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At least 793 records · Page 44

Migration and Distribution of Natural Organic Matter Injected into Subsurface Systems - 16523

The Savannah River Site (SRS) was one of the major U.S. Department of Energy facilities that produced large amounts of radioactive and hazardous waste during the Cold War era, a legacy of material production for defense purposes. The unlined F-Area seepage basins received approximately 1.8 billion gallons of acidic waste solutions containing low-level radioactivity from numerous isotopes generated by uranium slug and irradiated fuel processing. Sufficient quantities of uranium isotopes, I-129, Tc-99, and tritium migrated into the groundwater, creating an acidic plume with a pH between 3 and 5.5. Humic substances (HS) are complex heterogeneous mixtures of poly-dispersed materials formed by biochemical and chemical reactions during the decay and transformation of plant and microbial remains. They are known for their excellent binding capacity for metals, making them a strong candidate for remediation efforts to reduce the mobility of uranium (VI) in the subsurface. Studies showed that HS are an important ion exchange and metal-complexing ligand, carrying a large number of functional groups with high complexing capacity that can greatly affect the mobility behavior of actinides in natural systems. Hence, it is a potential in situ amendment for treating groundwater contaminated with these constituents. Column experiments were conducted to address the complexities of HS in flow-through porous media representative of the acidic aquifer at the SRS F-Area Seepage Basins. The humate source used, Huma-K, is high in humic and fulvic compounds. The column studies were done using the soil obtained from SRS's FAW-1 core-hole at a depth interval of 60'-70'. A bromide tracer test was performed to obtain the pore volume (PV), variance and Peclet number. The columns were saturated with an artificial groundwater solution prepared to mimic the groundwater at SRS that was pH adjusted to 3.5 and 5 until the effluent pH reached equilibrium. Approximately one (1) PV of 5000 ppm of Huma-K was injected into the columns at 2 ml/min to study the sorption of Huma-K on the sediment. Desorption of Huma-K was studied by injecting approximately four (4) PVs of the pH adjusted artificial groundwater solution. A faster increase in pH was observed in column 1 (saturated with pH 3.5 AGW) compared to column 2 (saturated with pH 5 AGW). After injection of 2 PV of AGW, the pH of the columns reached 6.5 and 7, respectively, for columns 1 and 2. After injecting an additional PV of AGW, the pH remained relatively stable. With an increase in pH from 3.5 to 5.0, the overall retention of HA increased from 461 mg/kg for the column with pH 3.5 to 642 mg/kg for the column with pH 5. This suggests that retention is not due to adsorption alone, but adsorption coupled with precipitation and re-dissolution of Huma-K as it flows through the columns is a possible explanation for greater retention at pH 5. This negates the use of a simple Langmuir isotherm to explain humate behavior in the acidic environment of column 1. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization of U(VI)-Bearing Precipitates Produced by Ammonia Gas Injection Technology for Unsaturated Sediments - 16600

The processing of irradiated fuel to extract plutonium for the nuclear arsenal has resulted in a legacy of uranium contamination in the vadose zone (VZ) of the Hanford 200 Area. This contamination is a potential source for groundwater contamination, posing a risk to receptors through water uptake from contaminated wells or discharges to surface water. The injection of reactive gases is an innovative technology being evaluated for reducing the mobility of radionuclide contaminants in the Hanford vadose zone. Ammonia (NH{sub 3}) gas in particular has been used to reduce uranium mobility in laboratory scale studies and is being evaluated for field scale application. The sediment of the Hanford vadose zone is composed of a complex of mineral phases including quartz, feldspar, mica, and calcium carbonates. The silica content in the 200 Area subsurface markedly outweighs the majority of elements, with aluminum following closely. The injection of ammonia gas into the vadose zone is associated with an increase in pH conditions as the gas partitions into the pore water. The resulting alkaline conditions significantly increase the solubility of some aluminum and silicate-containing minerals within the system. As pH decreases to natural conditions, the aluminosilicate minerals will precipitate, potentially coating and sequestering the uranium contaminants. Although previous laboratory scale tests have shown decreased uranium mobility, there are many questions regarding the application of the remediation method to 200 Area vadose zone conditions. In particular, additional testing is required to understand the impact of various environmental factors on the formation of uranium mineral phases with the application of the NH{sub 3} injection method. In order to answer some of the unknowns regarding this remediation technology for the 200 Area vadose zone, an effort was made to characterize the uranium-bearing precipitates being formed with the injection of ammonia gas. Rather than a sediment-water system, a synthetic pore water solution was prepared using the ion concentrations relevant to the 200 Area vadose zone. These solutions were limited to select constituents believed to play a major role in the remediation process. The use of this carefully composed solution allows for the thorough evaluation of the contribution the variable components make to the formation of the solid analyte. The characterization of solid samples was attempted using a host of complementary analytical techniques including scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) and X-ray diffraction (XRD). Though characterization of the samples is ongoing, the data produced thus far has allowed for the imaging and X-ray spectroscopy of the solid uranium phases produced as well as a tentative identification of cejkaite (Na{sub 4}(UO{sub 2})(CO{sub 3}){sub 3}) as the major uranium mineral phase. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

