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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Removing Atmospheric Effects From AVIRIS Data for Surface Reflectance Retrievals

Analysis of high resolution imaging spectrometer data requires a thorough compensation for atmospheric absorption and scattering. A method for retrieving surface reflectances from spectral data collected by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) is being developed. In this method, the integrated water vapor amount on a pixel by pixel basis is derived from the 0.94- and 1.14-micrometer water vapor features. The water vapor, carbon dioxide (CO2), oxygen (O2) and methane (CH4) transmission spectrum in the 0.4-2.5 micrometer region is calculated. The derived water vapor value and the solar and observational geometry are used in the spectral calculation. The AVIRIS spectrum is ratioed against the transmission spectrum to obtain the surface reflectance spectrum. Major mineral absorption features near 2.2 micrometer in retrieved reflectance spectra can be identified. Different vegetation absorption characteristics are observed. At present, the method is most useful for deriving surface reflectances from AVIRIS data measured on clear days with high visibilities. Atmospheric scattering effects will be included in our spectral calculations in the near future.

Gao, Bo-Cai↗
DOE OSTI2022

Investigating the Influence of Ni, ZrO 2 , and Y 2 O 3 from SOFC Anodes on Siloxane Deposition

Siloxanes, as a type of impurity in biogas, can poison the Ni-YSZ anode of SOFCs. However, the influence of individual components of the anode, such as Ni, ZrO 2 , and Y 2 O 3 , on the siloxane deposition process has not been investigated extensively. In this study, Ni, ZrO 2 , and Y 2 O 3 pellets were exposed to H 2 + N 2 + H 2 O + D4 (octamethylcyclotetrasiloxane, 2.5 ppmv) and H 2 + N 2 + D4 (2.5 ppmv siloxane) gas mixtures at 750 °C to investigate their affinity and tolerance for siloxane degradation. Surface morphology analysis and electrochemical analysis including electrochemical impedance spectroscopy (EIS), related distribution of relaxation times (DRT) analysis and equivalent circuit modeling with complex nonlinear least square (CNLS) fitting were conducted. Here, a microstructure parameter—tortuosity factor to porosity ratio $\tau /\varepsilon $ calculated by diffusion polarization resistance was utilized for siloxane deposition evaluation. After comparing pellets surface morphology changes before and after experiments and $\tau /\varepsilon $ change following the contamination, Ni is considered as a major factor in siloxane deposition reactions in Ni-YSZ anode.

25 ENERGY STORAGE↗
DOE OSTI2022

Image Analysis for Rapid Assessment and Quality-Based Sorting of Corn Stover

Imaging in the visible spectrum is a low-cost tool that can be readily deployed for in-field or over-belt monitoring of biomass quality for bio-refining operations. Rapid image analysis coupled with innovative preprocessing may reduce the impacts of feedstock variability through identification of contaminants or other material attributes to guide selective sorting and quality management. Image analysis was employed to evaluate the quality of corn stover in red-green-blue (RGB) chromatic space. This study used controlled, bench-scale imaging as a proof-of-concept for rapid quality assessment of corn stover based on variations in material attributes, including chemical and physical attributes, that relate to biological degradation and soil contamination. Additionally, logistic regression-based classification algorithms were used to develop a method for biomass screening as a function of biological degradation or soil contamination. This study demonstrated the use of image analysis to extract features from RGB color space to investigate variations in critical material attributes from chemical composition of corn stover. Fourier transform infrared (FT-IR) suggested a correlation between red band intensity and biological degradation, while detailed surface texture analysis was found to distinguish among variations in ash. These insights offer promise for development of a rapid screening tool that could be deployed by farmers for in-field assessment of biomass quality or biorefinery operators for in-line sorting and process optimization.

