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At least 793 records · Page 44

Volatilization Behavior of Supported Au Nanoparticle Arrays under H 2 at High Temperature

In this work, the fabrication and experimental study of model Au nanoparticle arrays (nanodots) was used to allow a direct comparison of reactive evaporation at elevated temperatures and nonambient H 2 -containing gas atmospheres with theoretical models. Strong temperature and H 2 -concentration dependencies were confirmed as expected, and the observed dependence in particle diameter with time was effectively described using a reactive evaporation and gas phase diffusion based quantitative model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Calibration of Two-dimensional Floodplain Modeling in the Atchafalaya River Basin Using SAR Interferometry

Two-dimensional (2D) satellite imagery has been increasingly employed to improve prediction of floodplain inundation models. However, most focus has been on validation of inundation extent, with little attention on the 2D spatial variations of water elevation and slope. The availability of high resolution Interferometric Synthetic Aperture Radar (InSAR) imagery offers unprecedented opportunity for quantitative validation of surface water heights and slopes derived from 2D hydrodynamic models. In this study, the LISFLOOD-ACC hydrodynamic model is applied to the central Atchafalaya River Basin, Louisiana, during high flows typical of spring floods in the Mississippi Delta region, for the purpose of demonstrating the utility of InSAR in coupled 1D/2D model calibration. Two calibration schemes focusing on Manning s roughness are compared. First, the model is calibrated in terms of water elevations at a single in situ gage during a 62 day simulation period from 1 April 2008 to 1 June 2008. Second, the model is calibrated in terms of water elevation changes calculated from ALOS PALSAR interferometry during 46 days of the image acquisition interval from 16 April 2008 to 1 June 2009. The best-fit models show that the mean absolute errors are 3.8 cm for a single in situ gage calibration and 5.7 cm/46 days for InSAR water level calibration. The optimum values of Manning's roughness coefficients are 0.024/0.10 for the channel/floodplain, respectively, using a single in situ gage, and 0.028/0.10 for channel/floodplain the using SAR. Based on the calibrated water elevation changes, daily storage changes within the size of approx 230 sq km of the model area are also calculated to be of the order of 107 cubic m/day during high water of the modeled period. This study demonstrates the feasibility of SAR interferometry to support 2D hydrodynamic model calibration and as a tool for improved understanding of complex floodplain hydrodynamics

Hahn Chul Jung↗

The Effect of Firn-Aquifer Drainage on the Greenland Subglacial System or Subglacial Efficiency and Storage Modified by the Temporal Pattern of High-Elevation Meltwater Input

Ice flow in marginal region of the Greenland Ice Sheet dynamically responds to summer melting as surface meltwater is routed through the supraglacial hydrologic system to the bed of the ice sheet via crevasses and moulins. Given the expected increases in surface melt production and extent, and the potential for high elevation surface-to-bed connections, it is imperative to understand how meltwater delivered to the bed from different high-elevation supraglacial storage features affects the evolution of the subglacial hydrologic system and associated ice dynamics. Here, we use the two-dimensional subglacial hydrologic model, GLaDS, which includes distributed and channelized water flow, to test how the subglacial system of an idealized outlet glacier responds to cases of high-elevation firn-aquifer-type and supraglacial-lake-type englacial drainage over the course of 5 years. Model outputs driven by these high elevation drainage types are compared to steady-state model results, where the subglacial system only receives the 1980- 2016 mean MERRA-2 runoff via low-elevation moulins. Across all experiments, the subglacial hydrologic system displays inter-annual memory, resulting in multiyear declines in subglacial pressure during the onset of seasonal melting and growth of subglacial channels. The gradual addition of water in firn-aquifer-type drainage scenarios resulted in small increases in subglacial water storage but limited changes in subglacial efficiency and channelization. Rapid, supraglacial- lake-type drainage resulted in short-term local increases in subglacial water pressure and storage, which gave way to spatially extensive decreases in subglacial pressure and downstream channelization. These preliminary results suggest that the character of high-elevation englacial drainage can have a strong, and possibly outsized, control on subglacial efficiency throughout the ablation zone. Therefore, understanding both how high elevation meltwater is stored supraglacially and the probability of crevassing at high elevations will play an important role in how the subglacial system, proglacial discharge and ice motion will respond to future increases in surface melt production and runoff.

