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At least 793 records · Page 44

Observations of Greenhouse Gases as Climate Indicators

Humans have significantly altered the energy balance of the Earth’s climate system mainly not only by extracting and burning fossil fuels but also by altering the biosphere and using halocarbons. The 3rd US National Climate Assessment pointed to a need for a system of indicators of climate and global change based on long-term data that could be used to support assessments and this led to the development of the National Climate Indicators System (NCIS). Here we identify a representative set of key atmospheric indicators of changes in atmospheric radiative forcing due to greenhouse gases (GHGs), and we evaluate atmospheric composition measurements, including non-CO2GHGs for use as climate change indicators in support of the US National Climate Assessment. GHG abundances and their changes over time can provide valuable information on the success of climate mitigation policies, as well as insights into possible carbon-climate feedback processes that may ultimately affect the success of those policies. To ensure that reliable information for assessing GHG emission changes can be provided on policy-relevant scales, expanded observational efforts are needed. Furthermore, the ability to detect trends resulting from changing emissions requires a commitment to supporting long-term observations. Long-term measurements of greenhouse gases, aerosols, and clouds and related climate indicators used with a dimming/brightening index could provide a foundation for quantifying forcing and its attribution and reducing error in existing indicators that do not account for complicated cloud processes.

greenhouse gases↗

Fluidized combustion of coal

A combustion technology that permits the burning of low quality coal, and other fuels, while maintaining stack emissions within State and Federal EPA limits is discussed. Low quality fuels can be burned directly in fluidized beds while taking advantage of low furnace temperatures and chemical activity within the bed to limit SO2 and NOx emissions. The excellent heat transfer characteristics of the fluidized beds also result in a reduction of total heat transfer surface requirements. Tests on beds operating at pressures of one to ten atmospheres, at temperatures as high as 1600 F, and with gas velocities in the vicinity of four to twelve feet per second, have proven the concept. The progress that has been made in the development of fluidized bed combustion technology and work currently underway are discussed.

Pope, M.↗

Effects of compression and expansion ramp fuel injector configuration on scramjet combustion and heat transfer

A scramjet combustor with four wall-ramp injectors containing Mach-1.7 fuel jets in the base of the ramps was investigated experimentally. During the test program, two swept ramp injector designs were evaluated. One swept-ramp model had 10-deg compression-ramps and the other had 10-deg expansion cavities between flush wall ramps. The scramjet combustor model was instrumented with pressure taps and heat-flux gages. The pressure measurements indicated that both injector configurations were effective in promoting mixing and combustion. Autoignition occurred for the compression-ramp injectors, and the fuel began to burn immediately downstream of the injectors. In tests of the expansion ramps, a pilot was required to ignite the fuel, and the fuel did not burn for a distance of at least two gaps downstream of the injectors. Once initiated, combustion was rapid in this configuration. Heat transfer measurements showed that the heat flux differed greatly both across the width of the combustor and along the length of the combustor.

Stouffer, Scott D.↗

Introduction to the special topic on inertial confinement fusion diagnostics

In the first decade of the 21st century, the United States began operating three leading Inertial Confinement Fusion (ICF) and High-Energy Density Physics (HEDP) facilities. The National Ignition Facility (NIF) began its quest to first surpass the Lawson Criterion and then reach thermonuclear ignition and thermonuclear gain. The Omega EP (Extended Performance) laser provides unprecedented energy, reliability, and consistency for petawatt (PW)-class laser experiments. The Omega laser continues to support over 1000 ICF and HEDP experiments each year. The Z pulsed power machine is a Z-pinch plasma confinement device that was refurbished to increase current drive and improve reliability. The extreme states of matter created in these new facilities required advancement of many technologies. The most important among these was the significant improvement in instrumentation capabilities needed to diagnose plasma conditions and resulting nuclear products. The instruments needed a better temporal, spatial, and energy resolution. They also needed to be hardened against EMP and radiation. Typical events in an ICF implosion include compressing the deuterium–tritium (DT) fuel to greater than 60 g/cm 3 and heating the DT to a temperature greater than 10 keV (110 000 000 K). The DT atoms react to produce 14 MeV neutrons from a volume with a radius of ~30 μm. When the fuel ignites, the DT burn prop agates into cold fuel and the neutron-emitting region can reach sizes of over 200 μm. Furthermore, the burn typically lasts less than 150 ps, but the burn duration will decrease as the DT yield increases. Burn durations as short as 90 ps have been recorded and are predicted to decrease still further to 20 ps. X-ray imaging diagnostics are needed to measure the acceleration and velocity of the capsule enclosing the DT, where the implosion velocities can reach over 400 km/s.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Miniature Gas-Turbine Power Generator

