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At least 793 records · Page 44

Reinforcement learning for online adaptation of model predictive controllers: Application to a selective catalytic reduction unit

Here we present a novel application of reinforcement learning (RL) for online dynamic tuning of model predictive controllers (MPC). Applying a state-action-reward-state-action (SARSA) algorithm for temporal difference learning with a control-specific reward function improves the error tracking performance of a standard MPC formulation. The proposed RL approach is also readily adaptable to other MPCs, or entirely different control approaches. Practical details for the implementation of the RL-MPC algorithm are also presented. The proposed algorithm is applied to a case study of controlling nitrogen oxide (NO x ) emissions in an industrial selective catalytic reduction (SCR) unit, a control problem characterized by significant nonlinearity and time delay. Along with an RL-MPC formulation for NOx control, another MPC is proposed to mitigate ammonia slip and decrease ammonia consumption in the SCR. Results showing the efficacy of the RL-MPC for NO x control through learning and implementation on the nonlinear SCR dynamic model are presented.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Environmental and Economic Implications of Emerging Plastic Recycling Technologies

Recycling will play a crucial role in mitigating plastic pollution and promoting a circular economy for polymers. Quantitative analysis can help guide the optimization and implementation of these plastic management strategies, enabling increased circularity while minimizing costs, energy use, greenhouse gas emissions, and other environmental impacts. This talk will outline the Bio-Optimized Technologies to keep Thermoplastics out of Landfills and the Environment (BOTTLE) Consortium's approach to analysis-guided plastic recycling research. Stringent process modelling, life cycle assessment, and techno-economic analysis are used to benchmark the technical feasibility, environmental impacts, and costs of chemical and biological recycling technologies in comparison to conventional fossil fuel-based plastic manufacturing. Across emerging recycling strategies, several key challenges become apparent - including plastic feedstock pretreatment requirements, high energy or chemical use, and recycled plastic yields and quality - highlighting opportunities for future innovation. Through this consistent and in-depth analysis approach, BOTTLE aims to provide the plastics community with key metrics and insights to drive plastic recycling innovation towards a more sustainable and circular economy.

circular economy↗

Closed and Not Closed: Mitigating a Mystery on Chandra's Door

The Chandra X-ray Observatory is part of NASA's fleet of "Great Observatories" along with the Hubble Space Telescope, the Spitzer Space Telescope, and the now deorbited Compton Gamma Ray Observatory. The observatory was designed to detect x-ray emissions from some of the hottest regions of the galaxy including exploded stars, clusters of galaxies, and matter around black holes. One of the observatory's key scientific instruments is the Advanced CCD Imaging Spectrometer (ACIS), which is one of four primary and two focal plane instruments. Due to the sensitivity of the charged coupled devices (CCD's), an aperture door was designed and built by Lockheed-Martin that protected the instrument during testing and the time leading up to launch. The design called for a system of wax actuators (manufactured by STARSYS Corp) to be used as components in a rotary actuator that would open and close the door during ground testing and on-orbit operations. Another feature of the design was an internal shear disc located in each actuator to prevent excessive internal pressure and to shield other components from damage.

Odom, Brian↗

A review of transformative strategies for climate mitigation by grasslands

Grasslands can significantly contribute to climate mitigation. However, recent trends indicate that human activities have switched their net cooling effect to a warming effect due to management intensification and land conversion. This indicates an urgent need for strategies directed to mitigate climate warming while enhancing productivity and efficiency in the use of land and natural (nutrients, water) resources. Here, in this work, we examine the potential of four innovative strategies to slow climate change including: 1) Adaptive multi-paddock grazing that consists of mimicking how ancestral herds roamed the Earth; 2) Agrivoltaics that consists of simultaneously producing food and energy from solar panels on the same land area; 3) Agroforestry with a reverse phenology tree species, Faidherbia (Acacia) albida, that has the unique trait of being photosynthetically active when intercropped herbaceous plants are dormant; and, 4) Enhanced Weathering, a negative emission technology that removes atmospheric CO 2 from the atmosphere. Further, we speculate about potential unknown consequences of these different management strategies and identify gaps in knowledge. We find that all these strategies could promote at least some of the following benefits of grasslands: CO 2 sequestration, non-CO 2 GHG mitigation, productivity, resilience to climate change, and an efficient use of natural resources. However, there are obstacles to be overcome. Mechanistic assessment of the ecological, environmental, and socio-economic consequences of adopting these strategies at large scale are urgently needed to fully assess the potential of grasslands to provide food, energy and environmental security.