Andrews, Lauren C.↗

Cardiovascular and hormonal (aldosterone) responses in a rat model which mimics responses to weightlessness

Cardiovascular responses and fluid/electrolyte shifts seen during spaceflight have been attributed to cephalad redistribution of vascular fluid. The antiorthostatic (AO) rat (suspended, head-down tilt of 15-20 deg) is used to model these responses. This study documents that elevated blood pressures in AO rats are sustained for periods of up to seven days, compared with presuspension values. Increased blood pressures in AO rats suggests a specific response to AO positioning, potentially relatable to a cephalad fluid shift. To assess a role for hormonal regulation of sodium excretion, serum aldosterone levels were measured. Circulating aldosterone concentrations were seen to increase approximately 100 percent during seven days of AO suspension, concurrently with a pronounced natriuresis. These results suggest that aldosterone may not be involved in the long term regulation of increased Na(+) excretion in AO animals. These studies continue to show the usefulness of models for the development of animal protocols for space flight.

Musacchia, X. J.↗

Urban air quality estimation study, phase 1

Possibilities are explored for applying estimation theory to the analysis, interpretation, and use of air quality measurements in conjunction with simulation models to provide a cost effective method of obtaining reliable air quality estimates for wide urban areas. The physical phenomenology of real atmospheric plumes from elevated localized sources is discussed. A fluctuating plume dispersion model is derived. Individual plume parameter formulations are developed along with associated a priori information. Individual measurement models are developed.

Diamante, J. M.↗

Fundamental Experimental Tests and Modeling of LOX/CH4 Engines at High Pressures

In recent years, the space travel industry has grown exponentially, resulting in the need for a low-cost, efficient rocket engine fuel. As such, there has been renewed interest in utilizing liquid natural gas (LNG) as it is less likely to soot than kerosene-based fuels and has widespread availability and low cost of use as compared to the traditional RP-X and even liquid methane (LCH4) fuels due to the reduced need for refinement. However, current literature does not fully cover varying blends of natural gas and the effects that impurities have on natural gas/methane fuels, with most studies being confined to low-pressure applications. Therefore, new experimental ignition delay time measurements at rocket engine relevant pressures are essential to ensure current chemical kinetic models capture the ignition behavior at these elevated conditions and to determine the optimal purity levels for a reliable, cost-efficient, aerospace-grade LCH4/LNG fuel. The current work explores various blends of natural gas/methane fuel with various impurities, including higher hydrocarbons as well as nitrogen-carriers. A shock tube study was carried out to study the ignition delay times and carbon monoxide time histories of these natural gas blends utilizing chemiluminescence and laser absorption spectroscopy at 20, 50 and 100 atm over temperatures ranging from 1400-1700K and at an equivalence ratio of 1. The experimental data was then compared to two different chemical kinetic mechanisms: the industry-standard GRI 3.0 and the in-house UCF 2022. The data is used to improve chemical kinetic mechanisms and modeling of LNG fuels for rocket engine applications.

Methane↗

ADVANCED THERMAL-HYDRAULIC MODEL OF HEAT RECOVERY STEAM GENERATORS

Steam-side oxidation at elevated temperatures in heat recovery steam generators (HRSGs) can lead to overheating of local tubes, potential oxide scale exfoliation, and damage to critical equipment. Predicting the oxide growth distribution requires detailed knowledge of the distribution of tube metal temperatures. To address these challenges, a computational fluid dynamics (CFD) model of a high-pressure superheater (HPSH) was developed within the Siemens’ STAR-CCM+ CFD commercial software. The HPSH section of the steam generator was selected for modeling because of its high oxidation rates.The model development included several steps. In the first step, an oxidation model based on a parabolic oxidation relationship was implemented. The oxidation growth predicted by the model was then verified for a full-load boiler operation case. In the second step, a three-dimensional CFD model was developed to account for the thermal and flow physics involved in HRSGs. The CFD model was then verified and validated on a simplified geometry that contained six row-tubes which mimicked the tube arrangements of an HPSH section. Numerical results compared well with published experimental results. In the third step, the oxidation model was coupled to the HRSG’s CFD model, and a comparison study was performed for two cases: (a) regular finless tubes and (b) finned tubes. Preliminary results showed that the oxide thickness predicted by the case with tube fins was higher compared to that of the finless tube case, thus demonstrating the need to model the effects of the tube fins on oxide thickness.

