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At least 793 records · Page 44

AC electrical transport detection of magnetic properties of small, granular, and heterogeneous samples

Experimental constraints and sample limitations can preclude ideal measurements of electrical transport properties of materials. In such situations, AC electrical transport methods are often employed due to a significant increase in signal-to-noise ratio they can provide. However, dynamic effects that are not often accounted for may be present that may modify the signals in these measurements. In particular, dynamic filtering effects are prominent in small, granular, and heterogeneous materials. We demonstrate that a lock-in amplifier based circuit can distinguish between these DC transport and AC filtering effects. Here, we further demonstrate that this filtering can reveal distinct signatures of magnetic transitions while providing a measure of sample quality.

47 OTHER INSTRUMENTATION↗

Small field campaign: aerosol – ice formation closure pilot study. Final Report

Prediction of atmospheric ice formation from aerosol particles by heterogeneous nucleation represents one of the grand challenges in atmospheric science. Our insufficient predictive understanding of primary ice formation is the reason that climate models typically do not include heterogeneous ice nucleation with subsequent effects on climate uncertainty. Mixed-phase clouds, where supercooled water droplets and ice crystals coexist play globally an important role regulating climate. This is especially the case for the Arctic region that experiences the greatest warming due to climate change compared to other regions in the world. Immersion freezing initiated by ice-nucleating particles (INPs) in supercooled water droplets is recognized as the dominant primary ice formation pathway in mixed-phase cloud regimes. For this reason, it is crucial to evaluate our capability to predict immersion freezing for a given ambient aerosol population. The goal of this project is conducting a field-based pilot study at the U.S. DOE Atmospheric Radiation Measurement (ARM) user facility at Southern Great Plains (SGP) to evaluate our capability to predict the number concentration of aerosol particles that serve as INPs in the immersion freezing mode. Successful prediction of INP number concentrations is also termed “closure”. This field-observational approach represents a first-of-its kind attempt of an aerosol–ice formation closure study (AEROICESTUDY). Very few closure studies related to INPs have been conducted, and to our knowledge, none using robust size-resolved ambient aerosol composition measurements as a starting point. Achievement of aerosol–ice formation closure relies on our ability to characterize the ambient aerosol population with respect to particles size and composition and to determine INP number concentrations for specified freezing temperatures. This requires numerous online and offline instrumentation resulting in this pilot field campaign being a multi-institutional and community-collaborative effort. We chose the ARM SGP megasite for this first aerosol-ice formation closure pilot study due to its significant measurement capabilities available to obtain detailed physical characterization of the local aerosol population including size distribution, mass loading, and chemical composition of non-refractory aerosol particles. The overall objective of this project is to identify ice nucleation parameterizations that produce the most robust predictions of INP numbers and thus are best suited to be included in cloud and climate models. This objective includes the following goals for this field and laboratory-based project: i) What are the crucial aerosol physicochemical property measurements needed to accurately guide ice nucleation representations in models and long-term INP measurements? ii) What level of parameter details needs to be known to achieve aerosol–ice formation closure? iii) What are the leading causes for climate model bias in INP predictions? We found that the advances in our understanding of immersion freezing garnered over the last 20 years allowed us to yield partial and full closures of atmospheric immersion freezing from ambient aerosol particles. When the aerosol population is physicochemically complex and parameterizations for representative INP types are not yet available, we still struggle to accurately predict INP number concentrations. This project clearly demonstrates that with more laboratory and field measurements that are accompanied by particle composition analysis, the necessary datasets to achieve aerosol–ice formation closure for various locations will emerge, thus providing a robust foundation for guiding the representation of INPs in cloud and climate models.

