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At least 793 records · Page 44

New techniques for the detection and capture of micrometeoroids

In order to understand the origin and distribution of the biogenic elements and their compounds in the solar system, it will be necessary to study materials from many classes of objects. Chemical, elemental, and isotopic measurements of returned samples of comets, asteroids, and possibly extra-solar system dust clouds would provide information on a particularly important class: primitive objects. Extraterrestrial micron-sized particles in the vicinity of Earth are one source of such materials that might otherwise be inaccessible. The Space Station appears to be an eminently suitable platform from which to collect and detect these various particles. The primary challenge, however, is to collect intact, uncontaminated particles which will be encountered at tens of kilometers per seconds. A concept for a micrometeoroid detector that could be deployed from the Space Station was developed which uses a large area detector plate implanted with acoustic transducers. When an impact event occurs, the resulting signal is subjected to spectral analysis providing positive detection, momentum information, and angle of incidence. The primary advantage of this detector is the large area which increases the probability of measuring events. A concept of a nondestuctive micrometeoroid collector for use from a Space Station was also developed. The collector utilizes input port charging of the incoming particle followed by staged high voltage deceleration for nondestructive capture. Low velocity particles (local contamination) would be rejected due to insufficient energy and only uncontaminated micrometeoroids would be collected.

Wolfe, J. H.↗

Preliminary imaging results from the second Mercury encounter

The second Mercury encounter has resulted in the acquisition of about 360 pictures of the south polar regions which provide a reliable cartographic and geologic tie between the two sides of the planet photographed on the first encounter. Stereoscopic coverage of large areas of the southern hemisphere was obtained by combining Mercury 1 and 2 pictures taken at different viewing angles. The south polar regions consist of heavily cratered terrain and intercrater plains interspersed with patches of smooth plains. No large areas of smooth plains similar to those surrounding Caloris occur in the south polar regions. No new types of terrain have been recognized, but lobate scarps are common. The second largest basin seen by Mariner 10 has been confirmed on the new photography. At high solar elevations the surface displays an abundance of rays and rayed craters.

Strom, R. G.↗

The Effect of Twin Boundaries on the Spectroscopic Performance of CdZnTe Detectors

Most single grains in cadmium zinc telluride (CdZnTe) grown by the high-pressure Bridgman (HPB) technique contain multiple twin boundaries. As a consequence, twin boundaries are one of the most common macroscopic material defects found in large area (400 to 700 sq mm) CdZnTe specimens obtained from HPB ingots. Due to the prevalence of twin boundaries, understanding their effect on detector performance is key to the material selection process. Twin boundaries in several 2 mm thick large area specimens were first, documented using infrared transmission imaging. These specimens were then fabricated into either 2 mm pixel or planar detectors in order to examine the effect of the twin boundaries on detector performance. Preliminary results show that twin boundaries, which are decorated with tellurium inclusions, produce a reduction in detector efficiency and a degradation in resolution. The extent of the degradation appears to be a function of the density of tellurium inclusions.

Parker, Bradford H.↗

Overview of processing activities aimed at higher efficiencies and economical production

An overview of processing activities aimed at higher efficiencies and economical production were presented. Present focus is on low-cost process technology for higher-efficiency cells of up to 18% or higher. Process development concerns center on the use of less than optimum silicon sheet, the control of production yields, and making uniformly efficient large-area cells. High-efficiency cell factors that require process development are bulk material perfection, very shallow junction formation, front-surface passivation, and finely detailed metallization. Better bulk properties of the silicon sheet and the keeping of those qualities throughout large areas during cell processing are required so that minority carrier lifetimes are maintained and cell performance is not degraded by high doping levels. When very shallow junctions are formed, the process must be sensitive to metallizatin punch-through, series resisitance in the cell, and control of dopant leaching during surface passivation. There is a need to determine the sensitivity to processing by mathematical modeling and experimental activities.

