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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Preview of the BATSE Earth Occultation Catalog of Low Energy Gamma Ray Sources

The Burst and Transient Source Experiment (BATSE) aboard the Compton Gamma Ray Observatory (CGRO) has been detecting and monitoring point sources in the high energy sky since 1991. Although BATSE is best known for gamma ray bursts, it also monitors the sky for longer-lived sources of radiation. Using the Earth occultation technique to extract flux information, a catalog is being prepared of about 150 sources potential emission in the large area detectors (20-1000 keV). The catalog will contain light curves, representative spectra, and parametric data for black hole and neutron star binaries, active galaxies, and super-nova remnants. In this preview, we present light curves for persistent and transient sources, and also show examples of what type of information can be obtained from the BATSE Earth occultation database. Options for making the data easily accessible as an "on line" WWW document are being explored.

Harmon, B. A.↗
NASA NTRS1993

Diacetylene and Polydiacetylene Derivatives of 2-Methyl-4-Nitroaniline for Second-Harmonic Generation

A novel diacetylene derivative of 2-Methyl-4-NitroAniline (MNA), a well-known material for Second-Harmonic Generation (SHG), is synthesized. This monomer DiAcetylene MethylNitroAniline, (DAMNA) is characterized by means of the Kurtz technique at 1064 nm and is found to have an SHG powder efficiency 62.5 % that of MNA itself. Thin crystalline films of DAMNA are grown onto quartz, Teflon, and Kapton substrates by means of vapor deposition in vacuum. These films are then polymerized in the solid state by exposure to long-wavelength UV radiation to give crystalline polydiacetylene thin films (PDAMNA). The films are next characterized for SHG, using an unpolymerized DAMNA film as a reference. Interestingly, films grown onto Teflon exhibit greater orientation and significantly greater SHG than those grown onto quartz and Kapton. This result is promising in that it demonstrates the potential of PDAMNA as both a crystalline and polymeric material for SHG applications, in which highly oriented thin films are desired. Computational modeling (usingAM1) is also carried out on DAMNA and is compared to the experimental results.

Paley, M. S.↗
DOE OSTI2022

Voltage waveform tailoring for high aspect ratio plasma etching of SiO 2 using Ar/CF 4 /O 2 mixtures: Consequences of ion and electron distributions on etch profiles

The quality of high aspect ratio (HAR) features etched into dielectrics for microelectronics fabrication using halogen containing low temperature plasmas strongly depends on the energy and angular distribution of the incident ions (IEAD) onto the wafer, as well as potentially that of the electrons (EEAD). Positive ions, accelerated to high energies by the sheath electric field, have narrow angular spreads and can penetrate deeply into HAR features. Electrons typically arrive at the wafer with nearly thermal energy and isotropic angular distributions and so do not directly penetrate deeply into features. These differences can lead to positive charging of the insides of the features that can slow etching rates and produce geometric defects such as twisting. In this work, we computationally investigated the plasma etching of HAR features into SiO 2 using tailored voltage waveforms in a geometrically asymmetric capacitively coupled plasma sustained in an Ar/CF 4 /O 2 mixture at 40 mTorr. The tailored waveform consisted of a sinusoidal wave and its higher harmonics with a fundamental frequency of 1 MHz. We found that some degree of control of the IEADs and EEADs is possible by adjusting the phase of higher harmonics φ through the resulting generation of electrical asymmetry and electric field reversal. However, the IEADs and EEADs cannot easily be separately controlled. The control of IEADs and EEADs is inherently linked. The highest quality feature was obtained with a phase angle φ = 0° as this value generated the largest (most negative) DC self-bias and largest electric field reversal for accelerating electrons into the feature. That said, the consequences of voltage waveform tailoring (VWT) on etched features are dominated by the change in the IEADs. Although VWT does produce EEADs with higher energy and narrower angular spread, the effect of these electrons on the feature compared to thermal electrons is not large. Finally, this smaller impact of VWT produced EEADs is attributed to thermal electrons being accelerated into the feature by electric fields produced by the positive in-feature charging.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Metal Bioavailability and Ecotoxicity of Bioremediated Oils and Tailings by BioTiger{sup TM}, a Microbial Consortium