54 ENVIRONMENTAL SCIENCES↗

Line positions and intensities of the phosphine (PH 3 ) Pentad near 4.5μm

In order to improve the spectroscopic database for remote sensing of the giant planets, line positions and intensities are determined for the five bands (2ν 2 , ν 2 + ν 4 , 2ν 4 , ν 1 and ν 3 ) that comprise the Pentad of PH 3 between 1950 and 2450 cm -1 . Knowledge of PH 3 spectral line parameters in this region is important for the exploration of dynamics and chemistry on Saturn, (using existing Cassini/VIMS observations) and future near-IR data of Jupiter from Juno and ESA’s Jupiter Icy Moons Explorer (JUICE). For this study, spectra of pure PH 3 from two Fourier transform spectrometers were obtained: (a) five high-resolution (0.00223 cm -1 ), high signal-to-noise (~1800) spectra recorded at room temperature (298.2 K) with the Bruker IFS 125HR Fourier transform spectrometer (FTS) at the Pacific Northwest National Laboratory (PNNL), Richland, Washington and (b) four high-resolution (at 0.0115 cm -1 resolution), high signal-to-noise (~700) spectra recorded at room temperature in the region 1800–5200 cm -1 using the McMath-Pierce Fourier transform spectrometer located at the National Solar Observatory (NSO) on Kitt Peak. Individual line parameters above 2150 cm -1 were retrieved by simultaneous multispectrum fittings of all five Bruker spectra, while retrievals with the four Kitt Peak spectra were done in the 1938–2168 cm -1 range spectrum by spectrum and averaged. In all, positions and intensities were obtained for more than 4400 lines. These included 53 A+A- split pairs of transitions (arising due to vibration–rotation interactions (Coriolis-type interaction) between the ν 3 and ν 1 fundamental bands) for K" = 3, 6, and 9. Over 3400 positions and 1750 intensities of these lines were ultimately identified as relatively unblended and modeled up to J = 14 and K = 12 with rms values of 0.00133 cm -1 and 7.7%, respectively. The PH 3 line parameters (observed positions and measured intensities with known quantum assignments) and Hamiltonian constants are reported. Finally, comparisons with other recent studies are discussed.

Environmental Molecular Sciences Laboratory↗

Moiré deflectometry using the Talbot-Lau interferometer as refraction diagnostic for High Energy Density plasmas at energies below 10 keV

The highly localized density gradients expected in High Energy Density (HED) plasma experiments can be characterized by x-ray phase-contrast imaging in addition to conventional attenuation radiography. Moiré deflectometry using the Talbot-Lau grating interferometer setup is an attractive HED diagnostic due to its high sensitivity to refraction induced phase shifts. We report on the adaptation of such a system for operation in the sub-10 keV range by using a combination of free standing and ultrathin Talbot gratings. This new x-ray energy explored matches well the current x-ray backlighters used for HED experiments, while also enhancing phase effects at lower electron densities. We studied the performance of the high magnification, low energy Talbot-Lau interferometer, for single image phase retrieval using Moiré fringe deflectometry. Our laboratory and simulation studies indicate that such a device is able to retrieve object electron densities from phase shift measurements. Using laboratory x-ray sources from 7 to 15 μm size we obtained accurate simultaneous measurements of refraction and attenuation for both sharp and mild electron density gradients.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Determining Confounding Sensitivities In Eddy Current Thin Film Measurements