Bickler, D. B.↗

Optimization and performance of Space Station Freedom solar cells

High efficiency, large area and low cost solar cells are the drivers for Space Station solar array designs. The manufacturing throughput, process complexity, yield of the cells, and array manufacturing technique determine the economics of the solar array design. The cell efficiency optimization of large area (8 x 8 m), dielectric wrapthrough contact solar cells are described. The results of the optimization are reported and the solar cell performance of limited production runs is reported.

Khemthong, S.↗

Superconductor lunar telescopes --Abstract only

We propose a new type of telescope designed specifically for the lunar environment of high vacuum and low temperature. Large area UV-Visible-IR telescope arrays can be built with ultra-light-weight replica optics. High T(sub c) superconductors provide support, steering, and positioning. Advantages of this approach are light-weight payload compatible with existing launch vehicles, configurable large area optical arrays, no excavation or heavy construction, and frictionless electronically controlled mechanisms. We have built a prototype and will be demonstarting some of its working characteristics.

Chen, P. C.↗

Scalable synthesis of nanoporous atomically thin graphene membranes for dialysis and molecular separations via facile isopropanol-assisted hot lamination

Scalable graphene synthesis and facile large-area membrane fabrication are imperative to advance nanoporous atomically thin membranes (NATMs) for molecular separations. Although chemical vapor deposition (CVD) allows for roll-to-roll high-quality monolayer graphene synthesis, facile transfer with atomically clean interfaces to porous supports for large-area NATM fabrication remains extremely challenging. Sacrificial polymer scaffolds commonly used for graphene transfer typically leave polymer residues detrimental to membrane performance and transfers without polymer scaffolds suffer from low yield resulting in high non-selective leakage through NATMs. In this study, we systematically study the factors influencing graphene NATM fabrication and report on a novel roll-to-roll manufacturing compatible isopropanol-assisted hot lamination (IHL) process that enables scalable, facile and clean transfer of CVD graphene on to polycarbonate track etched (PCTE) supports with coverage ≥99.2%, while preserving support integrity/porosity. We demonstrate fully functional centimeter-scale graphene NATMs that show record high permeances (~2–3 orders of magnitude higher) and better selectivity than commercially available state-of-the-art polymeric dialysis membranes, specifically in the 0–1000 Da range. Our work highlights a scalable approach to fabricate graphene NATMs for practical applications and is fully compatible with roll-to-roll manufacturing processes.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Applications of Skylab EREP photographs to mapping landforms and environmental geomorphology in the Great Plains and Midwest

The following evaluations of Skylab photographs were undertaken: (1) the 1290 Skylab S190A and S190B photographs of Illinois, Iowa, Kansas, Missouri, Nebraska, and South Dakota were evaluated in detail in terms of coverage, cloud cover, photographic quality, endlap, detectability of roads and stereorelief, and utility for geomorphologic mapping, and (2) the utility of the Skylab photos were tested for interpretive analytic mapping of geomorphologic features over large areas representative of different parts of this region. Photointerpretative maps of analytic geomorphology were obtained for various test areas representative of the varied landscapes in the region. These maps are useful for regional land-use planning, ground-water exploration, and other environmental geomorphologic-geologic applications. Compared with LANDSAT-1 MSS images, Skylab photos afford almost as extensive overviews of large areas but in considerably greater detail, and for many SL photos, moderate stereorelief. However, repetitive multiseasonal, cloud-free coverage by high-quality photos is very limited and many areas have no coverage at all.

Morrison, R. B.↗

Transfer of Millimeter‐Scale Strained Multiferroic Epitaxial Thin Films on Rigid Substrates via an Epoxy Method Producing Magnetic Property Enhancement

