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LuRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Lu is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Lu–Rh bond lengths are 3.11 Å. Rh is bonded to six equivalent Lu and six equivalent Rh atoms to form a mixture of edge, face, and corner-sharing RhLu6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.65 Å.
ErRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Er is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Er–Rh bond lengths are 3.12 Å. Rh is bonded to six equivalent Er and six equivalent Rh atoms to form a mixture of corner, edge, and face-sharing RhEr6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.66 Å.
PuRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Pu is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Pu–Rh bond lengths are 3.07 Å. Rh is bonded to six equivalent Pu and six equivalent Rh atoms to form a mixture of edge, face, and corner-sharing RhPu6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.62 Å.
GdRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Gd is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Gd–Rh bond lengths are 3.15 Å. Rh is bonded to six equivalent Gd and six equivalent Rh atoms to form a mixture of corner, edge, and face-sharing RhGd6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.69 Å.
MnRhAs crystallizes in the hexagonal P-62m space group. The structure is three-dimensional. Mn is bonded in a 10-coordinate geometry to six equivalent Rh and four As atoms. There are four shorter (2.79 Å) and two longer (2.82 Å) Mn–Rh bond lengths. There are two shorter (2.46 Å) and two longer (2.57 Å) Mn–As bond lengths. Rh is bonded in a 11-coordinate geometry to six equivalent Mn and five As atoms. There are one shorter (2.53 Å) and four longer (2.70 Å) Rh–As bond lengths. There are two inequivalent As sites. In the first As site, As is bonded in a 9-coordinate geometry to six equivalent Mn and three equivalent Rh atoms. In the second As site, As is bonded in a distorted trigonal planar geometry to three equivalent Mn and six equivalent Rh atoms.
ScRhSi2 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Sc is bonded in a 12-coordinate geometry to five equivalent Rh and seven Si atoms. There are a spread of Sc–Rh bond distances ranging from 2.87–3.12 Å. There are a spread of Sc–Si bond distances ranging from 2.77–2.86 Å. Rh is bonded in a 12-coordinate geometry to five equivalent Sc and five Si atoms. There are a spread of Rh–Si bond distances ranging from 2.43–2.55 Å. There are two inequivalent Si sites. In the first Si site, Si is bonded in a 2-coordinate geometry to four equivalent Sc, two equivalent Rh, and three equivalent Si atoms. There are one shorter (2.49 Å) and two longer (2.65 Å) Si–Si bond lengths. In the second Si site, Si is bonded in a 9-coordinate geometry to three equivalent Sc, three equivalent Rh, and three equivalent Si atoms.
YbRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Yb is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Yb–Rh bond lengths are 3.11 Å. Rh is bonded to six equivalent Yb and six equivalent Rh atoms to form a mixture of corner, edge, and face-sharing RhYb6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.65 Å.
NdRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Nd is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Nd–Rh bond lengths are 3.18 Å. Rh is bonded to six equivalent Nd and six equivalent Rh atoms to form a mixture of corner, edge, and face-sharing RhNd6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.71 Å.
Rh3Nb is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Nb is bonded to twelve equivalent Rh atoms to form NbRh12 cuboctahedra that share corners with twelve equivalent NbRh12 cuboctahedra, edges with twenty-four equivalent RhNb4Rh8 cuboctahedra, faces with six equivalent NbRh12 cuboctahedra, and faces with twelve equivalent RhNb4Rh8 cuboctahedra. All Nb–Rh bond lengths are 2.77 Å. Rh is bonded to four equivalent Nb and eight equivalent Rh atoms to form distorted RhNb4Rh8 cuboctahedra that share corners with twelve equivalent RhNb4Rh8 cuboctahedra, edges with eight equivalent NbRh12 cuboctahedra, edges with sixteen equivalent RhNb4Rh8 cuboctahedra, faces with four equivalent NbRh12 cuboctahedra, and faces with fourteen equivalent RhNb4Rh8 cuboctahedra. All Rh–Rh bond lengths are 2.77 Å.
PrRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Pr is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Pr–Rh bond lengths are 3.19 Å. Rh is bonded to six equivalent Pr and six equivalent Rh atoms to form a mixture of edge, face, and corner-sharing RhPr6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.72 Å.
MoRh3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Mo is bonded to twelve equivalent Rh atoms to form MoRh12 cuboctahedra that share corners with six equivalent MoRh12 cuboctahedra, corners with twelve equivalent RhMo4Rh8 cuboctahedra, edges with eighteen equivalent RhMo4Rh8 cuboctahedra, faces with eight equivalent MoRh12 cuboctahedra, and faces with twelve equivalent RhMo4Rh8 cuboctahedra. There are six shorter (2.71 Å) and six longer (2.76 Å) Mo–Rh bond lengths. Rh is bonded to four equivalent Mo and eight equivalent Rh atoms to form RhMo4Rh8 cuboctahedra that share corners with four equivalent MoRh12 cuboctahedra, corners with fourteen equivalent RhMo4Rh8 cuboctahedra, edges with six equivalent MoRh12 cuboctahedra, edges with twelve equivalent RhMo4Rh8 cuboctahedra, faces with four equivalent MoRh12 cuboctahedra, and faces with sixteen equivalent RhMo4Rh8 cuboctahedra. There are a spread of Rh–Rh bond distances ranging from 2.71–2.77 Å.
