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At least 793 records · Page 44

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NASA NTRS1978

Development of a plasma sprayed ceramic gas path seal for high pressure turbine application

Development of the plasma sprayed graded, layered ZRO2/CoCrAlY seal system for gas turbine engine blade tip seal applications up to 1589 K (2400 F) surface temperature was continued. The effect of changing ZRO2/CoCrAlY ratios in the intermediate layers on thermal stresses was evaluated analytically with the goal of identifying the materials combinations which would minimize thermal stresses in the seal system. Three methods of inducing compressive residual stresses in the sprayed seal materials to offset tensile thermal stresses were analyzed. The most promising method, thermal prestraining, was selected based upon potential, feasibility and complexity considerations. The plasma spray equipment was modified to heat, control and monitor the substrate temperature during spraying. Specimens were fabricated and experimentally evaluated to: (1) substantiate the capability of the thermal prestrain method to develop compressive residual stresses in the sprayed structure and (2) define the effect of spraying on a heated substate on abradability, erosion and thermal shock characteristics of the seal system. Thermal stress analysis, including residual stresses and material properties variations, was performed and correlated with thermal shock test results. Seal system performance was assessed and recommendations for further development were made.

Shiembob, L. T.↗

NASA NTRS1978

Process for utilizing low-cost graphite substrates for polycrystalline solar cells

Low cost polycrystalline silicon solar cells supported on substrates were prepared by depositing successive layers of polycrystalline silicon containing appropriate dopants over supporting substrates of a member selected from the group consisting of metallurgical grade polycrystalline silicon, graphite and steel coated with a diffusion barrier of silica, borosilicate, phosphosilicate, or mixtures thereof such that p-n junction devices were formed which effectively convert solar energy to electrical energy. To improve the conversion efficiency of the polycrystalline silicon solar cells, the crystallite size in the silicon was substantially increased by melting and solidifying a base layer of polycrystalline silicon before depositing the layers which form the p-n junction.

Chu, T. L.↗

NASA NTRS1977

Rare earth and trace element geochemistry of a fragment of Jurassic seafloor, Point Sal, California

Rocks from an ophiolite suite once on the seafloor were analyzed for rare earth elements (REE), Sc, Co, Na2O, Cr, Zn and FeO. Strontium isotope exchange noted in some of the lavas is attributed to basalt-seawater interaction; the Ce abundance in smectite- and zeolite-bearing lavas may also be due to prolonged exposure to seawater. The higher grades of metamorphic rock, however, show no variation from the usual flat or slightly light REE depleted profiles. Plutonic igneous rock, all light REE depleted, have total REE abundances varying by a factor of 100 between the dunites and diorites. In order of decreasing REE abundance are hornblende, clinopyroxene, plagioclase, orthopyroxene and olivine. Calculations of REE contents of liquids in equilibrium with early cumulative clinopyroxenes suggest that the parent to the stratiform sequence was more depleted in light REE than the parent to the lava pile.

Menzies, M.↗

NASA NTRS1976

Experiments to evaluate high-temperature rolling as a low-cost process for silicon solar cells

Mechanical rolling (a process used in industry for producing large quantities of metallic sheet and strip) has been suggested for the rapid low-cost manufacture of silicon sheet to be used for photovoltaic power generation equipment, such as solar arrays. The advantages of rolling include: high rates of production, wide sheets as products, good control of dimension, and (in the case of solar grade silicon) minimal development of impurities. Experiments have been performed using high-temperature, high-speed compression of polycrystalline silicon cylinders. Metallography and X-ray diffraction techniques have been used to examine the samples both before and after compression, and a model process has been designed to evaluate the technical practicality and economic feasibility of the method.

Noel, G. T.↗

NASA NTRS1977

Plasma /Na+/, /Ca++/, and volume shifts and thermoregulation during exercise in man

Graded-exercise experiments are conducted on six trained male runners (19-23 yr) subjected to ergometer exercise in a program consisting of 30-min resting control period, 60 min of rest or exercise at work loads that resulted in a maximal oxygen uptake equivalent to 6% (resting), 23%, 43%, and 62% of maximal oxygen uptake, followed by 30 min of recovery. The parameters measured and discussed are rectal temperature (T-re), skin temperatures at different spots, maximal oxygen uptake, plasma volume (PV), and various plasma electrolyte and protein concentrations. The objectives are to determine whether the increased T-re during progressively greater work loads are related to plasma sodium ion and calcium ion concentrations, as well as to evaluate the influence of PV shifts on the electrolyte and osmotic concentrations. The results suggest that the shift (loss) in PV accounts for the increases in the plasma constituent concentrations that result in significant correlations with T-re.

