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At least 793 records · Page 44
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NASA NTRS1997

Unsteady Crystal Growth Due to Step-Bunch Cascading

Based on our experimental findings of growth rate fluctuations during the crystallization of the protein lysozym, we have developed a numerical model that combines diffusion in the bulk of a solution with diffusive transport to microscopic growth steps that propagate on a finite crystal facet. Nonlinearities in layer growth kinetics arising from step interaction by bulk and surface diffusion, and from step generation by surface nucleation, are taken into account. On evaluation of the model with properties characteristic for the solute transport, and the generation and propagation of steps in the lysozyme system, growth rate fluctuations of the same magnitude and characteristic time, as in the experiments, are obtained. The fluctuation time scale is large compared to that of step generation. Variations of the governing parameters of the model reveal that both the nonlinearity in step kinetics and mixed transport-kinetics control of the crystallization process are necessary conditions for the fluctuations. On a microscopic scale, the fluctuations are associated with a morphological instability of the vicinal face, in which a step bunch triggers a cascade of new step bunches through the microscopic interfacial supersaturation distribution.

Vekilov, Peter G.↗
NASA NTRS2016

Cooling Rates of Lunar Volcanic Glass Beads

It is widely accepted that the Apollo 15 green and Apollo 17 orange glass beads are of volcanic origin. The diffusion profiles of volatiles in these glass beads are believed to be due to degassing during eruption (Saal et al., 2008). The degree of degassing depends on the initial temperature and cooling rate. Therefore, the estimations of volatiles in parental magmas of lunar pyroclastic deposits depend on melt cooling rates. Furthermore, lunar glass beads may have cooled in volcanic environments on the moon. Therefore, the cooling rates may be used to assess the atmospheric condition in an early moon, when volcanic activities were common. The cooling rates of glasses can be inferred from direct heat capacity measurements on the glasses themselves (Wilding et al., 1995, 1996a,b). This method does not require knowledge of glass cooling environments and has been applied to calculate the cooling rates of natural silicate glasses formed in different terrestrial environments. We have carried out heat capacity measurements on hand-picked lunar glass beads using a Netzsch DSC 404C Pegasus differential scanning calorimeter at University of Munich. Our preliminary results suggest that the cooling rate of Apollo 17 orange glass beads may be ~12 K/min, based on the correlation between temperature of the heat capacity curve peak in the glass transition range and glass cooling rate. The results imply that the parental magmas of lunar pyroclastic deposits may have contained more water initially than the early estimations (Saal et al., 2008), which used higher cooling rates, 60-180 K/min in the modeling. Furthermore, lunar volcanic glass beads could have been cooled in a hot gaseous medium released from volcanic eruptions, not during free flight. Therefore, our results may shed light on atmospheric condition in an early moon.

Hui, Hejiu↗
NASA NTRS1997

Molecular Hydrogen in Diffuse Interstellar Clouds of Arbitrary Three-Dimensional Geometry

We have constructed three-dimensional models for the equilibrium abundance of molecular hydrogen in diffuse interstellar clouds of arbitrary geometry that are illuminated by ultraviolet radiation. The position-dependent photodissociation rate of H2 in such clouds was computed with a 26 ray approximation to model the attenuation of the incident ultraviolet radiation field by dust and by H2 line absorption. We have applied our modeling technique to the isolated diffuse cloud G236+39, assuming that the cloud has a constant density and that the thickness of the cloud along the line of sight is at every point proportional to the 100 micron continuum intensity measured by IRAS. We find that our model can successfully account for observed variations in the ratio of 100 micron continuum intensity to H I column density, with larger values of that ratio occurring along lines of sight in which the molecular hydrogen fraction is expected to be the largest. Using a standard chi square analysis to assess the goodness of fit of our models, we find (at the 60 a level) that a three-dimensional model is more successful in matching the observational data than a one-dimensional model in which the geometrical extent of the cloud along the line of sight is assumed to be much smaller than its extent in the plane of the sky. If D is the distance to G236 + 39, and given standard assumptions about the rate of grain-catalyzed H2 formation, we find that the cloud has an extent along the line of sight that is 0.9 +/- 0.1 times its mean extent projected onto the plane of the sky and a gas density of 53 +/- 8 (100 pc/D) H nuclei/cc and is illuminated by a radiation field of 1.1 +/- 0.2 (100 pc/D) times the mean interstellar radiation field. The derived 100 micron emissivity per nucleon is 1.13 +/- 0.06 x 10(exp -20) MJy/sr sq cm.

