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At least 793 records · Page 44

Fluid volcanism on Miranda and Ariel - Flow morphology and composition

Several types of volcanic units have been recognized on the icy Uranian satellites Miranda and Ariel. On Miranda, ridges characterized by crest grooves are up to 10 km wide and 500 m high. A continuous flat-topped flow band also 10 km wide and 500 m high forms the outer southern margin of Elsinore Corona, which appears to comprise coalesced flow bands and ridges. On Ariel, in addition to at least one ridge unit similar to those on Miranda, flood plains material has covered the floors of deep chasmata (grabens) and an irregular depression. Flows on both satellites are characterized by linear vent geometries and distinct topographic margins, which indicate extrusion of a relatively viscous material. The topography of the flows can be used to estimate flow viscosity or yield strength using a Bingham plastic model. Extrusion viscosity estimates, incorporating plausible volcanologically based emplacement time scales and a rigid crust correction, range from 10 MP to 1 GP (10 TP in the unlikely absence of a chilled crust). Viscosity estimates are dependent on the assumed emplacement time scale, however, and could be as high as 10 PP, if a solid-state-based time scale is assumed.

Schenk, Paul M.↗

Optical polarization and spectral properties of the hydrogen-poor superluminous supernovae SN 2021bnw and SN 2021fpl

ABSTRACT New optical photometric, spectroscopic, and imaging polarimetry data are combined with publicly available data to study some of the physical properties of the two hydrogen-poor superluminous supernovae (SLSNe) SN 2021bnw and SN 2021fpl. For each SLSN, the best-fitting parameters obtained from the magnetar model with Modular Open-Source Fitter for Transients do not depart from the range of parameter obtained on other SLSNe discussed in the literature. A spectral analysis with SYN++ shows that SN 2021bnw is a W type, fast evolver, while SN 2021fpl is a 15bn type, slow evolver. The analysis of the polarimetry data obtained on SN 2021fpl at four epochs (+1.8, +20.6, +34.1, and +43.0 d, rest frame) shows >3σ polarization detections in the range of 0.8–1 per cent. A comparison of the spectroscopy data suggests that SN 2021fpl underwent a spectral transition a bit earlier than SN 2015bn, during which, similarly, it could have underwent a polarization transition. The analysis of the polarimetry data obtained on SN 2021bnw does not show any departure from symmetry of the photosphere at an empirical diffusion time-scale of ≈2 (+81.1 d rest frame). This result is consistent with those on the sample of W-type SLSN observed at empirical diffusion time-scale ≤ 1 with that technique, even though it is not clear the effect of limited spectral windows varying from one object to the other. Measurements at higher empirical diffusion time-scale may be needed to see any departure from symmetry as it is discussed in the literature for SN 2017egm.

Astronomy & Astrophysics↗

Upper atmosphere dynamics

The spatial distribution of stratospheric ozone is useful in diagnosis of some features of the large scale atmospheric circulation, and the ozone may also interact with the atmospheric general circulation. Local maxima in the column ozone distribution are often associated with disturbances in the lower stratosphere and upper troposphere, which may herald cyclone development in the troposphere. One research objective is to explore these issues by means of time series analysis of a zonal index of total column ozone, to suggest the existence or nonexistence of relationships between column ozone and dynamical processes which are known to occur on various time scales. Another objective is to investigate the correlation between the ozone mixing ratio on the 350 K isentropic surface and the column integrated ozone, and to investigate the use of an easily derived parameter as a proxy for ozone mixing ratio, which is conserved in the stratosphere for time scales shorter than the photochemical time scale. The source of data for these studies is the Total Ozone Mapping Spectrometer (TOMS) data set.

Miller, Timothy L.↗

Thixotropic spectra and Ashby-style charts for thixotropy

There is no universal model for thixotropy, and comparing thixotropic effects between different fluids is a subtle yet challenging problem. We introduce a generalized (model-insensitive) framework for comparing thixotropic properties based on thixotropic spectra. A superposition of exponential stress modes distributed over thixotropic time scales is used to quantify buildup and breakdown times and mode strengths in response to step-change input. This mathematical framework is tested with several experimental step-shear rate data on colloidal suspensions. Low-dimensional metrics based on moments of the distribution reveal characteristic average thixotropic properties, which are visualized on Ashby-style diagrams. This method outlines a framework for describing thixotropy across a diverse range of microstructures, supporting scientific studies as well as material selection for engineering design applications.