THERMAL STRUCTURAL AND SHOCK EVENT EVALUATIONS OF THE FUELING PELLET INJECTION SYSTEM FOR ITER

The US is among seven partner nations in a collaborative effort to design, build, and demonstrate fusion’s ability to be a large-scale carbon free energy source. Each country has its own Domestic Agencies (DA) that contribute directly to the ITER project. US ITER, which is a DOE Office of Science project managed by Oak Ridge National Laboratory, is developing world class engineering solutions to the design, construction, and assembly of the burning plasma experiment that can demonstrate the scientific and technological feasibility of fusion. US ITER’s scope includes completing the preliminary and final design, qualifying materials and processes for manufacture and testing, executing manufacturing, and delivering the Fueling Pellet Injection System (FPIS) to the ITER site for assembly. The US-ITER FPIS system is designed to inject cryogenically frozen pellets of deuterium-tritium (D-T) into the plasma. The FPIS has two main functions: 1. Provide a steady supply of deuterium and tritium fuel, 2. Mitigating the impact of edge localized modes on the plasma facing components. The FPIS will have the capability to reside in three port cells within a tritium second barrier containment cask. Each pellet cask contains three flight tubes linking with penetrations on the torus cryopump housing and vacuum vessel (VV): two for the magnetic high field side (HFS) pellet injection and one for the magnetic low field side (LFS) pellet injection. This paper presents results of the thermal-structural analyses of the FPIS flight tube structural components when subjected to various loads such as electromagnetic (EM) loads, nuclear heating, seismic, and operational, and dynamic shock events. The resulting temperatures and stresses under combined conditions have been found to satisfy the design criteria to ensure safe and reliable operation of the FPIS flight tubes within the vacuum vessel.

Martinez, Oscar↗

Use of Digital Real-Time Simulation and Optimization to Identify Maximum Real Power Injection on the Banshee Distribution Network: Preprint

This study investigates the hosting capacity of the Banshee Distribution Network by optimizing the real power injection at carefully selected Distributed Energy Resource (DER) locations. The analysis is conducted within the framework of power system operational constraints, including bus voltage ranges, thermal line ratings, and transformer loading limits. A Python-based Genetic Algorithm (GA), implemented using the PyGAD library, is employed to iteratively identify the optimal power injection configuration that maximizes network utilization while preserving system reliability. The methodology integrates a real-time simulation environment using the Real-Time Digital Simulator (RTDS), allowing high-fidelity evaluation of power flow and voltage behavior under each proposed injection scenario. By coupling the optimization algorithm with real-time simulation feedback, this approach ensures that both static and dynamic constraints are enforced during the evaluation process. The GA leverages evolutionary operators such as selection, crossover, and mutation to navigate the nonlinear search space efficiently. The results of the study delineate the feasible hosting capacity at three targeted buses, reflecting maximum real power levels that can be injected without causing voltage violations, transformer overloading, or line congestion. These findings provide a decision- support tool for distribution planners and utilities aiming to integrate higher penetrations of DERs in existing infrastructure. Additionally, the work lays the foundation for extending such optimization techniques to multi-objective formulations, including economic dispatch and reactive power coordination, in future studies.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Investigation of pressure-controlled injection molding on the mechanical properties and embodied energy of recycled high-density polyethylene