Oil Sands and Mature Fine Tailings: Oil sand reserves are a major source of oil for the United States. Oil sands are a mixture of sand, clay, water, and bitumen. The refining process requires large volumes of water and generates hazardous Mature Fine Tailings (MFTs) that are stored in engineered settling ponds. They are of major environmental concern due to their persistence and difficulty to naturally biodegrade. MFT Contaminants of Concern: Naphthenic Acids (NAs), Polycyclic Aromatic Hydrocarbons (PAHs), Benzene, Toluene, Ethylbenzene and Xylene (BTEX), Metals, Residual Bitumen. BioTiger{sup TM} (BT{sup TM}), the SRNL patented 12 component microbial consortia was found to cometabolically degrade some NAs and PAHs. Previous studies performing short term exposure (48 hours and 7 days) to BT{sup TM} have resulted in increased toxicity due to the partial degradation of PAHs forming toxic intermediates. Objective: Evaluate the ecotoxicity of BT{sup TM} remediated MFTs exposed to a 2 week period w/ yeast (Y) extract. This work will determine BT{sup TM}'s remediation of MFTs from Fort McMurray, Alberta. Acute toxicity tests will be performed under section 9 of EPA's Method for Measuring Acute Toxicity using the freshwater organism, Ceriodaphnia dubia. Monitor BT{sup TM} growth through Most Probable Number (MPN) counts, pH, and metal bioavailability will also be evaluated. Preparing tailing solutions for biodegradation: BT{sup TM} components were grown in R2A media and combined. Mother BT{sup TM} was centrifuged at 7000 rpm for 20 minutes and resuspended in Bushnell Haus. 33 g of tailings were added to 1100 mL Bushnell Haus along with yeast extract (11 g) to create a 3% tailing solution. Treatments were performed in triplicate. Preparing solutions for toxicity tests using C. dubia: Supernatant was collected immediately after centrifuging at 7000 rpm for 20 min. Supernatant was filtered via a 0.22 μm sterile system. All treatments except MFT, Y peaked at T=4. This decrease in microbial growth could be associated with toxicity from intermediate byproducts. Treatments containing only MFTs decreased in the initial 11 days before growing significantly. Final solution for MFT, Y treatment had the highest pH. This could potentially be due to increased microbial activity linked with yeast consumption. All treatments except MFT, Y peaked at T=4. This decrease in microbial growth could be associated with toxicity from intermediate byproducts. Treatments containing only MFTs decreased in the initial 11 days before growing significantly. Future Direction: Await results from Acute Toxicity Tests and Metal Bioavailability Quantification of biosurfactant production. Evaluate hydrocarbon degradation byproducts using an analytical chemistry approach. More toxicity experiments with variations in time and conditions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2003

Performance Enhancement of Tunable Bandpass Filters Using Selective Etched Ferroelectric Thin Films

The inclusion of voltage-tunable barium strontium titanate (BSTO) thin films into planar band pass filters offers tremendous potential to increase their versatility. The ability to tune the passband so as to correct for minor deviations in manufacturing tolerances, or to completely reconfigure the operating frequencies of a microwave communication system, are highly sought-after goals. However, use of ferroelectric films in these devices results in higher dielectric losses, which in turn increase the insertion loss and decrease the quality factors of the filters. This study explores the use of patterned ferroelectric layers to minimize dielectric losses without degrading tunability. Patterning the ferroelectric layers enables us to constrict the width of the ferroelectric layers between the coupled microstrip lines, and minimize losses due to ferroelectric layers. Coupled one-pole microstrip bandpass filters with fundamental resonances at approx. 7.2 GHz and well defined harmonic resonances at approx. 14.4 and approx. 21.6 GHz, were designed, simulated and tested. For one of the filters, experimental results verified that its center frequency was tunable by 528 MHz at a center frequency of 21.957 GHz, with insertion losses varying from 4.3 to 2.5 dB, at 0 and 3.5 V/micron, respectively. These data demonstrate that the tuning-to-loss figure of merit of tunable microstrip filters can be greatly improved using patterned ferroelectric thin films as the tuning element, and tuning can be controlled by engineering the ferroelectric constriction in the coupled sections.

