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At least 793 records · Page 44

Densified vertically lamellar electrode architectures for compact energy storage

As one of the most compact electrochemical energy storage systems, lithium-ion batteries (LIBs) are playing an indispensable role in the process of vehicle electrification to accelerate the shift to sustainable mobility. Making battery electrodes thicker is a promising strategy for improving the energy density of LIBs which is essential for applications with weight or volume constraints, such as electric-powered transportation; however, their power densities are often significantly restricted due to elongated and tortuous charge traveling distances. Here, we propose an effective methodology that couples bidirectional freeze-casting and compression-induced densification to create densified vertically lamellar electrode architectures for compact energy storage. The vertically lamellar architectures not only overcome the critical thickness limit for conventional electrodes but also facilitate and redistribute the lithium-ion flux enabling both high rate capability and stable cyclability. Furthermore, this proposed methodology is universal as demonstrated in various electrochemical active material systems. This study offers a facile approach that realizes simultaneous high energy and high power in high-loading battery electrodes and provides useful rationales in designing electrode architectures for scalable energy storage systems.

42 ENGINEERING↗

LOW-MASS PLANETS IN PROTOPLANETARY DISKS WITH NET VERTICAL MAGNETIC FIELDS: THE PLANETARY WAKE AND GAP OPENING

Some regions in protoplanetary disks are turbulent, while some regions are quiescent (e.g. the dead zone). In order to study how planets open gaps in both inviscid hydrodynamic disk (e.g. the dead zone) and the disk subject to magnetorotational instability (MRI), we carried out both shearing box two-dimensional inviscid hydrodynamical simulations and three-dimensional unstratified magnetohydrodynamical (MHD) simulations (having net vertical magnetic fields) with a planet at the box center. We found that, due to the nonlinear wave steepening, even a low mass planet can open gaps in both cases, in contradiction to the ''thermal criterion'' for gap opening. In order to understand if we can represent the MRI turbulent stress with the viscous {alpha} prescription for studying gap opening, we compare gap properties in MRI-turbulent disks to those in viscous HD disks having the same stress, and found that the same mass planet opens a significantly deeper and wider gap in net vertical flux MHD disks than in viscous HD disks. This difference arises due to the efficient magnetic field transport into the gap region in MRI disks, leading to a larger effective {alpha} within the gap. Thus, across the gap, the Maxwell stress profile is smoother than the gap density profile, and a deeper gap is needed for the Maxwell stress gradient to balance the planetary torque density. Comparison with previous results from net toroidal flux/zero flux MHD simulations indicates that the magnetic field geometry plays an important role in the gap opening process. We also found that long-lived density features (termed zonal flows) produced by the MRI can affect planet migration. Overall, our results suggest that gaps can be commonly produced by low mass planets in realistic protoplanetary disks, and caution the use of a constant {alpha}-viscosity to model gaps in protoplanetary disks.

79 ASTRONOMY AND ASTROPHYSICS↗

A SPATIALLY RESOLVED VERTICAL TEMPERATURE GRADIENT IN THE HD 163296 DISK

We analyze sensitive, sub-arcsecond resolution ALMA science verification observations of CO emission lines in the protoplanetary disk hosted by the young, isolated Ae star HD 163296. The observed spatial morphology of the {sup 12}CO J = 3-2 emission line is asymmetric across the major axis of the disk; the {sup 12}CO J = 2-1 line features a much less pronounced, but similar, asymmetry. The J = 2-1 emission from {sup 12}CO and its main isotopologues have no resolved spatial asymmetry. We associate this behavior with the direct signature of a vertical temperature gradient and layered molecular structure in the disk. This is demonstrated using both toy models and more sophisticated calculations assuming non-local thermodynamic equilibrium conditions. A model disk structure is developed to reproduce both the distinctive spatial morphology of the {sup 12}CO J = 3-2 line as well as the J = 2-1 emission from the CO isotopologues assuming relative abundances consistent with the interstellar medium. This model disk structure has {tau} = 1 emitting surfaces for the {sup 12}CO emission lines that make an angle of {approx}15 Degree-Sign with respect to the disk midplane. Furthermore, we show that the spatial and spectral sensitivity of these data can distinguish between models that have sub-Keplerian gas velocities due to the vertical extent of the disk and its associated radial pressure gradient (a fractional difference in the bulk gas velocity field of {approx}> 5%)