Manufacturing with secondary feedstock has been identified as an effective strategy to improve plastic circularity. However, product quality inconsistencies arise due to variations in molecular weight, rheology, and mechanical properties. This work evaluates the processing of recycled high-density polyethylene using pressure-controlled injection molding with a focus on processing behavior and energy consumption. Further, the effects of injection velocity, packing pressure, and transfer position are benchmarked against a conventional velocity-controlled process. The experimental results show that the novel process control strategy significantly affects the mechanical properties, in-mold rheology, and energy consumption. Parts fabricated using pressure-controlled injection molding showed higher tensile properties due to increased macromolecular orientation. Additionally, reduced energy was used due to lower melt pressures required to completely replicate the cavity geometry. The results demonstrate the potential of the technology to support increased utilization of secondary feedstock and reduced carbon footprint.

36 MATERIALS SCIENCE↗

Study on dynamics of photoexcited charge injection and trapping in CdS quantum dots sensitized TiO{sub 2} nanowire array film electrodes

The photoexcited electrons transfer dynamics of the CdS quantum dots (QDs) deposited in TiO{sub 2} nanowire array films are studied using surface photovoltage (SPV) and transient photovoltage (TPV) techniques. By comparing the SPV results with different thicknesses of QDs layers, we can separate the dynamic characteristics of photoexcited electrons injection and trapping. It is found that the TPV signals of photoexcited electrons trapped in the CdS QDs occur at timescales of about 2 × 10{sup −8} s, which is faster than that of the photoexcited electrons injected from CdS into TiO{sub 2}. More than 90 nm of the thickness of the CdS QDs layer will seriously affect the photoexcited electrons transfer and injection.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Thermal quench mitigation and current quench control by injection of mixed species shattered pellets in DIII-D

Injection of large shattered pellets composed of variable quantities of the main ion species (deuterium) and high-Z impurities (neon) in the DIII-D tokamak demonstrates control of thermal quench (TQ) and current quench (CQ) properties in mitigated disruptions. As the pellet composition is varied, TQ radiation fractions increase continuously with the quantity of radiating impurity in the pellet, with a corresponding decrease in divertor heating. Post-TQ plasma resistivities increase as a result of the higher radiation fraction, allowing control of current decay timescales based on the pellet composition. Magnetic reconstructions during the CQ show that control of the current decay rate allows continuous variation of the minimum safety factor during the vertically unstable disruption, reducing the halo current fraction and resulting vessel displacement. Both TQ and CQ characteristics are observed to saturate at relatively low quantities of neon, indicating that effective mitigation of disruption loads by shattered pellet injection (SPI) can be achieved with modest impurity quantities, within injection quantities anticipated for ITER. This mixed species SPI technique provides a possible approach for tuning disruption properties to remain within the limited ranges allowed in the ITER design.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Radiation asymmetry during shattered pellet and massive gas injection in DIII-D

Infrared thermography of the first wall in DIII-D is used to show the toroidal peaking of plasma radiation during mitigated disruptions with shattered pellet injection (SPI) and with massive gas injection (MGI). During MGI, the radiation peak location is shown to be due to the n = 1 magnetohydrodynamic (MHD) activity and continuously variable in toroidal phase based on externally applied error fields, consistent with previous experimental results. Furthermore, the measured toroidal peaking factor (TPF) is in agreement with the previous estimates based on radiometry, with a total TPF of 1.07 ± 0.05 when integrated over the entire duration of the disruption, and a value of 1.3 ± 0.1 during the thermal quench (TQ). For SPI, the location of the radiation peak is found to be determined predominantly by the particle source location, and thus can be varied on DIII-D by injecting from either of two toroidally separated injectors. 3D non-linear MHD simulations with the NIMROD code support this picture. The localized SPI particle source leads to higher peaking than for MGI, with a total TPF of 1.3 ± 0.1 over the full disruption and a TQ TPF of 1.9 +0.5/−0.3, a value also consistent with the NIMROD simulations. This TQ value is close to or potentially exceeding the allowable limit for the previously planned Be first wall in ITER, pointing to the importance of radiation asymmetries depending on the choice of first wall material.

