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At least 793 records · Page 44

Integrated Methane Monitoring Platform Extension, Volume I: Final Technical Report

The IMMPE project, DE-FE0032284, was to enhance methane monitoring technologies and their applications across various natural gas asset classes. The scope included deploying advanced methane detection and monitoring technologies to identify and mitigate fugitive methane emissions, measuring emission rates, and assessing impacts. The findings included the successful mitigation of identified emissions and quantification of emission rates. A key outcome was the development of a comprehensive template and summary of recommendations for methane emissions monitoring, which is replicable for both upstream and downstream applications. Furthermore, the project emphasized the importance of education by providing training opportunities for technicians and regulators, thereby fostering awareness and promoting the adoption of cost-effective methane emissions monitoring and management techniques.

02 PETROLEUM↗

Filament Extension Atomization for High Solids Loading in Energy Efficient Spray Drying Systems

We demonstrate that we could scale FEA to reach outputs needed by industrial production, while increasing solids loading of the sprayed product by at least 30% and maintaining equal or better spray powder. After testing a wide range of products, in collaboration with industry partners we decided on our primary spray products of dry whey and WPC-80, two common materials processed and sold by US manufacturers with different parameters. We sprayed these with FEA at solids loadings of 70% for dry whey and 45% for WPC-80 with a spray output with particle sizes similar to industrial particles sizes and reduced variation in particle size. We simultaneously scaled up FEA first with a multi-nip with 6 nips surrounding a central roller with parallel axis of rotation and eventually with a tapered design that solved problems we encountered with our initial design. We were able to achieve output from a single array from our first design of up to 4.7 liters per minute (L/min) and from an array of our second multi-nip of 8 L/min exceeding expectations. This demonstrates that FEA technology can indeed be scaled up to meet the needs of industrial production. More arrays can be added as necessary to meet a wide range of spray dryer designs. We also tested FEA to create dried powders from a small scale (10 L/hour of water removal) spray dryer. Though we were not able to produce large quantities of powder from FEA due to challenges in integration, the powder we produced was higher quality and produced from higher solids loading materials. From our technoeconomic analysis we for a typically sized spray dryer, we estimate a 27% cost reduction and 41% energy and carbon reduction for WPC-80 and a 39-57% cost reduction and 52-76% energy reduction for sweet dry whey (depending on the exact product).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

U.S. emissions of HFC-134a derived for 2008-2012 from an extensive flask-air sampling network: US emissions of HFC-134a

U.S. national and regional emissions of HFC-134a are derived for 2008-2012 based on atmospheric observations from ground and aircraft sites across the U.S. and a newly developed regional inverse model. Synthetic data experiments were first conducted to optimize the model assimilation design and to assess model-data mismatch errors and prior flux error covariances computed using a maximumlikelihood estimation technique. The synthetic data experiments also tested the sensitivity of derived national and regional emissions to a range of assumed prior emissions, with the goal of designing a system that was minimally reliant on the prior. We then explored the influence of additional sources of error in inversions with actual observations, such as those associated with background mole fractions and transport uncertainties. Estimated emissions of HFC-134a range from 52 to 61 Gg yr -1 for the contiguous U.S. during 2008-2012 for inversions using air transport from Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model driven by the 12km resolution meteorogical data from North American Mesoscale Forecast System (NAM12) and all tested combinations of prior emissions and background mole fractions. Estimated emissions for 2008-2010 were 20% lower when specifying alternative transport from Stochastic Time-Inverted Lagrangian Transport (STILT) model driven by the Weather Research and Forecasting (WRF) meteorology. Our estimates (for HYSPLIT-NAM12) are consistent with annual emissions reported by U.S. Environmental Protection Agency for the full study interval. The results suggest a 10-20% drop in U.S. national HFC-134a emission in 2009 coincident with a reduction in transportation-related fossil fuel CO 2 emissions, perhaps related to the economic recession. All inversions show seasonal variation in national HFC-134a emissions in all years, with summer emissions greater than winter emissions by 20-50%.

54 ENVIRONMENTAL SCIENCES↗

Extension of the Plutonium Oxide Nanocluster Family to Include {Pu 16 } and {Pu 22 }

Plutonium(IV) oxide nanoclusters represent an interesting scientific problem regarding structure-function relationships and are also relevant to global concerns surrounding plutonium reprocessing, the remediation of plutonium-contaminated soils, and the storage or disposal of plutonium-containing wastes. Here we report the synthesis of five unique Pu IV oxide nanoclusters containing 38,22, or 16 metal centers and capped only with inorganic ligands, such as chlorine and water, which prevent formation of the extended PuO 2 structure. The products are interrogated through single-crystal X-ray diffraction, bond valence calculations, and comparisons to other known metal-oxide nanoclusters. Of particular interest is the in-corporation of hydroxide linkages into the smaller plutonium oxide nanoclusters, which underscores previous observations and hypotheses regarding the formation of plutonium polymers and colloids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A clarification and extension of our model of regolith formation on hillslopes: A clarification of our model of regolith formation on hillslopes

In this paper we clarify that our weathering model from 2013 did not explicitly describe weathering of soil moving downhill along hillslopes. Additionally, we re-analyze the role of the term that we neglected that describes loss of regolith mass through mineral dissolution. We derive an equation for this term by including lateral flow of water inside the model hill. For the revised hill model, we define a dimensionless parameter that allows estimation of the effect of lateral flow on the steady-state hillslope. This parameter is equal to the ratio of averaged advective flux of dissolved species out of the hill to the rate of total denudation. The parameter also yields a criterion for the existence of a steady state regolith thickness for systems experiencing unidirectional advection at a constant velocity: for a ridge, the rate of downward flow of water (qy) must be less than the rate of upward movement of rock (E) after normalization by a small parameter, α. This parameter is equal to the equilibrium aqueous concentration divided by the concentration of the reacting mineral in the rock. Alternately, a steady state may exist for the case of both vertical and lateral flow in a hill for any value of erosion rate if the Darcy velocities decrease with depth. Subsurface flow systems play an essential role in the existence of both steady-state hillslopes and steady-state regolith thicknesses.