Mechanics↗

Limits to the Stability of Phase Transfer from Ground to Space

An alternative to having a primary frequency standard on board a spacecraft is to phase lock a simple oscillator on the spacecraft to a microwave tone transmitted from the ground. The received tone is transponded and rebroadcast to the ground. The round trip phase is measured, and used to correct for effects on time scales longer than the round trip light travel time. This method is used with the TDRSS relay satellites, and will be used for the Japanese space VLBI mission VSOP. There are several sources of error introduced by this process. The most important error source is a loss of the on board standard for all times that the satellite is out of contact with a ground tracking station. The fractional loss will be greater than 10% for almost any orbit, even with a network of several ground tracking stations, and it will be considerably worse for a low earth orbit. Only a geostationary orbit can eliminate this problem. Another error source is connected to the previous one. Round trip phase tracking can remove, after the fact, link effects during a tracking pass on time scales greater than the round trip light travel time. However, there will be a jump in the spacecraft clock when multiple passes are connected (e.g. when the spacecraft is reacquired after passing out of sight). These jumps will be equal in magnitude (except for a geometrical factor) to the accuracy with which the spacecraft orbit is known. With a GPS receiver and GPS-like beacon on a spacecraft, the orbit can be known to a few cm, giving timing jumps on the order of 100 picoseconds. Even with a geostationary orbit, these jumps would occur any time the link was interrupted due to mechanical or electrical problems.

Linfield, Roger P.↗

The East Asian Jet Stream and Asian-Pacific-American Climate

The upper-tropospheric westerly jet stream over subtropical East Asia and western Pacific, often referred to as East Asian Jet (EAJ), is an important atmospheric circulation system in the Asian-Pacific-American (APA) region during winter. It is characterized by variabilities on a wide range of time scales and exerts a strong impact on the weather and climate of the region. On the synoptic scale, the jet stream is closely linked to many phenomena such as cyclogenesis, frontogenesis, blocking, storm track activity, and the development of other atmospheric disturbances. On the seasonal time scale, the variation of the EAJ determines many characteristics of the seasonal transition of the atmospheric circulation especially over East Asia. The variabilities of the EAJ on these time scales have been relatively well documented. It has also been understood since decades ago that the interannual. variability of the EAJ is associated with many climate signals in the APA region. These signals include the persistent anomalies of the East Asian winter monsoon and the changes in diabatic heating and in the Hadley circulation. However, many questions remain for the year-to-year variabilities of the EAJ and their relation to the APA climate. For example, what is the relationship between the EAJ and El Nino/Southern Oscillation (ENSO)? Will the EAJ and ENSO play different roles in modulating the APA climate? How is the jet stream linked to the non-ENSO-related sea surface temperature (SST) anomalies and to the Pacific/North American (PNA) teleconnection pattern?

Yang, Song↗

The putative liquid-liquid transition is a liquid-solid transition in atomistic models of water. II

This paper extends our earlier studies of free energy functions of density and crystalline order parameters for models of supercooled water, which allows us to examine the possibility of two distinct metastable liquid phases [D. T. Limmer and D. Chandler, J. Chem. Phys.135, 134503 (2011) and preprint http://arxiv.org/abs/arXiv:1107.0337 (2011)]. Low-temperature reversible free energy surfaces of several different atomistic models are computed: mW water, TIP4P/2005 water, Stillinger-Weber silicon, and ST2 water, the last of these comparing three different treatments of long-ranged forces. In each case, we show that there is one stable or metastable liquid phase, and there is an ice-like crystal phase. The time scales for crystallization in these systems far exceed those of structural relaxation in the supercooled metastable liquid. We show how this wide separation in time scales produces an illusion of a low-temperature liquid-liquid transition. The phenomenon suggesting metastability of two distinct liquid phases is actually coarsening of the ordered ice-like phase, which we elucidate using both analytical theory and computer simulation. For the latter, we describe robust methods for computing reversible free energy surfaces, and we consider effects of electrostatic boundary conditions. We show that sensible alterations of models and boundary conditions produce no qualitative changes in low-temperature phase behaviors of these systems, only marginal changes in equations of state. On the other hand, we show that altering sampling time scales can produce large and qualitative non-equilibrium effects. Recent reports of evidence of a liquid-liquid critical point in computer simulations of supercooled water are considered in this light.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Surprising Dynamics of the McLafferty Rearrangement