Greenleaf, J. E.↗

NASA NTRS1978

Origin of magnetization in lunar breccias - An example of thermal overprinting

Twenty six samples from seven hand specimens, collected from the station 6 boulder at the Apollo 17 landing site, were studied magnetically. The boulder is a breccia consisting of three lithologic units distinguished by their clast population. The direction of magnetization of samples from unit B which is almost devoid of large clasts cluster fairly well after alternating field demagnetization. Samples from unit C which is characterized by abundant large clasts up to 1 m in size do not contain a uniform direction of magnetization but the distribution is not random. Based on these data we propose that the natural remanent magnetization (NRM) in these breccias is the vector sum of two magnetizations, a pre-impact magnetization and a partial thermoremanence acquired during breccia formation. The relative contribution of the two components is controlled by the thermal history of the ejecta, which in turn is determined by its clast population. Depending on the clast population, the NRM can be a total thermoremanence, a partial thermoremanence plus a pre-impact magnetization, or a pre-impact magnetization. This model of thermal overprinting might be applicable to all lunar breccias of medium and higher metamorphic grade.

Gose, W. A.↗

NASA NTRS1978

Investigation of the fracture mechanism of Ti-5Al-2.5Sn at cryogenic temperatures

Fractography and metallographic sectioning were used to investigate the influence of microstructure on the fracture mechanism and fracture toughness (KIC) of normal interstitial and extra low interstitial (ELI) Ti-5Al-25Sn at 20 K (-423 F) and 77 K (-320 F). Plates of each grade were mill annealed at 815 C followed by either air or furnace cooling. These variations in composition and cooling rate resulted in differences in the volume fraction and internal structure of the dispersed beta phase and in the ordering of the alpha matrix. The ELI alloys were tougher than the normal interstitial plates. KIC of the furnace-cooled ELI plate was 25% lower than that of the air-cooled ELI material. Variations in cooling rate had no influence of KIC of the normal interstitial alloys. Fractography showed that a large portion of the fracture surfaces were covered with elongated dimples. Metallographic sections of specimens deformed at 77 K showed that these features form at the intersections of slip bands or deformation twins with grain or twin boundaries. Ordering and higher interstitial levels increase the local strain in slip bands resulting in void nucleation at lower macroscopic strains and lower KIC values.

Van Stone, R. H.↗

NASA NTRS1978

Infrared /JHK/ photometry of meteorites and asteroids

The paper reports JHK colors observed for ten asteroids and synthesized JHK colors for seven meteorite groups, samples of iron and nickel metal, pyroxene, olivine, feldspar, a lunar anorthite and some terrestrial mineral samples. Pronounced differences are apparent between the chondritic and achondritic meteorite classes; the chondritic classes show less subdued trends in J-H color which reflect their metamorphic grade. We find small but significant differences between the JHK colors of the predominant C and S classes of asteroids. All JHK colors of asteroids observed here fall within the limited domain defined by the various chondritic and iron-rich meteorites but are strikingly different from those of most achondritic meteorites.

Leake, M.↗

NASA NTRS1978

Formation of lunar basin rings

The outer rings of impact basins are interpreted as the bounding rings of the excavated basin cavities analogous to Copernicus-type crater rim crests. It is suggested that the inner rings are strata from depth uplifted during excavation of the transient cavity. Spacing relations and morphology appear to indicate a transition from central peaks to rings but not from terraces to rings. Evidence related to terrestrial craters with rings or peaks produced by meteorite impacts suggests that one or more crater rims may form inside the main, outer crater rim, resulting in nested craters. There is some evidence that peaks grade into inner rings as material is ejected from their cores in progressively larger impacts. Multiply layered materials may produce multiple rings by differential excavation of the layers.

Hodges, C. A.↗

NASA NTRS1978

Synthesis of porous polyaromatic column packings for GC analysis of extraterrestrial atmospheres

The preparation of a polymer for the Pioneer-Venus Large Probe Gas Chromatograph and another polymer for gas-chromatographic analysis of the Jovian atmosphere is described. Technical-grade divinylbenzene is used as a reliable and economical source of monomer for the preparation of polymer beads. The discussion covers monomeric preparation, polymerization apparatus, first-stage polymer beads, second-stage polymer beads, amino-polymer, columns and gas-chromatographic testing instrumentation used. The polymer for the Pioneer-Venus gas chromatograph is also suitable for ammonia but not for amine analysis. However, the polymer for the analysis of the Jovian atmosphere is a chemically derivatized aromatic polymer that is suitable for amine analysis. The two-stage polymerization produces a highly efficient polymer packing clearly superior to others prepared by adjusted dilution of the aqueous-organic suspension system.

Woeller, F. H.↗

NASA NTRS1980

New approach to purifying silicon

Silicon tetrafluoride gas removes metallurgical-grade impurities when passed over silicon in quartz tube. Technique allows inexpensive increase in throughout rate. Approach could improve silicon production for silicon solar cells.

Chaney, R. E.↗

NASA NTRS1978

Development of sprayed ceramic seal systems for turbine gas path sealing

A ceramic seal system is reported that employs plasma-sprayed graded metal/ceramic yttria stabilized zirconium oxide (YSZ). The performance characteristics of several YSZ configurations were determined through rig testing for thermal shock resistance, abradability, and erosion resistance. Results indicate that this type of sealing system offers the potential to meet operating requirements of future gas turbine engines.

