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At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

Atmospheric Pre-Corrected Differential Absorption Techniques to Retrieve Columnar Water Vapor: Theory and Simulations

Two different approaches exist to retrieve columnar water vapor from imaging spectrometer data: (1) Differential absorption techniques based on: (a) Narrow-Wide (N/W) ratio between overlapping spectrally wide and narrow channels; (b) Continuum Interpolated Band Ratio (CIBR) between a measurement channel and the weighted sum of two reference channels. (2) Non-linear fitting techniques which are based on spectral radiative transfer calculations. The advantage of the first approach is computational speed and of the second, improved retrieval accuracy. Our goal was to improve the accuracy of the first technique using physics based on radiative transfer. Using a modified version of the Duntley equation, we derived an "Atmospheric Pre-corrected Differential Absorption" (APDA) technique and described an iterative scheme to retrieve water vapor on a pixel-by-pixel basis. Next we compared both, the CIBR and the APDA using the Duntley equation for MODTRAN3 computed irradiances, transmissions and path radiance (using the DISORT option). This simulation showed that the CIBR is very sensitive to reflectance effects and that the APDA performs much better. An extensive data set was created with the radiative transfer code 6S over 379 different ground reflectance spectra. The calculated relative water vapor error was reduced significantly for the APDA. The APDA technique had about 8% (vs. over 35% for the CIBR) of the 379 spectra with a relative water vapor error of greater than +5%. The APDA has been applied to 1991 and 1995 AVIRIS scenes which visually demonstrate the improvement over the CIBR technique.

Borel, Christoph C.↗
NASA NTRS2019

When There are Different Types of Smoke in the Sky It Changes How the Sun Light Goes Through the Sky

When the sky gets smoke in it, it can be more or less bright (white) than before. This is because the small smoke bits can change whether sun light gets through the sky to the ground, can change how much white sky water there is, and can change how the sky air moves around. If the smoke is blacker, it can make the sky warmer and if the smoke is whiter, it can make the sky (and the ground) cooler because the sun light doesn't get through. So we wanted to know whether the smoke is blacker or whiter over the big water far away from here, near where there are a lot of fires on the land.We went to the big water place and watched the sky, the air, the sky smoke, and the white sky water. We did this by flying in the sky with our computers. We watched the smoke in a lot of different ways: we can look at the smoke from near the water and see what sun light gets through the sky, or from above and see how the sun light comes back up to space, or go right in the smoke with our flying computer eyes. Then we looked at whether the different ways of seeing showed that the same smoke was different (blacker or whiter) or the same. A lot of time they said it was the same, at least in some ways, but sometimes the smoke looked different and it changed a lot in different places over the big water.We hope other people can put these answers into their computer studies, or into their computers that fly REALLY high, and then we can better understand how the sky gets warmer or cooler from smoke.

Pistone, Kristina↗
NASA NTRS2014

Use Of The Operational Air Quality Monitor (AQM) For In-Flight Water Testing Project

A primary requirement for manned spaceflight is Environmental Health which ensures air and water contaminants, acoustic profiles, microbial flora, and radiation exposures within the cabin are maintained to levels needed for crew health and for vehicle system functionality. The reliance on ground analyses of returned samples is a limitation in the current environmental monitoring strategy that will prevent future Exploration missions beyond low-Earth orbit. This proposal attempts to address this shortcoming by advancing in-flight analyses of water and air. Ground analysis of in-flight, air and water samples typically employ vapor-phase analysis by gas chromatography-mass spectrometry (GC-MS) to identify and quantify organic compounds present in the samples. We envision the use of newly-developed direct ionization approaches as the most viable avenue leading towards an integrated analytical platform for the monitoring of water, air, and, potentially bio-samples in the cabin environment. Development of an in-flight instrument capable of analyzing air and water samples would be the logical next step to meeting the environmental monitoring needs of Exploration missions. Currently, the Air Quality Monitor (AQM) on-board ISS provides this specific information for a number of target compounds in the air. However, there is a significant subset of common target compounds between air and water. Naturally, the following question arises, "Can the AQM be used for both air and water quality monitoring?" Previous directorate-level IR&D funding led to the development of a water sample introduction method for mass spectrometry using electrothermal vaporization (ETV). This project will focus on the integration of the ETV with a ground-based AQM. The capabilities of this integrated platform will be evaluated using a subset of toxicologically important compounds.

