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At least 793 records · Page 44

Particle scale impacts on deconstruction energy of pine residues

The goal of this Case Study was to quantify the impacts of variable moisture and ash on hammer mill throughput and energy consumption and on generation of fines that are not able to be fed to conversion, as compared to a status quo Base Case system. Also considered was convertible carbon content (minimum carbon specification) and maximum ash content and the delivered feedstock cost impacts of not being able to feed residue not meeting both specifications to the conversion reactor. Laboratory data on the impacts of input particle size and moisture content on the exit particle size were received from FCIC Subtask 5.2 from their single particle impact population balance modeling study. Additional throughput and energy consumption data were obtained from FCIC Subtask 5.2 for the same grinder with a 6 mm screen in place. These data were utilized to develop the necessary response surface equations to perform throughput analysis using discrete event simulation. Because the ash contents in the separated fines had not been analyzed in the laboratory at the time of the model runs, we chose to assume that the ash distributed proportionally with total mass into the overs and unders in the disk screen following grinding. Key takeaways from this Case Study are that it is significantly more cost effective to hammer mill the residue prior to drying, even though the grinder throughput is lower and energy consumption is higher versus drying first before grinding. An effect of dry grinding versus high moisture grinding is the production of higher amounts of fines during dry grinding, leading to significantly more of the ground feedstock being rejected by conversion for being below a minimum particle size. With wet grinding the system is still able to produce more preprocessed feedstock meeting the minimum particle size specification even though the instantaneous throughput is lower than for the case of grinding dry feedstock. Additionally, even without the higher fines production from dry grinding, the status quo would still be more costly than wet grinding because the material is rejected after the drying energy has already been input for the dry grinding case. Finally, significant reductions in drying energy are obtained by drying after grinding, and those reductions are of far greater magnitude than the grinding energy increase.

09 BIOMASS FUELS↗

Air classification of forest residue for tissue and ash separation efficiency

The goal of this Case Study was to evaluate the performance of air classification of logging residues toward meeting conversion CMAs for carbon and ash contents, as compared to the static status quo Base Case system in which the residues are first dried and then ground in a hammer mill with a 6 mm screen and fines < 1.18 mm are removed. Also considered were moisture and ash impacts on throughput and Overall Operating Effectiveness (OOE), as well as delivered feedstock cost and minimum fuel selling price (MFSP). Laboratory data on the impacts of fan speed and moisture content on the separation efficiency of soil ash, needles and bark from white wood were received from FCIC Subtask 5.2. Average throughput and energy consumption data were obtained from the Bioenergy Feedstock National User Facility (BFNUF) for the same air classifier. These data were utilized to develop the necessary response surface equations to perform throughput analysis using discrete event simulation. Because the Base Case status quo system utilizes drying prior to grinding, we modeled the Case Study with drying prior to air classification and subsequent grinding of the separated white wood to isolate the individual quality and cost impacts of air classification relative to the Base Case system. Key takeaways from this Case Study are that air classification improves the quality of the final material, but increases the production cost, especially when lights are disposed; this becomes a tradeoff between increased conversion yield and the extra cost. Removing material should be done as early in the process as possible. Each operation that occurs prior to removing the material increases the cost of the disposed material and leads to wasted energy expenditures. As processes are included or modified, the impact on monetary and energy cost should be included in the decision process. Identifying alternative uses and the associated value for material that is separated from the feedstock stream will have a significant impact on the delivered cost of the material. Although there was an increase in production cost by adding air classification, there was a resulting benefit to the MFSP when meeting or exceeding all of the conversion CMAs; this was an important finding that should be explored further with FCIC Subtask 8.3 and potentially FCIC Task 6.

