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At least 793 records · Page 44

Decarbonization of Wastewater Treatment with Microalgae Processes.

Microalgae can contribute to the decarbonization of wastewater treatment by municipalities, industries and agriculture, by substituting sunlight for energy intensive conventional treatment processes, while capturing nutrients and carbon in the algal biomass. The carbon fixed into the algal biomass can be converted to renewable natural gas (RNG) using anaerobic digestion or into renewable diesel and sustainable aviation fuel (SAF) using hydrothermal liquefaction (HTL), with greatly reduce the carbon footprints compared to conventional fuels. Bioplastics, biofertilizers and other bioproducts from microalgae biomass also provide potential benefits in greenhouse gas (GHG) reduction and domestic supply chains. Microalgae technologies can counter eutrophication caused by harmful algal blooms by recovering nutrients, N and P, from wastewaters, and even from very low nutrient concentrations found in surface waters. CO2 is required in microalgae cultivation and wastewater treatment to support maximal rates of the photosynthesis, with the CO2 obtained from the wastes themselves, other local sources or even atmospheric CO2. Greenhouse gas mitigation with microalgae processes is based on life cycle assessments, comparing such green processes with current energy intensive wastewater treatment, and nutrient reduction technologies. Microalgae technologies are specifically relevant to smaller, often disadvantaged, communities, where currently about 5,000 algae wastewater treatment ponds are operated by public utilities with many more are operated by industries. However, many, if not most, of these pond facilities require urgent technology upgrades to achieve the potential and goals of low cost GHG mitigation and efficient nutrient recycling. MicroBio Engineering Inc. is developing and has demonstrated several technologies that combine innovative carbon mitigation and decarbonization technologies for a circular economy, with longer-term potential for large-scale biofuels and biofertilizer production.

09 BIOMASS FUELS↗

Decarbonization of Wastewater Treatment with Microalgae Processes.

Microalgae can contribute to the decarbonization of wastewater treatment by municipalities, industries and agriculture, by substituting sunlight for energy intensive conventional treatment processes, while capturing nutrients and carbon in the algal biomass. The carbon fixed into the algal biomass can be converted to renewable natural gas (RNG) using anaerobic digestion or into renewable diesel and sustainable aviation fuel (SAF) using hydrothermal liquefaction (HTL), with greatly reduce the carbon footprints compared to conventional fuels. Bioplastics, biofertilizers and other bioproducts from microalgae biomass also provide potential benefits in greenhouse gas (GHG) reduction and domestic supply chains. Microalgae technologies can counter eutrophication caused by harmful algal blooms by recovering nutrients, N and P, from wastewaters, and even from very low nutrient concentrations found in surface waters. CO2 is required in microalgae cultivation and wastewater treatment to support maximal rates of the photosynthesis, with the CO2 obtained from the wastes themselves, other local sources or even atmospheric CO2. Greenhouse gas mitigation with microalgae processes is based on life cycle assessments, comparing such green processes with current energy intensive wastewater treatment, and nutrient reduction technologies. Microalgae technologies are specifically relevant to smaller, often disadvantaged, communities, where currently about 5,000 algae wastewater treatment ponds are operated by public utilities with many more are operated by industries. However, many, if not most, of these pond facilities require urgent technology upgrades to achieve the potential and goals of low cost GHG mitigation and efficient nutrient recycling. MicroBio Engineering Inc. is developing and has demonstrated several technologies that combine innovative carbon mitigation and decarbonization technologies for a circular economy, with longer-term potential for large-scale biofuels and biofertilizer production.

09 BIOMASS FUELS↗

Decarbonization of Wastewater Treatment with Microalgae Processes.