Panicker, Nithin↗

Optimizing long-term monitoring of radiation air-dose rates after the Fukushima Daiichi Nuclear Power Plant

Radiation air dose rates near the Fukushima Daiichi Nuclear Power Plant (FDNPP) have been steadily decreasing over the past eight years since the release of radioactive elements in March 2011. Currently, the radiation monitoring program is expected to transition to long-term monitoring after most of the remediation activities are completed. The main long-term monitoring objectives are to (1) confirm the continuing reduction of contaminant and hazard levels, (2) provide assurance for the public, (3) accumulate the basic datasets for scientific knowledge and future preparation, and (4) detect changes or anomalies in contaminant mobility (if they occur), or any unexpected processes or events. In this work, we have developed a methodology for optimizing the monitoring locations of radiation air dose-rate monitoring. Our approach consists of three steps in order to determine monitoring locations in a systematic manner: (1) prioritizing the critical locations, such as schools or regulatory requirement locations, (2) diversifying locations that cover the key environmental controls that are known to influence contaminant mobility and distributions, and (3) capturing the heterogeneity of radiation air-dose rates across the domain. Therefore, for the second step, we use a Gaussian mixture model to identify the representative locations among multiple environmental variables, such as elevation and land-cover types. For the third step, we use a Gaussian process model to capture and estimate the heterogeneity of air-dose rates across the domain. Employing an integrated dose-rate map derived from Bayesian geostatistical methods as a reference map, we distribute the monitoring locations in such a way as to capture the heterogeneity of the reference map. Our results have shown that this approach allows us to select monitoring locations in a systematic manner such that the heterogeneity of air dose rates is captured by the minimal number of monitoring locations.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Centrifugal inertia effects in two-phase face seal films

A simplified, semianalytical model has been developed to analyze the effect of centrifugal inertia in two-phase face seals. The model is based on the assumption of isothermal flow through the seal, but at an elevated temperature, and takes into account heat transfer and boiling. Using this model, seal performance curves are obtained with water as the working fluid. It is shown that the centrifugal inertia of the fluid reduces the load-carrying capacity dramatically at high speeds and that operational instability exists under certain conditions. While an all-liquid seal may be starved at speeds higher than a 'critical' value, leakage always occurs under boiling conditions.

Basu, P.↗

A Super-Resolution Algorithm for Enhancement of FLASH LIDAR data

A novel method for enhancement of the spatial resolution of 3-dimensional Flash Lidar images is being proposed for generation of elevation maps of terrain from a moving platform. NASA recognizes the Flash LIDAR technology as an important tool for enabling safe and precision landing in future unmanned and crewed lunar and planetary missions. The ability of the Flash LIDAR to generate 3-dimensional maps of the landing site area during the final stages of the descent phase for detection of hazardous terrain features such as craters, rocks, and steep slopes is under study in the frame of the Autonomous Landing and Hazard Avoidance (ALHAT) project. Since single frames of existing FLASH LIDAR systems are not sufficient to build a map of entire landing site with acceptable spatial resolution and precision, a super-resolution approach utilizing multiple frames has been developed to overcome the instrument s limitations. Performance of the super-resolution algorithm has been analyzed through a series of simulation runs obtained from a high fidelity Flash LIDAR model and a high resolution synthetic lunar elevation map. For each simulation run, a sequence of FLASH LIDAR frames are recorded and processed as the spacecraft descends toward the landing site. Simulations runs having different trajectory profiles and varying LIDAR look angles of the terrain are also analyzed. The results show that adequate levels of accuracy and precision are achieved for detecting hazardous terrain features and identifying safe areas of the landing site.