We report femtosecond time-resolved measurements of the McLafferty rearrange- ment following the strong-field tunnel ionization of 2-pentanone, 4-methyl-2-pentanone, and 4,4- dimethyl-2-pentanone. The pump–probe-dependent yields of the McLafferty product ion are fit to a biexponential function with fast (~100 fs) and slow (~10 ps) time constants, the latter of which is faster for the latter two compounds. Following nearly instantaneous ionization, the fast time scale is associated with rotation of the molecule to a six-membered cyclic intermediate that facilitates transfer of the γ-hydrogen, while the ~50–100 times longer time scale is associated with a π-bond rearrangement and bond cleavage between the α- and β-carbons to produce the enol cation. Furthermore, these experimental measurements are supported by ab initio molecular dynamics trajectories, which further confirm the time scale of this important stepwise reaction in mass spectrometry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dynamics of core accretion

In this paper, we perform three-dimensional hydrodynamic simulations of gas flowing around a planetary core of mass M pl = 10M ⊕ embedded in a near Keplerian background flow, using a modified shearing box approximation. We assume an ideal gas behaviour following an equation of state with a fixed ratio of the specific heats, γ = 1.42, consistent with the conditions of a moderate-temperature background disc with solar composition. No radiative heating or cooling is included in the models. We employ a nested grid hydrodynamic code implementing the ‘Piecewise Parabolic Method’ with as many as six fixed nested grids, providing spatial resolution on the finest grid comparable to the present-day diameters of Neptune and Uranus. We find that a strongly dynamically active flow develops such that no static envelope can form. The activity is not sensitive to plausible variations in the rotation curve of the underlying disc. It is sensitive to the thermodynamic treatment of the gas, as modelled by prescribed equations of state (either ‘locally isothermal’ or ‘locally isentropic’) and the temperature of the background disc material. The activity is also sensitive to the shape and depth of the core's gravitational potential, through its mass and gravitational softening coefficient. Each of these factors influences the magnitude and character of hydrodynamic feedback of the small-scale flow on the background, and we conclude that accurate modelling of such feedback is critical to a complete understanding of the core accretion process. The varying flow pattern gives rise to large, irregular eruptions of matter from the region around the core which return matter to the background flow: mass in the envelope at one time may not be found in the envelope at any later time. No net mass accretion into the envelope is observed over the course of the simulation and none is expected, due to our neglect of cooling. Except in cases of very rapid cooling however, as defined by locally isothermal or isentropic treatments, any cooling that does affect the envelope material will have limited consequences for the dynamics, since the flow quickly carries cooled material out of the core's environment entirely. The angular momentum of material in the envelope, relative to the core, varies both in magnitude and in sign on time-scales of days to months near the core and on time-scales a few years at distances comparable to the Hill radius. The dynamical activity contrasts with the largely static behaviour typically assumed within the framework of the core accretion model for Jovian planet formation. We show that material entering the dynamically active environment may suffer intense heating and cooling events the durations of which are as short as a few hours to a few days. Shorter durations are not observable in our work due to the limits of our resolution. Peak temperatures in these events range from T ~ 1000 K to as high as T ~ 3–4000 K, with densities ρ ~ 10 -9 to 10 -8 gcm -3 . These time-scales, densities and temperatures span a range consistent with those required for chondrule formation in the nebular shock model. Finally, we therefore propose that dynamical activity in the Jovian planet formation environment could be responsible for the production of chondrules and other annealed silicates in the solar nebula.