Bill, R. C.↗

NASA NTRS1978

Lifetime and diffusion length measurements on silicon material and solar cells

Experimental methods were evaluated for the determination of lifetime and diffusion length in silicon intentionally doped with potentially lifetime-degrading impurities found in metallurgical grade silicon, impurities which may be residual in low-cost silicon intended for use in terrestrial flat-plate arrays. Lifetime measurements were made using a steady-state photoconductivity method. Diffusion length determinations were made using short-circuit current measurements under penetrating illumination. Mutual consistency among all experimental methods was verified, but steady-state photoconductivity was found preferable to photoconductivity decay at short lifetimes and in the presence of traps. The effects of a number of impurities on lifetime in bulk material, and on diffusion length in cells fabricated from this material, were determined. Results are compared with those obtained using different techniques. General agreement was found in terms of the hierarchy of impurities which degrade the lifetime.

Othmer, S.↗

NASA NTRS1978

Process feasibility study in support of silicon material task 1

Process system properties are analyzed for materials involved in the alternate processes under consideration for solar cell grade silicon. The following property data are reported for trichlorosilane: critical constants, vapor pressure, heat of vaporization, gas heat capacity, liquid heat capacity, density, surface tension, viscosity, thermal conductivity, heat of formation, and Gibb's free energy of formation. Work continued on the measurement of gas viscosity values of silicon source materials. Gas phase viscosity values for silicon tetrafluoride between 40 C and 200 C were experimentally determined. Major efforts were expended on completion of the preliminary economic analysis of the silane process. Cost, sensitivity and profitability analysis results are presented based on a preliminary process design of a plant to produce 1,000 metric tons/year of silicon by the revised process.

Li, K. Y.↗

NASA NTRS1978

Evaluation of selected chemical processes for production of low-cost silicon, phases 1 and 2

A miniplant, consisting of a 5 cm-diameter fluidized-bed reactor and associated equipment was used to study the deposition parameters, temperature, reactant composition, seed particle size, bed depth, reactant throughput, and methods of reactant introduction. It was confirmed that the permissible range of fluidized-bed temperature was limited at the lower end by zinc condensation (918 C) and at higher temperatures by rapidly decreasing conversion efficiency. Use of a graded bed temperature was shown to increase the conversion efficiency over that obtained in an isothermal bed. Other aspects of the process such as the condensation and fused-salt electrolysis of the ZnCl2 by-product for recycle of zinc and chlorine were studied to provide information required for design of a 50 MT/year experimental facility. In view of the favorable technical and economic indications obtained, it was recommended that construction and operation of the 50 MT/year experimental facility be implemented.

Blocher, J. M.↗

NASA NTRS1978

Analysis and evaluation of process and equipment in tasks 2 and 4 of the Low Cost Solar Array project

Several experimental and projected Czochralski crystal growing process methods were studied and compared to available operations and cost-data of recent production Cz-pulling, in order to elucidate the role of the dominant cost contributing factors. From this analysis, it becomes apparent that substantial cost reductions can be realized from technical advancements which fall into four categories: an increase in furnace productivity; the reduction of crucible cost through use of the crucible for the equivalent of multiple state-of-the-art crystals; the combined effect of several smaller technical improvements; and a carry over effect of the expected availability of semiconductor grade polysilicon at greatly reduced prices. A format for techno-economic analysis of solar cell production processes was developed, called the University of Pennsylvania Process Characterization (UPPC) format. The accumulated Cz process data are presented.

Goldman, H.↗

NASA NTRS1978

Metamorphism, argon depletion, heat flow and stress on the Alpine fault

The Alpine fault of New Zealand is a major continental transform fault which was uplifted on its southeast side 4 to 11 km within the last 5 m.y. This uplift has exposed the Haast schists, which were metamorphosed from the adjacent Torlesse graywackes. The Haast schists increase in metamorphic grade from prehnite-pumpellyite facies 9-12 km from the fault through the chlorite and biotite zones of the greenschist facies to the garnet-oligoclase zone amphibolite facies within 4 km of the fault. These metamorphic zone boundaries are subparallel to the fault for 350 km along the strike. The K-Ar and Rb-Sr ages of the schists increase with distance from the fault: from 4 m.y. within 3 km of the fault to approximately 110 m.y. 20 km from the fault. Field relations show that the source of heat that produced the argon depletion aureole was the fault itself.

Scholz, C. H.↗

NASA NTRS1978

Synthesis of Silane and Silicon in a Non-equilibrium Plasma Jet

The original objective of this program was to determine the feasibility of high volume, low-cost production of high purity silane or solar cell grade silicon using a non equilibrium plasma jet. The emphasis was changed near the end of the program to determine the feasibility of preparing photovoltaic amorphous silicon films directly using this method. The non equilibrium plasma jet should be further evaluated as a technique for producing high efficiency photovoltaic amorphous silicon films.

Calcote, H. F.↗