54 ENVIRONMENTAL SCIENCES↗

Extension of lymphocyte viability for radiation biodosimetry: Potential implications for radiological/nuclear mass casualty incidents

Abstract Dicentric chromosome assay (DCA) is routinely used for estimating the absorbed radiation dose in exposed humans. Optimal lymphocyte viability is crucial for reliable dose estimation and most cytogenetic laboratories prefer the receipt of blood samples within 24 to 36 hours after collection. Delays in the shipment/receipt of samples can occur sometimes under certain unforeseen circumstances: (1) Adverse weather conditions, (2) distant location of blood collection sites, and (3) shipping and handling of a large number of samples after radiological/nuclear mass casualty incident(s). To circumvent some of these limitations, we evaluated the suitability of ex vivo irradiated blood samples stored in the presence of phytohemagglutinin (PHA) for 7 days at ambient temperature (22‐24°C) for radiation biodosimetry. Blood samples stored in the presence of PHA for up to 7 days showed a higher mitotic index than blood samples stored without PHA. To verify the use of stored blood samples for DCA, frequencies of X‐rays induced dicentric chromosomes were analyzed in the blood samples that were cultured either 24 hours after exposure or 7 days later after storage. Our results indicate that storage of ex vivo irradiated blood samples in the presence of PHA at ambient temperature was found optimal for DCA and that the radiation doses estimated by dicentric chromosome frequencies were grossly similar between the fresh and stored blood samples. Our study suggests that reliable and accurate biodosimetry results can be obtained for triage using blood samples stored for up to a week at ambient temperature in the presence of PHA.

Smith, Tammy↗

A practical extension of the recursive multi-fidelity model for the emulation of hole closure experiments

We report in regimes of high strain rate, the strength of materials often cannot be measured directly in experiments. Instead, the strength is inferred based on an experimental observable, such as a change in shape, that is matched by simulations supported by a known strength model. In hole closure experiments, the rate and degree to which a central hole in a plate of material closes during a dynamic loading event are used to infer material strength parameters. Due to the complexity of the experiment, many computationally expensive, three-dimensional simulations are necessary to train an emulator for calibration or other analyses. These simulations can be run at multiple grid resolutions, where dense grids are slower but more accurate. In an effort to reduce the computational cost, a combination of simulations with different resolutions can be combined to develop an accurate emulator within a limited training time. We explore the novel design and construction of an appropriate functional recursive multi-fidelity emulator of a strength model for tantalum in hole closure experiments that can be applied to arbitrarily large training data. Hence, by formulating a multi-fidelity model to employ low-fidelity simulations, we were able to reduce the error of our emulator by approximately 81% with only an approximately 1.6% increase in computing resource utilization.

36 MATERIALS SCIENCE↗

RDPM: An Extensible Tool for Resilience Design Patterns Modelling

Resilience to faults, errors, and failures in extreme-scale high-performance computing (HPC) systems is a critical challenge. Resilience design patterns offer a new, structured hardware and software design approach for improving resilience. While prior work focused on developing performance, reliability, and availability models for resilience design patterns, this paper extends it by providing a Resilience Design Patterns Modeling (RDPM) tool which allows (1) exploring performance, reliability, and availability of each resilience design pattern, (2) offering customization of parameters to optimize performance, reliability, and availability, and (3) allowing investigation of trade-off models for combining multiple patterns for practical resilience solutions.

Kumar, Mohit↗

Displaced vertex signatures of doubly charged scalars in the type-II seesaw and its left-right extensions

The type-II seesaw mechanism with an isospin-triplet scalar Δ L provides one of the most compelling explanations for the observed smallness of neutrino masses. The triplet contains a doubly-charged component $H^{±±}_{L}$, which dominantly decays to either same-sign dileptons or to a pair of W bosons, depending on the size of the triplet vacuum expectation value. However, there exists a range of Yukawa couplings ƒ L of the triplet to the charged leptons, wherein a relatively light $H^{±±}_{L}$ tends to be long-lived, giving rise to distinct displaced-vertex signatures at the high-energy colliders. We find that the displaced vertex signals from the leptonic decays $H^{±±}_{L} → ℓ^±_αℓ^±_β$ could probe a broad parameter space with 10 -10 ≲ |ƒ L | ≲ 10 -6 and 45.6 GeV<$M_{H^{±±}_{L}}$≲200 GeV at the high-luminosity LHC. Similar sensitivity can also be achieved at a future 1 TeV e + e - collider. The mass reach can be extended to about 500GeV at a future 100TeV proton-proton collider. Similar conclusions apply for the right-handed triplet $H^{±±}_{R}$ in the TeV-scale left-right symmetric models, which provide a natural embedding of the type-II seesaw. We show that the displaced vertex signals are largely complementary to the prompt same-sign dilepton pair searches at the LHC and the low-energy, high-intensity/precision measurements, such as neutrinoless double beta decay, charged lepton flavor violation, electron and muon anomalous magnetic moments, muonium-antimuonium oscillation and Møller scattering.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