Microalgae can contribute to the decarbonization of wastewater treatment by municipalities, industries and agriculture, by substituting sunlight for energy intensive conventional treatment processes, while capturing nutrients and carbon in the algal biomass. The carbon fixed into the algal biomass can be converted to renewable natural gas (RNG) using anaerobic digestion or into renewable diesel and sustainable aviation fuel (SAF) using hydrothermal liquefaction (HTL), with greatly reduce the carbon footprints compared to conventional fuels. Bioplastics, biofertilizers and other bioproducts from microalgae biomass also provide potential benefits in greenhouse gas (GHG) reduction and domestic supply chains. Microalgae technologies can counter eutrophication caused by harmful algal blooms by recovering nutrients, N and P, from wastewaters, and even from very low nutrient concentrations found in surface waters. CO2 is required in microalgae cultivation and wastewater treatment to support maximal rates of the photosynthesis, with the CO2 obtained from the wastes themselves, other local sources or even atmospheric CO2. Greenhouse gas mitigation with microalgae processes is based on life cycle assessments, comparing such green processes with current energy intensive wastewater treatment, and nutrient reduction technologies. Microalgae technologies are specifically relevant to smaller, often disadvantaged, communities, where currently about 5,000 algae wastewater treatment ponds are operated by public utilities with many more are operated by industries. However, many, if not most, of these pond facilities require urgent technology upgrades to achieve the potential and goals of low cost GHG mitigation and efficient nutrient recycling. MicroBio Engineering Inc. is developing and has demonstrated several technologies that combine innovative carbon mitigation and decarbonization technologies for a circular economy, with longer-term potential for large-scale biofuels and biofertilizer production.

09 BIOMASS FUELS↗

OPERATIONAL TECHNOLOGY BEHAVIORAL ANALYTICS (OTBA) – A DATA-CENTRIC APPROACH FOR REDUCING CYBERSECURITY RISK

This paper provides a summary of the methodology, findings, lessons learned, and insights from an investigation into the feasibility of the Operational Technology Behavioral Analytics (OTBA) cybersecurity approach. The concept was evaluated with data from the National Carbon Capture Center (NCCC) – a U.S. Department of Energy (DOE) funded facility that is managed and operated by Southern Company at Alabama Power’s E. C. Gaston generating power plant in Wilsonville, Alabama. Appropriate data sources for the post-combustion carbon capture system were identified. Infrastructure was deployed to monitor, capture and archive data for the system. Critical parameters for each subsystem were identified and analyzed. Machine-learning algorithms were used to establish and characterize normal operations and subsequently identify anomalies. This effort yielded valuable insights and formed the basis of a data-centric strategy for detecting cyber-attacks along with a coordinated response philosophy. A significant takeaway is that the OTBA cybersecurity approach is quite portable; it can be applied to other critical infrastructure beyond fossil power generation.

Black, Clifton↗

Mercury and Radiocesium Accumulation and Associations With Sublethal Endpoints in the Florida Green Watersnake ( Nerodia floridana )

Mercury (Hg) and radiocesium ( 137 Cs) are well-known environmental contaminants with the potential to impact the health of humans and wildlife. Snakes have several characteristics conducive to studying environmental contamination but have rarely been included in the monitoring of polluted sites. We investigated the bioaccumulation of Hg and 137 Cs and associations with sublethal effects (standard metabolic rate [SMR] and hemoparasite infections) in Florida green watersnakes (Nerodia floridana). We captured 78 snakes from three former nuclear cooling reservoirs on the US Department of Energy's Savannah River Site in South Carolina (USA). For captured snakes, we (1) determined whole-body 137 Cs, (2) quantified total Hg (THg) using snake tail clips, (3) conducted hemoparasite counts, and (4) measured the SMR. We used multiple regression models to determine associations among snake body size, capture location, sex, tail THg, whole-body 137 Cs, Hepatozoon spp. prevalence and parasitemia, and SMR. Average whole-body 137 Cs (0.23 ± 0.08 Becquerels [Bq]/g; range: 0.00–1.02 Bq/g) was correlated with snake body size and differed significantly by capture site (Pond B: 0.67 ± 0.05 Bq/g; Par Pond: 0.10 ± 0.02 Bq/g; Pond 2: 0.03 ± 0.02 Bq/g). Tail THg (0.33 ± 0.03 mg/kg dry wt; range: 0.16–2.10 mg/kg) was significantly correlated with snake body size but did not differ by capture site. We found no clear relationship between SMR and contaminant burdens. However, models indicated that the prevalence of Hepatozoon spp. in snakes was inversely related to increasing whole-body 137 Cs burdens. Our results indicate the bioaccumulation of Hg and 137 Cs in N. floridana and further demonstrate the utility of aquatic snakes as bioindicators. Furthermore, our results also suggest a decrease in Hepatozoon spp. prevalence related to increased burdens of 137 Cs. Although the results are intriguing, further research is needed to understand the dynamics between 137 Cs and Hepatozoon spp. infections in semiaquatic snakes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Electrolyte–Electrocatalyst Interfacial Effects of Polymeric Materials for Tandem CO 2 Capture and Conversion Elucidated Using In Situ Electrochemical AFM