Determining Confounding Sensitivities In Eddy Current Thin Film Measurements Ethan Gros, Lalita Udpa, Electrical Engineering, Michigan State University, East Lansing MI 48824 James A. Smith, Experiment Analysis, Idaho National Laboratory, Idaho Falls ID 83415 Eddy current (EC) techniques are widely used in industry to measure the thickness of non-conductive films on a metal substrate. This is done using a system whereby a coil carrying a high-frequency alternating current is used to create an alternating magnetic field at the surface of the instrument's probe. When the probe is brought near a conductive surface, the alternating magnetic field will induce ECs in the conductor. The substrate characteristics and the distance of the probe from the substrate (the coating thickness) affect the magnitude of the ECs. The induced currents load the probe coil affecting the terminal impedance of the coil. The measured probe impedance is related to the lift off between coil and conductor as well as conductivity of the test sample. For a known conductivity sample, the probe impedance can be converted into an equivalent film thickness value. The EC measurement can be confounded by a number of measurement parameters. It is the goal of this research to determine which physical properties of the measurement set-up and sample can adversely affect the thickness measurement. The eddy current testing is performed using a commercially available, hand held eddy current probe (ETA3.3H spring loaded eddy probe running at 8 MHz) that comes with a stand to hold the probe. The stand holds the probe and adjusts the probe on the z-axis to help position the probe in the correct area as well as make precise measurements. The signal from the probe is sent to a hand held readout, where the results are recorded directly in terms of liftoff or film thickness. Understanding the effect of certain factors on the measurements of film thickness, will help to evaluate how accurate the ETA3.3H spring loaded eddy probe is at measuring film thickness under varying experimental conditions. This research will study the effects of a number of factors such as i) calibration, ii) conductivity, iii) edge effect, iv) surface finish of base material and v) cable condition and compare with the long term reproducibility of a standard measurement. This work was performed with support from the Department of Energy under the United States National Nuclear Security Administration (NNSA) at the Idaho National Laboratory.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Hardware and software for ground tests of onboard charged particle spectrometers

The article presents a hardware and software complex for ground tests of onboard charged particle spectrometers that are designed at the National Research Nuclear University MEPhI for monitoring of nuclear-physical factors of space weather and can be installed in a wide class of satellites. The structural scheme and operating principles of component parts are discussed. The main algorithm and software features are presented. The technique of ground spectrometer tests and calibrations in various measurement modes at atmospheric cosmic particle flows, both in autonomous laboratories and in interface tests as part of a satellite, is also described.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

PeleC: An adaptive mesh refinement solver for compressible reacting flows

Reacting flow simulations for combustion applications require extensive computing capabilities. Leveraging the AMReX library, the Pele suite of combustion simulation tools targets the largest supercomputers available and future exascale machines. We introduce PeleC, the compressible solver in the Pele suite, and detail its capabilities, including complex geometry representation, chemistry integration, and discretization. We present a comparison of development efforts using both OpenACC and AMReX’s C++ performance portability framework for execution on multiple GPU architectures. We discuss relevant details that have allowed PeleC to achieve high performance and scalability. PeleC’s performance characteristics are measured through relevant simulations on multiple supercomputers. The success of PeleC’s design for exascale is exhibited through demonstration of a 160 billion cell simulation and weak scaling onto 100% of Summit, an NVIDIA-based GPU supercomputer at Oak Ridge National Laboratory. Our results provide confidence that PeleC will enable future combustion science simulations with unprecedented fidelity.

97 MATHEMATICS AND COMPUTING↗

Qualification of Radiocarbon Using Spectroscopic Means Final Report CRADA No. TC02170.0

The purpose of this Cooperative Research and Development Agreement (CRADA) between Picarro Inc. and Lawrence Livermore National Security, LLC, as operator of the Lawrence Livermore National Laboratory (referred to individually as "LLNL") is to develop a new capability for measuring 14 C in biological and environmental samples at levels near the isotopic natural abundance of this isotope.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Advancements in Heat Transfer and Fluid Mechanics (Fundamentals and Applications)

Thermo-fluid science is a foundational discipline for numerous mechanical systems, particularly in energy production and building equipment, where thermal and mechanical energy transfer play critical roles. Advancements in heat transfer and fluid mechanics have significantly enhanced these systems, driving progress in associated market sectors. For instance, evaporator and condenser coils are essential for optimizing vapor compression cycles in building equipment. Heat pumps used for space and water heating constitute a major share of building systems, with microchannel heat exchanger technology at the forefront of these innovations. It is worth mentioning that advancements in heat transfer and fluid mechanics significantly alleviate the challenge of designing energy-efficient building equipment. The development of research techniques has contributed significantly to the advancement of science; for example, in the experimental field, non-intrusive measurement techniques such as Particle Image Velocimetry (PIV) are now capable of resolving flow behavior in a 3D format for different length and time scales.

