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RhSn2 is Khatyrkite-like structured and crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. Rh is bonded in a 10-coordinate geometry to eight equivalent Sn atoms. All Rh–Sn bond lengths are 2.83 Å. Sn is bonded in a 4-coordinate geometry to four equivalent Rh atoms.
EuCu4Sn2 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. Eu is bonded in a 8-coordinate geometry to eight equivalent Cu atoms. All Eu–Cu bond lengths are 3.77 Å. Cu is bonded in a 9-coordinate geometry to two equivalent Eu, three equivalent Cu, and four equivalent Sn atoms. There are one shorter (3.05 Å) and two longer (3.08 Å) Cu–Cu bond lengths. There are a spread of Cu–Sn bond distances ranging from 3.11–3.22 Å. Sn is bonded in a 8-coordinate geometry to eight equivalent Cu atoms.
LiRh3 crystallizes in the orthorhombic Imm2 space group. The structure is three-dimensional. Li is bonded in a 12-coordinate geometry to ten Rh atoms. There are a spread of Li–Rh bond distances ranging from 2.61–2.74 Å. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded to four equivalent Li atoms to form a mixture of distorted edge and corner-sharing RhLi4 cuboctahedra. In the second Rh site, Rh is bonded in a 12-coordinate geometry to three equivalent Li atoms.
Rb2Mo15S19 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Rb1+ is bonded in a 7-coordinate geometry to seven S2- atoms. There are a spread of Rb–S bond distances ranging from 3.56–3.68 Å. There are three inequivalent Mo+2.40+ sites. In the first Mo+2.40+ site, Mo+2.40+ is bonded to four S2- atoms to form MoS4 trigonal pyramids that share corners with three equivalent MoS6 octahedra, corners with two equivalent MoS5 square pyramids, corners with three equivalent MoS4 trigonal pyramids, an edgeedge with one MoS5 square pyramid, and a faceface with one MoS5 square pyramid. The corner-sharing octahedra tilt angles range from 30–64°. There are a spread of Mo–S bond distances ranging from 2.29–2.43 Å. In the second Mo+2.40+ site, Mo+2.40+ is bonded to five S2- atoms to form distorted MoS5 square pyramids that share a cornercorner with one MoS6 octahedra, corners with two equivalent MoS4 trigonal pyramids, edges with four equivalent MoS5 square pyramids, an edgeedge with one MoS4 trigonal pyramid, and a faceface with one MoS4 trigonal pyramid. The corner-sharing octahedral tilt angles are 54°. There are a spread of Mo–S bond distances ranging from 2.41–2.75 Å. In the third Mo+2.40+ site, Mo+2.40+ is bonded to six S2- atoms to form MoS6 octahedra that share corners with two equivalent MoS5 square pyramids, corners with six equivalent MoS4 trigonal pyramids, and faces with two equivalent MoS6 octahedra. There are a spread of Mo–S bond distances ranging from 2.43–2.53 Å. There are five inequivalent S2- sites. In the first S2- site, S2- is bonded in a 5-coordinate geometry to one Rb1+ and four Mo+2.40+ atoms. In the second S2- site, S2- is bonded in a 7-coordinate geometry to one Rb1+ and three equivalent Mo+2.40+ atoms. In the third S2- site, S2- is bonded in a 3-coordinate geometry to six Mo+2.40+ atoms. In the fourth S2- site, S2- is bonded in a 4-coordinate geometry to one Rb1+ and three Mo+2.40+ atoms. In the fifth S2- site, S2- is bonded in a 4-coordinate geometry to four Mo+2.40+ atoms.
Gd2IFe2 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Gd is bonded in a 9-coordinate geometry to six equivalent Fe and three equivalent I atoms. There are three shorter (2.88 Å) and three longer (3.00 Å) Gd–Fe bond lengths. All Gd–I bond lengths are 3.40 Å. Fe is bonded in a 9-coordinate geometry to six equivalent Gd and three equivalent Fe atoms. All Fe–Fe bond lengths are 2.30 Å. I is bonded in a 6-coordinate geometry to six equivalent Gd atoms.
TaSn2 is Khatyrkite-like structured and crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. Ta is bonded in a 10-coordinate geometry to two equivalent Ta and eight Sn atoms. Both Ta–Ta bond lengths are 2.86 Å. There are a spread of Ta–Sn bond distances ranging from 2.89–2.99 Å. There are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a 4-coordinate geometry to four equivalent Ta atoms. In the second Sn site, Sn is bonded in a 4-coordinate geometry to four equivalent Ta atoms.