Physics - Plasma physics↗

Density and temperature profiles after low-Z and high-Z shattered pellet injections on DIII-D

Abstract In this work we utilize the recently upgraded Thomson scattering diagnostic to resolve density and temperature plasma profiles after pure deuterium and mixed neon/deuterium shattered pellet injections (SPIs) on DIII-D. This allows us to study individual components of the staggered scheme proposed for disruption mitigation on ITER, consisting of a low-Z material SPI followed by a delayed high-Z SPI. Obtained spatio-temporal density profiles exhibit very different dynamics after dominantly neon and pure deuterium SPIs. The neon SPI causes a fast radiative plasma collapse in a few milliseconds and results in almost flat density profile once the impurity mixes with the plasma during and after the thermal quench (TQ). The deuterium SPI leads to a disruption delayed by ten and more milliseconds, but very limited core fueling can be observed before the disruption. Even during and after the TQ, the edge deuterium density significantly exceeds the core density. 1D transport modeling suggests that this poor core fueling can be explained by strong outward grad-B-induced drift of the injected deuterium. Preliminary simulations show that larger pellet shards and greater injected quantity can be used to improve the penetration of the low-Z material into the core. These results call for optimization and further evaluation of the staggered SPI on ITER.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Spectrum of Ion Cyclotron Emission from Neutral Beam Injection Heated Plasma on the TUMAN-3M Tokamak

Radiation at the ion cyclotron resonance frequencies in both the ohmic mode and the injection heating mode—ion cyclotron emission (ICE)—is observed on the TUMAN-3M tokamak (minor radius a = 0.25 m, major radius R{sub 0} = 0.5 m, toroidal field B{sub T} = 1 T, plasma current I{sub p} ≤ 180 kA, and average plasma electron density n{sub e} ≤ 5 × 10{sup 19} m{sup –3}). Usually, the ICE is associated with the presence of high-energy ions in the plasma. Such ions may be products of a thermonuclear reaction or arise as a result of additional plasma heating, e.g., by means of electromagnetic waves or by injection of beams of high-energy atoms (neutral beam injection, NBI). The properties of the ICE in the TUMAN-3M tokamak in the NBI-heating mode and their possible connection with the features of fast ion trajectories and their energy spectrum are considered.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Seismic velocity changes associated with aseismic deformations of a fault stimulated by fluid injection

Fluid pressure plays an important role in the stability of tectonic faults. However, the in situ mechanical response of faults to fluid pressure variations is still poorly known. To address this question, we performed here a fluid injection experiment in a fault zone in shales while monitoring fault movements at the injection source and seismic velocity variations from a near-distance (<10 m) monitoring network. We measured and located the P and S wave velocity perturbations in and around the fault using repetitive active sources. We observed that seismic velocity perturbations dramatically increase above 1.5 MPa of injection pressure. This is consistent with an increase of fluid flow associated with an aseismic dilatant shearing of the fault as shown by numerical modeling. We find that seismic velocity changes are sensitive to both fault opening by fluid invasion and effective stress variations and can be an efficient measurement for monitoring fluid-driven aseismic deformations of faults.

58 GEOSCIENCES↗

Transretroperitoneal CT-guided Embolization of Growing Internal Iliac Artery Aneurysm after Repair of Abdominal Aortic Aneurysm: A Transretroperitoneal Approach with Intramuscular Lidocaine Injection Technique

