record of changes in the behavior of the East Antarctic icesheet during a climatologically interesting period.

Harvey, Ralph P.↗

NASA NTRS2004

Signatures in Martian Volatiles and the Magma Sources of NC Meteorites

We report nitrogen and xenon isotopic signatures in Yamato nakhlites and use the data to assess properties of the magma source of NC meteorites in planet Mars. The Chassigny meteorite was investigated by Floran et al, who classified it as a cumulate dunite with hydrous amphibole-bearing melt inclusions with no preferred orientation of the olivines. Their inferred composition of the parent magma, which was based on electron microprobe analyses, has been questioned. The trace and minor elements in minerals were analyzed in nakhlites and in Chassigny and the authors conclude that nakhlites may represent samples from different horizons of the same lithologic unit, but that Chassigny was not co-magmatic with the nakhlites.

Marti, K.↗

NASA NTRS2004

MER Field Geologic Traverse in Gusev Crater, Mars: Initial Results From the Perspective of Spirit

This report casts the initial results of the traverse and science investigations by the Mars Exploration Rover (MER) Spirit at Gusev crater [1] in terms of data sets commonly used in field geologic investigations: Local mapping of geologic features, analyses of selected samples, and their location within the local map, and the regional context of the field traverse in terms of the larger geologic and physiographic region. These elements of the field method are represented in the MER characterization of the Gusev traverse by perspective-based geologic/morphologic maps, the placement of the results from Mossbauer, APXS, Microscopic Imager, Mini-TES and Pancam multispectral studies in context within this geologic/ morphologic map, and the placement of the overall traverse in the context of narrow-angle MOC (Mars Orbiter Camera) and descent images. A major campaign over a significance fraction of the mission will be the first robotic traverse of the ejecta from a Martian impact crater along an approximate radial from the crater center. The Mars Exploration Rovers have been conceptually described as 'robotic field geologists', that is, a suite of instruments with mobility that enables far-field traverses to multiple sites located within a regional map/image base at which in situ analyses may be done. Initial results from MER, where the field geologic method has been used throughout the initial course of the investigation, confirm that this field geologic model is applicable for remote planetary surface exploration. The field geologic method makes use of near-field geologic characteristics ('outcrops') to develop an understanding of the larger geologic context through continuous loop of rational steps focused on real-time hypothesis identification and testing. This poster equates 'outcrops' with the locations of in situ investigations and 'regional context' with the geology over distance of several kilometers. Using this fundamental field geologic method, we have identified the basic local geologic materials on the floor of Gusev at this site, their compositions and likely lithologies, origins, processes that have modified these materials, and their potential significance in the interpretation of the regional geology both spatially and temporally.

Crumpler, L.↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Impact-Related Deposits

The session "Impact-Related Deposits" included:Evidence for a Lightning-Strike Origin of the Edeowie Glass; 57Fe M ssbauer Spectroscopy of Fulgurites: Implications for Chemical Reduction; Ca-Metasomatism in Crystalline Target Rocks from the Charlevoix Structure, Quebec, Canada: Evidence for Impact-related Hydrothermal Activity; Magnetic Investigations of Breccia Veins and Basement Rocks from Roter Kamm Crater and Surrounding Region, Namibia; Petrologic Complexities of the Manicouagan Melt Sheet: Implications for 40Ar-39Ar Geochronology; Laser Argon Dating of Melt Breccias from the Siljan Impact Structure, Sweden: Implications for Possible Relationship to Late Devonian Extinction Events; Lunar Impact Crater, India: Occurrence of a Basaltic Suevite?; Age of the Lunar Impact Crater, India: First Results from Fission Track Dating; The Fluidized Chicxulub Ejecta Blanket, Mexico: Implications for Mars; Low Velocity Ejection of Boulders from Small Lunar Craters: Ground Truth for Asteroid Surfaces; Ejecta and Secondary Crater Distributions of Tycho Crater: Effects of an Oblique Impact; Potassium Isotope Systematics of Crystalline Lunar Spherules from Apollo 16; Late Paleocene Spherules from the North Sea: Probable Sea Floor Precipitates: A Silverpit Provenance Unproven; A Lithological Investigation of Marine Strata from the Triassic-Jurassic Boundary Interval, Queen Charlotte Islands, British Columbia, Including a Search for Shocked Quartz; Triassic Cratered Cobbles: Shock Effects or Tectonic Pressure?; Regional Variations of Trace Element Composition Within the Australasian Tektite Strewn Field; Cretaceous-Tertiary Boundary Microtektite-bearing Sands and Tsunami Beds, Alabama Gulf Coastal Plain; Sand Lobes on Stewart Island as Probable Impact-Tsunami Deposits; Distal Impact Ejecta, Uppermost Eocene, Texas Coastal Plain; and Continental Impact Debris in the Eltanin Impact Layer.