79 ASTRONOMY AND ASTROPHYSICS↗

Radial transport of large-scale magnetic fields in accretion disks. I. Steady solutions and an upper limit on the vertical field strength

Large-scale magnetic fields are key ingredients of magnetically driven disk accretion. We study how large-scale poloidal fields evolve in accretion disks, with the primary aim of quantifying the viability of magnetic accretion mechanisms in protoplanetary disks. We employ a kinematic mean-field model for poloidal field transport and focus on steady states where inward advection of a field balances with outward diffusion due to effective resistivities. We analytically derive the steady-state radial distribution of poloidal fields in highly conducting accretion disks. The analytic solution reveals an upper limit on the strength of large-scale vertical fields attainable in steady states. Any excess poloidal field will diffuse away within a finite time, and we demonstrate this with time-dependent numerical calculations of the mean-field equations. We apply this upper limit to large-scale vertical fields threading protoplanetary disks. We find that the maximum attainable strength is about 0.1 G at 1 AU, and about 1 mG at 10 AU from the central star. When combined with recent magnetic accretion models, the maximum field strength translates into the maximum steady-state accretion rate of ∼10{sup –7} M {sub ☉} yr{sup –1}, in agreement with observations. We also find that the maximum field strength is ∼1 kG at the surface of the central star provided that the disk extends down to the stellar surface. This implies that any excess stellar poloidal field of strength ≳ kG can be transported to the surrounding disk. This might in part resolve the magnetic flux problem in star formation.

79 ASTRONOMY AND ASTROPHYSICS↗

The vertical metallicity gradient of the Milky Way disk: transitions in [α/Fe] populations

Using G dwarfs from the Sloan Extension for Galactic Understanding and Exploration (SEGUE) survey, we have determined the vertical metallicity gradient in the Milky Way's disk and examined how this gradient varies for different [α/Fe] subsamples. Our sample contains over 40,000 stars with low-resolution spectroscopy over 144 lines of sight. It also covers a significant disk volume, between ∼0.3 and 1.6 kpc from the Galactic plane, and allows us to examine the disk in situ, whereas previous analyses were more limited in scope. Furthermore, this work does not presuppose a disk structure, whether composed of a single complex population or distinct thin and thick disk components. We employ the SEGUE Stellar Parameter Pipeline to obtain estimates of stellar parameters, [Fe/H], and [α/Fe] and extract multiple volume-complete subsamples of approximately 1000 stars each. Based on SEGUE's target-selection algorithm, we adjust each subsample to determine an unbiased picture of disk chemistry; consequently, each individual star represents the properties of many. The metallicity gradient is –0.243{sub −0.053}{sup +0.039} dex kpc{sup –1} for the entire sample, which we compare to various literature results. This gradient stems from the different [α/Fe] populations inhabiting different ranges of height above the Galactic plane. Each [α/Fe] subsample shows little change in median [Fe/H] with height. If we associate [α/Fe] with age, the negligible gradients of our [α/Fe] subsamples suggest that stars formed in different epochs exhibit comparable vertical structure, implying similar star formation processes and evolution.

79 ASTRONOMY AND ASTROPHYSICS↗

Type I planet migration in a magnetized disk. II. Effect of vertical angular momentum transport

We study the effects of a large-scale, ordered magnetic field in protoplanetary disks on Type I planet migration using a linear perturbation analysis in the ideal-magnetohydrodynamic limit. We focus on wind-driving disks, in which a magnetic torque ∝B{sub 0z}∂B{sub 0φ}/∂z (where B{sub 0z} and B{sub 0φ} are the equilibrium vertical and azimuthal field components) induces vertical angular momentum transport. We derive the governing differential equation for the disk response and identify its resonances and turning points. For a disk containing a slightly subthermal, pure-B{sub 0z} field, the total three-dimensional torque is close to its value in the two-dimensional (2D) limit, but remains lower than the hydrodynamic torque. In contrast with the 2D pure-B{sub 0φ} field model considered by Terquem, inward migration is not reduced when the field amplitude decreases with radius. The presence of a subdominant B{sub 0φ} component whose amplitude increases from zero at z = 0 has little effect on the torque when acting alone, but in conjunction with a B{sub 0z} component it gives rise to a strong torque that speeds up the inward migration by a factor ≳200. This factor could, however, be reduced in a real disk by dissipation and magnetic diffusivity effects. Unlike all previously studied disk migration models, in the B{sub 0z}+∂B{sub 0φ}/∂z case the dominant contributions to the torque add with the same sign from the two sides of the planet. We attribute this behavior to a new mode of interaction wherein a planet moves inward by plugging into the disk’s underlying angular momentum transport mechanism.