This study was designed to evaluate the efficacy and safety of CT-guided embolization of internal iliac artery aneurysm (IIAA) after repair of abdominal aortic aneurysm by transretroperitoneal approach using the lidocaine injection technique to iliacus muscle, making window for safe needle path for three patients for whom CT-guided embolization of IIAA was performed by transretroperitoneal approach with intramuscular lidocaine injection technique. Transretroperitoneal access to the IIAA was successful in all three patients. In all three patients, the IIAA was first embolized using microcoils. The aneurysmal sac was then embolized with glue and coils without complication. With a mean follow-up of 7 months, the volume of the IIAAs remained stable without residual endoleaks. Transretroperitoneal CT-guided embolization of IIAA using intramuscular lidocaine injection technique is effective, safe, and results in good outcome.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Radiation Dose Reduction in CT Fluoroscopy-Guided Cervical Transforaminal Epidural Steroid Injection by Modifying Scout and Planning Steps

Background and PurposeIn CT fluoroscopy (CTF)-guided cervical transforaminal epidural steroid injection (TFESI), the majority of radiation dose is contributed by the planning CT scan rather than the CTF procedure itself. We replaced the planning helical CT with a spot CTF and accordingly changed the patient posture during scout and planning scans. The aim of this study was to test whether radiation dose reduction would be achieved by this protocol modification while still maintaining technical performance.MethodsOverall, 338 consecutive procedures before (control group: n = 163) and after (study group: n = 175) instituting the above-mentioned protocol modification were analyzed retrospectively, comparing patient characteristics (age, sex, neck diameter, and level injected) and technical performance [technical success rate, dose-length product (DLP), inadvertent contrast flow incidence, number of CTF acquisitions, and procedural time] between the two groups.ResultsAll injections were technically successful at every level from C3–C4 to C7–T1 without serious complications in both groups. The median DLP of the study group (7.92 mGy·cm) was significantly reduced compared to that of the control group (39.05 mGy·cm, P < 0.001). There were no significant differences between the two groups regarding the incidence of inadvertent contrast flow (20.6 vs. 17.2 %, P = 0.426), number of CTF acquisitions (median 5 vs. 4, P = 0.123), and the procedural time (median 6.62 vs. 6.90 min, P = 0.100).ConclusionsWhen conducting CTF-guided cervical TFESIs, a significant radiation dose reduction (median 79.7 % in DLP) can be achieved by modifying scout and planning steps, without compromising the technical performance.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Paravertebral Collateral Arteries in Patients with Carotid Stenosis: Is There a Safe Space for Transforaminal Cervical Nerve Root Injections?

Aim: Image-guided cervical nerve root injections can cause serious complications including spinal cord infarction. This risk may be increased in patients with carotid stenosis who develop collateral arteries. The aim of this study is to describe the prevalence, and anatomical location, of arterial collateral vessels in relation to the optimal needle tip position in cervical nerve root injections. Materials and Methods: This retrospective study included 25 patients who had > 70% stenosis on a carotid CT angiogram. For each foramen the position of collateral arteries and the most anterior point of the facet joint were recorded, as Cartesian coordinates, by two independent observers. Descriptive statistics were used to analyse and present the results. Results: 14 patients had unilateral and 11 had bilateral stenoses. A total of 85 collaterals were identified at all levels, the most common being C2/3. The median distance from collateral to optimal needle tip placement was 9.6 mm (95% CI median: 6.7–12.4, IQR: 5.6–15.6). The minimum distance was 2.9 mm. Inter-observer reliability was “substantial” (ICC 0.78, 95% CI 0.71–0.83). Conclusion: Collateral arteries were common in our cohort of patients with carotid artery stenosis and half lay within 10 mm of the optimal position for transforaminal cervical nerve root injection.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

A microfabricated electroosmotic pump coupled to a gas-diffusion microchip for flow injection analysis of ammonia

Here we have microfabricated two functional components toward developing a microchip flow injection analysis (FIA) system, i.e., an open-channel electroosmotic pump and a gas-diffusion chip, consisting of two microfabricated glass wafers and a porous polytetrafluoroethylene membrane. This is the first application of gas-diffusion separation in a microchip FIA system. To demonstrate the feasibility of using these two components for performing gas-diffusion FIA, we have incorporated them together with a regular FIA injection valve and a capillary electrophoresis absorbance detector in a flow injection system for determination of ammonia in environmental water samples. This system has a limit of detection of 0.10 mg L -1 NH 3 , with a good repeatability (relative standard deviation of less than 5 % for 4.0 mg L - 1 NH 3 ). We also discuss parameters affecting its performance.