54 ENVIRONMENTAL SCIENCES↗

Life cycle analysis of polylactic acids from different wet waste feedstocks

Producing a valuable chemical product through diversion of wet wastes can simultaneously resolve the problems associated with increasing wastes and greenhouse gas emissions from conventional chemical production processes. In this work, we investigated the life-cycle greenhouse gas emissions, water, and fossil-fuel consumption for waste-derived polylactic acids (PLA) from three different waste feedstocks, namely wastewater sludge, food waste, and swine manure, using the Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies (GREET) model. The decarbonization potential of replacing fossil-based resins with the waste-derived polymer was also investigated. The results show that swine manure-to-PLA pathway was the least carbon intensive (—1.4 kgCO 2 e/kg) among the three waste-to-PLA pathways on a cradle-to-grave basis, followed by the food waste case (—1.3 kgCO 2 e/kg) and then by the wastewater sludge case (0.6 kgCO 2 e/kg). In the baseline scenario, all three waste-to-PLA pathways were less carbon intensive than both fossil-based PET and HDPE on a cradle-to-grave basis: 66% (vs. PET) and 56% (vs. HDPE), 171 and 192%, 181 and 205% reduction in GHG emissions for wastewater sludge-, food waste-, and swine manure-to-PLA pathway, respectively. For all sensitivity cases investigated, the food waste- and swine manure-to-PLA pathways were significantly less carbon intensive than their fossil-counterparts. In terms of the annual decarbonization potential of replacing fossil-based PET or HDPE, the wastewater sludge- and food waste-pathway showed higher mitigation potential than the swine manure-pathway: i) 18–28 kilotons CO 2 e-reduction per year for wastewater sludge pathway; ii) 23–26 kTCO 2 e-reduction/yr for food waste pathway; and iii) about 5 kTCO 2 e-reduction/yr for swine manure pathway depending on the type of conventional resin replaced. However, given the abundant availability of the swine manure feedstocks across the United States, the decarbonization potential of swine manure-based pathway can also increase as the plant capacity or the number of plants grow.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantifying air quality co-benefits to industrial decarbonization: the local Air Emissions Tracking Atlas

Many decarbonization technologies have the added co-benefit of reducing short-lived climate pollutants, such as particulate matter (PM), nitrogen oxides (NO x ), and sulfur dioxide (SO 2 ), creating a unique opportunity for identifying strategies that promote both climate change solutions and opportunities for air quality improvement. However, stakeholders and decision-makers may struggle to quantify how these co-benefits will impact public health for the communities most affected by industrial air pollution. To address this problem, the LOCal Air Emissions Tracking Atlas (LOCAETA) fills a data availability and analysis gap by providing estimated air quality benefits from industrial decarbonization options, such as carbon capture and storage (CCS). These co-benefits are calculated using an algorithm that connects disparate datasets that separately report greenhouse gas emissions and other pollutants at U.S. industrial facilities. Version 1.0 of LOCAETA displays the estimated primary PM 2.5 emission reduction co-benefits from additional pretreatment equipment for CCS on industrial and power facilities across the state of Louisiana, as well as the potential for VOC and NH 3 generation. The emission reductions are presented in the tool alongside facility pollutant emissions information and relevant air quality, environmental, demographic, and public health datasets, such as air toxics cancer risk, satellite and in situ pollutant measurements, and population vulnerability metrics. LOCAETA enables regulators, policymakers, environmental justice communities, and industrial and commercial users to compare and contrast quantifiable public health benefits due to air quality impacts from various climate change mitigation strategies using a free and publicly-available tool. Additional pollutant reductions can be calculated using the same methodology and will be available in future versions of the tool.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Quantized electronic transitions in electrodeposited copper indium selenide nanocrystalline homojunctions