09 BIOMASS FUELS↗

Agricultural residue production by county - mature-market medium scenario

This dataset contains data on agricultural residue production by county from 2022 to 2041. The agricultural residue includes barley straw, corn stover, oats straw, sorghum stubble, and wheat straw. The dataset was obtained from the database of the BT23 (Davis et al., 2024) for the mature-market medium scenario with biomass market prices from $50 to $130 per dry ton. For access to this dataset, please use the contact form and indicate the dataset by name.

agricultural residues↗

Agricultural crop and residue production by county - mature-market medium scenario at $70

This dataset contains data on agricultural crop and residue production by county from 2022 to 2041. The agricultural crop in this dataset includes barley, biomass sorghum, corn, cotton, energy cane, eucalyptus, grain sorghum, hay, miscanthus, oats, pine, poplar, rice, soybean, switchgrass, wheat, and willow, and the agricultural residue includes barley straw, corn stover, oats straw, sorghum stubble, and wheat straw. The dataset was obtained from the database of the BT23 (Davis et al., 2024) for the mature-market medium scenario with biomass market prices of up to $70 per dry ton.

agricultural production↗

Influence of Oscillatory Smoothing on the Residual Stress in Cylindrical Components

The influence of oscillatory smoothing on the residual stress in cylindrical components is investigated by simulation and laboratory experiments. The residual stress is found to depend on the tool supply, the interference, the workpiece speed, the oscillatory frequency, and the tool’s angular position (inclination). The experimental results are in good agreement with the modeling data.

42 ENGINEERING↗

Assessment and Non-Destructive Evaluation of the Influence of Residual Solvent on a Two-Part Epoxy-Based Adhesive Using Ultrasonics

Polymers are increasingly being used in higher demanding applications due to their ability to tailor the properties of structures while allowing for a weight and cost reduction. Solvents play an important role in the manufacture of polymeric structures since they allow for a reduction in the polymer’s viscosity or assist with the dispersion of fillers into the polymer matrix. However, the incorrect removal of the solvent affects both the physical and chemical properties of polymeric materials. The presence of residual solvent can also negatively affect the curing kinetics and the final quality of polymers. Destructive testing is mainly performed to characterize the properties of these materials. However, this type of testing involves using lab-type equipment that cannot be taken in-field to perform in situ testing and requires a specific sample preparation. Here, a method is presented to non-destructively evaluate the curing process and final viscoelastic properties of polymeric materials using ultrasonics. In this study, changes in longitudinal sound speed were detected during the curing of an aerospace epoxy adhesive as a result of variations in polymer chemistry. To simulate the presence of residual solvent, samples containing different weight percentages of isopropyl alcohol were manufactured and tested using ultrasonics. Thermogravimetric analysis was used to show changes in the decomposition of the adhesive due to the presence of IPA within the polymer structure. Adding 2, 4, and 6 wt.% of IPA decreased the adhesive’s lap shear strength by 40, 58, and 71%, respectively. Ultrasonics were used to show how the solvent influenced the curing process and the final sound speed of the adhesive. Young’s modulus and Poisson’s ratio were determined using both the longitudinal and shear sound speeds of the adhesive. Using ultrasonics has the potential to non-invasively characterize the quality of polymers in both an in-field and manufacturing settings, ensuring their reliability during use in demanding applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Lifecycle Assessment and Techno-Economic Analysis of Biochar Pellet Production from Forest Residues and Field Application

Biochar produced from low-value forest biomass can provide substantial benefits to ecosystems and mitigate climate change-induced risks such as forest fires. Forest residues from restoration activities and timber harvest and biochar itself are bulky and thus incur high logistic costs, so are considered major bottlenecks for the commercialization of the biochar industry. The objectives of this study were to assess the environmental footprints and techno-economic feasibility of converting forest residues in Pacific Northwest United States into biochar pellets using portable systems followed by delivery of the final product to end-users for land application (dispersion). Two portable systems (Biochar Solutions Incorporated (BSI) and Air Curtain Burner (ACB)) were considered for biochar production. A cradle-to-grave lifecycle assessment (LCA) and a discounted cash flow analysis method were used to quantify the environmental impacts and minimum selling price (MSP) of biochar. The global warming (GW) impact of biochar production through BSI and ACB was estimated to be 306–444, and 750–1016 kgCO₂eq/tonne biochar applied to the field, respectively. The MSP of biochar produced through BSI and ACB was 1674–1909 and 528–1051 USD/tonne biochar applied to the field, respectively. Pelletizing of biochar reduced GW impacts during outbound logistics (~8–20%) but increased emissions during pelletizing (~1–9%). Results show the BSI system was a more viable option in terms of GW impact, whereas the ACB system can produce biochar with lower MSP. The results of the study conclude that the production of biochar pellets through the two portable systems and applied to fields can be both an environmentally beneficial and economically viable option.