The demonstration of epitaxial thin film transfer has enormous potential for thin film devices free from the traditional substrate epitaxy limitations. However, large-area continuous film transfer remains a challenge for the commonly reported polymer-based transfer methods due to bending and cracking during transfer, especially for highly strained epitaxial thin films. In this work, a new epoxy-based, rigid transfer method is used to transfer films from an SrTiO 3 (STO) growth substrate onto various new substrates, including those that will typically pose significant problems for epitaxy. An epitaxial multiferroic Bi 3 Fe 2 Mn 2 O x (BFMO) layered supercell (LSC) material is selected as the thin film for this demonstration. The results of surface and structure studies show an order of magnitude increase in the continuous area of transferred films when compared to previous transfer methods. The magnetic properties of the BFMO LSC films are shown to be enhanced by the release of strain in this method, and ferromagnetic resonance is found with an exceptionally low Gilbert damping coefficient. The large-area transfer of this highly strained complex oxide BFMO thin film presents enormous potential for the integration of many other multifunctional oxides onto new substrates for future magnetic sensors and memory devices.

bismuth oxides↗

CIGS2 Thin-Film Solar Cells on Flexible Foils for Space Power

CuIn(1-x)Ga(x)S2 (CIGS2) thin-film solar cells are of interest for space power applications because of the near optimum bandgap for AM0 solar radiation in space. CIGS2 thin film solar cells on flexible stainless steel (SS) may be able to increase the specific power by an order of magnitude from the current level of 65 Wkg(sup -1). CIGS solar cells are superior to the conventional silicon and gallium arsenide solar cells in the space radiation environment. This paper presents research efforts for the development of CIGS2 thin-film solar cells on 127 micrometers and 20 micrometers thick, bright-annealed flexible SS foil for space power. A large-area, dual-chamber, inline thin film deposition system has been fabricated. The system is expected to provide thickness uniformity of plus or minus 2% over the central 5" width and plus or minus 3% over the central 6" width. During the next phase, facilities for processing larger cells will be acquired for selenization and sulfurization of metallic precursors and for heterojunction CdS layer deposition both on large area. Small area CIGS2 thin film solar cells are being prepared routinely. Cu-rich Cu-Ga/In layers were sputter-deposited on unheated Mo-coated SS foils from CuGa (22%) and In targets. Well-adherent, large-grain Cu-rich CIGS2 films were obtained by sulfurization in a Ar: H2S 1:0.04 mixture and argon flow rate of 650 sccm, at the maximum temperature of 475 C for 60 minutes with intermediate 30 minutes annealing step at 120 C. Samples were annealed at 500 C for 10 minutes without H2S gas flow. The intermediate 30 minutes annealing step at 120 C was changed to 135 C. p-type CIGS2 thin films were obtained by etching the Cu-rich layer segregated at the surface using dilute KCN solution. Solar cells were completed by deposition of CdS heterojunction partner layer by chemical bath deposition, transparent-conducting ZnO/ZnO: Al window bilayer by RF sputtering, and vacuum deposition of Ni/Al contact fingers through metal mask. PV parameters of a CIGS2 solar cell on 127 micrometers thick SS flexible foil measured under AM 0 conditions at NASA GRC were: V(sub oc) = 802.9 mV, J(sub sc) = 25.07 mA per square centimeters, FF = 60.06%, and efficiency 0 = 8.84%. For this cell, AM 1.5 PV parameters measured at NREL were: V(sub oc) = 788 mV, J(sub sc) = 19.78 mA per square centimeter, FF = 59.44%, efficiency 0 = 9.26%. Quantum efficiency curve showed a sharp QE cutoff equivalent to CIGS2 bandgap of approximately 1.50 eV, fairly close to the optimum value for efficient AM0 PV conversion in the space.

Dhere, Neelkanth G.↗

Disbond Detection in Bonded Aluminum Joints Using Lamb Wave Amplitude and Time-of-Flight

In recent years, there was a need of developing efficient nondestructive integrity assessment techniques for large area laminate structures, such as detections of disbond, crack, and corrosion in fuselage of an aircraft. Together with the improving tomography and computer technologies, progress has been made in many fields in NDE towards a faster inspection. Ultrasonically, Lamb wave is considered to be a candidate for large area inspections based on its capability of propagating a relatively long distance in thin plates and its media-thickness-dependent propagation properties. Moreover, the occurence of disbonds, corrosion, and even cracks often results in reduction of effective thickness of a laminate. The idea is to assess the condition of a structure by sensing the response of propagating Lamb waves to these flaws over long path length. A series of tests in the sequence of disbond, corrosion, and crack have been done on various types of specimen to investigate the feasibility of this approach. This paper will present some of the test results for disbond detection on aluminum lap splice joints.