Bulyshev, Alexander↗

Matrix dominated stress/strain behavior in polymeric composites: Effects of hold time, nonlinearity and rate dependency

In order to understand matrix dominated behavior in laminated polymer matrix composites, an elastic/viscoplastic constitutive model was developed and used to predict stress strain behavior of off-axis and angle-ply symmetric laminates under in-plane, tensile axial loading. The model was validated for short duration tests at elevated temperatures. Short term stress relaxation and short term creep, strain rate sensitivity, and material nonlinearity were accounted for. The testing times were extended for longer durations, and periods of creep and stress relaxation were used to investigate the ability of the model to account for long term behavior. The model generally underestimated the total change in strain and stress for both long term creep and long term relaxation respectively.

Gates, Thomas S.↗

Investigating Ozone Sources in California Using AJAX Airborne Measurements and Models: Implications for Stratospheric Intrusion and Long Range Transport

High ozone concentrations at low altitudes near the surface were detected from airborne Alpha Jet Atmospheric eXperiment (AJAX) measurements on May 30, 2012. We investigate the causes of the elevated ozone concentrations using the airborne measurements and various models. GEOSchem and WRF-STILT model simulations show that the contribution from local sources is small. From MERRA reanalysis, it is found that high potential vorticity (PV) is observed at low altitudes. This high PV appears to be only partially coming through the stratospheric intrusions because the air inside the high PV region is moist, which shows that mixing appears to be enhanced in the low altitudes. Considering that diabatic heating can also produce high PV in the lower troposphere, high ozone is partially coming through stratospheric intrusion, but this cannot explain the whole ozone concentration in the target areas of the western U.S. A back-trajectory model is utilized to see where the air masses originated. The air masses of the target areas came from the lower stratosphere (LS), upper (UT), mid- (MT), and lower troposphere (LT). The relative number of trajectories coming from LS and UT is low (7.7% and 7.6%, respectively) compared to that from LT (64.1%), but the relative ozone concentration coming from LS and UT is high (38.4% and 20.95%, respectively) compared to that from LT (17.7%). The air mass coming from LT appears to be mostly coming from Asia. Q diagnostics show that there is sufficient mixing along the trajectory to indicate that ozone from the different origins is mixed and transported to the western U.S. This study shows that high ozone concentrations can be detected by airborne measurements, which can be analyzed by integrated platforms such as models, reanalysis, and satellite data.

gas composition↗

Investigation of Ozone Sources in California Using AJAX Airborne Measurements and Models: Implications for Stratospheric Intrusion and Long Range Transport

High ozone concentrations at low altitudes near the surface were detected from airborne Alpha Jet Atmospheric eXperiment (AJAX) measurements on May 30, 2012. We investigate the causes of the elevated ozone concentrations using the airborne measurements and various models. GEOS-chem and WRF-STILT model simulations show that the contribution from local sources is small. From MERRA reanalysis, it is found that high potential vorticity (PV) is observed at low altitudes. This high PV appears to be only partially coming through the stratospheric intrusions because the air inside the high PV region is moist, which shows that mixing appears to be enhanced in the low altitudes. Considering that diabatic heating can also produce high PV in the lower troposphere, high ozone is partially coming through stratospheric intrusion, but this cannot explain the whole ozone concentration in the target areas of the western U.S. A back-trajectory model is utilized to see where the air masses originated. The air masses of the target areas came from the lower stratosphere (LS), upper (UT), mid- (MT), and lower troposphere (LT). The relative number of trajectories coming from LS and UT is low (7.7 and 7.6, respectively) compared to that from LT (64.1), but the relative ozone concentration coming from LS and UT is high (38.4 and 20.95, respectively) compared to that from LT (17.7). The air mass coming from LT appears to be mostly coming from Asia. Q diagnostics show that there is sufficient mixing along the trajectory to indicate that ozone from the different origins is mixed and transported to the western U.S. This study shows that high ozone concentrations can be detected by airborne measurements, which can be analyzed by integrated platforms such as models, reanalysis, and satellite data.