42 ENGINEERING↗

Interactive information processing for NASA's mesoscale analysis and space sensor program

The Atmospheric Sciences Division (ASD) of the Systems Dynamics Laboratory at NASA's Marshall Space Flight Center (MSFC) is currently involved in interactive information processing for the Mesoscale Analysis and Space Sensor (MASS) program. Specifically, the ASD is engaged in the development and implementation of new space-borne remote sensing technology to observe and measure mesoscale atmospheric processes. These space measurements and conventional observational data are being processed together to gain an improved understanding of the mesoscale structure and the dynamical evolution of the atmosphere relative to cloud development and precipitation processes. To satisfy its vast data processing requirements, the ASD has developed a Researcher Computer System consiting of three primary computer systems which provides over 20 scientists with a wide range of capabilities for processing and displaying a large volumes of remote sensing data. Each of the computers performs a specific function according to its unique capabilities.

Parker, K. G.↗

Soil moisture retrieval in the Oberpfaffenhofen testsite using MAC Europe AIRSAR data

Soil moisture content is an important parameter in many disciplines of science like hydrology, meteorology, agriculture and others. Microwave remote sensing technique has a high potential in measuring the dielectric constant of soils, which is strongly governed by the soil moisture. Much excellent work has been done on investigating the relationship between backscattering coefficient and soil moisture. Most of these studies are measured in a laboratory or are carried out with a multitemporal data set. This means, that the variation in the backscattering coefficient is only related to the soil moisture because all other parameters influencing the backscattering like surface roughness, vegetation cover, plant geometry, phenology of plants and row direction are kept constant. In this study the sensitivity of the backscattering coefficient to soil moisture of corn fields is investigated. In the framework of the MAC-Europe Campaign in June 1991, the NASA/JPL three-frequency polarimetric AIRSAR system collected data over the test site Oberpfaffenhofen. The AIRSAR campaign in Oberpfaffenhofen was complemented with intensive ground truth measurements. The sampled corn fields are nearly in the range of the same incidence angle (approximately 20 deg) and belong to different soil types. The evaluation was carried out at a single data set. The results show that the backscattering, measured at P-band, can be described with only two parameters very well. The main parameter influencing the backscattering is the soil moisture content; the second subordinated parameter is the row direction.

Wever, Tobias↗

Some Impacts of Solar Irradiance Variation on Terrestrial Climate

As chairman of the Special Session addressing the above topic, a brief overview of the problem will be offered, after which 20-minute talks will be given on the determination of solar irradiance variations from space observations (Dr. Judit Pap) and from groundbased measurements of solar magnetic fields (Dr. Harrison Jones). The chairman will then introduce four panel members representing different areas of expertise bearing on the topic. Each panel member will offer a brief 5-minute summary of his views. Panel members are: Chick Keller, Los Alamos National Laboratory; Drew Shindell, Goddard Institute for Space Science, Columbia University; Michael Schlesinger, University of Illinois; Sabatino Sofia, Yale University. General Circulation Models of the terrestrial atmosphere, the possible impact on this atmosphere of large percentage changes in the solar EUV over a solar cycle, and the role of strong magnetic field in the solar convection zone on irradiance variation will all be considered in brief summaries. The chairman will conclude the session by facilitating a discussion between the audience, the main speakers, and the panel members.