A proposed microelectromechanical system (MEMS) containing a closed- Brayton-cycle turbine would serve as a prototype of electric-power generators for special applications in which high energy densities are required and in which, heretofore, batteries have been used. The system would have a volume of about 6 cm3 and would operate with a thermal efficiency >30 percent, generating up to 50 W of electrical power. The energy density of the proposed system would be about 10 times that of the best battery-based systems now available, and, as such, would be comparable to that of a fuel cell. The working gas for the turbine would be Xe containing small quantities of CO2, O2, and H2O as gaseous lubricants. The gas would be contained in an enclosed circulation system, within which the pressure would typically range between 5 and 50 atm (between 0.5 and 5 MPa). The heat for the Brayton cycle could be supplied by any of a number of sources, including a solar concentrator or a combustor burning a hydrocarbon or other fuel. The system would include novel heat-transfer and heat-management components. The turbine would be connected to an electric power generator/starter motor. The system would include a main rotor shaft with gas bearings; the bearing surfaces would be made of a ceramic material coated with nanocrystalline diamond. The shaft could withstand speed of 400,000 rpm or perhaps more, with bearing-wear rates less than 10(exp -)4 those of silicon bearings and 0.05 to 0.1 those of SiC bearings, and with a coefficient of friction about 0.1 that of Si or SiC bearings. The components of the system would be fabricated by a combination of (1) three-dimensional xray lithography and (2) highly precise injection molding of diamond-compatible metals and ceramic materials. The materials and fabrication techniques would be suitable for mass production. The disadvantages of the proposed system are that unlike a battery-based system, it could generate a perceptible amount of sound, and, if it were to burn fuel, then it would also generate exhaust, similarly to other combustion-based power sources.

Wiberg, Dean↗

The effect of initial diameter in sperically symmetric droplet combustion of sooting fuels

The effect of initial droplet diameter on the burning rate of sooting fuels - n-heptane and 1-chloro-octane - was examined experimentally at low gravity. A 1.2s drop tower provided a low gravity environment to minimize buoyancy and achieve spherically symmetric flames for stationary droplets. Free-floating and fiber-supported droplets were burned, and both techniques gave matching results for droplets of similar initial diameter. Burning rate constants for both fuels were measured for a large number of droplets ranging from 0.4 to 1.1mm in initial diameter.

Jackson, G. S.↗

Alternative-Fuel Effects on Contrails & Cruise Emissions (ACCESS-2) Flight Experiment

Although the emission performance of gas-turbine engines burning renewable aviation fuels have been thoroughly documented in recent ground-based studies, there is still great uncertainty regarding how the fuels effect aircraft exhaust composition and contrail formation at cruise altitudes. To fill this information gap, the NASA Aeronautics Research Mission Directorate sponsored the ACCESS flight series to make detailed measurements of trace gases, aerosols and ice particles in the near-field behind the NASA DC-8 aircraft as it burned either standard petroleum-based fuel of varying sulfur content or a 50:50 blend of standard fuel and a hydro-treated esters and fatty acid (HEFA) jet fuel produced from camelina plant oil. ACCESS 1, conducted in spring 2013 near Palmdale CA, focused on refining flight plans and sampling techniques and used the instrumented NASA Langley HU-25 aircraft to document DC-8 emissions and contrails on five separate flights of approx.2 hour duration. ACCESS 2, conducted from Palmdale in May 2014, engaged partners from the Deutsches Zentrum fuer Luft- und Raumfahrt (DLR) and National Research Council-Canada to provide additional scientific expertise and sampling aircraft (Falcon 20 and CT-133, respectively) with more extensive trace gas, particle, or air motion measurement capability. Eight, muliti-aircraft research flights of 2 to 4 hour duration were conducted to document the emissions and contrail properties of the DC-8 as it 1) burned low sulfur Jet A, high sulfur Jet A or low sulfur Jet A/HEFA blend, 2) flew at altitudes between 6 and 11 km, and 3) operated its engines at three different fuel flow rates. This presentation further describes the ACCESS flight experiments, examines fuel type and thrust setting impacts on engine emissions, and compares cruise-altitude observations with similar data acquired in ground tests.

