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At least 793 records · Page 44

New approach to hyperfine structure - Application to the Li ground state

Global identities for delta functions, given by Hiller, Sucher and Feinberg (HSF) are applied to the calculation of the hyperfine structure (HFS) of the ground state of Li. It is shown that use of the HSF identity together with configuration interaction type wavefunctions can yield values of the HFS constant f which are comparable in accuracy to that obtained by Larsson with a 100-term Hylleraas-type wavefunction. The implications of this result for HFS calculations for atoms with many electrons are discussed.

Bhatia, A. K.↗

Polarization asymmetry in two-electron photodetachment - A cogent test of the ionization threshold law

A very sensitive test of the electron-atom ionization threshold law is suggested: for spin-aligned heavy negative ions it consists of measuring the polarization asymmetry A(PA) coming from double detachment by left- versus right-circularly polarized light. The respective yields are worked out for the Te(-) (5p)5 2P(3/2) ion. The Coulomb-dipole theory predicts A(PA) to be the ratio of two oscillating functions in sharp contrast to any power law (specifically that of Wannier, 1953) for which the ratio is expected to be a smooth function of energy.

Temkin, A.↗

Measuring Transmission Efficiencies Of Mass Spectrometers

Coincidence counts yield absolute efficiencies. System measures mass-dependent transmission efficiencies of mass spectrometers, using coincidence-counting techniques reminiscent of those used for many years in calibration of detectors for subatomic particles. Coincidences between detected ions and electrons producing them counted during operation of mass spectrometer. Under certain assumptions regarding inelastic scattering of electrons, electron/ion-coincidence count is direct measure of transmission efficiency of spectrometer. When fully developed, system compact, portable, and used routinely to calibrate mass spectrometers.

Srivastava, Santosh K.↗

Introduction to dissociative recombination

Dissociative recombination (DR) of molecular ions with electrons has important consequences in many areas of physical science. Ab-initio calculations coupled with resonant scattering theory and multichannel quantum defect studies have produced detailed results illuminating the role of ion vibrational excitation, the quantum yields of the DR products, and the role of Rydberg states. The theoretical and experimental results are discussed.

Guberman, Steven L.↗

Coherent Doppler Wind Lidar Technology for Space Based Wind Measurements Including SPARCLE

It has been over 30 years since coherent lidar systems first measured wind velocity, and over 20 years since the "ultimate application" of measuring Earth's winds from space was conceived. Coherent or heterodyne optical detection involves the combination (or mixing) of the returned optical field with a local oscillator (LO) laser's optical field on the optical detector. This detection technique yields the benefits of dramatically improved signal-to-noise ratios; insensitivity to detector noise, background light and multiply scattered light; reduction of the returned signal's dynamic range; and preservation of the optical signal spectrum for electronic and computer processing. (Note that lidar systems are also referred to as optical radar, laser radar, and LADAR systems.) Many individuals, agencies, and countries have pursued the goal of space-based wind measurements through technology development, experiments, field campaigns and studies.

Kavaya, Michael J.↗

Combinatorial Optimization of Heterogeneous Catalysts Used in the Growth of Carbon Nanotubes

Libraries of liquid-phase catalyst precursor solutions were printed onto iridium-coated silicon substrates and evaluated for their effectiveness in catalyzing the growth of multi-walled carbon nanotubes (MWNTs) by chemical vapor deposition (CVD). The catalyst precursor solutions were composed of inorganic salts and a removable tri-block copolymer (EO)20(PO)70(EO)20 (EO = ethylene oxide, PO = propylene oxide) structure-directing agent (SDA), dissolved in ethanol/methanol mixtures. Sample libraries were quickly assayed using scanning electron microscopy after CVD growth to identify active catalysts and CVD conditions. Composition libraries and focus libraries were then constructed around the active spots identified in the discovery libraries to understand how catalyst precursor composition affects the yield, density, and quality of the nanotubes. Successful implementation of combinatorial optimization methods in the development of highly active, carbon nanotube catalysts is demonstrated, as well as the identification of catalyst formulations that lead to varying densities and shapes of aligned nanotube towers.