Pairing semiconductors with electrochemical processing offers an untapped opportunity to create novel nanostructures for practical devices. Here we report the results of one such pairing: the in-situ formation of highly-doped, interface-matched, sharp nanocrystalline homojunctions (NHJs) with single step electrodeposition of two copper-indium-selenide (CISe) compounds on flexible foil. It produces a homogenous film, comprising inherently ordered, 3-dimensional interconnected network of pn -CISe NHJs. These CISe NHJs exhibit surprising non-linear emissions, quantized transitions, large carrier mobility, low trap-state-density, long carrier lifetime and possible up-conversion. They facilitate efficient separation of minority carriers, reduce recombination and essentially function like quantum materials. This approach mitigates the material issues and complex fabrication of incumbent nanoscale heterojunctions; it also overcomes the flexibility and scale-up challenges of conventional planar pn junctions. The self-stabilized CISe NHJ film can be roll-to-roll processed in ambient atmosphere, thus providing a promising platform for a range of optoelectronic technologies. This concept exemplified by CISe compounds can be adapted to create nano-scale pn junctions with other inorganic semiconductors.

36 MATERIALS SCIENCE↗

Forward modeling fluctuations in the DESI LRGs target sample using image simulations

We use the forward modeling pipeline, Obiwan, to study the imaging systematics of the Luminous Red Galaxies (LRGs) targeted by the Dark Energy Spectroscopic Instrument (DESI). Imaging systematics refers to the false fluctuation of galaxy densities due to varying observing conditions and astrophysical foregrounds corresponding to the imaging surveys from which DESI LRG target galaxies are selected. We update the Obiwan pipeline, which we previously developed to simulate the optical images used to target DESI data, to further simulate WISE images in the infrared. This addition allows simulating the DESI LRGs sample, which utilizes WISE data in the target selection. Deep DESI imaging data combined with a method to account for biases in their shapes is used to define a truth sample of potential LRG targets. We inject these data evenly throughout the DESI Legacy Imaging Survey footprint at declinations between -30 and 32.375 degrees. We simulate a total of 15 million galaxies to obtain a simulated LRG sample (Obiwan LRGs) that predicts the variations in target density due to imaging properties. We find that the simulations predict the trends with depth observed in the data, including how they depend on the intrinsic brightness of the galaxies. We observe that faint LRGs are the main contributing source of the imaging systematics trend induced by depth. We also find significant trends in the data against Galactic extinction that are not predicted by Obiwan. These trends depend strongly on the particular map of Galactic extinction chosen to test against, implying systematic contamination in the Galactic extinction maps is a likely root cause (e.g., Cosmic-Infrared Background, dust temperature correction). We additionally observe a morphological change of the DESI LRGs population evidenced by a correlation between OII emission line average intensity and the size of the z-band PSF. This effect most likely results from uncertainties in background subtraction. The detailed findings we present should be used to guide any observational systematics mitigation treatment for the clustering of the DESI LRGs sample.

79 ASTRONOMY AND ASTROPHYSICS↗

End-Use Savings Shapes Measure Documentation: Window Film

This documentation focuses on a single end-use savings shape measure - window film. The window film studied in this analysis, called solar control film, is a passive retrofit solution for windows that does not involve window replacement. This type of film is composed of transparent, tinted, or metalized laminated polyester layers and can be attached to an existing window surface (either on the exterior or interior side of the window). The properties of the window film are designed to shift the thermal and optical performances of the overall glazing system in order to serve various needs the customer would have (e.g., heat, glare). While the practical goal of purchasing and installing a window film varies widely in the real market, this study only focuses on the goal of energy savings, and highlighting the corresponding emissions. Other important aspects that customers typically consider include visual comfort, privacy, aesthetics, ultraviolet protection, etc. Thus, in practice, customers often choose a window film product not only to save energy (or cost) but also to mitigate issues around glare, excessive light, daytime privacy, or inconsistent appearance of the building. Window film products that were modeled in this analysis significantly reduced the solar heat gain coefficient of the overall glazing system, resulting in better energy savings for buildings in hot climate regions. However, significantly reducing the solar heat gain coefficient that can block unfavorable heat during the summer can actually harm blocking favorable heat during the winter. By applying window films on a stock of buildings covering various load and weather conditions, this analysis highlights when (e.g., time of day) and where (e.g., geospacial location) we can save energy with window films.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Actively Controlled Louver for Human Spacecraft Radiator Ultraviolet (UV), Dust, and Freeze Protection