Integrating CO 2 capture and electrochemical conversion has been proposed as a strategy to reduce the net energy required for CO 2 regeneration in traditional CO 2 capture and conversion schemes and can be coupled with carbon-free renewable electricity. Polyethylenimine (PEI)-based materials have been previously studied as CO 2 capture materials and can be integrated in these reactive capture processes. PEI-based electrolytes have been found to significantly increase the CO 2 loading, and impact selectivity and rate of product formation when compared to the conventional aqueous electrolytes. However, the influence of these materials at the catalyst–electrode interface is currently not well understood. In this study, PEI-based electrolytes were prepared and their impact on the morphology of a silver electrode performing electrochemical CO 2 reduction (CO 2 R) was studied using in situ electrochemical atomic force microscopy (EC-AFM). The presence of PEI on the electrode surface could be distinguished based on nanomechanical properties (DMT modulus), and changes were observed as negative polarization was applied, revealing a reorganization of the PEI chains due to electrostatic interactions. These changes were impacted by the electrolyte composition, including the addition of supporting electrolyte KHCO 3 salt, as well as CO 2 captured by the PEI-based electrolyte, which minimized the change in surface mechanical properties and degree of PEI alignment on the electrode surface. The changes in surface mechanical properties were also dependent on the PEI polymer length, with higher molecular weight PEI showing different reconfiguration than the shorter polymer brushes. The study highlights that the choice of polymer material, the electrolyte composition, and CO 2 captured impact the nearelectrode environment, which has implications for CO 2 R, and presents EC-AFM as a new tool that can be used to probe the dynamic behavior of these interfaces during electrocatalysis.

36 MATERIALS SCIENCE↗

Abstract for CRADA among National Energy Technology Laboratory, Research Triangle Institute, Lawrence Livermore National Laboratory, and Los Alamos National Laboratory (AGMT-0921)

Through the Carbon Capture Simulation for Industry Impact (CCSI 2 ) project, the National Energy Technology Laboratory (NETL), Lawrence Livermore National Laboratory (LLNL), and Los Alamos National Laboratory (LANL) (herein collectively “the CCSI 2 team”) will collaborate through a CRADA with the Research Triangle Institute (RTI). This collaboration will develop a modeling framework of RTI’s Non-Aqueous Solvent (NAS) process using physical and thermodynamic data and models previously developed by RTI. RTI will provide existing models and data on its NAS system to inform the model construction effort by the CCSI 2 team.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A measurement of cosmic-ray beryllium isotopes from 200 to 1500 MeV per nucleon

A balloon-borne superconducting magnetic spectrometer was used in the measurement of cosmic-ray isotopic abundances from lithium through oxygen in the energy range 200-1500 MeV per nucleon. Except for Be-7 all isotopic composition is essentially energy-independent. Be-10 is nearly absent, indicating a mean cosmic-ray age of 6(-3, +10) x 10 to the 6th years. Above about 500 MeV per nucleon, Be-7 drops dramatically in abundance relative to Be-9 and C. By 1500 MeV per nucleon, the relative abundance of Be-7 has become one-half of its lower-energy value. Since Be-7 is the only isotope measured which decays by electron capture, this result is interpreted as indicating that higher-energy Be-7 had an appreciable probability of not being stripped of all its electrons before entering interstellar space where electron pickup is negligible.

Buffington, A.↗

Enhanced Depolarized Electro-Membrane System (EDEMS) for Direct Capture of Carbon Dioxide from Ambient Air (Final Report)

The goal of this final project report is to summarize the work conducted on project DE-FE0031962. In accordance with the Statement of Project Objectives (SOPO), the University of Kentucky Center for Applied Energy Research (UK CAER) (Recipient) developed an intensified process to capture CO2 from ambient conditions (400 ppm CO2). The process combines low-temperature solvent-aided membrane capture with electrochemically-mediated solvent regeneration to simultaneously capture ambient CO2 while regenerating the solvent. The technology employs only two primary units (regenerator and absorber/contactor) while generating high purity hydrogen as a co-product that can be sold, used for energy storage, or cost-saving depolarization of the direct air capture (DAC) system during the grid peak demand, allowing for flexible operation. When depolarization is employed, the operating voltage is reduced by more than 1 V. Since the technology is powered directly by DC electricity, it can seamlessly tie in with power sources like solar cells without the need for AC/DC converters, therefore allowing for a remote operation to further mitigate greenhouse gas generation toward deploying a negative carbon emissions technology that is completely decoupled from the carbon emissions from the power source for the DAC unit. The project results verified that UK CAER’s integrated approach addressed the complexities of incumbent DAC systems by demonstrating at ambient conditions, including (1) low gas-side pressure-drop facile CO2 capture via a membrane contactor with in-situ generated hydroxide as capture solvent, (2) multi-functional electrochemical regenerator for hydroxide regeneration, CO2 concentration and hydrogen production, and (3) depolarization using cathode-produced hydrogen to reduce energy requirement. The EH&S Assessment of the process did not identify any obvious concern for the bench-scale operation and no apparent barriers to implementing UK CAER’s carbon capture and solvent regeneration system at a larger scale.