Miranda, Felix A.↗
NASA NTRS2011

Shunted Piezoelectric Vibration Damping Analysis Including Centrifugal Loading Effects

Excessive vibration of turbomachinery blades causes high cycle fatigue problems which require damping treatments to mitigate vibration levels. One method is the use of piezoelectric materials as passive or active dampers. Based on the technical challenges and requirements learned from previous turbomachinery rotor blades research, an effort has been made to investigate the effectiveness of a shunted piezoelectric for the turbomachinery rotor blades vibration control, specifically for a condition with centrifugal rotation. While ample research has been performed on the use of a piezoelectric material with electric circuits to attempt to control the structural vibration damping, very little study has been done regarding rotational effects. The present study attempts to fill this void. Specifically, the objectives of this study are: (a) to create and analyze finite element models for harmonic forced response vibration analysis coupled with shunted piezoelectric circuits for engine blade operational conditions, (b) to validate the experimental test approaches with numerical results and vice versa, and (c) to establish a numerical modeling capability for vibration control using shunted piezoelectric circuits under rotation. Study has focused on a resonant damping control using shunted piezoelectric patches on plate specimens. Tests and analyses were performed for both non-spinning and spinning conditions. The finite element (FE) shunted piezoelectric circuit damping simulations were performed using the ANSYS Multiphysics code for the resistive and inductive circuit piezoelectric simulations of both conditions. The FE results showed a good correlation with experimental test results. Tests and analyses of shunted piezoelectric damping control, demonstrating with plate specimens, show a great potential to reduce blade vibrations under centrifugal loading.

Min, James B.↗
DOE OSTI2023

Scissors modes of a Bose-Einstein condensate in a synthetic magnetic field

We study the scissors modes of a harmonically trapped Bose-Einstein condensate under the influence of a synthetic magnetic field, which induces rigid rotational components in the velocity field. Our investigation reveals that the scissors mode, excited in the plane perpendicular to the synthetic magnetic field, becomes coupled to the quadrupole modes of the condensate, giving rise to typical beating effects. Moreover, the two scissors modes excited in the vertical planes are also coupled together by the synthetic magnetic field, resulting in intriguing gyroscope dynamics. Our analytical results, derived from a spinor hydrodynamic theory, are further validated through numerical simulations of the three-dimensional Gross-Pitaevskii equation. These predictions for the condensates subject to a synthetic magnetic field are experimentally accessible with current cold-atom setups and hold promise for potential applications in quantum sensing.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1983

Ion trajectories in a space-charge wave on a relativistic electron beam

The motion of an ion in a space-charge wave on a strongly magnetized electron beam is investigated. The motions of the ion perpendicular and parallel to the beam direction are coupled by a nonlinear term in the ion Hamiltonian that is proportional to the wave amplitude, and this coupling causes the motion of the ion to deviate significantly from that of a linear harmonic oscillator in certain resonant regions of phase space. A sequence of canonical transformations is employed to investigate the motion of the ion in these regions. It is determined that wave amplitudes that are too small to trap beam electrons are too small to cause these resonances to overlap. When this overlap does not occur, the motion is found not to be discernibly ergodic in any three-dimensional subspace of the energy hypersurface because there exists a third constant of the motion in addition to the total energy and angular momentum. The numerically integrated ion trajectories are studied using surface-of-section techniques in order to verify these findings. It is found that the third constant of the motion constrains an ion initially trapped in a potential well of the wave to remain trapped in this well. It is concluded that ergodic behavior poses no threat at attempts at collective ion acceleration in space-charge waves on an electron beam.