09 BIOMASS FUELS↗
NASA NTRS2024

Role of Oxygen Fugacity on the Melting Properties of Enstatite Chondrites and Implications for Mercury’s Magmatic Evolution

Mercury, the innermost terrestrial planet, is the most reduced planet in our solar system. Insights from MESSENGER mission data revealed the presence of several distinct geochemical terranes, evidence of complex magmatic processes and collisional processes exposing subsurface materials. Surface chemical analysis indicated elevated S (~2-3 wt%) and low FeO (~1.5 wt%) concentrations. The high sulfur concentration indicates reduced conditions with an average of 5.4 log units below the Iron-Wüstite (IW) oxygen fugacity ( O 2 ) buffer (IW-5.4). Surface compositions also show a range in redox conditions during mantle melting and eruption, with inferred log f O 2 , ranging from IW-6.5 to IW-3.5. The effects of oxygen fugacity on magmatic differentiation are poorly constrained, despite their significance in our understanding of mantle-crust differentiation in the solar system. Enstatite High-Fe (EH) chondrites are very reduced undifferentiated meteorites with elevated concentrations of Fe and volatiles like S, Cl, Na, and K as compared to other chondrites. These characteristics suggest that EH chondrites are a potential analog for Mercury’s building blocks. However, the comparison of Mercury’s surface composition with melting products of EH chondrites is necessary to determine whether Mercury surface materials may be derived from EH chondrite- like materials. Here, we investigate the role of f O 2 on EH melting properties and its implications for Mercury’s accretion and differentiation.

Mercury↗
NASA NTRS1991

Analysis of images obtained by the Phobos 2 spacecraft

The reflection spectrum and density of the Martian satellite, Phobos, suggests that it may be a captured C-type asteroid and hence may contain relatively unaltered organic material from the early history of the solar system. Since there is evidence from isotopic anomalies that meteorites presumably derived from such asteroids contain preserved interstellar material, it is conceivable that evidence for interstellar matter might also be present on Phobos. The present research concerns interpretation of the chemical composition of Phobos' surface and analysis of images of Phobos taken by the FREGAT camera equipment aboard the Phobos 2 Spacecraft, including both disk-integrated and disk-resolved photometry. Because the surface of Phobos is a regolith, spectral information on the surface composition will be convolved with information on the surface texture. A primary goal was to untangle these effects. Unfortunately, the Phobos 1 Spacecraft lost contact with Earth during its transit to Mars, and Phobos 2 likewise lost contact after two months in orbit around Mars. Thus, the hovering phase of very close approach and the landing of instruments on the surface of Phobos did not take place, so no data on the elemental composition of the surface is available. However, 37 images were obtained of the satellite. The results include the first such observations at near infrared wavelengths, for which disk-integrated results show that the corresponding geometric albedo is quite small and very similar to the value in the blue. The resolved surface photometry was analyzed by developing new methods of radiative transfer in rough surface layers and a procedure referred to as statistical photoclinometry. The results provide root mean square surface slopes on scales from the order of 1 millimeter to 250 meters, albedo fluctuations, and corresponding correlation lengths.

Irvine, W. M.↗
DOE OSTI2025

ToF-SIMS spectral data analysis of Paenibacillus sp. 300A biofilms and planktonic cells

Analysis of bacterial biofilms is particularly challenging and important with diverse applications from systems biology to biotechnology. Among the variety of techniques that have been applied, time-of-flight secondary ion mass spectrometry (ToF-SIMS) has many promising features in studying the surface characteristics of biofilms. ToF-SIMS offers high spatial resolution and high mass accuracy, which permit surface sensitive analysis of biofilm components. Thus, ToF-SIMS provides a powerful solution to addressing the challenge of bacterial biofilm analysis. This dataset covers ToF-SIMS analysis of Paenibacillus sp. 300A (300A) isolated from the Hanford site in Richland, WA. The strain is known to have metal and sulfur reducing properties and can be used for bioremediation, wastewater treatment, bioengineering and technology development. There is a current need to identify small molecules and fragments produced from bacterial biofilms. Static ToF-SIMS spectra of 300A were obtained using an IONTOF TOF-SIMS V instrument equipped with a 25 keV Bi 3 + metal ion gun. Identified molecules and molecular fragments are compared against known biological databases and the reported peaks have at least 65 ppm mass accuracy. These molecules range from lipids and fatty acids to flavonoids, quinolones, and other naturally occurring organic compounds. It is anticipated that the spectral identification of key peaks will assist detection of metabolites, extracellular polymeric substance molecules like polysaccharides, and biologically relevant small molecules using ToF-SIMS in future surface and interface research of bacterial biofilms.