Source record↗

NASA NTRS2004

Analysis of Orientation-dependence of Martian Gullies

The recent discovery of small Martian gullies has stimulated debate about the role that water plays on the Martian surface under current or recent conditions. Of critical importance in evaluating various gully hypotheses is reliable morphometric and orientation data. The former centers on such questions as whether the water (or another fluid) emanated from a surface or sub-surface source and the duration of flow. The latter ties into whether solar insolation has an important effect on formation of the initial water source and subsequent mobilization. Initial studies of gullies indicated a poleward orientation dependence, an observation which has recently been challenged. Herein we investigate the orientation of Martian gullies and the dependence of various parameters on the orientation. Whereas previous studies have been global or through most of the southern hemisphere, we focus on several specific regions. This approach offers some advantages in that regional variations are factored out, such that of lithology, ground water table depth (if any), surface thermal properties, and other parameters are more or less the same in a given region. Differences in gully attributes as a function of orientation within a region can more easily be attributable to solar insolation effects than is the case for global statistics. We use the orientation to constrain several classes of gully formation hypotheses. 1) A favored orientation toward the pole across all regions could indicate a process dominated by melting of cold trapped ice, snow, or condensed volatiles from incident sunlight during summer under current conditions. 2) Variations among all regions would be more consistent with mechanisms less strongly tied to current solar insolation, such as geothermal heating of ice. 3) Favored orientations within specific regions, but differing among regions, could indicate a preference for poleward ices and melting, with orientation being a function of age and dependent on variations in obliquity and precision. We find that the gullies fall into either categories 2 or 3, but not 1, indicating the recent melting of cold trapped condensates is unlikely the sole formation mechanism.

Mohan, S.↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Lunar Crust as Sampled by Basins and Craters

The session "Lunar Crust as Samples by Basins and Craters" included:Radar Properties of Lunar Basin Deposits; Numerical Modeling of the South Pole-Aitkin Impact; Lunar South Pole-Aitken Impact Basin: Topography and Mineralogy; Comparison of the Geologic Setting of the South Pole-Aitken Basin Interior with Apollo 16: Implications for Regolith Components; Identifying Impact Events Within the Lunar Cataclysm from 40Ar-39Ar Ages of Apollo 16 Impact Melt Rocks; Apollo 16 Mafic Glass: Geochemistry, Provenance, and Implications; Lunar Meteorite PCA 02 007: A Feldspathic Regolith Breccia with Mixed Mare/Highland Components; Compositional Constraints on the Launch Pairing of LAP 02205 and PCA 02007 with Other Lunar Meteorites; An In-Situ Study of REE Abundances in Three Anorthositic Impact Melt Lunar Highland Meteorites; A Crustal Rock Clast in Magnesian Anorthositic Breccia, Dhofar 489 and Its Excavation from a Large Basin; The Origin and Impact History of Lunar Meteorite Yamato 86032; Evolved Lithologies and Their Inferred Sources in the Northwestern Procellarum Region of the Moon; and Revisiting the Interpretation of Thorium Abundances at Hansteen Alpha.

Source record↗

NASA NTRS2004

The Origin and Impact History of Lunar Meteorite Yamato 86032

Yamato (Y) 86032 is a feldspathic lunar highland breccia having some characteristics of regolith breccia. The absence of KREEP components in the matrix in Y86032 indicates that these meteorites came from a long distance from Mare Imbrium, perhaps from the far-side of the moon. One ferroan anorthosite (FAN) clast in Y86032 has a very old Ar-Ar age of approximately 4.35-4.4 Ga. The negative Nd of this clast may suggest a direct link with the primordial magma ocean. The facts indicate that Y86032 contains components derived from a protolith of the original lunar crust. Detailed petrologic characterization of each component in this breccia is essential to understand the early impact history and origin of the lunar highland crust. We made a large slab (5.2 x 3.6 cm x 3-5 mm) of Y86032 to better understand the relationship of various lithologies and their petrologic origin.