Russell, D. A.↗
NASA NTRS2012

Earth Radiation Imbalance from a Constellation of 66 Iridium Satellites: Technological Aspects

Iridium Communications Inc. is launching a new generation of polar orbiting communication satellites in 2015-2017. Iridium will provide a hosted payload bay on each of the 66 satellites (plus 6 in-space spares). This offers the potential for a paradigm shift in the way we measure Earth radiation imbalance from space, as well as massive cost savings. Because the constellation provides 24/7 global coverage, there is no need to account for diurnal cycle via extrapolations from uncalibrated narrowband geostationary imagers. And the spares can be rolled over to view the Sun and deep space, then transfer their calibration to the other members of the constellation during the frequent cross-overs. In part using simulations of the constellation viewing realistic Earth scenes, this presentation will address the technological aspects of such a constellation: (1) the calibration strategy; (2) the highly-accurate and stable radiometers for measuring outgoing flux; and (3) the GRACE-inspired algorithms for representing the outgoing flux field in spherical harmonics and thus achieving rv500-km spatial resolution and two-hour temporal resolution.

Wiscombe, W.↗
DOE OSTI2022

Aqueous Photoelectrochemical CO 2 Reduction to CO and Methanol over a Silicon Photocathode Functionalized with a Cobalt Phthalocyanine Molecular Catalyst

Abstract We report a precious‐metal‐free molecular catalyst‐based photocathode that is active for aqueous CO 2 reduction to CO and methanol. The photoelectrode is composed of cobalt phthalocyanine molecules anchored on graphene oxide which is integrated via a (3‐aminopropyl)triethoxysilane linker to p‐type silicon protected by a thin film of titanium dioxide. The photocathode reduces CO 2 to CO with high selectivity at potentials as mild as 0 V versus the reversible hydrogen electrode (vs RHE). Methanol production is observed at an onset potential of −0.36 V vs RHE, and reaches a peak turnover frequency of 0.18 s −1 . To date, this is the only molecular catalyst‐based photoelectrode that is active for the six‐electron reduction of CO 2 to methanol. This work puts forth a strategy for interfacing molecular catalysts to p‐type semiconductors and demonstrates state‐of‐the‐art performance for photoelectrochemical CO 2 reduction to CO and methanol.

Shang, Bo↗
NASA NTRS2006

Repeat Ground Track Lunar Orbits in the Full-Potential Plus Third-Body Problem

A high degree and order Lunar gravitational field is superimposed on the Earth-Moon Restricted Three Body model to capture the dominating forces on a spacecraft in the vicinity of the Moon. For the synchronously rotating Moon, periodic orbits in this model map repeat ground tracks and represent higher order solutions to the frozen orbit problem. The near-circular, stable or near-stable solutions are found over a wide range of defining characteristics making them suitable for long-lifetime parking applications such as science orbits, crew exploration vehicle parking orbits, and global coverage constellation orbits. A full ephemeris is considered for selected orbits to evaluate the validity of the time-invariant, simplified model. Of the most promising results are the low-altitude families of near-circular, inclined orbits that maintain long-term stability despite the highly non-spherical Lunar gravity. The method is systematic and enables rapid design and analysis of long-life orbits around any tidally-locked celestial body with an arbitrarily high degree and order spherical harmonic gravity field. .

periodic↗
DOE OSTI2023

Eddy Current Shielding of the Magnetic Field Ripple in the EIC Electron Storage Ring Vacuum Chambers

The EIC electron storage ring (ESR) has very tight tolerances for the beam position and size stability at the interaction point. The oscillations at the proton betatron frequency and its harmonics are the most dangerous because, for instance, they could lead to unacceptable proton emittance growth from the oscillating beam-beam kick from the electrons at the amplitude of the positional oscillations as low as 10 -4 of the beam size. Even at much lower frequencies, down to the single Hz range, the position oscillations at a few percent level of the nominal beam size were found to be dangerous. These oscillations could have different causes including magnet power supply ripple, mag net vibration, noise in the main and crab RF systems, and some collective instabilities. To specify the acceptable level of the current ripple and noise of the magnet power supplies we need to accurately account for the eddy current shielding by the vacuum chamber, as well as, potentially, by the laminated magnet yokes (considered elsewhere). With some ap proximations, the chamber shielding can be described analytically. The main objective of this note is to derive these analytical expressions and to document the resulting shielding performance of the ESR chamber.