Anderson, Bruce E.↗

Combustor exhaust-emissions and blowout-limits with diesel number 2 and Jet A fuels utilizing air-atomizing and pressure-atomizing nozzles

The effect of fuel properties on exhaust emissions and blowout limits of a high-pressure combustor segment is evaluated using a splash-groove air-atomizing fuel injector and a pressure-atomizing simplex fuel nozzle to burn both diesel number 2 and Jet A fuels. Exhaust emissions and blowout data are obtained and compared on the basis of the aromatic content and volatility of the two fuels. Exhaust smoke number and emission indices for oxides of nitrogen, carbon monoxide, and unburned hydrocarbons are determined for comparison. As compared to the pressure-atomizing nozzle, the air-atomizing nozzle is found to reduce nitrogen oxides by 20%, smoke number by 30%, carbon monoxide by 70%, and unburned hydrocarbons by 50% when used with diesel number 2 fuel. The higher concentration of aromatics and lower volatility of diesel number 2 fuel as compared to Jet A fuel appears to have the most detrimental effect on exhaust emissions. Smoke number and unburned hydrocarbons are twice as high with diesel number 2 as with Jet A fuel.

Ingebo, R. D.↗

System Modeling and Diagnostics for Liquefying-Fuel Hybrid Rockets

A Hybrid Combustion Facility (HCF) was recently built at NASA Ames Research Center to study the combustion properties of a new fuel formulation that burns approximately three times faster than conventional hybrid fuels. Researchers at Ames working in the area of Integrated Vehicle Health Management recognized a good opportunity to apply IVHM techniques to a candidate technology for next generation launch systems. Five tools were selected to examine various IVHM techniques for the HCF. Three of the tools, TEAMS (Testability Engineering and Maintenance System), L2 (Livingstone2), and RODON, are model-based reasoning (or diagnostic) systems. Two other tools in this study, ICS (Interval Constraint Simulator) and IMS (Inductive Monitoring System) do not attempt to isolate the cause of the failure but may be used for fault detection. Models of varying scope and completeness were created, both qualitative and quantitative. In each of the models, the structure and behavior of the physical system are captured. In the qualitative models, the temporal aspects of the system behavior and the abstraction of sensor data are handled outside of the model and require the development of additional code. In the quantitative model, less extensive processing code is also necessary. Examples of fault diagnoses are given.

Poll, Scott↗

Tribological Properties Of Coal Slurries

Report describes study of tribological properties of coal/methanol slurries with pin-on-disk tribometer. Coefficients of friction, rates of wear of steel pin, and morphological studies of worn surfaces conducted on pins and disks of AISI 440C HT stainless steel and M-50 tool steel, both used as bearing steels. Coal slurries considered as replacement fuels in terrestrial oil-burning facilities and possible fuels for future aircraft turbine engines. Rates of wear of metallic components through which slurries flow limit such practical applications.

Fusaro, Robert L.↗

An experimental study of high-pressure droplet combustion

The results are presented of an experimental study on suspended n-heptane droplet combustion in air for reduced pressures up to P(r) = 2.305. Transition to fully transient heat-up through the critical state is demonstrated above a threshold pressure corresponding to P(r) of roughly 1.4. A silhouette imaging technique resolves the droplet surface for reduced pressures up to about P(r) roughly 0.63, but soot formation conceals the surface at higher pressures. Images of the soot plumes do not show any sudden change in behavior indicative of critical transition. Mean burning rate constants are computed from the d-squared variation law using measured effective droplet diameters at ignition and measured burn times, and corrected burning times are computed for an effective initial droplet diameter. The results show that the burning rates increase as the fuel critical pressure is approached and decrease as the pressure exceeds the fuel critical pressure. Corrected burning times show inverse behavior.