Yamaguchi, A.↗

NASA NTRS2004

Remote Sensing of the Haughton Impact Structure (HIS): A Terrestrial Proof of Concept for Using the Remote Sensing of Martian Craters as a Probe of Subsurface Composition

Impact cratering is the most widespread geological process in the Solar System. Impact craters can provide 'windows' into the subsurfaces of planetary bodies through excavation and uplift. By utilizing remote methods in the visible and near infrared (VNIR; 0.4-1.4 micron), short-wavelength infrared (SWIR; 1.4-2.5 micron) and thermal infrared (TIR 7-14 micron), subsurface mineral compositions may be identified and mapped via impact craters. Complex craters in particular, expose minerals from both the shallow and deep-seated subsurface, which may be identified spectroscopically. Complex craters have morphological features such as central peaks or peak rings, which are composed of relatively coherent lithologies tapped from deep-seated crustal components. While near-surface crustal components can be observed as coherent rocks uplifted and exposed in the rim and the crater walls, and from the ejecta deposits. Only two previously published studies using this approach have been successful on large planetary bodies. Tompkins and Pieters utilized ultraviolet and VNIR from Clementine to characterize near- and deep-subsurface materials in and around lunar craters. The work of Ramsey and Wright was the first remote spectroscopic study to successfully identify near-subsurface materials in the ejecta and crater wall of a terrestrial impact structure, namely Meteor Crater. Here we present early results of a third such study, a remote spectroscopy evaluation of the Haughton impact structure (HIS). The purpose of this study is to serve as terrestrial proof of concept that remote visible/infrared spectroscopic methods in this case, analysis of LANDSAT 7 ETM+ and ASTER data of the well-preserved HIS can be utilized in deciphering the subsurface composition of planetary crusts. This technique is particularly promising for Mars were limited tectonic uplift and ubiquitous dust-mantling offer few opportunities to access subsurface information.

Tornabene, L. L.↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Achondrite Mishmash

The session "Achondrite Mishmash" included teh following presentations:Constraining the Formation and Evolution of IAB Irons - High Precision; 40Ar/39Ar Ages on Plagioclase Separates from Silicate Inclusions of the Campo Del Cielo Meteorite; Radiogenic 129-Xenon in Silicate Inclusions in the Campo Del Cielo Iron Meteorite; Significance of Iron Isotope Mineral Fractionation in Pallasite and Iron Meteorites; An Experimental Study of Phosphoran Olivine and Its Significance in Main Group Pallasites; Characterization of the Distribution of Siderophile and Highly Siderophile Elements in the Milton and Eagle Station Pallasites; Relationships Between HED and Mesosiderite Meteorites: An Iron Isotope Perspective; Production Rates for Noble-Gas Isotopes in Eucrites; Evidence for Subsolidus Metasomatism in the Eucrite Parent Body; Possible Contact Metamorphism of the Polymict Eucrite Petersburg; Early and Late Stage Metals and Sulfides in Diogenites; Constraints on the Lithological Variation near the Surface of the HED Planetoid from the Petrology of 91 & 92 Series Antarctic Achondrites; Cosmic Ray Exposure Ages, Ar-Ar Ages, and the Origin and History of Eucrites; Trace Elements Abundances Vs Closure Temperature in Orthopyroxenes from Howardites; The First Mesosiderite-like Clast in a Howardite; 39Ar-40Ar Dating of Unusual Eucrite NWA 011: Is it from Vesta?; Trace Element Systematics of Northwest Africa 011: A "Eucritic" Basalt from a Non-Eucrite Parent Body ; 33S Anomaly in Acapulcoites and Lodranites; Magnetic Force Microscopy of Primitive Achondrites; Experimental Constraints on Ureilite Petrogenesis; Reflectance Spectra of Ureilites: Nature of the Mafic Silicate Absorption Features; Nitrogen and Noble Gases in Two Monomict Ureilites Acfer 277 and FRO 90036 from Hot and Cold Deserts; Solar Noble Gases in the Angrite Parent Body - Evidence from Volcanic Volatiles Trapped in D'Orbigny Glass; Trace Element Distribution Between Phases of the D'Orbigny Angrite ; Petrological Study of Six Angrites Including New Type; and Manganese-Chromium Isotope Systematics of Basaltic Achondrite Northwest Africa 011.