79 ASTRONOMY AND ASTROPHYSICS↗

Accumulation of a swarm of small planetesimals

The present gasdynamic study of the planetesimal-accumulation stage in which 10-km bodies in the neighborhood of 1 AU grow to 10 to the 25th-10 to the 27th g mass, or 'planetary embryo' size, attempts to identify the circumstances under which runaway growth forms a small number of massive embryos in the terrestrial-planet region on a 0.1-1.0 million year time-scale. No runaways are found, however, unless more plausible physical processes are invoked; in that case, runaways in the terrestrial planet region are probable on a 0.1 million-year time-scale, and the final stage of planetary accumulation may involve the growth of these embryos into the present planets on a 10-100 million-year time-scale.

Wetherill, G. W.↗

Optimal Power Flow Pursuit

Past works that focused on addressing power-quality and reliability concerns related to renewable energy resources (RESs) operating with business-as-usual practices have looked at the design of Volt/VAr and Volt/Watt strategies to regulate real or reactive powers based on local voltage measurements, so that terminal voltages are within acceptable levels. These control strategies have the potential of operating at the same time scale of distribution-system dynamics, and can therefore mitigate disturbances precipitated fast time-varying loads and ambient conditions; however, they do not necessarily guarantee system-level optimality, and stability claims are mainly based on empirical evidences. On a different time scale, centralized and distributed optimal power flow (OPF) algorithms have been proposed to compute optimal steady-state inverter setpoints, so that power losses and voltage deviations are minimized and economic benefits to end-users providing ancillary services are maximized. However, traditional OPF schemes may offer decision making capabilities that do not match the dynamics of distribution systems. Particularly, during the time required to collect data from all the nodes of the network (e.g., loads), solve the OPF, and subsequently dispatch setpoints, the underlying load, ambient, and network conditions may have already changed; in this case, the DER output powers would be consistently regulated around outdated setpoints, leading to suboptimal system operation and violation of relevant electrical limits. The present work focuses on the synthesis of distributed RES-inverter controllers that leverage the opportunities for fast feedback offered by power-electronics interfaced RESs. The overarching objective is to bridge the temporal gap between long-term system optimization and real-time control, to enable seamless RES integration in large scale with stability and efficiency guarantees, while congruently pursuing system-level optimization objectives. The design of the control framework is based on suitable linear approximations of the AC power-flow equations as well as Lagrangian regularization methods. The proposed controllers enable an update of the power outputs at a time scale that is compatible with the underlying dynamics of loads and ambient conditions, and continuously drive the system operation towards OPF-based solutions.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Short timescale photometric and polarimetric behavior of two BL Lacertae type objects

Context. Blazars are astrophysical sources whose emission is dominated by non-thermal processes, typically interpreted as synchrotron and inverse Compton emission. Although the general picture is rather robust and consistent with observations, many aspects are still unexplored. Aims. Polarimetric monitoring can offer a wealth of information about the physical processes in blazars. Models with largely different physical ingredients can often provide almost indistinguishable predictions for the total flux, but usually are characterized by markedly different polarization properties. We explore, with a pilot study, the possibility to derive structural information about the emitting regions of blazars by means of a joint analysis of rapid variability of the total and polarized flux at optical wavelengths. Methods. Short timescale (from tens of seconds to a couple of minutes) optical linear polarimetry and photometry for two blazars, BL Lacertae and PKS 1424+240, was carried out with the PAOLO polarimeter at the 3.6 m Telescopio Nazionale Galileo. Several hours of almost continuous observations were obtained for both sources. Results. Our intense monitoring allowed us to draw strongly different scenarios for BL Lacertae and PKS 1424+240, with the former characterized by intense variability on time-scales from hours to a few minutes and the latter practically constant in total flux. Essentially the same behavior is observed for the polarized flux and the position angle. The variability time-scales turned out to be as short as a few minutes, although involving only a few percent variation of the flux. The polarization variability time-scale is generally consistent with the total flux variability. Total and polarized flux appear to be essentially uncorrelated. However, even during our relatively short monitoring, different regimes can be singled out. Conclusions. No simple scenario is able to satisfactorily model the very rich phenomenology exhibited in our data. As a result, detailed numerical simulations show that the emitting region should be characterized by some symmetry, and the inclusion of turbulence for the magnetic field may constitute the missing ingredient for a more complete interpretation of the data.