Biofilms↗
NASA NTRS2008

NASA's Earth Science Use of Commercially Availiable Remote Sensing Datasets: Cover Image

The cover image incorporates high resolution stereo pairs acquired from the DigitalGlobe(R) QuickBird sensor. It shows a digital elevation model of Meteor Crater, Arizona at approximately 1.3 meter point-spacing. Image analysts used the Leica Photogrammetry Suite to produce the DEM. The outside portion was computed from two QuickBird panchromatic scenes acquired October 2006, while an Optech laser scan dataset was used for the crater s interior elevations. The crater s terrain model and image drape were created in a NASA Constellation Program project focused on simulating lunar surface environments for prototyping and testing lunar surface mission analysis and planning tools. This work exemplifies NASA s Scientific Data Purchase legacy and commercial high resolution imagery applications, as scientists use commercial high resolution data to examine lunar analog Earth landscapes for advanced planning and trade studies for future lunar surface activities. Other applications include landscape dynamics related to volcanism, hydrologic events, climate change, and ice movement.

Underwood, Lauren W.↗
NASA NTRS2012

Laser Time-of-Flight Mass Spectrometry for Future In Situ Planetary Missions

Laser desorption/ionization time-of-flight mass spectrometry (LD-TOF-MS) is a versatile, low-complexity instrument class that holds significant promise for future landed in situ planetary missions that emphasize compositional analysis of surface materials. Here we describe a 5kg-class instrument that is capable of detecting and analyzing a variety of analytes directly from rock or ice samples. Through laboratory studies of a suite of representative samples, we show that detection and analysis of key mineral composition, small organics, and particularly, higher molecular weight organics are well suited to this instrument design. A mass range exceeding 100,000 Da has recently been demonstrated. We describe recent efforts in instrument prototype development and future directions that will enhance our analytical capabilities targeting organic mixtures on primitive and icy bodies. We present results on a series of standards, simulated mixtures, and meteoritic samples.

Getty, S. A.↗
DOE OSTI2024

ToF-SIMS spectral analysis of Shewanella oneidensis MR-1 biofilms

Analysis of bacterial biofilms is particularly challenging and important with diverse applications from systems biology to biotechnology. Among the variety of techniques that have been applied, time-of-flight secondary ion mass spectrometry (ToF-SIMS) has many powerful features in studying the surface characteristics of biofilms. ToF-SIMS offers high spatial resolution, mass resolution, and mass accuracy, which permit surface sensitive analysis of biofilm components. Thus, ToF-SIMS provides a powerful solution to addressing the challenge of bacterial biofilm analysis. This dataset covers ToF-SIMS analysis of Shewanella oneidensis MR-1 isolated from freshwater lake sediment in New York state. The MR-1 strain is known to have metal and sulfur reducing properties and it can be used for bioremediation and wastewater treatment. There is a current need to identify small molecules and fragments produced from bacterial biofilms, especially those from extracellular polymeric substance (EPS). Static ToF-SIMS spectra of MR-1 were obtained using an IONTOF TOF.SIMS V instrument equipped with a 25 keV Bi$^+_3$ metal ion gun. Identified molecules and molecular fragments are compared against known biological databases and the reported peaks have at least 65 ppm mass accuracy. These molecules range from lipids, fatty acids, flavonoids, and quinolones to other naturally occurring organic compounds. It is anticipated that the mass spectral identification of key peaks will assist detection of metabolites, EPS molecules like polysaccharides, and biologically relevant small organic molecules using ToF-SIMS in future surface and interface research.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1999

Electron Microscopy and Image Analysis for Selected Materials

This particular project was completed in collaboration with the metallurgical diagnostics facility. The objective of this research had four major components. First, we required training in the operation of the environmental scanning electron microscope (ESEM) for imaging of selected materials including biological specimens. The types of materials range from cyanobacteria and diatoms to cloth, metals, sand, composites and other materials. Second, to obtain training in surface elemental analysis technology using energy dispersive x-ray (EDX) analysis, and in the preparation of x-ray maps of these same materials. Third, to provide training for the staff of the metallurgical diagnostics and failure analysis team in the area of image processing and image analysis technology using NIH Image software. Finally, we were to assist in the sample preparation, observing, imaging, and elemental analysis for Mr. Richard Hoover, one of NASA MSFC's solar physicists and Marshall's principal scientist for the agency-wide virtual Astrobiology Institute. These materials have been collected from various places around the world including the Fox Tunnel in Alaska, Siberia, Antarctica, ice core samples from near Lake Vostoc, thermal vents in the ocean floor, hot springs and many others. We were successful in our efforts to obtain high quality, high resolution images of various materials including selected biological ones. Surface analyses (EDX) and x-ray maps were easily prepared with this technology. We also discovered and used some applications for NIH Image software in the metallurgical diagnostics facility.