20 FOSSIL-FUELED POWER PLANTS↗

Lidar-Based Evaluation of HRRR Performance in California’s Diablo Range

The performance of the NOAA High-Resolution Rapid Refresh (HRRR) model for capturing low-level winds near a wind energy production site during summer 2019 is evaluated. This study catalogs the ability of HRRR to predict boundary layer dynamics relevant to wind energy interests over complex terrain, which has presented challenges for weather and energy forecasting. Performance is evaluated by comparing HRRR output to wind-profiling Doppler lidars at Lawrence Livermore National Laboratory Site 300. HRRR captured the diurnal profile of horizontal winds in the observed 150-m layer, despite strong underpredictions (∼4 m s −1 ) during evening and nighttime hours. These underpredictions may be a result of local speedup flows observed by the lidars, which were unresolved in HRRR due to their small spatial extent. HRRR bias magnitude relative to observations was found to be minimal during days with synoptic-scale troughs and strong 850-hPa geopotential gradients, while bias magnitude was maximal during days with synoptic ridging and weak 850-hPa geopotential gradients. To translate wind speed predictions to energy forecasting, generic turbine models were used to estimate power generation for turbines characteristic of the nearby Altamont Pass Wind Resource Area. Results show that HRRR-based energy estimates predicted daytime power generation adequately relative to lidar-based estimates with an 18-h lead time (bias magnitude < 0.4 MW from 0900 to 1400 LT) but overpredicted power during the rest of the diurnal cycle (bias > 1 MW). These results demonstrate conditions under which HRRR performs well for wind energy applications in complex terrain, while highlighting biases that require further investigation to support usage of a high-resolution model for wind energy forecasts.

Boundary layer↗

Food–energy–water implications of negative emissions technologies in a +1.5 °C future

Scenarios for meeting ambitious climate targets rely on large-scale deployment of negative emissions technologies (NETs), including direct air capture (DAC). However, the tradeoffs between food, water and energy created by deploying different NETs are unclear. Here we show that DAC could provide up to 3 GtCO 2 yr -1 of negative emissions by 2035—equivalent to 7% of 2019 global CO 2 emissions—based on current-day assumptions regarding price and performance. DAC in particular could exacerbate demand for energy and water, yet it would avoid the most severe market-mediated effects of land-use competition from bioenergy with carbon capture and storage and afforestation. This could result in staple food crop prices rising by approximately fivefold relative to 2010 levels in many parts of the Global South, raising equity concerns about the deployment of NETs. Overall, these results highlight that delays in aggressive global mitigation action greatly increase the requirement for DAC to meet climate targets, and correspondingly, energy and water impacts.

54 ENVIRONMENTAL SCIENCES↗

A Simple Panel System to Overcome Interface Challenges for Retrofits: Preprint

Retrofitting buildings is usually an expensive and labor-intensive process. Weatherization measures can improve comfort and energy affordability to some extent, but deep energy retrofits are needed to optimize performance and comfort, and to achieve significant energy cost savings. Barriers to deep energy retrofits include a limited supply of skilled labor, different building types, planning complexity, split incentives, and a long or non-existent ROI horizon. The "Simple Panel System" (SPS) workflow developed and demonstrated in this effort streamlines deep energy retrofits by applying advanced site capture, machine learning, and mixed reality to panelized construction. The result is a one-stop, product-independent solution for rapidly scalable retrofits with the potential to reduce construction time and project costs by 50%. Soft costs are reduced by more than 66%, total costs by more than 50%, and field construction time by more than 50% - not to mention the reduction in construction waste, improvement in working conditions, and the ability to scale without an influx of skilled labor. This paper presents the SPS and the preliminary results and findings from the pilot project.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Next-Generation Desiccant-Based Gas Clothes Dryer Systems