Sun, Keun J.↗

Mapping Vegetation at Species Level with High-Resolution Multispectral and Lidar Data Over a Large Spatial Area: A Case Study with Kudzu

Mapping vegetation species is critical to facilitate related quantitative assessment, and mapping invasive plants is important to enhance monitoring and management activities. Integrating high-resolution multispectral remote-sensing (RS) images and lidar (light detection and ranging) point clouds can provide robust features for vegetation mapping. However, using multiple sources of high-resolution RS data for vegetation mapping on a large spatial scale can be both computationally and sampling intensive. Here, we designed a two-step classification workflow to potentially decrease computational cost and sampling effort and to increase classification accuracy by integrating multispectral and lidar data in order to derive spectral, textural, and structural features for mapping target vegetation species. We used this workflow to classify kudzu, an aggressive invasive vine, in the entire Knox County (1362 km2) of Tennessee (U.S.). Object-based image analysis was conducted in the workflow. The first-step classification used 320 kudzu samples and extensive, coarsely labeled samples (based on national land cover) to generate an overprediction map of kudzu using random forest (RF). For the second step, 350 samples were randomly extracted from the overpredicted kudzu and labeled manually for the final prediction using RF and support vector machine (SVM). Computationally intensive features were only used for the second-step classification. SVM had constantly better accuracy than RF, and the producer’s accuracy, user’s accuracy, and Kappa for the SVM model on kudzu were 0.94, 0.96, and 0.90, respectively. SVM predicted 1010 kudzu patches covering 1.29 km2 in Knox County. We found the sample size of kudzu used for algorithm training impacted the accuracy and number of kudzu predicted. The proposed workflow could also improve sampling efficiency and specificity. Our workflow had much higher accuracy than the traditional method conducted in this research, and could be easily implemented to map kudzu in other regions as well as map other vegetation species.

59 BASIC BIOLOGICAL SCIENCES↗

Search for New Cosmic-Ray Acceleration Sites within the 4FGL Catalog Galactic Plane Sources

Cosmic rays are mostly composed of protons accelerated to relativistic speeds. When those protons encounter interstellar material, they produce neutral pions, which in turn decay into gamma-rays. This offers a compelling way to identify the acceleration sites of protons. A characteristic hadronic spectrum, with a low-energy break around 200 MeV, was detected in the gamma-ray spectra of four supernova remnants (SNRs), IC 443, W44, W49B, and W51C, with the Fermi Large Area Telescope. This detection provided direct evidence that cosmic-ray protons are (re-)accelerated in SNRs. Here, we present a comprehensive search for low-energy spectral breaks among 311 4FGL catalog sources located within 5° from the Galactic plane. Using 8 yr of data from the Fermi Large Area Telescope between 50 MeV and 1 GeV, we find and present the spectral characteristics of 56 sources with a spectral break confirmed by a thorough study of systematic uncertainty. Our population of sources includes 13 SNRs for which the proton–proton interaction is enhanced by the dense target material; the high-mass gamma-ray binary LS I+61 303; the colliding wind binary η Carinae; and the Cygnus star-forming region. This analysis better constrains the origin of the gamma-ray emission and enlarges our view to potential new cosmic-ray acceleration sites.

79 ASTRONOMY AND ASTROPHYSICS↗

A Stochastic Model of Space-Time Variability of Tropical Rainfall: I. Statistics of Spatial Averages