1424+240↗

Melt inclusion shapes: Timekeepers of short-lived giant magma bodies

The longevity of giant magma bodies in the Earth’s crust prior to eruption is poorly constrained, but recognition of short time scales by multiple methods suggests that the accumulation and eruption of these giant bodies may occur rapidly. We describe a new method that uses textures of quartz-hosted melt inclusions, determined using quantitative three-dimensional propagation phase-contrast X-ray tomography, to estimate quartz crystallization times and growth rates, and we compare the results to those from Ti diffusion profiles. We investigate three large-volume, high-silica rhyolite eruptions: the 240 ka Ohakuri-Mamaku and 26.5 ka Oruanui (Taupo Volcanic Zone, New Zealand), and the 760 ka Bishop Tuff (California, USA). Our results show that (1) longevity estimates from melt inclusion textures and Ti diffusion profiles are comparable, (2) quartz growth rates average ~10-12 m/s, and (3) quartz melt inclusions give decadal to centennial time scales, revealing that giant magma bodies can develop over notably short historical time scales.

58 GEOSCIENCES↗

On the high correlation between long-term averages of solar wind speed and geomagnetic activity

Six-month and yearly averages of solar-wind speed from 1962 to 1975 are shown to be highly correlated with geomagnetic activity as measured by averages of the Ap index. On the same time scale the correlation between the southward component of the interplanetary magnetic field and geomagnetic activity is poor. Previous studies with hourly averages gave opposite results. The better correlation with the southward component on an hourly time scale is explained by its large variation compared with the relatively constant solar-wind speed. However, on a yearly time scale the magnitude of the variations in both parameters are about the same. This problem can be solved by invoking an energy transfer mechanism which is proportional to the first power of the southward component and a higher power of the solar-wind speed.

Crooker, N. U.↗

SPARC-X: Quantum simulations at extreme scale - reactive dynamics from first principles

We have developed the massively parallel electronic structure code SPARC-X: a computational framework for performing Kohn-Sham Density Functional Theory (DFT) calculations that can scale linearly with the number of atoms in the system, while being able to leverage petascale and emerging exascale parallel computers to study chemical phenomena at unprecedented length and time scales. SPARC-X exploits a recent breakthrough in electronic structure methodologies: systematically improvable, strictly local, orthonormal, discontinuous real-space bases that efficiently and systematically capture the local chemistry of the system. With further adaptation using new machine-learning techniques and the use of the massively parallel Spectral Quadrature (SQ) electronic structure method, the algorithmic complexity and prefactor associated with DFT calculations involving semilocal as well as hybrid functionals are dramatically reduced. Using petascale computational resources, SPARC-X enables quantum mechanical simulations at length and time scales previously accessible only by empirical approaches, e.g., 1,000,000 atoms for a few picoseconds using semilocal functionals or 1,000 atoms for a few picoseconds using hybrid functionals. Using exascale resources, the sizes and times targeted are two orders of magnitude larger. Such a capability has applications in a wide variety of chemical sciences, including reactive interfaces where large length- and/or long time-scales are needed and traditional force fields fail. This is particularly important in dynamic catalysis, where bond breaking and formation must be understood in detail. We developed, tested, and employed the SPARC-X framework to understand the photocatalytic properties of TiO 2 nanoparticles, revealing finite size effects that cannot be captured with standard model systems or functionals. This integrated development and application strategy ensures that SPARC-X remains a robust, efficient, and scalable software package for quantum simulations on current petascale and emerging exascale computing resources.