The goal of the project is to develop an advanced gas clothes dryer system demonstrating significant improvements in fuel efficiency and drying performance compared to current gas clothes dryer technologies. The new system decouples latent and sensible loads to effectively utilize the latent heat associated with laundry moisture as an advantageous energy source. In other words, the system captures the waste latent heat from moisture produced during the fabric-drying process and reuses it to improve drying efficiency.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

High-Fidelity Large-Signal Order Reduction Approach for Composite Load Model

With the increasing penetration of electronic loads and distributed energy resources, conventional load models cannot capture their dynamics. Therefore, a new comprehensive composite load model is developed by Western Electricity Coordinating Council (WECC). However, this model is a complex high-order non-linear system with multi-time-scale property, which poses challenges on power system studies with heavy computational burden. In order to reduce the model complexity, the authors firstly develop a large-signal order reduction (LSOR) method using singular perturbation theory. In this method, the fast dynamics are integrated into the slow ones to preserve transient characteristics of the former. Then, accuracy assessment conditions are proposed and embedded into the LSOR to improve and guarantee the accuracy of reduced-order model. Finally, the reduced-order WECC composite load model is derived by using the proposed algorithm. Overall, simulation results show that the reduced-order large-signal model significantly alleviates the computational burden while maintaining similar dynamic responses as the original composite load model.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Operational Technology Behavioral Analytics (OTBA) (Final Technical Report DE-FE0031640)

This final report provides a summary of the methodology, findings, lessons learned, and insights from an investigation into the feasibility of the Operational Technology Behavioral Analytics (OTBA) cybersecurity approach. The concept was evaluated with data from the National Carbon Capture Center (NCCC) – a U.S. Department of Energy (DOE) funded facility that is managed and operated by Southern Company Services, Inc. at Alabama Power Company’s E. C. Gaston generating power plant in Wilsonville, Alabama. Appropriate data sources for the post-combustion carbon capture system were identified. Infrastructure was deployed to monitor, capture and archive data for the system. Critical parameters for each subsystem were identified and analyzed. Machine-learning algorithms were used to establish and characterize normal operations and subsequently identify anomalies. This effort yielded valuable insights and formed the basis of a data-centric strategy for detecting cyber-attacks along with a coordinated response philosophy. A significant takeaway is that the OTBA cybersecurity approach is quite portable; it can be applied to other critical infrastructure beyond fossil power generation.

20 FOSSIL-FUELED POWER PLANTS↗

Identifying mechanistic differences between co-fed CO 2 hydrogenation and reactive CO 2 capture using Ru and Pd dual function materials

Dual function materials (DFMs) enable reactive carbon capture (RCkeC), an intensified approach to carbon dioxide capture and utilization for cost and energy input reductions. Yet, there is a fundamental lack of understanding of mechanisms around CO 2 adsorption and subsequent conversion on these materials, hindering further development. Herein, we investigated several supported alkaline metal oxides for their CO 2 adsorption characteristics to find that Na/Al 2 O 3 had the highest CO 2 adsorption capacity, accompanied by a variety of CO 2 adsorption geometries as identified by in situ DRIFTS and computational modeling. The addition of catalytic metals (Ru, Pd) increased the adsorption capacity of Na/Al 2 O 3 without altering binding modes. In the subsequent reactive desorption step, acetate and formate intermediates were observed. Notably, this mechanistic investigation identified that the formation of acetate species was unique to RCC on a DFM, as these species were not observed in co-fed hydrogenation over the DFM or RCC over a Na-free catalyst.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Machine learning and deep learning tools for the automated capture of cancer surveillance data

The National Cancer Institute and the Department of Energy strategic partnership applies advanced computing and predictive machine learning and deep learning models to automate the capture of information from unstructured clinical text for inclusion in cancer registries. Applications include extraction of key data elements from pathology reports, determination of whether a pathology or radiology report is related to cancer, extraction of relevant biomarker information, and identification of recurrence. With the growing complexity of cancer diagnosis and treatment, capturing essential information with purely manual methods is increasingly difficult. These new methods for applying advanced computational capabilities to automate data extraction represent an opportunity to close critical information gaps and create a nimble, flexible platform on which new information sources, such as genomics, can be added. This will ultimately provide a deeper understanding of the drivers of cancer and outcomes in the population and increase the timeliness of reporting. These advances will enable better understanding of how real-world patients are treated and the outcomes associated with those treatments in the context of our complex medical and social environment.

60 APPLIED LIFE SCIENCES↗