Jordan, Stuart D.↗

Long-Term Total Solar Irradiance (TSI) Variability Trends: 1984-2004

The incoming total solar irradiance (TSI), typically referred to as the solar constant, is being studied to identify long-term TSI changes, which may trigger global climate changes. The TSI is normalized to the mean earth-sun distance. Studies of spacecraft TSI data sets confirmed the existence of 0.1 %, long-term TSI variability component with a period of 10 years. The component varied directly with solar magnetic activity associated with recent 10-year sunspot cycles. The 0.1 % TSI variability component is clearly present in the spacecraft data sets from the 1984-2004, Earth Radiation Budget Experiment (ERBE) active cavity radiometer (ACR) solar monitor; 1978-1993, Nimbus-7 HF; 1980-1989, Solar Maximum Mission [SMM] ACRIM; 1991-2004, Upper Atmosphere Research Satellite (UARS) ACRIM; 1996-2003, Solar and Heliospheric Observatory (SOHO)/VIRGO, Space Science (ATLAS), 2000-2004, ACRIMSAT; and 2003-2004 SOlar Radiation and Climate Experiment (SORCE) active cavity radiometer (ACR) missions. From October 1984, through March 2004, the ERBS/ERBE solar monitor was used to produce the longest continuous data set of total solar irradiance (TSI) variability measurements. The solar monitor is located on Shuttle Atmospheric Laboratory for Applications and the NASA Earth Radiation Budget Satellite (ERBS). Maximum TSI values occurred during the 1989-1991, and 1998-2002, time frames; while minimum [quiet sun] TSI levels occurred during 1986 and 1996. Recent ERBS measurements indicate that the TSI is decreasing to forecasted, minimum levels by 2006. Using the discontinuous non-operational Nimbus-7, SMM ACRIM, and UARS ACRIM mission TSI data sets, Wilson and Mordvinor (2003) suggested the existence of an additional long-term TSI variability component, 0.05 %, with a period longer than a decade. Analyses of the ERBS/ERBE data set do not support the Wilson and Mordvinor analyses approach because it used the Nimbus-7 data set which exhibited a significant ACR response shift of 0.7 Wm-2

Lee, Robert Benjamin, III↗

Lunar and Planetary Science XXXVI, Part 13

Contents include the following: A Fast, Non-Destructive Method for Classifying Ordinary Chondrite Falls Using Density and Magnetic Susceptibility. An Update on Results from the Magnetic Properties Experiments on the Mars Exploration Rovers, Spirit and Opportunity. Measurement Protocols for In Situ Analysis of Organic Compounds at Mars and Comets. Piping Structures on Earth and Possibly Mars: Astrobiological Implications. Uranium and Lead in the Early Planetary Core Formation: New Insights Given by High Pressure and Temperature Experiments. The Mast Cameras and Mars Descent Imager (MARDI) for the 2009 Mars Science Laboratory. MGS MOC: First Views of Mars at Sub-Meter Resolution from Orbit. Analysis of Candor Chasma Interior Layered Deposits from OMEGA/MEX Spectra. Analysis of Valley Networks on Valles Marineris Plateau Using HRSC/MEX Data. Solar Abundance of Elements from Neutron-Capture Cross Sections. Preliminary Evaluation of the Secondary Ion/Accelerator Mass Spectrometer, MegaSIMS. Equilibrium Landforms in the Dry Valleys of Antarctica: Implications for Landscape Evolution and Climate Change on Mars. Continued Study of Ba Isotopic Compositions of Presolar Silicon Carbide Grains from Supernovae. Paleoenviromental Evolution of the Holden-Uzboi Area. Stability of Magnesium Sulfate Minerals in Martian Environments. Tungsten Isotopic Constraints on the Formation and Evolution of Iron Meteorite Parent Bodies. Migration of Dust Particles and Volatiles Delivery to the Inner Planets. On the Sitting of Trapped Noble Gases in Insoluble Organic Matter of Primitive Meteorites. Trapping of Xenon Upon Evaporation-Condensation of Organic Matter Under UV Irradiation: Isotopic Fractionation and Electron Paramagnetic Resonance Analysis. Stability of Water on Mars. A Didactic Activity. Analysis of Coronae in the Parga Chasma Region, Venus. Photometric and Compositional Surface Properties of the Gusev Crater Region, Mars, as Derived from Multi-Angle, Multi-Spectral Investigation of Mars Express HRSC Data. Mapping Compositional Diversity on Mars: Spatial Distribution and Geological Implications. A New Simulation Chamber for Studying Planetary Environments. Folded Structure in Terra Sirenum. Mars. Nitrogen-Noble Gas Static Mass Spectrometry of Genesis Collector Materials. Neon Isotope Heterogeneity in the Terrestrial Mantle: Implication for the Acquisition of Volatile Elements in Terrestrial Planets. The Cosmic Clock, the Cycle of Terrestrial Mass Extinctions.