Spaans, Marco↗
NASA NTRS1976

Comparison of stratospheric ozone destruction by fluorocarbons 11, 12, 21, and 22

Measured photoabsorption cross sections for fluorocarbons (FC) 11, 12, 21, and 22 are presented for the wavelength region from 1740 A to about 2200 A. Solar radiation in this region dissociates these molecules in the stratosphere releasing atomic chlorine which participates in catalytic reactions that destroy ozone. Photolysis by solar UV is the only known loss mechanism for FC11 and FC12. However, FC21, and FC22 also react with OH in the troposphere reducing the amount of ground level releases which reach the stratosphere. Calculations comparing the steady state stratospheric C1X due to equal release rates of fluorocarbons 11, 12, 21, and 22 are presented using a range of OH profiles and eddy diffusion coefficients. These calculations indicate approximately a factor of 20 to 450 less C1X in the stratosphere for FC21 and a factor of 40 to 130 for FC22, compared to an equal release rate of FC11 and FC12.

Robbins, D. E.↗
NASA NTRS1999

Periodic Excitation for Jet Vectoring and Enhanced Spreading

The effects of periodic excitation on the evolution of a turbulent jet were studied experimentally. A short, wide-angle diffuser was attached to the jet exit and excitation was introduced at the junction between the jet exit and the diffuser inlet. The introduction of high amplitude periodic excitation at the jet exit enhances the mixing and promotes attachment of the jet shear-layer to the diffuser wall. Vectoring is achieved by applying the excitation over a fraction of the circumference of the circular jet, enhancing its spreading rate on the excited side and its tendency to reattach to that side. Static deflection studies demonstrate that the presence of the wide-angle diffuser increases the effectiveness of the added periodic momentum due to a favorable interaction between the excitation, the jet shear-layer and the diffuser wall. This point was further demonstrated by the evolution of a wave packet that was excited in the jet shear-layer. Strong amplification of the wave packet was measured with a diffuser attached to the jet exit. The turbulent jet responds quickly (10-20 msec) to step changes in the level of the excitation input. The response scales with the jet exit velocity and is independent of the Reynolds number. Jet deflection angles were found to be highly sensitive to the relative direction between the excitation and the jet flow and less sensitive to the excitation frequency. The higher jet deflection angles were obtained for a diffuser length of about two diameters and for diffusers with half-angles greater than 15 degrees.

Pack, LaTunia G.↗
NASA NTRS1987

Vertical constituent transport in the mesosphere

Ground-based microwave spectroscopy measurements of mesospheric CO and H2O vertical mixing ratio profiles are used to infer vertical mixing rates in the upper mesosphere. The CO and H2O data consistently imply vertical eddy diffusion coefficients in the 70- to 85-km region of 100,000-200,000 sq cm/s during spring through summer at midlatidues. Although chemical acceleration of vertical transport is substantial for O and O3, below the mesopause, the divergences of their associated fluxes are modest, with at most a factor of 2 effect on the concentrations of O and O3 for measured variability in gravity wave activity. Comparison of Solar Mesosphere Explorer (SME) O3 data with model results reinforces the conclusions of slow vertical mixing in the upper mesosphere as a consequence of the reduced HO(x) catalytic loss of odd oxygen. The changes in chemical rate constants recommended by Rusch and Eckman (1985), in conjunction with slow vertical mixing, yield good agreement with SME O3 data. The slow vertical mixing deduced in this study is consistent with upper limits obtained from studies of the mesospheric heat budget and could be construed as evidence for an advectively controlled mesosphere. A comparison of the vertical eddy diffusion coefficients for momentum stresses, constituent transport, and heat transport suggests that the eddy Prandtl number must be of order 10.

Strobel, Darrell F.↗
NASA NTRS1986

Chemical zoning and homogenization of olivines in ordinary chondrites and implications for thermal histories of chondrules

The extent and degree of homogenization of chemical zoning of olivines in type 3 ordinary chondrites is studied in order to obtain some constraints on cooling histories of chondrites. Based on Mg-Fe and CaO zoning, olivines in type 3 chondrites are classified into four types. A single chondrule usually contains olivines with the same type of zoning. Microporphyritic olivines show all four zoning types. Barred olivines usually show almost homogenized chemical zoning. The cooling rates or burial depths needed to homogenize the chemical zoning are calculated by solving the diffusion equation, using the zoning profiles as an initial condition. Mg-Fe zoning of olivine may be altered during initial cooling, whereas CaO zoning is hardly changed. Barred olivines may be homogenized during initial cooling because their size is relatively small. To simulated microporphyritic olivine chondrules, cooling from just below the liquidus at moderately high rates is preferable to cooling from above the liquidus at low rates. For postaccumulation metamorphism of type 3 chondrites to keep Mg-Fe zoning unaltered, the maximum metamorphic temperature must be less than about 400 C if cooling rates based on Fe-Ni data are assumed. Calculated cooling rates for both Fa and CaO homogenization are consistent with those by Fe-Ni data for type 4 chondrites. A hot ejecta blanket several tens of meters thick on the surface of a parent body is sufficient to homogenize Mg-Fe zoning if the temperature of the blanket is 600-700 C. Burial depths for petrologic types of ordinary chondrites in a parent body heated by Al-26 are broadly consistent with those previously proposed.