Cassell, Alan M.↗

Tentative Identification of Interstellar CS by UV Absorption in the C-X Transition

Current chemical models of translucent clouds imply that sulfur is depleted with respect to its average abundance in diffuse clouds as determined by Morton (1975 ApJ,197, 85) by factors exceeding 10. Existing gigahertz emission observations yield sizable uncertainties in the column densities to background stars, and attempts to measure column densities of CS in the lines-of-sight to various stars through the absorption in the A-X (0,0) electronic transition near 257.6 nm have been unsuccessful. CS dissociates primarily through discrete absorptions into predissociating states. In analogy with CO the strongest of these is the C-X band found near 140.0 nm. We report the tentative identification of the C-X band of CS in the interstellar spectra of HD 24398 (zeta Per), HD 148184 (chi Oph), and HD 154368. The estimated column densities will be compared to the predictions of prevailing chemical models.

Smith, Andrew↗

Porous cobalt spheres for high temperature gradient magnetically assisted fluidized beds

Porous metallic cobalt spheres have been prepared as high temperature capable media for employment in gradient magnetically assisted fluidization and filtration technologies. Cobalt impregnated alginate beads are first formed by extrusion of an aqueous suspension of Co3O4 into a Co(II) chloride solution. The organic polymer is thermally decomposed yielding cobalt oxide spheres, followed by reduction to the metallic state, and densification. Cobalt beads have been produced with porosities ranging between 10 and 50%, depending upon sintering conditions. The product media have been characterized by scanning electron microscopy (SEM), nitrogen adsorption porosimetry, and vibrating sample magnetometry. c2003 Elsevier Science Ltd. All rights reserved.

NASA Discipline Life Support Systems↗

Curved Diffractive X-ray Optics for X-ray Astronomy

We report on a concept for curved diffractive X-ray optics (CDXO). CDXO would enable potential new optical designs for X-ray instruments, such as a two element spectrometer, in which the secondary element of an X-ray mirror pair is patterned with an X-ray grating. A two-element spectrometer design eliminates the grating assembly, resulting in decreased instrument mass and reduced power requirements. In addition, a two-element spectrometer may realize cost/schedule savings by eliminating a separate grating alignment effort, and yield increased effective area over three element designs. We present a raytrace concept study of a two-element spectrometer compact enough to fit within a sounding rocket payload. We also review the progress made in electron-beam lithography (EBL) techniques that would enable curved diffractive X-ray optics to be patterned, and outline a procedure by which the accuracy of the EBL patterning process can be measured interferometrically.

Casey T. DeRoo↗

Quick and Correlative TOF-SIMS Analysis of Dispersoid Content in Powder Feedstock and Printed Oxide Dispersion Strengthened Alloys

Oxide dispersion strengthening (ODS) of metal alloys, when combined with additive manufacturing (AM), can be used to solve high-temperature material application problems. The performance of ODS materials is dependent on nano-scale oxide being distributed uniformly throughout the metal matrix; a homogenous distribution is critical to the creep and yield strength. Therefore, quantifying and analyzing these oxide nanoparticles is essential for ODS alloy development. Assessing the chemistry and morphology of dispersoids in a material can be conducted using a variety of X-ray and electron-based methods. Time of Flight Secondary Ion Mass Spectrometry (TOF-SIMS), which assesses chemical concentrations from ion masses, provides the necessary spatial resolution and avoids potential spectral overlap of all elements present. In this work, preparing ODS powder feedstock and Laser Powder Bed Fusion AM was conducted with a NiCoCr alloy and yttria dispersoid, mixed with a Resodyn resonance mixer and printed on an EOS M100 3D printer at NASA Glenn. TOF-SIMS was performed on a Physical Electronics NanoTOF TRIFT V TOF-SIMS at Case Western Reserve University. The TOF-SIMS results collected on the feedstock powder samples correspond to the qualitative interpretation of the homogeneity of the oxide coating on the metal powder from SEM images. This provides quantitative support to the qualitative microscopy images collected earlier in the process design phase. The variance in the yttrium distribution on the powder feedstock samples also correlated with the variance of the yttrium distribution detected in the printed samples. This correlation supported the hypothesis that an even coating of yttria on the metal powders contributes to an even distribution of yttria in the printed material.