Macatangay, Ariel↗
NASA NTRS1981

On the uncertainty in the determination of ground reflectance and temperature from TM measurements

Uncertainties in the derivation of the ground reflectance and temperature relative to the uncertainty in the estimation of aerosol loading and water vapor amount are presented. To compute the reflectance for TM 1 (thematic mapper) through TM6, a doubling model is used, and to compute satellite-received radiance for TM7, an emission-transmission model is employed. It is shown that at a water vapor concentration of higher than 50% above normal, the relative sensitivity remains as low as 8% for ground reflectance determinations. The relative sensitivity for determining ground temperature for midlatitude summer climatological profile is less than 5%, but as the ground temperature is approximately 300 K, low sensitivity still means a variation of a few degrees. An increase in water vapor amount causes an uncertainty in ground temperature and reflectance calculations comparable to the uncertainty in aerosol loading and water vapor amount estimations.

Kiang, R. K.↗
NASA NTRS1969

Millimeter-wave atmospheric loss prediction method

Relationship between atmospheric attenuation and the ground temperature and humidity provides a reference from which changes in temperature and humidity will produce a corresponding atmospheric loss figure. Computer program computes atmospheric loss due to water content, given the measured loss and ground temperature and humidity.

Stelzried, C. T.↗
NASA NTRS2004

Ground Ice at the Phoenix Landing Site: A Preflight Assessment

One of the objectives of the Mars Scout mission, Phoenix, is to characterize the present state of water in the martian environment, in a location where water may play a significant role in the present and past habitability of Mars. Given the generally dry and cold climate of Mars today any substantial amount of water is expected to occur in the form of ground ice (subsurface ice) within the regolith. The Mars Odyssey Gamma Ray Spectrometer has indicated abundant subsurface hydrogen and inferred ground ice at high latitudes. Therefore, the Phoenix mission will be targeted to land in the northern high latitudes (approximately 65 degrees N - 75 degrees N) where ground ice is expected to be abundantly available for analysis. The lander will be capable of excavating, sampling, and analyzing, dry and water-rich/icy soils. The location and depth of excavation necessary to achieve the goals of sampling and analysis of icy material become important parameters to assess. In the present work we ask two key questions: 1) At what depth within the regolith do we expect to find ice? 2) How might this depth vary over the region of potential landing sites? Numerous lines of evidence can be employed to provide an indication of the presence or absence of shallow ground ice at the potential landing sites. For example geomorphology, neutrons, gamma rays, and theory each contribute clues to an overall understanding of the distribution of ice. Orbital observations provide information on a variety of spatial scales, typically 10 s of meters (patterned ground) to 100 s of kilometers (gamma rays). While information on all of these scales are important, of particular interest is how the presence and depth of ground ice might vary on spatial scales comparable to the lander and its work area. While ground ice may be stable (and present) on a regional scale, local-scale slopes and changes in the physical characteristics of soils can result in significant variations in the distribution of ice.

Mellon, M. T.↗
NASA NTRS1976

Application of remote sensing in the determination of water quality in Nebraska reservoirs

In June, July, and August, 1975, ground truth was collected from Lake McConaughy, a 35,000 acre reservoir in western Nebraska, coincident with the overflights of LANDSAT. Water samples were collected on six different dates and analyzed for turbidity, suspended solids, and chlorophyll, parameters which had correlated well with CCT reflectances. The correlations and regressions reported were derived from data obtained on only three of the six sampling dates. The radiance values from each of the four spectral bands were printed out in the form of a map of Lake McConaughy. Reflectances in the various bands were then obtained from the map at the appropriate sampling sites. The dependent variables chlorophyll, suspended solids, and turbidity were compared to the independent variables - reflectances in the four bands - by regression analysis. Both multiple and univariate regressions were examined. It is concluded that CCT's from LANDSAT can be used to detect and quantify the water quality parameters suspended solids, turbidity, and chlorophyll.

Hergenrader, G. L.↗
NASA NTRS1992

Ice in the Martian regolith

A number of possible morphologic indicators of ground ice on Mars are discussed, with emphasis on rampart craters and terrain softening. Geologic evidence indicates that the Martian surface has been substantially modified by the action of liquid water, and that much of that water still resides beneath the surface as ground ice. Calculations of the thermodynamic stability of ground ice on Mars suggest that it can exist very close to the surface at high latitudes, but can persist only at substantial depths near the equator. A variety of observed Martian landforms can be attributed to creep of the Martian regolith abetted by deformation of ground ice. Global mapping of creep features also supports the idea that ice is present in near-surface materials at latitudes higher than +/- 30 deg, and suggests that ice is largely absent from such materials at lower latitudes.