43 PARTICLE ACCELERATORS↗
NASA NTRS1975

Solutions to Kuessner's integral equation in unsteady flow using local basis functions

The computational procedure and numerical results are presented for a new method to solve Kuessner's integral equation in the case of subsonic compressible flow about harmonically oscillating planar surfaces with controls. Kuessner's equation is a linear transformation from pressure to normalwash. The unknown pressure is expanded in terms of prescribed basis functions and the unknown basis function coefficients are determined in the usual manner by satisfying the given normalwash distribution either collocationally or in the complex least squares sense. The present method of solution differs from previous ones in that the basis functions are defined in a continuous fashion over a relatively small portion of the aerodynamic surface and are zero elsewhere. This method, termed the local basis function method, combines the smoothness and accuracy of distribution methods with the simplicity and versatility of panel methods. Predictions by the local basis function method for unsteady flow are shown to be in excellent agreement with other methods. Also, potential improvements to the present method and extensions to more general classes of solutions are discussed.

Fromme, J. A.↗
NASA NTRS2001

Modeling Wave Driven Non-linear Flow Oscillations: The Terrestrial QBO and a Solar Analog

The Quasi Biennial Oscillation (QBO) of the zonal circulation observed in the terrestrial atmosphere at low latitudes is driven by wave mean flow interaction as was demonstrated first by Lindzen and Holton (1968), shown in a laboratory experiment by Plumb and McEwan (1978), and modeled by others (e.g., Plumb, Dunkerton). Although influenced by the seasonal cycle of solar forcing, the QBO, in principle, represents a nonlinear flow oscillation that can be maintained by a steady source of upward propagating waves. The wave driven non-linearity is of third or odd order in the flow velocity, which regenerates the fundamental harmonic itself to keep the oscillation going - the fluid dynamical analog of the displacement mechanism in the mechanical clock. Applying Hines' Doppler Spread Parameterization (DSP) for gravity waves (GW), we discuss with a global-scale spectral model numerical experiments that elucidate some properties of the QBO and its possible effects on the climatology of the atmosphere. Depending on the period of the QBO, wave filtering can cause interaction with the seasonal variations to produce pronounced oscillations with beat periods around 10 years. Since the seasonal cycle and its variability influence the period of the QBO, it may also be a potent conduit of solar activity variations to lower altitudes. Analogous to the terrestrial QBO, we propose that a flow oscillation may account for the 22-year periodicity of the solar magnetic cycle, potentially answering Dicke (1978) who asked, "Is there a chronometer hidden deep inside the Sun?" The oscillation would occur below the convection region, where gravity waves can propagate. Employing a simplified, analytic model, Hines' DSP is applied to estimate the flow oscillation. Depending on the adopted horizontal wavelengths of GW's, wave amplitudes less than 10 m/s can be made to produce oscillating zonal flows of about 20 m/s that should be large enough to generate a significant oscillation in the magnetic field. For the large length scales of the Sun, the flow cycle period tends to be very long. The period, however, can be made to be 22 years, provided the buoyancy frequency (stability) is sufficiently small, thus placing the proposed flow near the base of the convection zone where a dynamo is now believed to operate.

Mayr, Hans G.↗
NASA NTRS1989

Reflection of solar radiation by a cylindrical cloud

Potential applications of an analytic method for computing the solar radiation reflected by a cylindrical cloud are discussed, including studies of radiative transfer within finite clouds and evaluations of these effects on other clouds and on remote sensing problems involving finite clouds. The pattern of reflected sunlight from a cylindrical cloud as seen at a large distance has been considered and described by the bidirectional function method for finite cloud analysis, as previously studied theoretically for plane-parallel atmospheres by McKee and Cox (1974); Schmetz and Raschke (1981); and Stuhlmann et al. (1985). However, the lack of three-dimensional radiative transfer solutions for anisotropic scattering media have hampered theoretical investigations of bidirectional functions for finite clouds. The present approach permits expression of the directional variation of the radiation field as a spherical harmonic series to any desired degree and order.