Norton, Chris M.↗

Ignition, Burning and Extinction of a Strained Fuel Strip with Complex Kinetics

Flame structure and ignition and extinction processes associated with a strained fuel strip are explored numerically using detailed transport and complex kinetics for a propane-air reaction. Ignition modes are identified that are similar to those predicted by one-step activation energy asymptotics, i.e., modes in which diffusion flames can ignite as independent or dependent interfaces and modes in which single premixed or partially premixed flames ignite and burn. These ignition modes have been found to be dependent on critical combinations of strain rate, fuel strip thickness and initial reactant temperatures. The formation of NO/NO2 is found to be strongly dependent on strain rate and the local molecular mixing of reactants which occurs as a consequence of strain. Extinction in this configuration is seen to occur due to fuel consumption by adjacent flames, although viscosity is seen to have the effect of delaying extinction by reducing the effective strain rate experienced by the flames. Response of the flames to oscillatory strain rates is seen to be strongly dependent on the amplitude and frequency of the oscillation.

Selerland, T.↗

A Multifaceted Analysis of Chemical-Absorption Heat Pump Technology for Integrated Energy Systems

Integrated Energy Systems (IES) research and development is essential for improving the economic usage of lowcarbon energy sources such as nuclear power, solar, and wind in the U.S. An ideal IES uses various energy sources and delivers energy to the power grid and industry as efficiently as possible. As part of this effort, there are many opportunities to use low-carbon energy for industries requiring process heat for production of many chemicals and fuels [1]. Currently, industries only have the option to burn CO2 emitting fuels or use resistance heaters for this process heat. Using resistance heaters is one way to electrify a process, allowing for low-carbon energy sources to be used, but is an inefficient method unless temperatures exceed 1000?C. Heat pumps have long been used to provide efficient heating or cooling by moving heat instead of generating it. More traditional heat pumps such as vapor compression heat pumps and absorption heat pumps are limited to temperatures below 300?C due to refrigerant and component material limits. However, chemical heat pumps have been investigated as an option for pumping heat at temperatures above 600?C [2], making the heat more applicable to many more chemical and fuel production processes.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Cropland and Land-Clearing Emission Factors From Firex-AQ

The Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign is a NOAA/NASA interagency intensive study of North American fires that took place from July to September 2019. Agricultural fires were sampled on 7 flights from August 21st to September 3rd, 2019. We present emission factors for gas-phase and aerosol-phase species for the different fuel types identified during the campaign. We discuss the dependence of these emission factors on both fuel type and burning characteristics such as modified combustion efficiency (MCE). We analyze 73 fires encompassing four different agricultural fuels (corn, rice, soybean, wheat) and four different types of land-clearing fuels (grass, slash, pile, shrub). Approximately half of all sampled fires were burning corn agricultural residue. We report emission factors for 118 VOCs, where two thirds of emissions are made up of species with lifetimes against oxidation by OH of less than 12 hours (near-field impacts) and the remainder have longer-lifetimes (far-field impacts). We also include an additional 9 aerosol species, 12 halogenated species, 5 sulfur-containing species, and 22 nitrogen-containing species, including NH3 and NOx. There is a statistically significant difference in MCE between agricultural and land-clearing fires that accounts for some of the differences in emission factors across these fuels. VOCs generally have a strong negative correlation with MCE but with different slopes across fuel types. There is a significant positive relationship between MCE and three gas-phase (NO, NO2, SO2) and two aerosol-phase (pCl, pNH4) species. Many emission factors show additional dependence factors beyond MCE that could be related to fuel composition, fire temperature, soil moisture, or other possible differences in burning conditions. Therefore, important differences in emission factors may result when averaging together different types of agricultural and land-clearing fuels in compilations for use in modeling efforts.

biomass burning↗

In Situ Measurements of Ammonia In Plumes Emitted From Wildfires And Agricultural Fires in the US

Emissions of trace gases and particles from fires have a major impact on climate, visibility, air quality, and public health. Biomass burning emissions include reactive nitrogen gases, among which ammonia (NH3) plays a prominent role. NH3 is a short-lived gas that acts as precursor for secondary inorganic aerosols. This process is still poorly constrained in downwind fire plumes. In summer 2019, NASA and NOAA carried out the joint airborne FIREX-AQ (Fire Influence on Regional to global Environments and Air Quality) mission over the continental US to sample plumes from wildfires and agricultural fires. On board the NASA DC-8, we used a modified PTR-ToF-MS instrument for measuring NH3 in situ and at high time resolution. Over the course of the mission, we collected a large set of NH3 data in plumes emitted from fires differing in fuel type and burning stage. Herein, we will present the measured NH3 emissions ratios and factors, compare them with the literature, and investigate the dependence of NH3 emissions on fuel type and burning conditions.