Source record↗

NASA NTRS2004

High Resolution Digital Elevation Models of Pristine Explosion Craters

In order to effectively capture a realistic terrain applicable to studies of cratering processes and landing hazards on Mars, we have obtained high resolution digital elevation models of several pristine explosion craters at the Nevada Test Site. We used the Airborne Terrain Mapper (ATM), operated by NASA's Wallops Flight Facility to obtain DEMs with 1 m spacing and 10 cm vertical errors of 4 main craters and many other craters and collapse pits. The main craters that were mapped are Sedan, Scooter, Schooner, and Danny Boy. The 370 m diameter Sedan crater, located on Yucca Flat, is the largest and freshest explosion crater on Earth that was formed under conditions similar to hypervelocity impact cratering. As such, it is effectively pristine, having been formed in 1962 as a result of a controlled detonation of a 100 kiloton thermonuclear device, buried at the appropriate equivalent depth of burst required to make a simple crater. Sedan was formed in alluvium of mixed lithology and subsequently studied using a variety of field-based methods. Nearby secondary craters were also formed at the time and were also mapped by ATM. Adjacent to Sedan and also in alluvium is Scooter, about 90 m in diameter and formed by a high-explosive event. Schooner (240 m) and Danny Boy (80 m) craters were also important targets for ATM as they were excavated in hard basalt and therefore have much rougher ejecta. This will allow study of ejecta patterns in hard rock as well as engineering tests of crater and rock avoidance and rover trafficability. In addition to the high resolution DEMs, crater geometric characteristics, RMS roughness maps, and other higher-order derived data products will be generated using these data. These will provide constraints for models of landing hazards on Mars and for rover trafficability. Other planned studies will include ejecta size-frequency distribution at the resolution of the DEM and at finer resolution through air photography and field measurements, correlation of ejecta size and composition with radar and visible-thermal IR remote sensing signatures, and comparison of these results with similar measurements of Mars. The final DEMs, ancillary data sets, and derived data products will be made available to the community.

T G Farr↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Impacts on Mars and Earth

The session "Impacts on Mars and Earth" included the following reports:A Timescale for Major Events in Early Mars Crustal Evolution; Impact Craters in Arabia Terra, Mars; Ancient Giant Basin/Aquifer System in the Arabia Region, Mars; Small Crater Morphology Within Gusev Crater and Isidis Planitia: Evidence for Widespread Secondaries on Mars; Martian Surface Properties: Inferences from Resolved Differences in Crater Geometries; Asymmetric Ramparts of Secondary Craters in Cerberus, Mars: Interpretation and Implications for Local Stratigraphy; Depth to Diameter Relationships of Craters in the High Latitudes (70 -80 ) of Mars: Implications for Geologic History of Those Areas; Impact Cratering on Mars: Search for Target Influence on Morphology; Starting Conditions for Hydrothermal Systems Underneath Martian Craters: Hydrocode Modeling; Impact-induced Hydrothermal System at the Sudbury Crater: Duration, Temperatures, Mechanics, and Biological Implications; Major and Trace Element Variations in Impact Crater Clay from Chicxulub, Lonar, and Mistastin, Implications for the Martian Soil; Stable Isotopes and Hydrothermal Fluid Source in the Yaxcopoil-1 Borehole, Chicxulub Impact Structure, Mexico; and Chicxulub Impact Melts: Geochemical Signatures of Target Lithology Mixing and Post-Impact Hydrothermal Fluid Processes.

Source record↗

NASA NTRS1997

Geochemistry of approximately 1.9 Ga sedimentary rocks from northeastern Labrador, Canada