Source record↗

NASA Self-Assessment of Space Radiation Research

Space exploration involves unavoidable exposures to high-energy galactic cosmic rays whose penetration power and associated secondary radiation makes radiation shielding ineffective and cost prohibitive. NASA recognizing the possible health dangers from cosmic rays notified the U.S. Congress as early as 1959 of the need for a dedicated heavy ion accelerator to study the largely unknown biological effects of galactic cosmic rays on astronauts. Information and scientific tools to study radiation health effects expanded over the new decades as NASA exploration programs to the moon and preparations for Mars exploration were carried out. In the 1970 s through the early 1990 s a more than 3-fold increase over earlier estimates of fatal cancer risks from gamma-rays, and new knowledge of the biological dangers of high LET radiation were obtained. Other research has increased concern for degenerative risks to the central nervous system and other tissues at lower doses compared to earlier estimates. In 1996 a review by the National Academy of Sciences Space Science Board re-iterated the need for a dedicated ground-based accelerator facility capable of providing up to 2000 research hours per year to reduce uncertainties in risks projections and develop effective mitigation measures. In 1998 NASA appropriated funds for construction of a dedicated research facility and the NASA Space Radiation Laboratory (NSRL) opened for research in October of 2003. This year marks the 8th year of NSRL research were about 1000 research hours per year have been utilized. In anticipation of the approaching ten year milestone, funded investigators and selected others are invited to participate in a critical self-assessment of NSRL research progress towards NASA s goals in space radiation research. A Blue and Red Team Assessment format has been integrated into meeting posters and special plenary sessions to allow for a critical debate on the progress of the research and major gaps areas. Blue teams will highlight progress and important new knowledge gained. Red teams will challenge the Blue teams on proposed highlights and point to Gaps not considered. We will review the current space radiation Risks and Gaps under investigation at NASA, critical data sets and research highlights anticipated, and possible goals for future research at NSRL.

Cucinotta, Francis A.↗

NASA Tech Briefs, January 2012

Contents of this issue are: (1) Energy-Based Tetrahedron Sensor for High-Temperature, High-Pressure Environments (2) Handheld Universal Diagnostic Sensor (3) Large-Area Vacuum Ultraviolet Sensors (4) Fiber Bragg Grating Sensor System for Monitoring Smart Composite Aerospace Structures (5) Health-Enabled Smart Sensor Fusion Technology (6) Extended-Range Passive RFID and Sensor Tags (7) Hybrid Collaborative Learning for Classification and Clustering in Sensor Networks (8) Self-Healing, Inflatable, Rigidizable Shelter (9) Improvements in Cold-Plate Fabrication (10) Technique for Radiometer and Antenna Array Calibration - TRAAC (11) Real-Time Cognitive Computing Architecture for Data Fusion in a Dynamic Environment (12) Programmable Digital Controller (13) Use of CCSDS Packets Over SpaceWire to Control Hardware (14) Key Decision Record Creation and Approval Module (15) Enhanced Graphics for Extended Scale Range (16) Debris Examination Using Ballistic and Radar Integrated Software (17) Data Distribution System (DDS) and Solar Dynamic Observatory Ground Station (SDOGS) (18) Integration Manager (19) Eclipse-Free-Time Assessment Tool for IRIS (20) Automated and Manual Rocket Crater Measurement Software (21) MATLAB Stability and Control Toolbox Trim and Static Stability Module (22) Patched Conic Trajectory Code (23) Ring Image Analyzer (24) SureTrak Probability of Impact Display (25) Implementation of a Non-Metallic Barrier in an Electric Motor (26) Multi-Mission Radioisotope Thermoelectric Generator Heat Exchangers for the Mars Science Laboratory Rover (27) Uniform Dust Distributor for Testing Radiative Emittance of Dust-Coated Surfaces (28) MicroProbe Small Unmanned Aerial System (29) Highly Stable and Active Catalyst for Sabatier Reactions (30) Better Proton-Conducting Polymers for Fuel-Cell Membranes (31) CCD Camera Lens Interface for Real-Time Theodolite Alignment (32) Peregrine 100-km Sounding Rocket Project (33) SOFIA Closed- and Open-Door Aerodynamic Analyses (34) Sonic Thermometer for High-Altitude Balloons (35) Near-Infrared Photon-Counting Camera for High-Sensitivity Observations (36) Integrated Optics Achromatic Nuller for Stellar Interferometry (37) High-Speed Digital Interferometry (38) Ultra-Miniature Lidar Scanner for Launch Range Data Collection (39) Shape and Color Features for Object Recognition Search (40) Explanation Capabilities for Behavior-Based Robot Control (41) A DNA-Inspired Encryption Methodology for Secure, Mobile Ad Hoc Networks (42) Quality Control Method for a Micro-Nano-Channel Microfabricated Device (43) Corner-Cube Retroreflector Instrument for Advanced Lunar Laser Ranging (44) Electrospray Collection of Lunar Dust (45) Fabrication of a Kilopixel Array of Superconducting Microcalorimeters with Microstripline Wiring Spacecraft Attitude Tracking and Maneuver Using Combined Magnetic Actuators (46) Coherent Detector for Near-Angle Scattering and Polarization Characterization of Telescope Mirror Coatings