Williams, George↗
DOE OSTI2021

Efficient passivation of n-type and p-type silicon surface defects by hydrogen sulfide gas reaction

An efficient surface defect passivation is observed by reacting clean Si in a dilute hydrogen sulfide-argon gas mixture (< 5% H2S in Ar) for both n-type and p-type Si wafers with planar and textured surfaces. Surface recombination velocities of 1.5 and 8 cm/s are achieved on n-type and p-type Si wafers, respectively, at an optimum reaction temperature of 550oC that are comparable to the best surface passivation quality used in high efficiency Si solar cells. Surface chemical analysis using x-ray photoelectron spectroscopy shows that sulfur is primarily bonded in a sulfide environment, and synchrotron-based soft x-ray emission spectroscopy of the adsorbed sulfur atoms suggests the formation of S-Si bonds. Furthermore, the sulfur surface passivation layer is unstable in air, attributed to surface oxide formation and a simultaneous decrease of sulfide bonds. However, the passivation can be stabilized by a low-temperature (300oC) deposited amorphous silicon nitride (a-Si:NX:H) capping layer.

14 SOLAR ENERGY↗
NASA NTRS1971

Elasto-plastic analysis of a mode I edge crack with application to a surface notch.

A finite element analysis has been undertaken of the mechanical state of a plate containing a crack subjected to mode I loading. Specifically, a localized, well-defined surface depression (dimple) previously observed on the back surface of plate specimens immediately behind the plane of the crack was examined. The approach taken is concerned with defining more precisely the dimpling behavior as a function of relative flaw depth and applied stress level, as well as the development of the plastic zone at the crack tip.

Francis, P. H.↗
NASA NTRS1987

Structure and grain coarsening during the processing of engineering ceramics

Studies have been made of three ceramic systems (Al2O3, Y2O3/MgO, and SiC/C/B), both to explore a surface area/density diagram approach to examining the coarsening processes during sintering and to explore an alternative coarsening parameter, i.e., the grain boundary surface area (raising it at a given value of the density) and not the pore surface area; therefore, pinning of the grain boundaries by solid-solution drag is the only function evidenced by these results. The importance of such pinning even at densities as low as 75% of theoretical is linked to the existence of microstructural inhomogeneities. The early stages of sintering of Y2O3 powder have been examined using two techniques, BET surface area analysis and transmission electron microscopy. Each has given some insight into the process occurring and, used together, have provided some indication of the effect of MgO on coarsening during sintering. Attempts to further elucidate effects of MgO on the coarsening behavior of Y2O3 by the surface area/density diagram approach were unsuccessful due to masking effects of contaminating reactions during sintering and/or thermal etching. The behavior of the undoped SiC which only coarsens can be clearly distinguished by the surface area/density diagram from that of SiC/C/B which also concurrently densifies. Little additional information was obtainable by this method due to unfavorable sample etching characteristics. The advantages, disadvantages, and difficulties of application of these techniques to the study of coarsening during sintering are discussed.

Shaw, Nancy J.↗
NASA NTRS1992

Statistical crystallography of surface micelle spacing

The aggregation of the recently reported surface micelles of block polyelectrolytes is analyzed using techniques of statistical crystallography. A polygonal lattice (Voronoi mosaic) connects center-to-center points, yielding statistical agreement with crystallographic predictions; Aboav-Weaire's law and Lewis's law are verified. This protocol supplements the standard analysis of surface micelles leading to aggregation number determination and, when compared to numerical simulations, allows further insight into the random partitioning of surface films. In particular, agreement with Lewis's law has been linked to the geometric packing requirements of filling two-dimensional space which compete with (or balance) physical forces such as interfacial tension, electrostatic repulsion, and van der Waals attraction.