Global maps of rainfall are of great importance in connection with modeling of the earth s climate. Comparison between the maps of rainfall predicted by computer-generated climate models with observation provides a sensitive test for these models. To make such a comparison, one typically needs the total precipitation amount over a large area, which could be hundreds of kilometers in size over extended periods of time of order days or months. This presents a difficult problem since rain varies greatly from place to place as well as in time. Remote sensing methods using ground radar or satellites detect rain over a large area by essentially taking a series of snapshots at infrequent intervals and indirectly deriving the average rain intensity within a collection of pixels , usually several kilometers in size. They measure area average of rain at a particular instant. Rain gauges, on the other hand, record rain accumulation continuously in time but only over a very small area tens of centimeters across, say, the size of a dinner plate. They measure only a time average at a single location. In making use of either method one needs to fill in the gaps in the observation - either the gaps in the area covered or the gaps in time of observation. This involves using statistical models to obtain information about the rain that is missed from what is actually detected. This paper investigates such a statistical model and validates it with rain data collected over the tropical Western Pacific from ship borne radars during TOGA COARE (Tropical Oceans Global Atmosphere Coupled Ocean-Atmosphere Response Experiment). The model incorporates a number of commonly observed features of rain. While rain varies rapidly with location and time, the variability diminishes when averaged over larger areas or longer periods of time. Moreover, rain is patchy in nature - at any instant on the average only a certain fraction of the observed pixels contain rain. The fraction of area covered by rain decreases, as the size of a pixel becomes smaller. This means that within what looks like a patch of rainy area in a coarse resolution view with larger pixel size, one finds clusters of rainy and dry patches when viewed on a finer scale. The model makes definite predictions about how these and other related statistics depend on the pixel size. These predictions were found to agree well with data. In a subsequent second part of the work we plan to test the model with rain gauge data collected during the TRMM (Tropical Rainfall Measuring Mission) ground validation campaign.

Kundu, Prasun K.↗

Fully Printed, Flexible, Phased Array Antenna for Lunar Surface Communication

NASAs future exploration missions focus on the manned exploration of the Moon, Mars, and beyond, which will rely heavily on the development of a reliable communications infrastructure from planetary surface-to-surface, surface-to-orbit, and back to Earth. Flexible antennas are highly desired in many scenarios. Active phased array antennas (active PAAs) with distributed control and processing electronics at the surface of an antenna aperture offer numerous advantages for radar communications. Large-area active PAAs on flexible substrates are of particular interest in NASA s space radars due to their efficient inflatable package that can be rolled up during transportation and deployed in space. Such an inflatable package significantly reduces stowage volume and mass. Because of these performance and packaging advantages, large-area inflatable active PAAs are highly desired in NASA s surface-to-orbit and surface-to-relay communications. To address the issues of flexible electronics, a room-temperature printing process of active phased-array antennas on a flexible Kapton substrate was developed. Field effect transistors (FETs) based on carbon nanotubes (CNTs), with many unique physical properties, were successfully proved feasible for the PAA system. This innovation is a new type of fully inkjet-printable, two-dimensional, high-frequency PAA on a flexible substrate at room temperature. The designed electronic circuit components, such as the FET switches in the phase shifter, metal interconnection lines, microstrip transmission lines, etc., are all printed using a special inkjet printer. Using the developed technology, entire 1x4, 2x2, and 4x4 PAA systems were developed, packaged, and demonstrated at 5.3 GHz. Several key solutions are addressed in this work to solve the fabrication issues. The source/drain contact is developed using droplets of silver ink printed on the source/drain areas prior to applying CNT thin-film. The wet silver ink droplets allow the silver to wet the CNT thin-film area and enable good contact with the source and drain contact after annealing. A passivation layer to protect the device channel is developed by bonding a thin Kapton film on top of the device channel. This film is also used as the media for transferring the aligned CNT thin-film on the device substrate. A simple and cost-effective technique to form multilayer metal interconnections on flexible substrate is developed and demonstrated. Contact vias are formed on the second substrate prior to bonding on the first substrate. Inkjet printing is used to fill the silver ink into the via structure. The printed silver ink penetrates through the vias to contact with the contact pads on the bottom layer. It is then annealed to form a good connection. One-dimensional and two-dimensional PAAs were fabricated and characterized. In these circuits, multilayer metal interconnects were used to make a complete PAA system.