Source record↗

Determination of Aerothermal Environment and Ablator Material Response Using Inverse Methods

The Mars Science Laboratory (MSL) was protected during entry into the Martian atmosphere by a thermal protection system that used NASA’s Phenolic Impregnated Carbon Ablator (PICA). The heat shield of the probe was instrumented with the Mars Entry Descent and Landing Instrument (MEDLI) suite of sensors. MEDLI Integrated Sensor Plugs (MISP) included thermocouples that measured in-depth temperatures at various locations on the heatshield. The flight data has been used as a benchmark for validating ablation codes within NASA. This work seeks to refine the estimate of the material properties for the MSL heat shield and the aerothermal environment during Mars entry using estimation methods in DAKOTA on the temperature data obtained from MEDLI.

Thornton, John M.↗

Hexavalent chromium sensor for real-time In situ measurement of ground water contamination - 15433

Hexavalent chromium (Cr{sup 6+}) is a contaminant of concern at multiple Department of Energy (DOE) and industrial sites across the United States. It is used in stainless steel production, textile dyes, tanning, wood preservation, and in conversion coatings. It was used at DOE sites, such as the Hanford Nuclear Reservation in Washington state, in the form sodium dichromate (Na{sub 2}Cr{sub 2}O{sub 7}) to inhibit corrosion. This has resulted in the release of chromate (CrO{sub 4}{sup 2-}) to groundwater. Chromate is anionic and is readily transported with ground water through the subsurface to receptors such as river biota at Hanford, and in some regions to potable water wells. To improve Cr{sup 6+} groundwater plume monitoring while reducing monitoring cost, a cable-deployed, submersible sensor was developed for direct measurements of Cr{sup 6+} in natural groundwater. With a diameter of 3.8 cm (1.5 inch) the sensor could be deployed in 5 cm (2 inch) diameter screened wells. The sensor uses ultra violet (UV) photo-spectroscopy to measure Cr{sup 6+} at concentrations as low as 5 to 10 μg L{sup -1} (as hexavalent chromium, Cr{sup +6}) in natural water. Turbidity, caused by colloidal material suspended in natural water, can interfere with the chromate measurement but was automatically compensated within the instrument. Because the instrument had some temperature sensitivity, a correction was also applied based on in situ temperature measurements in the sensor. The sensor has been tested in the laboratory and was deployed to the field with encouraging results. Laboratory calibrations consistently yielded concentration measurements that correlate well with standard analytical methods (r{sup 2} = 0.99). (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