Smith, G. L.↗
DOE OSTI2022

Structural characterization of protective non-neutralizing antibodies targeting Crimean-Congo hemorrhagic fever virus

Crimean-Congo Hemorrhagic Fever Virus (CCHFV) causes a life-threatening disease with up to a 40% mortality rate. With no approved medical countermeasures, CCHFV is considered a public health priority agent. The non-neutralizing mouse monoclonal antibody (mAb) 13G8 targets CCHFV glycoprotein GP38 and protects mice from lethal CCHFV challenge when administered prophylactically or therapeutically. Here, we reveal the structures of GP38 bound with a human chimeric 13G8 mAb and a newly isolated CC5-17 mAb from a human survivor. These mAbs bind overlapping epitopes with a shifted angle. The broad-spectrum potential of c13G8 and CC5-17 and the practicality of using them against Aigai virus, a closely related nairovirus were examined. Binding studies demonstrate that the presence of non-conserved amino acids in Aigai virus corresponding region prevent CCHFV mAbs from binding Aigai virus GP38. This information, coupled with in vivo efficacy, paves the way for future mAb therapeutics effective against a wide swath of CCHFV strains.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2024

Time series methods for the analysis of soundscapes and other cyclical ecological data

Biodiversity monitoring has entered an era of ‘big data’, exemplified by a near-continuous collection of sounds, images, chemical and other signals from organisms in diverse ecosystems. Such data streams have the potential to help identify new threats, assess the effectiveness of conservation interventions, as well as generate new ecological insights. However, appropriate analytical methods are often still missing, particularly with respect to characterizing cyclical temporal patterns. Here, we present a framework for characterizing and analysing ecological responses that represent nonstationary, complex temporal patterns and demonstrate the value of using Fourier transforms to decorrelate continuous data points. In our example, we use a framework based on three approaches (spectral analysis, magnitude squared coherence, and principal component analysis) to characterize differences in tropical forest soundscapes within and across sites and seasons in Gabon. By reconstructing the underlying, cyclic behaviour of the soundscape for each site, we show how one can identify circadian patterns in acoustic activity. Soundscapes in the dry season had a complex diel cycle, requiring multiple harmonics to represent daily variation, while in the wet season there was less variance attributable to the daily cyclic patterns. Our framework can be applied to most continuous, or near-continuous ecological data collected at a fine temporal resolution, allowing ecologists to explore patterns of temporal autocorrelation at multiple levels for biologically meaningful trends. Such methods will become indispensable as biological big data are used to understand the impact of anthropogenic pressures on biodiversity and to inform efforts to mitigate them.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Aqueous Photoelectrochemical CO 2 Reduction to CO and Methanol over a Silicon Photocathode Functionalized with a Cobalt Phthalocyanine Molecular Catalyst

We report a precious-metal-free molecular catalyst-based photocathode that is active for aqueous CO 2 reduction to CO and methanol. The photoelectrode is composed of cobalt phthalocyanine molecules anchored on graphene oxide which is integrated via a (3-aminopropyl)triethoxysilane linker to p-type silicon protected by a thin film of titanium dioxide. The photocathode reduces CO 2 to CO with high selectivity at potentials as mild as 0 V versus the reversible hydrogen electrode (vs RHE). Methanol production is observed at an onset potential of –0.36 V vs RHE, and reaches a peak turnover frequency of 0.18 s –1 . To date, this is the only molecular catalyst-based photoelectrode that is active for the six-electron reduction of CO 2 to methanol. Furthermore, this work puts forth a strategy for interfacing molecular catalysts to p-type semiconductors and demonstrates state-of-the-art performance for photoelectrochemical CO 2 reduction to CO and methanol.

14 SOLAR ENERGY↗