Squyres, S. W.↗
NASA NTRS2018

Airborne, Direct-Detection, 2-μm Triple-Pulse IPDA Lidar for Simultaneous and Independent Atmospheric Water Vapor and Carbon Dioxide Active Remote Sensing

Atmospheric water vapor and carbon dioxide are important greenhouse gases that significantly contribute to the global radiation budget on Earth. A 2-micron triple-pulse, Integrated Path Differential Absorption (IPDA) lidar instrument for ground and airborne atmospheric carbon dioxide and water vapor concentration measurements using direct detection was developed at NASA Langley Research Center. This active remote sensing instrument provides an alternate approach with significant advantages for measuring atmospheric concentrations of the gases. A high energy pulsed laser transmitter approach coupled with sensitive receiver detection provides a high-precision measurement capability by having a high signal-to-noise ratio. This paper presents the concept, development, integration and testing of the 2-micron triple-pulse IPDA. The integration includes the various IPDA transmitter, receiver and data acquisition subsystems and components. Ground and airborne testing indicated successful operation of the IPDA lidar.

Refaat, Tamer F.↗
NASA NTRS1974

Dynamic conversion of solar generated heat to electricity

The effort undertaken during this program led to the selection of the water-superheated steam (850 psig/900 F) crescent central receiver as the preferred concept from among 11 candidate systems across the technological spectrum of the dynamic conversion of solar generated heat to electricity. The solar power plant designs were investigated in the range of plant capacities from 100 to 1000 Mw(e). The investigations considered the impacts of plant size, collector design, feed-water temperature ratio, heat rejection equipment, ground cover, and location on solar power technical and economic feasibility. For the distributed receiver systems, the optimization studies showed that plant capacities less than 100 Mw(e) may be best. Although the size of central receiver concepts was not parametrically investigated, all indications are that the optimal plant capacity for central receiver systems will be in the range from 50 to 200 Mw(e). Solar thermal power plant site selection criteria and methodology were also established and used to evaluate potentially suitable sites. The result of this effort was to identify a site south of Inyokern, California, as typically suitable for a solar thermal power plant. The criteria used in the selection process included insolation and climatological characteristics, topography, and seismic history as well as water availability.

Powell, J. C.↗
NASA NTRS2022

SMAP Soil Moisture Assimilation To Enhance Streamflow Estimates Across South Asia

Streamflow estimation across areas facing water scarcity is important considering the evolving climatic conditions. In this study, the impact of assimilating Soil Moisture Active Passive (SMAP) soil moisture retrievals on the modeled streamflow across three main river basins in South Asia is explored. Model estimated runoff was hydraulically routed using the HYMAP routing model within the NASA Land Information System (LIS) framework. Streamflow estimates via soil moisture assimilation highlighted the potential improvements in streamflow across low-flow river tributaries in irrigated regions. Limited relative change was noted along high-flow river tributaries. Modeled streamflow tended to underestimate the flow magnitude at upstream stations and overestimated the streamflow at downstream stations within the Indus basin due to missing physics related to reservoir operation. Improvement of the modeling systems representativeness of the ground conditions by the inclusion of water management information would potentially improve the current streamflow modeling capability across South Asia.

Jawairia Ahmad↗
DOE OSTI2020

Evaluation of Radiolysis Data for Hydrogen Gas Generation During Gamma Irradiation of Pre-Corroded and Pristine Aluminum Samples - An Aluminum SNF Dry Storage Study Interim Report

Information and data from radiolysis testing to measure hydrogen (H₂) generated from hydrated oxides on aluminum exposed to ⁶⁰Co radiation were reviewed to evaluate hydrogen generation with radiation dose. Hydrogen generation rate is a primary input to the coupled thermal-chemical system model of the performance of aluminum-clad spent nuclear fuel in a dry storage canister (ASNF-in-canister) over its storage life. Hydrogen generation data and hydrogen generation rate (hydrogen generated per absorbed radiation dose, $\Delta$(H₂)/$\Delta$(dose)) were reported in two reports for radiolysis testing [1, 2]. The testing involved first-time data¹ for radiolytic yield of hydrogen from hydrated-oxides-on-aluminum substrates, and from pristine (non-corroded) aluminum substrates. The laboratory-grown hydrated-oxides-on-aluminum substrates contained a ~ 5 μm film consisting of the trihydroxide bayerite (Al(OH)₃) with amounts of the oxyhydroxide boehmite (AlOOH). These specimens were assumed to also contain physisorbed water (unquantified). The pristine substrates were flat coupons of aluminum that were ground to a 600-grit finish but were not immersed in water to grow a hydrated oxide. The pristine substrates were tested as companion specimens to provide information on hydrogen generation from material without chemisorbed water and were assumed to contain physisorbed water (unquantified).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

The distribution of Martian ground ice at other epochs

The past orbital evolution of Mars is examined in relation to changes in ice stability as well as the condensation, sublimation, and diffusion of atmospheric water in an exchange with the regolith. The Martian obliquity has undergone significant oscillations in its recent past. During periods of high obliquity, the solar energy would have been distributed such that the equatorial and midlatitude regions would have been colder that at present and the polar regions would have been warmer. Warmer polar regions would result in the sublimation of more polar cap water into the atmosphere and thus higher atmospheric water abundances. This combination of effects would have resulted in ground ice being stable globally. During periods of low obliquity the opposite would have occurred. Modeling results of the regolith thermal behavior and the molecular diffusion of water vapor within the regolith and in exchange with the atmosphere have shown significant quantities of ground ice can form at all latitudes within the top 50 cm to 1 m of the regolith during periods of high obliquity. The amount of ice that forms can be as much as the regolith pores can hold. During low obliquity most or all of this ice sublimes and diffuses away. Below this depth a longer-term stability is observed at some latitudes where ice steadily increases in concentration regardless of orbital oscillations that occur.