This paper examines the use of actively controlled louvers to attenuate UV and dust, as well as mitigate freezing concerns for human spacecraft radiators during Artemis missions. Artemis missions to the lunar orbit or surface will expose the radiators to high energy UV radiation and dust, which will degrade the radiator’s coating emissivity and consequently reduce heat rejection performance. In addition, subfreezing environmental temperatures during transit to lunar orbit and nighttime on lunar south pole can rupture coolant tubes, reduce heat rejection performance, and worst-case scenario result in a Loss of Mission (LOM). Louver technology would be a promising solution to maintaining radiator performance and integrity for Artemis missions, but heritage louvers are passively controlled. This technology needs maturing to active control, or motor actuation, to achieve faster thermal response times. Actively controlled louver design considerations are discussed in this paper. The analysis that follows shows actively controlled louvers can attenuate high energy UV radiation and dust, as well as protect the coolant from freezing.

Louver↗

Actively Controlled Louver for Human Spacecraft Radiator Ultraviolet (UV), Dust, and Freeze Protection

This paper examines the use of actively controlled louvers to attenuate UV and dust, as well as mitigate freezing concerns for human spacecraft radiators during Artemis missions. Artemis missions to the lunar orbit or surface will expose the radiators to high energy UV radiation and dust, which will degrade the radiator’s coating emissivity and consequently reduce heat rejection performance. In addition, subfreezing environmental temperatures during transit to lunar orbit and nighttime on lunar south pole can rupture coolant tubes, reduce heat rejection performance, and worst-case scenario result in a Loss of Mission (LOM). Louver technology would be a promising solution to maintaining radiator performance and integrity for Artemis missions, but heritage louvers are passively controlled. This technology needs maturing to active control, or motor actuation, to achieve faster thermal response times. Actively controlled louver design considerations are discussed in this paper. The analysis that follows shows actively controlled louvers can attenuate high energy UV radiation and dust, as well as protect the coolant from freezing.

Louver↗

Acoustic Emission Health Monitoring of Fill Purge COPV's Used in Aerospace and Automotive Applications and Designed for Long Cycle Life

Cumulative composite damage in composite pressure vessels (CPVs) currently is not monitored on-orbit. Consequently, hazards due to catastrophic burst before leak (BBL) or compromised CPV reliability cannot be ascertained or mitigated, posing a risk to crew and mission assurance. The energy associated with CPV rupture can be significant, especially with high pressure gases are under containment, and the energy releases can be severe enough to cause injury, death, loss of assets or mission. Dual-Use Rationale: CPVs similar to those used by NASA on ISS, for example, are finding increasing use in automotive and transportation industry applications. These CPVs generally have a nonload sharing liner and are repeatedly filled over their service lifetime, typically with hydrogen or compressed natural gas (CNG). The same structural health monitoring equipment and software developed by NASA WSTF for evaluating, in real-time, the health of NASA CPVs on ISS will be used to evaluate the health of automotive CPVs, the only differences being the type and design of the CPV, and the in-service lifetime pressure histories. HSF Need(s)/Performance Characteristic(s) Supported: 1) Enable on-board vehicle systems management for mission critical functions at destinations with > 3 second time delay 2) Enable autonomous nominal operations and FDIR for crewed and un-crewed systems 3) Reduce on-board crew time to sustain and manage vehicle by factor of 2x at destinations with > 6 second time delay (see Crew Autonomy sheet) 4) Reduce earth-based mission ops "back room engineering" requirements for distant mission support delay (see Mission Autonomy sheet)