Subbaraman, Harish↗

Novel Lightweight, Low-Cost Heliostat for Concentrating Solar Power (SBIR Phase I Final Report)

The overall goal of this Department of Energy (DOE) SBIR Phase I project was to demonstrate the feasibility of the L.Garde, Inc. heliostat mirror facet for use in concentrated solar power applications. Prior to this Phase I project, L.Garde, Inc. developed a design for a lightweight and low cost mirror facet and successfully fabricated small scale (0.667 m 2 ) with a mirror surface flatness of 0.7 mrad. Therefore, the focus of the Phase I effort was to (1) demonstrate scalability by fabricating larger size mirrors while retaining the same mirror surface flatness, (2) demonstrate the design can withstand operating environment conditions through field testing, and (3) perform cost analysis to show the heliostat mirror facet design can meet DoE goals of < 12 kg/m2 and <$30/m 2 . During the Phase I project, L.Garde successfully fabricated large area (1.395 m 2 ) heliostat mirror facets, with a mass per unit area of 8 kg/m 2 and a cost of $29.80/m 2 . Surface flatness measurements (using contact probe technique) were performed on the mirror surface and results showed a flatness of 0.68 mrad, which were in agreement with previously fabricated small scale mirror facets. Slope error measurements was also performed on the mirror surface and results showed a slope error of 0.77 mrad which also was in agreement with previously fabricated small scale mirror facets. One large area mirror facet was subjected to a three (3) month field test. Surface flatness and slope error measurements were performed on the mirror surface after the field test and results were 0.663 mrad and 0.58 mrad respectively. The large scale heliostat mirror facets were also subjected to accelerated aging. However, during this exposure we observed failure due to the breaking of the mirror facets. Further investigation into the source of the failure showed that the mirror component alone showed signs of degradation during the same accelerated aging test. We believe that moisture ingress is occurring when subjected to high humidity, leading to buildup of water with the layers of protective paints and resulting in mirror breakage when water expands in freezing conditions. In order to mitigate or eliminate this issue, a new weatherproofing strategy may be implemented or a new mirror component may be used that is able to survive accelerated aging conditions.

14 SOLAR ENERGY↗

Overview of SERI's high efficiency solar cell research

The bulk of the research efforts supported by the Solar Energy Research Institute (SERI) High Efficiency Concepts area has been directed towards establishing the feasibility of achieving very high efficiencies, 30% for concentrator and more than 20% for thin film flat plate, in solar cell designs which could possibly be produced competitively. The research has accomplished a great deal during the past two years. Even though the desired performance levels have not yet been demonstrated, based on the recent progress, a greater portion of the terrestrial photovoltaics community believes that these efficiencies are attainable. The program will now allocate a larger portion of resources to low cost, large area deposition technology. The program is currently shifting greater emphasis on to the study of crystal growth in order to provide the understanding and tools needed to design a large area process.

Benner, J. P.↗

Engineering Perovskite Precursor Inks for Scalable Production of High‐Efficiency Perovskite Photovoltaic Modules

Abstract Blade coating of perovskite solar cells (PSCs) and modules has progressed considerably toward the industrial production of perovskite photovoltaics. Developing stable perovskite precursors is critical for achieving uniform coating over large areas. Here, the engineering of a perovskite precursor solution consisting of 2‐methoxyethanol (2‐Me) and 1,3‐dimethyl‐imidazolidinone (DMI) with superior intermediate phase stability that enables scalable production of efficient perovskite solar modules is reported. With this perovskite precursor solution, uniform and pinhole‐less perovskite film is deposited over a large area of > 100 cm 2 and higher‐efficiency PSCs and modules are obtained. The best‐performing unit cell and module with n‐i‐p configuration reach power conversion efficiencies of 23.4% and 20.1%, respectively. Additionally, a series of non‐destructive metrology methods, such as spectroscopic ellipsometry, hyperspectral photoluminescence, electroluminescence, and laser beam‐induced current mapping, are employed to assess and guide the development the blade‐coated perovskite modules. This results show that rational engineering of precursor inks for blade coating is promising for the scalable production of efficient perovskite solar modules.

36 MATERIALS SCIENCE↗