09 BIOMASS FUELS↗

Exploratory Studies of Mechanical Properties, Residual Stress, and Grain Evolution at the Local Regions near Pores in Additively Manufactured Metals

Directed energy deposition (DED) is gaining widespread acceptance in various industrial applications since its unique manufacturing features allow the DED to print metallic parts with very complex geometries. However, DED inevitably generates a lot of internal pores which can limit the widespread applications of the DED technique. The current studies on DED porosity are mostly focused on analyzing pores’ bulk-scale influences on mechanical properties and performances. Since DED pores have a micro-scale existence, with dimensions ranging from a few microns to several hundred microns, it is fundamental to explore the pores’ influences on the micro-scale, including local mechanical properties, residual stress, and grains near pores. However, this important research direction has been neglected. The objective of this work is to fill the above gap in DED porosity research and acquire a fundamental understanding of the role of porosity on a microscopic scale. The authors used nanoindentation approaches to investigate internal pores’ effects on mechanical properties and residual stress in local regions surrounding the pores. In addition, the grains near pores were observed through EBSD, and simulated with the Kinetic Monte Carlo model. The research findings can be provided for DED researchers and industrial practitioners as technical guidance. Most importantly, the research results can work as a good reference for tracing the source of bulk-scale mechanical performances and properties of DED parts with internal pores.

36 MATERIALS SCIENCE↗

Residual Thrust in a Solid Rocket Motor: A Model Applied to the Mars Ascent Vehicle

A model for solid rocket motor residual thrust is built from the concept that hot nozzle phenolic or carbon materials provide a radiating source of heat flux to the insulation, leading to continued off-gassing by pyrolysis. This model is 1. Fitted to flight datasets and scaled to the Mars Ascent Vehicle second stage motor (MAV SRM2), and 2. Derived with MAV SRM2 design and material estimates. The two methods show a potential range of modeling uncertainty for use by mission analysts. Further loss methods that could reduce the maximum residual impulse are identified but left to further work to evaluate.

Solid rocket motors↗

Residual Thrust in a Solid Rocket Motor: A Model Applied to the Mars Ascent Vehicle

A model for solid rocket motor residual thrust is built from the concept that hot nozzle phenolic or carbon materials provide a radiating source of heat flux to the insulation, leading to continued off-gassing by pyrolysis. This model is 1. Fitted to flight datasets and scaled to the Mars Ascent Vehicle second stage motor (MAV SRM2), and 2. Derived with MAV SRM2 design and material estimates. The two methods show a potential range of modeling uncertainty for use by mission analysts. Further loss methods that could reduce the maximum residual impulse are identified but left to further work to evaluate.

Solid rocket motors↗

An Examination of Autumn Southern Polar Ozone Tendencies and the Residual Circulation in MERRA-2 Products

Changes in lower stratospheric ozone caused by dynamical transport can be difficult to characterize and thus are sometimes difficult to distinguish from chemical losses. Correlations between ozone changes and various dynamical proxies (e.g., the eddy heat flux) from year to year can be of interest, but they do little in themselves to explain the ozone transport mechanisms behind such correlations. In this study, we use products from the Modern-Era Retrospective analysis for Research and Applications Version 2 (MERRA-2) to calculate the ozone mass flux, integrating it in space and time over the upper tropospheric/lower stratospheric Southern polar cap during periods when little chemical loss is expected. The ozone mass flux is expressed in terms of components of the residual circulation of the Transformed Eulerian Mean (TEM, i.e., 𝑣𝑣̅ ∗and 𝑤𝑤(∗) as well as eddy mixing terms. We relate these terms to the local ozone mass tendency ("#! "$ ), similarly integrated, and we find that the interannual variability of the ozone changes are strongly related to the residual meridional circulation and the meridional eddy mixing terms. These directly calculated dynamical transport terms provide clearer ozone proxies. Removing these advective terms from a long-term ozone time series can more effectively reveal ozone variations and long-term trends, specifically those caused by photochemical production and losses (e.g., human-produced ozone depletion).