79 ASTRONOMY AND ASTROPHYSICS↗

ON VERTICALLY GLOBAL, HORIZONTALLY LOCAL MODELS FOR ASTROPHYSICAL DISKS

Disks with a barotropic equilibrium structure, for which the pressure is only a function of the density, rotate on cylinders in the presence of a gravitational potential, so that the angular frequency of such a disk is independent of height. Such disks with barotropic equilibria can be approximately modeled using the shearing box framework, representing a small disk volume with height-independent angular frequency. If the disk is in baroclinic equilibrium, the angular frequency does generally depend on height, and it is thus necessary to go beyond the standard shearing box approach. In this paper, we show that given a global disk model, it is possible to develop approximate models that are local in horizontal planes without an expansion in height with shearing-periodic boundary conditions. We refer to the resulting framework as the vertically global shearing box (VGSB). These models can be non-axisymmetric for globally barotropic equilibria but should be axisymmetric for globally baroclinic equilibria. We provide explicit equations for this VGSB which can be implemented in standard magnetohydrodynamic codes by generalizing the shearing-periodic boundary conditions to allow for a height-dependent angular frequency and shear rate. We also discuss the limitations that result from the radial approximations that are needed in order to impose height-dependent shearing periodic boundary conditions. We illustrate the potential of this framework by studying a vertical shear instability and examining the modes associated with the magnetorotational instability.

79 ASTRONOMY AND ASTROPHYSICS↗

Ferromagnetic resonance in single vertices and 2D lattices macro-dipoles of elongated nanoelements: measurements and simulations

We report broadband ferromagnetic resonance measurements of the in-plane magnetic field response of three- and four-fold symmetric vertices formed by non-contacting permalloy nano-ellipses together with extended lattices constructed from them. Complementing the experimental data with simulations, we are able to show that, as far as the most intense FMR responses are concerned, the spectra of vertices and lattices can largely be interpreted in terms of a superposition of the underlying hysteretic responses of the individual ellipses, as elemental building blocks of the system. Here, this property suggest that it is possible to understand the orientation of the individual magnetic dipole moments in a dipole network in terms of dynamic measurements alone, thereby offering a powerful tool to analyze the alignment statistics in frustrated systems that are exposed to various magnetic histories.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Fabrication and field emission properties of vertical, tapered GaN nanowires etched via phosphoric acid

The controlled fabrication of vertical, tapered, and high-aspect ratio GaN nanowires via a two-step top-down process consisting of an inductively coupled plasma reactive ion etch followed by a hot, 85% H 3 PO 4 crystallographic wet etch is explored. The vertical nanowires are oriented in the $[0001]$ direction and are bound by sidewalls comprising of $\{33\bar{6}2\}$ semipolar planes which are at a 12° angle from the [0001] axis. High temperature H3PO4 etching between 60 °C and 95 °C result in smooth semipolar faceting with no visible micro-faceting, whereas a 50 °C etch reveals a micro-faceted etch evolution. High-angle annular dark-field scanning transmission electron microscopy imaging confirms nanowire tip dimensions down to 8–12 nanometers. The activation energy associated with the etch process is 0.90 ± 0.09 eV, which is consistent with a reaction-rate limited dissolution process. The exposure of the $\{33\bar{6}2\}$ type planes is consistent with etching barrier index calculations. The field emission properties of the nanowires were investigated via a nanoprobe in a scanning electron microscope as well as by a vacuum field emission electron microscope. Finally, the measurements show a gap size dependent turn-on voltage, with a maximum current of 33 nA and turn-on field of 1.92 V nm -1 for a 50 nm gap, and uniform emission across the array.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Fast calculation of the tokamak vertical instability

There has been recent interest in fast calculations of the tokamak axisymmetric vertical instability for real time feedback control purposes. It is shown that the maximum eigenvalue for the basic rigid version of this stability problem can be obtained by finding the positive root to a simple scalar function. This function can be generalized to include plasma mass and has complexity linear in the number of conductive elements. The formulation is based on standard matrix decompositions of the fixed-geometry part of the eigenproblem. The calculation bottleneck is the summary of mutual inductances from the reconstructed equilibrium current density. The with-mass spectrum can be made fully real-valued by the addition of a critical amount of damping with negligible effect on the vertical growth rate. Furthermore, the calculation has been implemented in the plasma control system at the DIII-D tokamak and used in experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Surface heat flux feedback controlled impurity seeding experiments with Alcator C-Mod's high-Z vertical target plate divertor: performance, limitations and implications for fusion power reactors

