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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44

Investigation of Ruthenium Dissolution in Advanced Membrane Electrode Assemblies for Direct Methanol Based Fuel Cell Stacks

Dissolution of ruthenium was observed in the 80-cell stack. Duration testing was performed in single cell MEAs to determine the pathway of cell degradation. EDAX analysis on each of the single cell MEAs has shown that the Johnson Matthey commercial catalyst is stable in DMFC operation for 250 hours, no ruthenium dissolution was observed. Changes in the hydrophobicity of the cathode backing papers was minimum. Electrode polarization analysis revealed that the MEA performance loss is attributed to changes in the cathode catalyst layer. Ruthenium migration does not seem to occur during cell operation but can occur when methanol is absent from the anode compartment, the cathode compartment has access to air, and the cells in the stack are electrically connected to a load (Shunt Currents). The open-to-air cathode stack design allowed for: a) The MEAs to have continual access to oxygen; and b) The stack to sustain shunt currents. Ruthenium dissolution in a DMFC stack can be prevented by: a) Developing an internally manifolded stacks that seal reactant compartments when not in operation; b) Bringing the cell voltages to zero quickly when not in operation; and c) Limiting the total number of cells to 25 in an effort to limit shunt currents.

alternative power sources↗

Batteries and Fuel Cells in Space

The year 2000 will mark the 44th anniversary of the space program that started with the launch of the first Sputnik on October 4, 1956.

batteries fuel cells space↗

Reduced Toxicity Fuel Satellite Propulsion System Including Fuel Cell Reformer with Alcohols Such as Methanol

A reduced toxicity fuel satellite propulsion system including a reduced toxicity propellant supply for consumption in an axial class thruster and an ACS class thruster. The system includes suitable valves and conduits for supplying the reduced toxicity propellant to the ACS decomposing element of an ACS thruster. The ACS decomposing element is operative to decompose the reduced toxicity propellant into hot propulsive gases. In addition the system includes suitable valves and conduits for supplying the reduced toxicity propellant to an axial decomposing element of the axial thruster. The axial decomposing element is operative to decompose the reduced toxicity propellant into hot gases. The system further includes suitable valves and conduits for supplying a second propellant to a combustion chamber of the axial thruster, whereby the hot gases and the second propellant auto-ignite and begin the combustion process for producing thrust.

Steven J Schneider↗

Portable direct methanol fuel cell systems

This article includes discussion of the specific power and power density requirements for various portable system applications, the status of stack technology, progress in the implementation of balance-of-plant designs, and a summary of the characteristics of various DMFC portable power source demonstrations.

direct methanol fuel cells↗

Nafion(TM) Coats For Electrodes In Liquid-Feed Fuel Cells

Coating or impregnation with commercially available material enables oxidation of organic liquid fuels. Nafion(TM) investigated for use in application because of known combination of desirable characteristics: It is perfluorinated, hydrophilic, proton-conducting ion-exchange polymer exhibiting relatively high thermal and electrochemical stability and not detrimental to kinetics of electrochemical processes. Available in solubilized form and used to apply stable coats to surfaces of electrodes.

Narayanan, Sekharipuram R.↗

Hollow-fiber H2/O2 fuel cell

Dual-membrane hollow-fiber electrode increases reliability and lowers costs. Leakage of fuel or oxidizer through fiber does not result in failure; excess product water migrates into electrolyte where it is removed by evaporation or distillation; constant exposure of fiber to electrolyte eliminates problems of drying and consequent failure; reference electrode monitors current collectors and overall cell performance.

Ingham, J. D.↗

An expert system to manage the operation of the Space Shuttle's fuel cell cryogenic reactant tanks

This paper describes a rule-based expert system to manage the operation of the Space Shuttle's cryogenic fuel system. Rules are based on standard fuel tank operating procedures described in the EECOM Console Handbook. The problem of configuring the operation of the Space Shuttle's fuel tanks is well-bounded and well defined. Moreover, the solution of this problem can be encoded in a knowledge-based system. Therefore, a rule-based expert system is the appropriate paradigm. Furthermore, the expert system could be used in coordination with power system simulation software to design operating procedures for specific missions.

Murphey, Amy Y.↗