Ozone↗

A residual stress study in similar and dissimilar welds

Residual strain distributions in similar and dissimilar welds were measured using neutron diffraction (ND) method. Then, using three strain components, three-dimensional stress states were calculated. The results were used to determine the effect of the martensitic phase transformation and material properties on residual stress (RS) distribution. It was observed that smaller longitudinal RS was induced in the low carbon steel side of dissimilar weld when compared to its similar weld. Also, it was found that the transverse RS near and within the weld zone (WZ) in dissimilar weld exhibited a distinctive trend, with tensile mode reaching the yield strength of the base metal (BM). In order to characterize the WZ in dissimilar weld, we deployed optical microscopy, hardness, and energy dispersive X-ray spectroscopy (EDAX). This study not only provides further insight into the RS state in similar and dissimilar welds; it also delivers important consequences of phase transformation in the latter case.

36 MATERIALS SCIENCE↗

Separation and recovery of uranium from residues to allow disposal as VLLW - 15379

During fabrication of uranium fuel, significant amounts of uranium contaminated wastes are generated. The uranium concentration in the waste is typically 1-10% in weight. With this uranium concentration, the residues constitute long lived Low Level Waste (LL-LLW) which need to be disposed of in a repository specifically for this type of waste. Through recovery of uranium from the primary waste, the potential for reducing the concentration of uranium to such low levels that the remaining waste qualifies as Very Low Level Waste (VLLW) are significant. The remaining waste could then be disposed of in a less costly disposal than the primary waste. A method for recovery of uranium from waste has been developed and used in Sweden and includes leaching with sulphuric acid, solvent extraction and precipitation. The final result is ammonium di-uranate (ADU). The remaining waste typically has residual uranium content in the range of 100 g uranium per tonne of waste. In several countries this would permit disposal at a hazardous waste landfill site after conditional clearance. During the development process, it has been shown that for certain types of waste it's possible to reduce the uranium concentration even further. The paper gives an overview of the technology, its applications as well as advantages and limitations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Compressional residual stress in Bastogne boudins revealed by synchrotron X-ray microdiffraction

Lattice distortions in crystals can be mapped at the micron scale using synchrotron X-ray Laue microdiffraction (μXRD). From lattice distortions the shape and orientation of the elastic strain tensor can be derived and interpreted in terms of residual stress. We apply the new method to vein quartz from the original boudinage locality at Bastogne, Belgium. Furthermore, a long-standing debate surrounds the kinematics of the Bastogne boudins. The μXRD measurements reveal a shortening residual elastic strain, perpendicular to the vein wall, corroborating the model that the Bastogne boudins formed by layer-parallel shortening and not by layer-parallel extension, as is in the geological community generally inferred by the process of boudinage.

58 GEOSCIENCES↗

High‐efficiency adsorption of various heavy metals by tea residue biochar loaded with nanoscale zero‐valent iron

Abstract Nanoscale zero‐valent iron (nZVI) loaded on tea residue biochar activated with phosphoric acid composites was synthesized. This adsorbent can efficiently adsorb multiple heavy metal ions such as Pb (II), Cr (III), Cu (II), and Ni (II) simultaneously. The adsorption process was found to follow the pseudo‐second‐order kinetic model. Equilibrium adsorption capacities reached 288.18, 162.34, 242.72, and 267.22 mg·g −1 for Pb(II), Cr(III), Cu(II), and Ni(II), respectively. The common interfering ions exhibited lower influence on its adsorption capacity. The adsorption mechanism includes reduction, ion exchange, surface complexation and precipitation. Furthermore, the waste adsorbent was converted into a catalyst in situ, which could catalyze the degradation of Congo red by establishing an electron transfer pathway. This research provides a new concept for the sustainable utilization of industrial tea residues and the harmless treatment of waste nZVI composite adsorbents.