Laura G. Wilson↗

A Global Map of Mars' Crustal Magnetic Field Based on Electron Reflectometry

One of the great surprises of the Mars Global Surveyor mission was the discovery of intensely magnetized crust. Magnetic sources on Mars are at least ten times stronger than their terrestrial counterparts, probably requiring large volumes of coherently magnetized material, very strong remanence, or both. Although much of the attention so far has been placed on the strong crustal fields in the southern highlands, magnetic sources do exist in the younger low-lying plains. The strength and morphology of these sources could yield clues to the thermal and magnetic history of the northern plains. Low altitude (approx. 100 km) Magnetometer (MAG) data obtained during aerobraking have the greatest spatial resolution and sensitivity for identifying crustal magnetic sources from orbit, but those data are sparse and therefore limit the ability to discern morphology. Fully sampled MAG data obtained in the 400-km altitude mapping orbit have been differenced with respect to latitude (Br/Lat) to minimize the influence of induced fields from the solar wind interaction and thus enhance the sensitivity to weak crustal sources. Here we describe independent results from the Electron Reflectometer (ER), which remotely measures the magnetic field intensity at approx. 170 km altitude, and is roughly seven times more sensitive to crustal magnetic sources than measurements of Br from the mapping orbit.

Mitchell, D. L.↗

Assessments of Hollow Cathode Wear in the Xenon Ion Propulsion System (XIPs(c)) by Numerical Analyses and Wear Tests

The standard approach presently followed by NASA to qualify electric propulsion for the required mission throughput has been based largely on life tests, which can be costly and time consuming. Revised electric propulsion lifequalification approaches are being formulated that combine analytical and/or computational methods with (shorter-duration) wear tests. As a model case, a wear test is being performed at JPL to assess the lifetime of the discharge hollow cathode in the Xenon Ion Propulsion System (XIPS(c)), a 25-cm ion engine developed by L-3 Communications Electron Technologies, Inc. for commercial applications. Wear and plasma data accumulated throughout this life-assessment program are being used to validate the existing 2-D hollow cathode code OrCa2D. We find that the OrCa2D steady-state solution predicts very well the time-averaged plasma data and the keeper voltage after 5500 hrs of operation in high-power mode. When the wave motion that occurs naturally in these devices is accounted for, based on an estimate of the maximum wave amplitude, the molybdenum-keeper erosion profile observed in the XIPS(c) discharge cathode is also reproduced within a factor of two of the observation. When the same model is applied to predict the erosion of a tantalum keeper we find that erosion is reduced by more than two orders of magnitude compared to the molybdenum keeper due the significantly lower sputtering yield of tantalum. A tantalum keeper would therefore allow keeper lifetimes that greatly exceed the present requirements for deep-space robotic missions considered by NASA. Moreover, such large reduction of the erosion renders the largest uncertainties in the models, which are associated with the wave amplitude estimates and the electron transport model, negligible.

plasma simulations↗

Theory of a cylindrical probe in a collisionless magnetoplasma

A theory is presented for a cylindrical electrostatic probe in a collisionless plasma in the case where the probe axis is inclined at an angle to a uniform magnetic field. The theory is applicable to electron collection, and under more restrictive conditions, to ion collection. For a probe at space potential, the theory is exact in the limit where probe radius is much less than Debye length. At attracting probe potentials, the theory yields an upper bound and an adiabatic limit for current collection. At repelling probe potentials, it provides a lower bound. The theory is valid if the ratios of probe radius to Debye length and probe radius to mean gyroradius are not simultaneously large enough to produce extrema in the probe sheath potential. The numerical current calculations are based on the approximation that particle orbits are helices near the probe, together with the use of kinetic theory to relate velocity distributions near the probe to those far from it. Probe characteristics are presented for inclination angles from 0 to 90 deg and for probe-radius mean-gyroradius ratios from 0.1 to infinity. For an angle of 0 deg, the end-effect current is calculated separately.

Laframboise, J. G.↗

Shallow-homojunction GaAs solar cells

Single-crystal GaAs shallow-homojunction solar cells on GaAs or Ge substrates, without Ga sub 1-x Al sub x As window layers, that have conversion efficiencies exceeding 20% at AM1 (17% at AMO). Using a simple theoretical model, good fits were obtained between computer calculations and experimental data for external quantum efficiency and conversion efficiency of cells with different values of n+ layer thickness. The calculations not only yield values for material properties of the GaAs layers composing the cells but will also permit the optimization of cell designs for space and terrestrial applications. Preliminary measurements indicate that the shallow-homojunction cells are resistant to electron irradiation. In the best test so far, bombardment with 1 x 10 to the 16th power/sq cm fluence of 1 MeV electrons reduced the short-circuit current by only about 6%.