The Alcator C-Mod team has recently developed a feedback system to measure and control surface heat flux in real-time. The system uses real-time measurements of surface heat flux from surface thermocouples and a pulse-width modulated piezo valve to inject low-Z impurities (typically N 2 ) into the private flux region. It has been used in C-Mod to mitigate peak surface heat fluxes >40 MW m -2 down to <10 MW m -2 while maintaining excellent core confinement, H 98 > 1. While the system works quite well under relatively steady conditions, use of it during transients has revealed important limitations on feedback control of impurity seeding in conventional vertical target plate divertors. In some cases, the system is unable to avoid plasma reattachment to the divertor plate or the formation of a confinement-damaging x-point MARFE. This is due to the small operational window for mitigated heat flux in the parameters of incident plasma heat flux, plasma density, and impurity density as well as the relatively slow response of the impurity gas injection system compared to plasma transients. Given the severe consequences for failure of such a system to operate reliably in a reactor, there is substantial risk that the conventional vertical target plate divertor will not provide an adequately controllable system in reactor-class devices. Finally, these considerations motivate the need to develop passively stable, highly compliant divertor configurations and experimental facilities that can test such possible solutions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DECAF Cross-device characterization of tokamak disruptions indicated by abnormalities in plasma vertical position and current

Abnormal (deviating from target) variations in the plasma vertical position Z and current I p (such as vertical displacements, transient I p 'spikes' and quenches) constitute common elements of a disruption, a phenomenon that is to be mitigated, or ultimately avoided in future reactor-relevant tokamaks. While those abnormalities are generally recognized cross-shot and cross-device, details in terms of appearance (or not) and order of those abnormalities in disruption event chains is bound with the plasma state at the time of the chain initiation. Detection of those abnormalities is thus indicative not only of the onset of the plasma collapse itself, but also of the disruption driving cause that is promoted at the particular plasma state. Here, occurrence of disruptions, explored via detection of a Ip quench, and analysis of disruption event chains constituted by Ip and Z abnormalities, is reported for in total 7 full years of operation of 3 devices (KSTAR, MAST-U and NSTX-U) using the DECAFTM code expanded tools and capabilities. It is shown that the disruption occurrence depends not only on details of the plasma state, but also on (device-dependent) technical elements of the shot exit scenario. A year-to-year change in main disruption causes and a reduction of the disruptivity rate, bound with device and operation upgrades, are reported. Particular trigger instances of disruption event chains (and the full chains, when applicable) are shown to occupy different parts of the operation space diagrams, in accordance with prior expectation. Plasma elongation is identified as an important factor influencing details of the chains and its role will be further explored.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Roles of non-axisymmetric perturbations in free drift vertical displacement events on EAST

Abstract The safe operation of most tokamaks, especially the large ones, relies on the feedback control of vertical displacement events (VDEs). However, most of these feedback control systems are based on axisymmetric VDE models. In this study, we use NIMROD simulations to study the role of non-axisymmetric perturbations in free drift vertical displacement events on EAST. The high- n modes in the non-axisymmetric VDE grow first, which drives the formation of high- n magnetic island chains. Subsequently, the magnetic island chains grow and overlap with each other, leading to the destruction of the magnetic flux surface, which induces a minor disruption and accelerates the start of the following major disruption. The magnetic island and the stochastic magnetic field allow the toroidally non-axisymmetric poloidal plasma current to jet towards the hoop force direction, forming finger-like and filamentary structures. Such a plasma current non-axisymmetry strongly depends on the anisotropy in the thermal transport coefficients.