ammonia↗

Effect of degree of fuel vaporization on emissions for a premixed-prevaporized combustor system

The impact of the degree of fuel vaporization upon emission from a flametube combustor was studied using an inlet air pressure of 3 x 10 to the 5th power pascals, inlet air temperatures of 600K and 700K, a reference velocity of 35 meters per second and equivalence ratios of .6 and .72 using Jet A fuel. Incoming air was preheated to temperatures from 600K to 700K by a nonvitiating preheater. Jet A fuel was injected into this airstream through two different fuel injectors manifolded together and mounted in series upstream of a watercooled preforated plate flameholder. The fuel-air mixture burned in a watercooled combustor section. Samples of the fuel-air mixture upstream of the flameholder were obtained for analysis to determine the local degree of fuel vaporization and the fuel-air ratio. Samples of the combustion products were analyzed to determine gaseous emissions. The effects of vaporization on carbon monoxide and nitric on carbon monoxide and nitric oxide emissions are presented.

Cooper, L. P.↗

Flammability of Materials on the Moon

Lunar gravity has been found to increase the limits of flammability for some materials compared to Earth gravity, presenting a goldilocks zone of reduced convective heat loss, while generating enough buoyant flow to replenish fresh oxygen into the flame zone. Combined with the elevated oxygen concentrations of planned Space Exploration Atmospheres (Sea), a long duration fire experiment in Lunar gravity is important to help understand and mitigate the increased risk. Flammability of Materials on the Moon (FM2) is a robotic, self-contained, combustion chamber which will be sent to the surface of the Moon on a Commercial Lunar Payload Services (CLPS) lander mission CP-21. The environmental control system can replicate and conduct fire experiments automatically in the expected atmospheres, specifically 21% oxygen at 14.7 psia, and 34% oxygen at 8.2 psia, which are of immediate interest to the Human Lander System (HLS) and Lunar Rover. The laboratory prototype became operational this summer. There are four samples currently planned; two SIBAL fabrics (cotton/fiberglass blend) which will be burned in air and two acrylic rods which will be burned in Normoxic Space Exploration Atmospheres (SEA). One of each fuel will be burned upward and downward. SIBAL fabric has been found to only burn downward in air in lunar gravity (via Lunar gravity centrifuge and parabolic flight) where on Earth’s gravity it extinguishes immediately after ignition.

Jennifer Zayac↗

Experimental investigation of a solid rocket combustion simulator

The response of solid rocket motor materials to high-temperature corrosive gases is usually accomplished by testing the materials in a subscale solid rocket motor. While this imposes the proper thermal and chemical environment, a solid rocket motor does not provide practical features that would enhance systematic evaluations such as: the ability to throttle for margin testing, on/off capability, low test cost, and a low-hazards test article. Solid Rocket Combustion Simulators (SRCS) are being evaluated by NASA to test solid rocket nozzle materials and incorporate these essential practical features into the testing of rocket materials. The SRCS is designed to generate the thermochemical environment of a solid rocket. It uses hybrid rocket motor technology in which gaseous oxygen (Gox) is injected into a chamber containing a solid fuel grain. Specific chemicals are injected in the aft mixing chamber so that the gases entering the test section match the temperature and a non-dimensional erosion factor B' to insure similarity with a solid motor. Because the oxygen flow can be controlled, this approach allows margin testing, the ability to throttle, and an on/off capability. The fuel grains are inert which makes the test article very safe to handle. The objective of this work was to establish the baseline operating characteristics of a Labscale Solid Rocket Combustion Simulator (LSRCS). This included establishing the baseline burning rates of plexiglass fuels and the evaluation of a combustion instability for hydroxy-terminated polybutadyene (HTPB) propellants. The scope of the project included: (1) activation of MSFC Labscale Hybrid Combustion Simulator; (2) testing of plexiglass fuel at Gox ranges from 0.025 to 0.200 lb/s; (3) burning HTPB fuels at a Gox rate of 0.200 lb/s using four different mixing chamber configurations; and (4) evaluating the fuel regression and chamber pressure responses of each firing.

Frederick, Robert A., Jr.↗