Fan, J. C. C.↗

X-ray spectra of A0620-00 obtained with a Bragg crystal spectrometer

The OSO 8 graphite crystal spectrometer was used to obtain observations, in October 1975 and January 1976, of the transient X-ray source A0620-00, which yield upper limits of no more than about 10 eV to the equivalent widths of narrow emission lines of Si XIII, Si XIV, S XV, and S XVI. Photoionization is unlikely to alter the principal conclusion that the electron scattering in the source is substantial. High-resolution spectra obtained in October 1975 reveal a featureless continuum which is better characterized as blackbody (kT about 0.5 keV) than as thin bremsstrahlung emission.

Long, K. S.↗

Signatures of current loop coalescence in solar flares

The nonlinear coalescence instability of current carrying solar loops can explain many of the characteristics of the solar flares such as their impulsive nature, heating and high energy particle acceleration, amplitude oscillations of electromagnetic emission as well as the characteristics of 2-D microwave images obtained during a solar flare. The physical characteristics of the explosive coalescence of currents are presented in detail through computer simulation and theory. Canonical characteristics of the explosive coalescence are: (1) a large amount of impulsive increase of kinetic energies of electrons and ions; (2) simultaneous heating and acceleration of electrons and ions in high and low energy spectra; (3) ensuing quasi-periodic amplitude oscillations in fields and particle quantities; and (4) the double peak (or triple peak) structure in these profiles, participate in the coalescence process, yielding varieties of phenomena.

Sakai, J.↗

Radiation and temperature effects in gallium arsenide, indium phosphide and silicon solar cells

The effects of radiation on performance are determined for both n(+)p and p(+)n GaAs and InP cells and for silicon n(+)p cells. It is found that the radiation resistance of InP is greater than that of both GaAs and Si under 1 MeV electron irradiation. For silicon, the observed decreased radiation resistance with decreased resistivity is attributed to the presence of a radiation induced boron-oxygen defect. Comparison of radiation damage in both p(+)n and n(+)p GaAs cells yields a decreased radiation resistance for the n(+)p cell attributable to increased series resistance, decreased shunt resistance, and relatively greater losses in the cell's p-region. For InP, the n(+)p configuration is found to have greater radiation resistance than the p(+)n cell. The increased loss in this latter cell is attributed to losses in the cell's emitter region. Temperature dependency results are interpreted using a theoretical relation for dVoc/cT which predicts that increased Voc should results in decreased numerical values for dPm/dT. The predicted correlation is observed for GaAs but not for InP a result which is attributed to variations in cell processing.

Weinberg, I.↗

Transverse deflection and dissipation of small plasma beams and clouds in magnetized media

Propagation of a quasi-neutral plasma beam or cloud across a magnetic field is considered for the case where the transverse dimension of the beam or cloud is sufficiently small compared to ion gyroradii. This situation commonly arises for active experiments in near-earth space. Two mechanisms are presented for transverse deflection of a beam or cloud in the -v0 x B0 direction where v0 is the velocity relative to the ambient medium. In the first, asymmetric escape of ions from an electrically polarized beam or cloud causes transverse deflection by means of a rocket effect. The transverse deflection distance is estimated to be a few times the initial transverse dimension of the beam or cloud. Dissipation occurs within a few times the thermal ion transverse crossing time. In the second mechanism, asymmetric charging results from localized accumulation of incident ions from the ambient medium. This excess positive charge distorts electric equipotentials and drives electron Hall currents that maintain an asymmetric compressed magnetic field region. The asymmetry of the magnetic stress contributes to transverse deflection with the same sign as the rocket effect. The asymmetric magnetic field also focuses incident ions to yield the localized charge accumulation. These ideas are qualitatively consistent with observations of the Active Magnetospheric Particle Tracer Explorers artificial comet releases.

Cheng, Andrew F.↗