Mellon, M. T.↗
DOE OSTI2024

Influence of tritium exposure route on vegetation types at the Savannah River Site

Plant, soil, water, and other media from various locations at the Savannah River Site were measured for total tritium (T) content and T speciation to characterize T in these areas, as well as investigate its uptake behavior and the transport of T species in these media. This characterization included the isolation and measurement of T in tritiated water (HTO), and (when possible) exchangeable organic bound T (E-OBT) and non-exchangeable organic bound T (NE-OBT). Two areas of interest were investigated: (1) a holding pond with T-contaminated water and (2) open basins or streams with low to background levels of T. Water in the holding pond is used to irrigate forest plots in the local area as a T remediation approach. This study compares the analytical data for water, soil/sediment, plants, and lichens from these locations. Here, the results indicate that the behavior of T in plants from these areas can be a function of one or more of the following: seasonal precipitation, the plant's primary route of access to the T-contamination (such as water uptake through the root vs. shoot), plant physical location (relative to T-contaminated water sources), plant rooting depth, pond water level, and plant height above the ground. Total T concentrations were lowest in the un-irrigated forest plants, followed by irrigated forest plants, shallow rooting plants near the pond, deep rooting plants further from the pond, and then water-saturated plants. The OBT:HTO and NE-OBT:E-OBT ratios were always greater for plants from irrigated forest plots compared to those from the holding pond.

36 MATERIALS SCIENCE↗
NASA NTRS2000

The Video Guidance Sensor: Space, Earth, Ground, and Sea

Engineers at the Marshall Space Flight Center (MSFC) have been developing and testing video-based sensors for automated spacecraft guidance for several years. The next generation of Video Guidance Sensor (VGS) is being designed to be faster and more capable than ever. It will have applications to relative position measurement in any field of endeavor. The system works by sequentially firing two different wavelengths of laser diodes at the target (which has retroreflectors) and processing the two images. Since the target only reflects one wavelength, it shows up well in one image and not at all in the other. Because the target's dimensions are known, the relative positions and attitudes of the target and the sensor can be computed from the spots reflected from the target. The current sensor operates at 5 Hz at ranges from 1 to 110 meters with a 20 deg. field-of-view. The Video Guidance Sensor (VGS) developed over the past several years has performed well in testing and met the objective of being used as the terminal guidance sensor for an automated rendezvous and capture system. The first VGS was successfully tested in closed-loop 3-degree-of-freedom (3-DOF) tests in 1989 and then in 6-DOF open-loop tests in 1992 and closed-loop tests in 1993-4. Development and testing continued, and in 1995 approval was given to test the VGS in an experiment on the Space Shuttle. The VGS flew in 1997 and in 1998, performing well during both flight experiments. During the development and testing before, during, and after the flight experiments, numerous areas for improvement were found. The next generation of VGS is being designed to operate at up to 100 Hz tracking rates and at ranges from 0.5 to 200 meters. In addition to its use as a spacecraft guidance sensor, it could be used as an alignment aid for an operator of a remote system (giving position and attitude feedback data), as a feedback system for a robotic arm, or for automated vehicle guidance. The next generation VGS, with its higher tracking rates, smaller size, and lower power could be used in more places than the original VGS, and by using LED's instead of laser diodes, the system would be eye-safe at any range. More potential applications include aerial station keeping (keeping 2 or more autonomous aircraft within particular relative positions), under-water robotics, and the guidance of ground vehicles in predefined areas equipped with sets of targets.

Howard, Richard T.↗
DOE OSTI2020

A variational Monte Carlo approach for core excitations

In this work, we present a systematically improvable approach to core excitations in variational Monte Carlo. Building on recent work in excited-state-specific Monte Carlo, we show how a straightforward protocol, starting from a quantum chemistry guess, is able to capture core state's strong orbital relaxations, maintain accuracy in the near-nuclear region during these relaxations, and explicitly balance accuracy between ground and core excited states. In water, ammonia, and methane, which serve as prototypical representatives for oxygen, nitrogen, and carbon core states, respectively, this approach predicts core excitation energies within 0.3 eV of experiment and core excitation peak separations within 0.1 eV of experiment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