Noever, David A.↗
NASA NTRSDate not supplied

Icing Physics Studies Using the 3D SIDRM Test Article: Aerodynamic and Supercooled Liquid Icing Analysis

In-flight icing is an important safety issue and is a factor that affects aircraft design and performance. Newer regulations are driving a need for improvements in airframe and engine icing simulation capability. Experimental data is required for development of icing physics models and simulation validation. To that end, this paper presents the analysis of the supercooled liquid icing data subset from tests conducted in 2022 at the NASA Icing Research Tunnel that studied both supercooled water and ice-crystal icing. The test article that was utilized replicated 3D geometrical features of an inter-compressor duct and strut region of a turbofan engine. The surfaces of the Simulated Inter-compressor Duct Research Model (SIDRM) can be heated to simulate the warm surfaces of the turbofan inter-compressor duct. The test article is instrumented with pressure taps, heaters, heat flux gauges, and thermocouples, while a 3D laser scanner, cameras, and a scale to measure ice mass were utilized to characterize the icing behavior. The aim of these tests was to generate ice accretions on the SIDRM test article under well-characterized supercooled liquid icing and ice crystal icing conditions. This paper discusses measurements related to aerodynamic testing and supercooled liquid icing tests that were conducted. Aerodynamic measurements were analyzed and compared to computational simulations and were found to be in good agreement for the range of airspeeds (50 to 230 knots) and angles of attack (0 to 4°) tested. Various parametric sweeps were conducted during the supercooled liquid icing portion of the test entry (cloud median volumetric diameter ranged from 15 to 90 µm, total air temperature from -3 to -17 °C, angle of attack from 0 to 4°, and accretion time from 5 to 20 min). These sweeps were performed to measure that parameter’s impact on ice accretion size, location (icing extent), characteristics (such as glaze/rime ice and shedding behavior), and test article surface temperature. Analysis of the test data showed that clouds composed of larger drops, colder air temperatures, smaller angles of attack, and longer spray times were the primary parameters that resulted in accretions with greater ice mass. Test article angle of attack and cloud droplet size influenced the location of ice accretion as these two parameters directly impact collection efficiency. With respect to icing characteristics, total air temperature dictated icing type, and smaller cloud drop size along with warmer air temperatures resulted in greater amounts of ice shedding. Surface temperature increased during ice accretion from the release of latent (fusion) heat, where total air temperature and cloud drop size impacted the amount of surface temperature change. The icing measurements collected during the SIDRM tests will be used to develop and validate 3D computational engine icing tools, such as GlennICE, that predictively assesses the onset and growth of ice. One of the goals of the sponsoring NASA project is to develop simulation models and tools that can assist in the design and certification of engines for flight in icing conditions in a cost effective way.

supercooled liquid icing↗
NASA NTRS1973

Martian lineaments from Mariner 6 and 7 photographs

Mariner 6 and 7 photographs were used to investigate the nature and importance of linear surface trends on Mars. Cross correlations of frequency-azimuth distributions of linear trends from different Mariner frames indicate that lineations not recognized as topographic features have a component of pseudoforms, probably introduced during digital reconstruction of the pictures. Similar statistical tests may aid in the analysis of surface trends from future satellites and space probes. The most reliable data were separated into photometrically defined provinces. Meridiani Sinus and Margaritifer Sinus display five major trends in common, which are interpreted as extensions of crustal weaknesses related to the enormous equatorial canyon revealed in Mariner 6 and 9 pictures. Alignments of crater wall segments generally match these trends and suggest structural control of crater plan. Crater chains, however, do not match these trends and are interpreted as secondary impacts. Rose diagrams of lineations in Deucalionis Regio exhibit much more complexity and are believed to reflect a better preserved or more complex geologic history.

Schultz, P. H.↗
NASA NTRS1981

Influence of surface-albedo in subtropical regions on July circulation

A simulation study to examine the influence of surface-albedo on July circulation in subtropical regions is presented. The results are based on two 47-day integrations. In the first integration, called the control run, surface albedos were normally prescribed, whereas in the second integration, called the anomaly run, the surface albedo was modified in four regions: the Sahel in Africa, the Great Plains in the United States, the Thar Desert border in the Indian subcontinent, and Brazil in South America. Each run was started from observed initial conditions for June 15, 1979 based on NMC analysis. The surface albedo in each of the regions was arbitrarily made 30%.

Sud, Y.↗