Pr2INi2 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Pr is bonded in a 9-coordinate geometry to six equivalent Ni and three equivalent I atoms. There are three shorter (2.99 Å) and three longer (3.01 Å) Pr–Ni bond lengths. All Pr–I bond lengths are 3.46 Å. Ni is bonded in a 9-coordinate geometry to six equivalent Pr and three equivalent Ni atoms. All Ni–Ni bond lengths are 2.36 Å. I is bonded in a 6-coordinate geometry to six equivalent Pr atoms.
LaPt crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. La2+ is bonded in a 7-coordinate geometry to seven equivalent Pt2- atoms. There are a spread of La–Pt bond distances ranging from 3.03–3.22 Å. Pt2- is bonded in a 7-coordinate geometry to seven equivalent La2+ atoms.
LaPd crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. La is bonded in a 7-coordinate geometry to seven equivalent Pd atoms. There are a spread of La–Pd bond distances ranging from 3.09–3.17 Å. Pd is bonded in a 7-coordinate geometry to seven equivalent La atoms.
In7Pd3 crystallizes in the cubic Im-3m space group. The structure is three-dimensional. Pd is bonded in a 8-coordinate geometry to eight In atoms. There are four shorter (2.82 Å) and four longer (2.84 Å) Pd–In bond lengths. There are two inequivalent In sites. In the first In site, In is bonded in a 8-coordinate geometry to four equivalent Pd atoms. In the second In site, In is bonded in a 3-coordinate geometry to three equivalent Pd atoms.
IrV is alpha iridium vanadium structured and crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. V is bonded in a 9-coordinate geometry to one V and eight equivalent Ir atoms. The V–V bond length is 2.38 Å. All V–Ir bond lengths are 2.66 Å. Ir is bonded in a 8-coordinate geometry to eight equivalent V atoms.
Sr(OsP)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Sr2+ is bonded in a 8-coordinate geometry to eight equivalent Os2- atoms. All Sr–Os bond lengths are 3.49 Å. Os2- is bonded in a 12-coordinate geometry to four equivalent Sr2+ and four equivalent P1+ atoms. All Os–P bond lengths are 2.35 Å. P1+ is bonded in a 4-coordinate geometry to four equivalent Os2- atoms.
ZrSb is alpha-derived structured and crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Zr3+ is bonded in a 7-coordinate geometry to seven equivalent Sb3- atoms. There are a spread of Zr–Sb bond distances ranging from 2.96–3.14 Å. Sb3- is bonded in a 7-coordinate geometry to seven equivalent Zr3+ atoms.
Sr2NI is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. The structure is three-dimensional. Sr2+ is bonded in a 6-coordinate geometry to three equivalent N3- and three equivalent I1- atoms. All Sr–N bond lengths are 2.68 Å. All Sr–I bond lengths are 3.48 Å. N3- is bonded to six equivalent Sr2+ atoms to form edge-sharing NSr6 octahedra. I1- is bonded in a 6-coordinate geometry to six equivalent Sr2+ atoms.
UPt crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. U is bonded in a 5-coordinate geometry to seven equivalent Pt atoms. There are a spread of U–Pt bond distances ranging from 2.79–3.12 Å. Pt is bonded in a 5-coordinate geometry to seven equivalent U atoms.
YbPt crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Yb2+ is bonded in a 7-coordinate geometry to seven equivalent Pt2- atoms. There are a spread of Yb–Pt bond distances ranging from 2.92–3.02 Å. Pt2- is bonded in a 7-coordinate geometry to seven equivalent Yb2+ atoms.
Pr4Ge3 crystallizes in the cubic I-43d space group. The structure is three-dimensional. Pr is bonded in a 6-coordinate geometry to six equivalent Ge atoms. There are three shorter (3.04 Å) and three longer (3.38 Å) Pr–Ge bond lengths. Ge is bonded in a 8-coordinate geometry to eight equivalent Pr atoms.
Pr3Pt4 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Pr is bonded in a 9-coordinate geometry to nine Pt atoms. There are a spread of Pr–Pt bond distances ranging from 2.95–3.42 Å. There are three inequivalent Pt sites. In the first Pt site, Pt is bonded in a 6-coordinate geometry to six equivalent Pr atoms. In the second Pt site, Pt is bonded in a 10-coordinate geometry to seven equivalent Pr and three equivalent Pt atoms. There are one shorter (2.95 Å) and two longer (3.05 Å) Pt–Pt bond lengths. In the third Pt site, Pt is bonded in a 6-coordinate geometry to six equivalent Pr atoms.