Physics↗

Design and testing of the first 2D Prototype Vertically Integrated Pattern Recognition Associative Memory

An associative memory-based track finding approach has been proposed for a Level 1 tracking trigger to cope with increasing luminosities at the LHC. The associative memory uses a massively parallel architecture to tackle the intrinsically complex combinatorics of track finding algorithms, thus avoiding the typical power law dependence of execution time on occupancy and solving the pattern recognition in times roughly proportional to the number of hits. This is of crucial importance given the large occupancies typical of hadronic collisions. The design of an associative memory system capable of dealing with the complexity of HL-LHC collisions and with the short latency required by Level 1 triggering poses significant, as yet unsolved, technical challenges. For this reason, an aggressive R&D program has been launched at Fermilab to advance state of-the-art associative memory technology, the so called VIPRAM (Vertically Integrated Pattern Recognition Associative Memory) project. The VIPRAM leverages emerging 3D vertical integration technology to build faster and denser Associative Memory devices. The first step is to implement in conventional VLSI the associative memory building blocks that can be used in 3D stacking, in other words, the building blocks are laid out as if it is a 3D design. In this paper, we report on the first successful implementation of a 2D VIPRAM demonstrator chip (protoVIPRAM00). The results show that these building blocks are ready for 3D stacking.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

VERTICAL KINK OSCILLATION OF A MAGNETIC FLUX ROPE STRUCTURE IN THE SOLAR CORONA

Vertical transverse oscillations of a coronal magnetic rope, observed simultaneously in the 171 Å and 304 Å bandpasses of the Atmospheric Imaging Assembly on board the Solar Dynamics Observatory (SDO), are detected. The oscillation period is about 700 s and the displacement amplitude is about 1 Mm. The oscillation amplitude remains constant during the observation. Simultaneous observation of the rope in the bandpasses corresponding to the coronal and chromospheric temperatures suggests that it has a multi-thermal structure. Oscillatory patterns in 171 Å and 304 Å are coherent, which indicates that the observed kink oscillation is collective, in which the rope moves as a single entity. We interpret the oscillation as a fundamental standing vertically polarized kink mode of the rope, while the interpretation in terms of a perpendicular fast wave could not be entirely ruled out. In addition, the arcade situated above the rope and seen in the 171 Å bandpass shows an oscillatory motion with the period of about 1000 s.

79 ASTRONOMY AND ASTROPHYSICS↗

EFFECTS OF NITROGEN PHOTOABSORPTION CROSS SECTION RESOLUTION ON MINOR SPECIES VERTICAL PROFILES IN TITAN’S UPPER ATMOSPHERE

The significant variations in both measured and modeled densities of minor species in Titan’s atmosphere call for the evaluation of possible influencing factors in photochemical modeling. The effect of nitrogen photoabsorption cross section selection on the modeled vertical profiles of minor species is analyzed here, with particular focus on C{sub 2}H{sub 6} and HCN. Our results show a clear impact of cross sections used on all neutral and ion species studied. Affected species include neutrals and ions that are not primary photochemical products, including species that do not even contain nitrogen. The results indicate that photochemical models that employ low-resolution cross sections may significantly miscalculate the vertical profiles of minor species. Such differences are expected to have important implications for Titan’s overall atmospheric structure and chemistry.

79 ASTRONOMY AND ASTROPHYSICS↗

Layer and material-type dependent photoresponse in Se 2 /WS 2 vertical heterostructures

Transition metal dichalcogenide (TMD) heterostructures are promising for a variety of applications in photovoltaics and photosensing. Successfully exploiting these heterostructures will require an understanding of their layer-dependent electronic structures. However, there is no experimental data demonstrating the layer-number dependence of photovoltaic effects (PVEs) in vertical TMD heterojunctions. Here, by combining scanning electrochemical cell microscopy (SECCM) with optical probes, we report the first layer-dependence of photocurrents in WSe 2 /WS 2 vertical heterostructures as well as in pristine WS 2 and WSe 2 layers. For WS 2 , we find that photocurrents increase with increasing layer thickness, whereas for WSe 2 the layer dependence is more complex and depends on both the layer number and applied bias (V b ). Further, we find that photocurrents in the WSe 2 /WS 2 heterostructures exhibit anomalous layer and material-type dependent behaviors. Our results advance the understanding of photoresponse in atomically thin WSe 2 /WS 2 heterostructures and pave the way to novel nanoelectronic and optoelectronic devices.

36 MATERIALS SCIENCE↗

Characterization of the Vertical Evolution of the Three-Dimensional Turbulence for Fatigue Design of Tidal Turbines

A system of two coupled four-beam acoustic Doppler current profilers was used to collect turbulence measurements over a 36-h period at a highly energetic tidal energy site in Alderney Race. This system enables the evaluation of the six components of the Reynolds stress tensor throughout a large proportion of the water column. The present study provides mean vertical profiles of the velocity, the turbulence intensity and the integral lengthscale along the streamwise, spanwise and vertical direction of the tidal current.

Alderney Race↗