Waller, Jess↗

Thermochromic Halide Perovskite Windows with Ideal Transition Temperatures

Abstract Urban centers across the globe are responsible for a significant fraction of energy consumption and CO 2 emission. As urban centers continue to grow, the popularity of glass as cladding material in urban buildings is an alarming trend. Dynamic windows reduce heating and cooling loads in buildings by passive heating in cold seasons and mitigating solar heat gain in hot seasons. Here, reduced energy consumption in highly glazed buildings in a mesoscopic building energy model is demonstrated when thermochromic windows are employed. Savings are realized across eight disparate climate zones of the United States. The model is used to determine ideal critical transition temperatures of 20–27.5 °C for thermochromic windows based on metal halide perovskite materials. Ideal transition temperatures are realized experimentally in composite metal halide perovskite films composed of perovskite crystals and an adjacent reservoir phase. The transition temperature is controlled by cointercalating methanol, instead of water, with methylammonium iodide and tailoring the hydrogen‐bonding chemistry of the reservoir phase. Thermochromic windows based on metal halide perovskites represent a clear opportunity to mitigate the effects of energy‐hungry buildings.

14 SOLAR ENERGY↗

Economic solution for low carbon process heat: A horizontal, compact high temperature gas reactor

In 2018, nuclear energy generated 55% of United States’ and one third of the world’s carbon free electricity, making nuclear energy a key tool in efforts to mitigate climate change before 2050. However, the current nuclear technology, light water reactors (LWRs), is limited to 300°C, so it cannot be used to decarbonize industrial process heat which accounts for 12% of US greenhouse gas emissions. High temperature gas reactors (HTGRs) can meet the high temperature demand with carbon free nuclear heat. The estimated cost of HTGRs, such as the Next Generation Nuclear Plant (NGNP), are even higher than state-of-the-art LWRs. In this paper, we expanded our nuclear cost estimating tool to include HTGRs and find that the NGNP overnight capital costs were 32% higher than an advanced LWR per unit capacity. The higher cost will naturally result in larger risk to cost overrun as recently experienced by larger LWRs in western nations. With a design-to-build mindset to minimize cost and construction risk, we introduce the horizontal, compact HTGR (HC-HTGR). The reactor core and steam generator are mounted horizontally on rails and in-line with one another, decreasing the size of the reactor building relative to the power capacity four times when compared to traditional HTGRs. The HC-HTGR reduced overnight civil structure costs by 42%, indirect costs by 38%, and total capital costs by 20% from NGNP. We discussed the required engineering of new systems for the HC-HTGR including vessel supports, the reactor cavity cooling system, and steam generator design. Finally, we estimated the fuel and operations costs of the HC-HTGR, and a survey of low-carbon industrial process heat technology showed the HC-HTGR can deliver a highly competitive levelized cost of heat in the range of $6.13–12.48/GJ.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Spurious Correlations between Galaxies and Multiepoch Image Stacks in the DESI Legacy Surveys

A nonnegligible source of systematic bias in cosmological analyses of galaxy surveys is the on-sky modulation that is caused by foregrounds and variable image characteristics, such as observing conditions. Standard mitigation techniques perform a regression between the observed galaxy density field and sky maps of the potential contaminants. Such maps are ad hoc lossy summaries of the heterogeneous sets of coadded exposures that contribute to the survey. We present a methodology for addressing this limitation, and we extract spurious correlations between the observed distributions of galaxies and arbitrary stacks of single-epoch exposures. We study four types of galaxies (luminous red galaxies, emission-line galaxies, quasars, and Lyman-break galaxies) in the three regions of the DESI Legacy Surveys (North, South, and Dark Energy Survey), resulting in 12 samples with varying levels and types of contamination. We find that the new technique outperforms the traditional ones in all cases, and is able to remove higher levels of contamination. This paves the way for new methods that extract more information from multiepoch galaxy survey data and mitigate large-scale biases more effectively.