Fifty-eight rock chips from fifteen samples of sedimentary rocks from the Ramah Group (approximately 1.9 Ga) in northeastern Labrador, Canada, were analyzed for major and minor elements, including C and S, to elucidate weathering processes on the Earth's surface about 1.9 Ga ago. The samples come from the Rowsell Harbour, Reddick Bight, and Nullataktok Formations. Two rock series, graywackes-gray shales of the Rowsell Harbour, Reddick Bight and Nullataktok Formations, and black shales of the Nullataktok Formation, are distinguishable on the basis of lithology, mineralogy, and major and trace element chemistry. The black shales show lower concentrations than the graywackes-gray shales in TiO2 (0.3-0.7 wt% vs. 0.7-1.8 wt%), Al2O3 (9.5-20.1 wt% vs. 13.0-25.0 wt%), and sigma Fe (<1 wt% vs. 3.8-13.9 wt% as FeO). Contents of Zr, Th, U, Nb, Ce, Y, Rb, Y, Co, and Ni are also lower in the black shales. The source rocks for the Ramah Group sediments were probably Archean gneisses with compositions similar to those in Labrador and western Greenland. The major element chemistry of source rocks for the Ramah Group sedimentary rocks was estimated from the Al2O3/TiO2 ratios of the sedimentary rocks and the relationship between the major element contents (e.g., SiO2 wt%) and Al2O3/TiO2 ratios of the Archean gneisses. This approach is justified, because the Al/Ti ratios of shales generally retain their source rock values; however, the Zr/Al, Zr/Ti, and Cr/Ni ratios fractionate during the transport of sediments. The measured SiO2 contents of shales in the Ramah Group are generally higher than the estimated SiO2 contents of source rocks by approximately 5 wt%. This correction may also have to be applied when estimating average crustal compositions from shales. Two provenances were recognized for the Ramah Group sediments. Provenance I was comprised mostly of rocks of bimodal compositions, one with SiO2 contents approximately 45 wt% and the other approximately 65 wt%, and was the source for most sedimentary rocks of the Ramah Group, except for black shales of the Nullataktok Formation. The black shales were apparently derived from Provenance II that was comprised mostly of felsic rocks with SiO2 contents approximately 65 wt%. Comparing the compositions of the Ramah Group sedimentary rocks and their source rocks, we have recognized that several major elements, especially Ca and Mg, were lost almost entirely from the source rocks during weathering and sedimentation. Sodium and potassium were also leached almost entirely during the weathering of the source rocks. However, significant amounts of Na were added to the black shales and K to all the rock types during diagenesis and/or regional metamorphism. The intensity of weathering of source rocks for the Ramah Group sediments was much higher than that of typical Phanerozoic sediments, possibly because of a higher PCO2 in the Proterozoic atmosphere. Compared to the source rock values, the Fe3+/Ti ratios of many of the graywackes and gray shales of the Ramah Group are higher, the Fe2+/Ti ratios are lower, and the sigma Fe/Ti ratios are the same. Such characteristics of the Fe geochemistry indicate that these sedimentary rocks are comprised of soils formed by weathering of source rocks under an oxygen-rich atmosphere. The atmosphere about 1.9 Ga was, therefore, oxygen rich. Typical black shales of Phanerozoic age exhibit positive correlations between the organic C contents and the concentrations of S, U, and Mo, because these elements are enriched in oxygenated seawater and are removed from seawater by organic matter in sediments. However, such correlations are not found in the Ramah Group sediments. Black shales of the Ramah Group contain 1.7-2.8 wt% organic C, but are extremely depleted in sigma Fe (<1 wt% as FeO), S (<0.3 wt%), U (approximately l ppm), Mo (<5 ppm), Ni (<2 ppm), and Co (approximately 0 ppm). This lack of correlation, however, does not imply that the approximately 1.9 Ga atmosphere-ocean system was anoxic. Depletion of these elements from the Ramah Group sediments may have occurred during diagenesis.

Non-NASA Center↗

NASA NTRS1994

Depositional and tectonic setting of the Archean Moodies Group, Barberton Greenstone Belt, South Africa

The 3.22-3.10 Ga old Moodies Group, uppermost unit of the Swaziland Supergroup in the Barberton Greenstone Belt (BGB), is the oldest exposed, well-preserved quartz-rich sedimentary sequence on earth. It is preserved in structurally separate blocks in a heavily deformed fold-and-thrust belt. North of the Inyoka Fault, Moodies strata reach up to 3700 m in thickness. Detailed mapping, correlation of measured sections, and systematic analysis of paleocurrents show that the lower Moodies Group north of the Inyoka Fault forms a deepening- and fining-upward sequence from a basal alluvial conglomerate through braided fluvial, tidal, and deltaic sandstones to offshore sandy shelf deposits. The basal conglomerate and overlying fluvial facies were derived from the north and include abundant detritus eroded from underlying Fig Tree Group dacitic volcanic rocks. Shoreline-parallel transport and extensive reworking dominate overlying deltaic, tidal, and marine facies. The lithologies and arrangement of Moodies Group facies, sandstone petrology, the unconformable relationship between Moodies strata and older deformed rocks, presence of at least one syndepositional normal fault, and presence of basaltic flow rocks and airfall fall tuffs interbedded with the terrestrial strata collectively suggest that the lower Moodies Group was deposited in one or more intramontane basins in an extensional setting. Thinner Moodies sections south of the Inyoka Fault, generally less than 1000 m thick, may be correlative with the basal Moodies Group north of the Inyoka Fault and were probably deposited in separate basins. A northerly derived, southward-thinning fan-delta conglomerate in the upper part of the Moodies Group in the central BGB overlies lower strata with an angular unconformity. This and associated upper Moodies conglomerates mark the beginning of basin shortening by south- to southeast-directed thrust faulting along the northern margin of the BGB and suggest that the upper Moodies Group was deposited in a foreland basin. Timing, orientation, and style of shortening suggest that this deformation eventually incorporated most of the BGB into a major fold-and-thrust belt.

NASA Discipline Exobiology↗