Miyamoto, Masamichi↗
NASA NTRS1999

Diffusion Barriers to Increase the Oxidative Life of Overlay Coatings

Currently, most blades and vanes in the hottest section of aero gas turbine engines require some type of coating for oxidation protection. Newly developed single crystal superalloys have the mechanical potential to operate at increasingly higher component temperatures. However, at these elevated temperatures, coating/substrate interdiffusion can shorten the protective life of the coating. Diffusion barriers between overlay coatings and substrates are being examined to extend the protective life of the coating. A previously- developed finite-difference diffusion model has been modified to predict the oxidative life enhancement due to use of a diffusion barrier. The original diffusion model, designated COSIM, simulates Al diffusion in the coating to the growing oxide scale as well as Al diffusion into the substrate. The COSIM model incorporates an oxide growth and spalling model to provide the rate of Al consumption during cyclic oxidation. Coating failure is predicted when the Al concentration at the coating surface drops to a defined critical level. The modified COSIM model predicts the oxidative life of an overlay coating when a diffusion barrier is present eliminating diffusion of Al from the coating into the substrate. Both the original and the modified diffusion models have been used to predict the effectiveness of a diffusion barrier in extending the protective life of a NiCrAl overlay coating undergoing cyclic oxidation at 1100 C.

Nesbitt, James A.↗
NASA NTRS1990

The kinetics of the Au-InP interaction

An analysis of the reaction of Au and Au-In alloys with InP has permitted the identification of the mechanisms occurring during the first two stages of the Au-InP interaction. The first stage of the interaction, during which the Au is converted to a saturated Au (In) solution, is controlled by the vacancy-generation rate at the free surface of the metallization. The activation energy for this process is the activation energy for Au self-diffusion. Evidence is presented for the existence of large localized variations in this value due to surface related effects. At the completion of stage I stage II becomes active and continues until the metallization is converted to Au3In. This process, proceeding via an interstitial interchange mechanism, is many orders of magnitude slower than stage I. The rate-limiting step, with an activation energy of 2.8 eV, is shown to be the diffusion of In from the InP-metal interface. The P atoms that are released when In enters the metallization during stage I leave the system without reacting, whereas in stage II they form a compound (Au2P3) at the InP-metal interface. The presence of the Au2P3 severely retards the stage II interaction rate.

Fatemi, Navid S.↗
NASA NTRS1977

An experimental estimate of the O/+/-O resonant charge transfer cross section, collision frequency, and energy transfer rate

The resonant-charge-transfer cross section dominates the interaction between neutral and ionized atomic oxygen at temperatures greater than several hundred degrees Kelvin. This cross section is of direct importance to F-region studies of ion diffusion, ion thermal balance, and neutral atmospheric winds and pressure gradients, since it determines collision frequencies and energy and momentum transfer rates. However, the uncertainty in this cross section is roughly 25-40%. Incoherent-scatter measurements allow determination of the product of the atomic oxygen concentration multiplied by the cross section. If present-day atmospheric models are accepted as statistically representative of F-region atomic oxygen concentrations experimental (aeronomical) data presented indicate that the resonant-charge-transfer cross section is about 1.3 times greater than the value presently in general use, though in excellent agreement with the only other available (laboratory) experimental value. This revised cross section has obvious implications for thermospheric studies.

Carlson, H. C.↗
NASA NTRS1981

Formation of a conical distribution and intense ion heating in the presence of hydrogen cyclotron waves

In the considered investigation, it is assumed that the field aligned currents are responsible for producing electrostatic harmonic cyclotron waves (EHC). Using a one-dimensional simulation model in which the electron velocity distribution is maintained by a constant injection of the initial distribution, it is shown that, in contrast to earlier initial value simulations, EHC waves grow to a large amplitude, resulting in the formation of an anisotropic ion velocity distribution. Both the heating rate and the anisotropy are in reasonable agreement with the quasi-linear theory, taking into account the cyclotron resonance. The results show that the saturation is due to the combined effects of wave induced diffusion in an electron velocity space and the heating of ions perpendicularly. Both these effects reduce the growth rate.