79 ASTRONOMY AND ASTROPHYSICS↗

Luminescence-Based Diagnostics of Thermal Barrier Coating Health and Performance

Thermal barrier coatings (TBCs) are typically composed of translucent ceramic oxides that provide thermal protection for metallic components exposed to high-temperature environments in both air- and land-based turbine engines. For advanced turbine engines designed for higher temperature operation, a diagnostic capability for the health and performance of TBCs will be essential to indicate when a mitigating action needs to be taken before premature TBC failure threatens engine performance or safety. In particular, it is shown that rare-earth-doped luminescent sublayers can be integrated into the TBC structure to produce luminescence emission that can be monitored to assess TBC erosion and delamination progression, and to map surface and subsurface temperatures as a measure of TBC performance. The design and implementation of these TBCs with integrated luminescent sublayers are presented.

Eldridge, Jeffrey I.↗

​​Updates to Anaerobic Digestion Pathways for Animal Manure in R&D GREET 2025​

Livestock and poultry manure management in the U.S. is a greenhouse gas (GHG) intensive process, emitting 81.7 MMT CO 2 e in 2022 (1.5% of net U.S. GHG emissions). The primary GHG is methane (CH 4 ), with 2,312 kt released in 2022 (9% of U.S. CH 4 emissions). Manure management methods are commonly categorized by whether they are anaerobic (“wet”) or aerobic (“dry”) techniques. Although dry methods manage the largest share of manure, the majority of GHG emissions are generated during storage of manure in anaerobic conditions – typically in water-filled tanks, pits, or lagoons. There has been a 65% increase in emissions from 1990, primarily due to an increasing cattle population. Also, this rise in population has been coupled with a rise in animal confinement and density, which typically adopt wet manure management methods. Within wet methods, anaerobic bacteria proliferate and decompose volatile solids (VS) within the manure in a process called anaerobic digestion to produce roughly equal mixtures of CH 4 and carbon dioxide (CO 2 ). These GHGs are fugitive, in that they are assumed to be released to the atmosphere and contribute to GHGs within U.S. GHG inventories. If the methane is captured and purified (i.e., “upgraded”) this simultaneously mitigates GHGs that would have otherwise been released and produces a valuable energy product known colloquially as Renewable Natural Gas (RNG). Such processes are acknowledged by U.S. policy through programs such as the U.S. Renewable Fuels Standard (RFS), the federal Clean Fuel Production Credit (45Z), and state clean fuel standards (CFS). In the 45Z and CFS schemes, the GHG emissions of the business-as-usual (BAU) manure management system is taken as a baseline, and credits are received based on GHG reductions relative to this baseline. Thus, estimating the GHG emissions of the BAU scenario (also known as the “counterfactual”) is necessary.

09 BIOMASS FUELS↗

Forecasted Climate Penalties to Surface Ozone Across the 21st Century

Future climate change may bring local benefits or penalties to surface ozone pollution, resulting from changing temperature, precipitation, and transport patterns, as well as climate-sensitive natural precursor emissions. Here, we estimate climate penalty and benefits at the end of this century using version 2.0 of the Global Change and Air Pollution (GCAP 2.0) model framework, a one-way offline coupling between version E2.1 of the NASA Goddard Institute for Space Studies (GISS) general circulation model (GCM) and the GEOS-Chem global 3-D chemical-transport model (CTM). We archive meteorology for driving GEOS-Chem from the E2.1 contributions to Phase 6 of the Coupled Model Intercomparison Project (CMIP6) for the present day (2005-2014 C.E.) and end-of-the 21st century (2090-2099 C.E.). Emissions and boundary conditions used for input to GEOS-Chem are consistent with the CMIP6 experimental design. We apply the model to isolate the impact of forecasted anthropogenic precursor emission changes versus climate-only driven changes on surface ozone for warming limited to 1.9 W m-2 versus 8.5 W m-2 above preindustrial levels. We find a global climate penalty of 47 (16-77) thousand additional deaths due to surface ozone at the end of the century in the extreme warming scenario, but only 13 (4-21) thousand additional deaths in the extreme mitigation scenario. Similarly, the extreme warming scenario is associated with a 40 % increase in economic losses due to crop damage from climate-only changes in surface ozone, but only an 8 % increase in the extreme mitigation scenario. The simulated climate penalties to surface ozone are most severe in South and East Asia.

Climate penalties↗