low altitude↗

Advancing Solid Earth Science through Improved Atmosphere Modeling

We proposed to investigate and develop better models for the effect of the hydrostatic and water vapor components of the neutral atmosphere on delay for VLBI and GPS by using a Numerical Weather Model to better simulate realistic atmosphere conditions. By using a raytrace calculation through the model atmosphere at the times of actual VLBI observations, the potential improvement in geodetic results can be evaluated. Also, by calculating the actual variation of delays with elevation and azimuth, the errors in current mapping function models can be assessed. The VLBI data to be initially analyzed are the fifteen days of the CONT02 sessions of 2002 October which included eight stations. There are three segments to the research. 1) The PSU/NCAR fifth generation mesoscale numerical weather model (MM5) will be used to provide the state of the atmosphere with highest horizontal resolution of 3 km. 2) A three-dimensional raytrace program will be developed to determine the delays through the model atmosphere at the times and in the directions of the VLBI observations for each of the sites. 3) The VLBI data will be analyzed using both standard models for the atmosphere mapping functions and the mapping functions derived from the NWM raytracing.

Niell, A. E.↗

Crystal plasticity modeling and analysis for the transition from intergranular to transgranular failure in nickel-based alloy Inconel 740H at elevated temperature

The precipitation-strengthened Nickel alloy Inconel® 740H® (IN740H) exhibits increased ductility at higher applied strain rates during quasi-static tensile tests at an elevated temperature of 760°C. The examination of fracture surfaces in this context reveals a noteworthy transition of underlying fracture mechanisms from transgranular to intergranular fracture as the applied strain rate decreases from 1×10 -3 / s to 0.83×10 -4 / s . To thoroughly understand the mechanical response of IN740H under these conditions, this study develops a crystal plasticity finite element (CPFE) model. Further, this model incorporates various deformation mechanisms including dislocation slips, climb, and grain boundary sliding, which are relevant to the test conditions. The model is calibrated using data from both tensile tests at different strain rates and creep tests across a broad stress range at 760°C, enabling the accurate determination of model parameters for each mechanism. Simulation results well captured the experimental observations of different failure modes. At higher strain rates, the model shows a dominance of dislocation slip leading to heterogeneous plastic deformation and formation of transgranular shear bands causing the failure, while at lower strain rates, an increased activity of grain boundary sliding causes grain boundaries crack leading to intergranular failure.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Structure-property relationships in oxide-dispersed iron-beryllia alloys

Two BeO dispersed iron alloys containing about 2.5 and 5.5 v/o dispersoid were produced by attritting, internally oxidizing, and extruding dilute, prealloyed Fe-Be powders. As-extruded alloys were given various thermomechanical treatments involving room temperature swaging and annealing above and below the allotropic transformation temperature. The elevated temperature rupture strengths were measured and correlated with changes in structure; strengthening trends were examined in the light of proposed models for such strengthening. The results obtained showed that the elevated temperature strength was determined by the oxide interparticle spacing (IPS) in recrystallized material and IPS as well as prior deformation in swaged specimens. In fact, a parametric correlation was found between rupture strength values in the longitudinal direction with prestrain during swaging. The overall pattern in strength and microstructural observations were more consistent with a strength-stored energy (substructure) dependence than a strength-grain shape (grain aspect ratio) relation.

Wolf, S.↗

Characterizing the vertical structure of forests in the Brazilian Amazon

Little is known about the structure of tropical forests despite its critical role in the provisioning of ecosystem services. Here we assess the vertical structure of forests in the Brazilian Amazon with a large-scale airborne LiDAR dataset. We show that fire has greater impact in the lowest forest strata, differently from selective logging and windthrow. We also find that secondary forests quickly recover or even exceed reference areas at the 1-10 m height stratum but that full recovery for the 20-30 m height stratum has not been achieved even after 35 years. Our modeling results suggest that proximity to roads, elevation, precipitation, soil pH, and proportion of sand in the soil are the most important predictors of forest structure. Finally, we identify 5 forest structural types (FSTs) and use them to visualize the spatial distribution of forest structure. This study provides important information for forest monitoring, management, and conservation.

Biogeography↗