42 ENGINEERING↗

The availability of hydrogeologic data associated with areas identified by the US Geological Survey as experiencing potentially induced seismicity resulting from subsurface injection

A critical need exists for site-specific hydrogeologic data in order to determine potential hazards of induced seismicity and to manage risk. By 2015, the United States Geological Survey (USGS) had identified 17 locations in the USA that are experiencing an increase in seismicity, which may be potentially induced through industrial subsurface injection. These locations span across seven states, which vary in geological setting, industrial exposure and seismic history. Comparing the research across the 17 locations revealed patterns for addressing induced seismicity concerns, despite the differences between geographical locations. Most induced seismicity studies evaluate geologic structure and seismic data from areas experiencing changes in seismic activity levels, but the inherent triggering mechanism is the transmission of hydraulic pressure pulses. This research conducted a systematic review of whether data are available in these locations to generate accurate hydrogeologic predictions, which could aid in managing seismicity. After analyzing peer-reviewed research within the 17 locations, this research confirms a lack of site-specific hydrogeologic data availability for at-risk areas. Commonly, formation geology data are available for these sites, but hydraulic parameters for the seismically active injection and basement zones are not available to researchers conducting peer-reviewed research. Obtaining hydrogeologic data would lead to better risk management for injection areas and provide additional scientific evidential support for determining a potentially induced seismic area.

58 GEOSCIENCES↗

Effect of Bath Depth and Nozzle Geometry on Spout Height in Submerged Gas Injection at Bottom

Spout height is a widely used parameter to quantitatively analyze the performance of the submerged gas injection in industrial applications. However, the effect of bath depth and nozzle geometry on spout height in submerged gas injection is still unclear. In this work, the effect of bath depth and nozzle geometry on spout height in submerged gas injection at bottom was experimentally investigated. Circular-shaped, three-leaf-shaped, four-leaf-shaped, and four-flower-shaped nozzles were used for this study. Spout height was extracted from the images captured by high-speed camera and analyzed by digital image processing. The results indicate that the effect of nozzle geometry on spout height is as important as gas flow rate and bath depth. Through dimensional analysis, predictive correlations of spout height from circular shape and four-leaf shape were developed with dimensionless bath depth and a modified Froude number using orifice perimeter and opening area as characteristic parameters. Experimental data were compared with the correlations from literature and good agreement was found.

36 MATERIALS SCIENCE↗

Multi-stage heat pump with two-phase injection for cold climate applications implementing natural refrigerants

Heat pump adoption in cold climates is limited by various technical challenges, including heat capacity degradation, compressor deterioration, and frost accumulation on the outdoor heat exchanger. Furthermore, wide-spread adoption of heat pumps with high global warming potential presents a possible environmental concern. Thus, we present a heat pump concept termed the “saturation cycle,” which uses numerous compression stages to improve energy efficiency and injects two-phase refrigerant between compression stages to dramatically reduce compressor discharge temperatures. Given the growing interest in heat pumps, there is a need for a straightforward framework for parametric evaluation of natural refrigerants in high-efficiency heat pump cycle architectures, like the saturation cycle, in adverse climates. This work develops a thermodynamic modeling framework and focuses on the application of natural refrigerants to explore the performance trends at extremely cold climates down to −25 °C. This study shows that a two-stage saturation cycle and four-stage saturation cycle can reduce the compressor discharge superheating by up to 51–57 % or 73–80 %, respectively, depending on the refrigerant. Furthermore, at −25 °C, a two-stage R-290 saturation cycle heat pump theoretically can use 25 % less power than a single-stage heat pump or can provide up to 59 % more heating capacity when using the same compressor power as the baseline single-stage heat pump. The exergetic parametric analyses show that two-phase refrigerant injection fundamentally improves the thermodynamic performance of the heat pump, reducing overall exergy destruction by 10 % compared to a vapor-injection heat pump, compared at −25 °C. Thus, the saturation cycle is a promising heat pump cycle architecture for cold climate applications due to its superior energy savings (or capacity improvement) and substantial de-superheating capabilities.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