Liu, Shuang↗

Assessing ecological risks to the fish community from residual coal fly ash in Watts Bar Reservoir, Tennessee

For this research, extensive site-specific biological and environmental data were collected to support an evaluation of risks to the fish community in Watts Bar Reservoir from residual ash from the December 2008 Tennessee Valley Authority (TVA) Kingston ash release. This paper describes the approach used and results of the risk assessment for the fish community, which consists of multiple measurement endpoints (measures of exposure and effects) for fish. The lines of evidence included 1) comparing postspill annual fish community assessments with nearby prespill data and data from other TVA reservoirs, 2) evaluating possible effects of exposures of fish eggs and larval fish to ash in controlled laboratory toxicity tests, 3) evaluating reproductive competence of field-exposed fish, 4) assessing individual fish health through physical examination, histopathology, and blood chemistry, 5) comparing fish tissue concentrations with literature-based critical body residues, and 6) comparing concentrations of ash-related contaminants in surface waters with US Environmental Protection Agency's (USEPA) Ambient Water Quality Standards for Fish and Aquatic Life. These measurement endpoints were treated as independent lines of evidence that were integrated into an overall weight-of-evidence estimate of risk to the fish community. Collectively, the data and analysis presented here indicate that ash and ash-related constituents pose negligible risks to the fish communities in Watts Bar Reservoir. This conclusion contradicts the predictions by some researchers immediately following the ash release of devastating effects on the aquatic ecology of Watts Bar Reservoir. The information presented in this article reaffirms the wisdom of carefully evaluating the evidence before predicting probable ecological effects of a major event such as the TVA Kingston ash release. Lastly, this study demonstrates that a thorough and detailed investigation using multiple measurement endpoints is needed to properly evaluate ecological effects.

54 ENVIRONMENTAL SCIENCES↗

Critical amino acid residues in the N-terminal domain of NADPH-dependent assimilatory sulfite reductase flavoprotein mediate octameric assembly

How large, flexible enzymes assemble into defined oligomeric architectures remains a central question in biology. NADPH-dependent assimilatory sulfite reductase (SiR) forms a heterododecamer built on an octameric flavoprotein (SiRFP) core, yet the molecular basis for this assembly has been unresolved because of its disordered N-terminus. Here, we use ion mobility mass spectrometry, small-angle neutron scattering, and mutagenesis to define the mechanism of SiRFP oligomerization. We show that SiRFP forms a discrete, stable octamer in solution. We also report that its N-terminal 52-residue segment is necessary and sufficient to mediate assembly, also mediating oligomerization when fused to a heterologous protein. Structure-guided mutagenesis identifies four residues (Gln22, Tyr39, Phe40, and Gln47) whose substitution disrupts the octamer, producing concentration-dependent lower-order species while retaining catalytic activity. These findings define the determinants of SiRFP assembly with broader implications for engineering homomeric protein complexes.

Nagy, Gergely [ORNL] (ORCID:0000000327420198)↗

Structures of Hsp90α and Hsp90β bound to a purine-scaffold inhibitor reveal an exploitable residue for drug selectivity

Hsp90α and Hsp90β are implicated in a number of cancers and neurodegenerative disorders but the lack of selective pharmacological probes confounds efforts to identify their individual roles. Here, we analyzed the binding of an Hsp90α-selective PU compound, PU-11-trans, to the two cytosolic paralogs. We determined the co-crystal structures of Hsp90α and Hsp90β bound to PU-11-trans, as well as the structure of the apo Hsp90β NTD. The two inhibitor-bound structures reveal that Ser52, a nonconserved residue in the ATP binding pocket in Hsp90α, provides additional stability to PU-11-trans through a water-mediated hydrogen-bonding network. Mutation of Ser52 to alanine, as found in Hsp90β, alters the dissociation constant of Hsp90α for PU-11-trans to match that of Hsp90β. Our results provide a structural explanation for the binding preference of PU inhibitors for Hsp90α and demonstrate that the single nonconserved residue in the ATP-binding pocket may be exploited for α/β selectivity.

60 APPLIED LIFE SCIENCES↗