97 MATHEMATICS AND COMPUTING↗

Final Report. Analysis and Reduction of Complex Networks Under Uncertainty

The project was a collaborative effort among MIT, Sandia National Laboratories (local PI Dr. Habib Najm), the University of Southern California (local PI Prof. Roger Ghanem), and The Johns Hopkins University (local PI Prof. Omar Knio, now at Duke University). Our focus was the analysis and reduction of large-scale dynamical systems emerging from networks of interacting components. Such networks underlie myriad natural and engineered systems. Examples important to DOE include chemical models of energy conversion processes, and elements of national infrastructure—e.g., electric power grids. Time scales in chemical systems span orders of magnitude, while infrastructure networks feature both local and long-distance connectivity, with associated clusters of time scales. These systems also blend continuous and discrete behavior; examples include saturation phenomena in surface chemistry and catalysis, and switching in electrical networks. Reducing size and stiffness is essential to tractable and predictive simulation of these systems. Computational singular perturbation (CSP) has been effectively used to identify and decouple dynamics at disparate time scales in chemical systems, allowing reduction of model complexity and stiffness. In realistic settings, however, model reduction must contend with uncertainties, which are often greatest in large-scale systems most in need of reduction. Uncertainty is not limited to parameters; one must also address structural uncertainties—e.g., whether a link is present in a network—and the impact of random perturbations, e.g., fluctuating loads or sources. Research under this project developed new methods for the analysis and reduction of complex multiscale networks under uncertainty, by combining computational singular perturbation (CSP) with probabilistic uncertainty quantification. CSP yields asymptotic approximations of reduceddimensionality “slow manifolds” on which a multiscale dynamical system evolves. Introducing uncertainty in this context raised fundamentally new issues, e.g., how is the topology of slow manifolds transformed by parametric uncertainty? How to construct dynamical models on these uncertain manifolds? To address these questions, we used stochastic spectral polynomial chaos (PC) methods to reformulate uncertain network models and analyzed them using CSP in probabilistic terms. Finding uncertain manifolds involved the solution of stochastic eigenvalue problems, facilitated by projection onto PC bases. These problems motivated us to explore the spectral properties stochastic Galerkin systems. We also introduced novel methods for rank-reduction in stochastic eigensystems—transformations of a uncertain dynamical system that lead to lower storage and solution complexity. These technical accomplishments are detailed below. This report focuses on the MIT portion of the joint project.

97 MATHEMATICS AND COMPUTING↗

A multi-scale time-series dataset with benchmark for machine learning in decarbonized energy grids

The electric grid is a key enabling infrastructure for the ambitious transition towards carbon neutrality as we grapple with climate change. With deepening penetration of renewable resources, the reliable operation of the electric grid becomes increasingly challenging. In this paper, we present PSML, a first-of-its-kind open-access multi-scale time-series dataset, to aid in the development of data-driven machine learning (ML)-based approaches towards reliable operation of future electric grids. The dataset is synthesized from a joint transmission and distribution electric grid to capture the increasingly important interactions and uncertainties of the grid dynamics, containing power, voltage and current measurements over multiple spatio-temporal scales. Using PSML, we provide state-of-the-art ML benchmarks on three challenging use cases of critical importance to achieve: (i) early detection, accurate classification and localization of dynamic disturbances; (ii) robust hierarchical forecasting of load and renewable energy; and (iii) realistic synthetic generation of physical-law-constrained measurements. We envision that this dataset will provide use-inspired ML research in safety-critical systems, while simultaneously enabling ML researchers to contribute towards decarbonization of energy sectors.

54 ENVIRONMENTAL SCIENCES↗

Deep convolutional neural networks for multi-scale time-series classification and application to disruption prediction in fusion devices

The multi-scale, mutli-physics nature of fusion plasmas makes predicting plasma events challenging. Recent advances in deep convolutional neural network architectures (CNN) utilizing dilated convolutions enable accurate predictions on sequences which have long-range, multi-scale characteristics, such as the time-series generated by diagnostic instruments observing fusion plasmas. Here we apply this neural network architecture to the popular problem of disruption prediction in fusion tokamaks, utilizing raw data from a single diagnostic, the Electron Cyclotron Emission imaging (ECEi) diagnostic from the DIII-D tokamak. ECEi measures a fundamental plasma quantity (electron temperature) with high temporal resolution over the entire plasma discharge, making it sensitive to a number of potential pre-disruptions markers with different temporal and spatial scales. Promising, initial disruption prediction results are obtained training a deep CNN with large receptive field ({$\sim$}30k), achieving an $F_1$-score of {$\sim$}91\% on individual time-slices using only the ECEi data.

convolutional neural networks↗