PaRh3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Pa is bonded to twelve equivalent Rh atoms to form PaRh12 cuboctahedra that share corners with twelve equivalent PaRh12 cuboctahedra, edges with twenty-four equivalent RhPa4Rh8 cuboctahedra, faces with six equivalent PaRh12 cuboctahedra, and faces with twelve equivalent RhPa4Rh8 cuboctahedra. All Pa–Rh bond lengths are 2.87 Å. Rh is bonded to four equivalent Pa and eight equivalent Rh atoms to form distorted RhPa4Rh8 cuboctahedra that share corners with twelve equivalent RhPa4Rh8 cuboctahedra, edges with eight equivalent PaRh12 cuboctahedra, edges with sixteen equivalent RhPa4Rh8 cuboctahedra, faces with four equivalent PaRh12 cuboctahedra, and faces with fourteen equivalent RhPa4Rh8 cuboctahedra. All Rh–Rh bond lengths are 2.87 Å.
TmRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Tm is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Tm–Rh bond lengths are 3.12 Å. Rh is bonded to six equivalent Tm and six equivalent Rh atoms to form a mixture of face, edge, and corner-sharing RhTm6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.66 Å.
Rh3W is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. W is bonded to twelve equivalent Rh atoms to form WRh12 cuboctahedra that share corners with six equivalent WRh12 cuboctahedra, corners with twelve equivalent RhRh8W4 cuboctahedra, edges with eighteen equivalent RhRh8W4 cuboctahedra, faces with eight equivalent WRh12 cuboctahedra, and faces with twelve equivalent RhRh8W4 cuboctahedra. There are six shorter (2.71 Å) and six longer (2.76 Å) W–Rh bond lengths. Rh is bonded to four equivalent W and eight equivalent Rh atoms to form RhRh8W4 cuboctahedra that share corners with four equivalent WRh12 cuboctahedra, corners with fourteen equivalent RhRh8W4 cuboctahedra, edges with six equivalent WRh12 cuboctahedra, edges with twelve equivalent RhRh8W4 cuboctahedra, faces with four equivalent WRh12 cuboctahedra, and faces with sixteen equivalent RhRh8W4 cuboctahedra. There are a spread of Rh–Rh bond distances ranging from 2.72–2.77 Å.
Sr2Rh2In3 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Sr is bonded in a 1-coordinate geometry to four equivalent Rh and eight In atoms. There are a spread of Sr–Rh bond distances ranging from 3.10–3.53 Å. There are a spread of Sr–In bond distances ranging from 3.43–3.62 Å. Rh is bonded in a 9-coordinate geometry to four equivalent Sr and five In atoms. There are a spread of Rh–In bond distances ranging from 2.73–2.88 Å. There are two inequivalent In sites. In the first In site, In is bonded in a 4-coordinate geometry to six equivalent Sr and four equivalent Rh atoms. In the second In site, In is bonded in a 3-coordinate geometry to five equivalent Sr and three equivalent Rh atoms.
Pb2Rh is Khatyrkite structured and crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. Rh is bonded in a 10-coordinate geometry to two equivalent Rh and eight equivalent Pb atoms. Both Rh–Rh bond lengths are 2.97 Å. All Rh–Pb bond lengths are 2.94 Å. Pb is bonded in a 7-coordinate geometry to four equivalent Rh and one Pb atom. The Pb–Pb bond length is 3.22 Å.
MnRhAs crystallizes in the hexagonal P-62m space group. The structure is three-dimensional. Mn is bonded in a 11-coordinate geometry to six equivalent Rh and five As atoms. There are two shorter (2.82 Å) and four longer (2.95 Å) Mn–Rh bond lengths. There are one shorter (2.63 Å) and four longer (2.69 Å) Mn–As bond lengths. Rh is bonded in a 10-coordinate geometry to six equivalent Mn and four As atoms. There are two shorter (2.42 Å) and two longer (2.50 Å) Rh–As bond lengths. There are two inequivalent As sites. In the first As site, As is bonded in a 9-coordinate geometry to three equivalent Mn and six equivalent Rh atoms. In the second As site, As is bonded in a 9-coordinate geometry to six equivalent Mn and three equivalent Rh atoms.
BaRh2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Ba is bonded in a 12-coordinate geometry to twelve equivalent Rh atoms. All Ba–Rh bond lengths are 3.30 Å. Rh is bonded to six equivalent Ba and six equivalent Rh atoms to form a mixture of edge, corner, and face-sharing RhBa6Rh6 cuboctahedra. All Rh–Rh bond lengths are 2.82 Å.