Okuda, H.↗
NASA NTRS2005

Rate of Iron Transfer Through the Horse Spleen Ferritin Shell Determined by the Rate of Formation of Prussian Blue and Fe-desferrioxamine Within the Ferritin Cavity

Iron (2+ and 3+) is believed to transfer through the three-fold channels in the ferritin shell during iron deposition and release in animal ferritins. However, the rate of iron transit in and out through these channels has not been reported. The recent synthesis of [Fe(CN)(sub 6)](3-), Prussian Blue (PB) and desferrioxamine (DES) all trapped within the horse spleen ferritin (HoSF) interior makes these measurements feasible. We report the rate of Fe(2+) penetrating into the ferritin interior by adding external Fe(2+) to [Fe(CN)(sub 6)](3-) encapsulated in the HoSF interior and measuring the rate of formation of the resulting encapsulated PB. The rate at which Fe(2+) reacts with [Fe(CN)(sub 6)](3-) in the HoSF interior is much slower than the formation of free PB in solution and is proceeded by a lag period. We assume this lag period and the difference in rate represent the transfer of Fe(2+) through the HoSF protein shell. The calculated diffusion coefficient, D approx. 5.8 x 10(exp -20) square meters per second corresponds to the measured lag time of 10-20 s before PB forms within the HoSF interior. The activation energy for Fe(2+) transfer from the outside solution through the protein shell was determined to be 52.9 kJ/mol by conducting the reactions at 10 to approximately 40 C. The reaction of Fe(3+) with encapsulated [Fe(CN)6](4-) also readily forms PB in the HoSF interior, but the rate is faster than the corresponding Fe(2+) reaction. The rate for Fe(3+) transfer through the ferritin shell was confirmed by measuring the rate of the formation of Fe-DES inside HoSF and an activation energy of 58.4 kJ/mol was determined. An attempt was made to determine the rate of iron (2+ and 3+) transit out from the ferritin interior by adding excess bipyridine or DES to PB trapped within the HoSF interior. However, the reactions are slow and occur at almost identical rates for free and HoSF-encapsulated PB, indicating that the transfer of iron from the interior through the protein shell is faster than the rate-limiting step of PB dissociation. The method described in this work presents a novel way of determining the rate of transfer of iron and possibly other small molecules through the ferritin shell.

Zhang, Bo↗
NASA NTRS1975

Cratering and cosmogenic nuclides

A simple probabilistic model was constructed for the average value of a cosmogenic nuclide as a function of depth in a regolith. An arbitrary function was chosen for the size distribution of craters. The resulting integro-differential equation was found to reduce in limiting cases to the marching equation with a characteristic residence time and to the diffusion equation. The regolith diffusion constant is shown to be a simple integral of the cratering rate weighted by geometrical terms. This formal treatment provides a direct and general connection between cosmogenic nuclides and cratering rates and crater population in a simple analytical form. The validity of this model remains to be tested.

Blake, M. L.↗
NASA NTRS1977

The NASA Ames Research Center one- and two-dimensional stratospheric models. Part 1: The one-dimensional model

A one-dimensional model of stratospheric trace constituents is described in detail. Specifically, the numerical solution of the species continuity equations, including a technique for treating the stiff differential equations representing the chemical kinetic terms, and an appropriate method for simulating the diurnal variations of the species concentrations, are discussed. A specialized treatment of atmospheric photodissociation rates is outlined in the text. The choice of a vertical eddy diffusivity profile and its success in predicting the vertical tracer distributions (carbon 14, methane, and nitrous oxide) are also discussed.

Turco, R. P.↗
NASA NTRS1976

Ring current loss mechanisms and composition as inferred from equatorial pitch angle distributions observed during a storm recovery phase

Explorer 45 measurements of pitch angle distributions (PAD's) of ring current ions were examined for evidence of charge exchange or pitch-angle diffusion as loss mechanisms for the ring current during a storm recovery phase. The observed rounding of the PAD's above a minimum parallel energy is seen as resulting from pitch angle diffusion driven by resonant interactions with ion cyclotron waves. Calculations of growth rates using observed ion fluxes and PAD's have shown that ion cyclotron waves can be significantly amplified by the ring current plasma. However, wave growth off the equator must be taken into account in order to understand the time evolution of the observed PAD's. Isotropic distributions at lower energies remain isotropic at L-values between 3 and 4 despite the presence of charge exchange losses. An explanation for this apparent inconsistency may be that ring current is dominated by some ion species other than protons during recovery phase.

Lyons, L. R.↗
NASA NTRS1981

A quantitative study of factors influencing lamellar eutectic morphology during solidification

The factors that influence the shape of the solid-liquid interface of a lamellar binary eutectic alloy are evaluated. Alloys of carbon tetrabromide and hexachloroethane which serve as a transparent analogue of lamellar metallic eutectics are used. The observed interface shapes are analyzed by computer-aided methods. The solid-liquid interfacial free energies of each of the individual phases comprising the eutectic system are measured as a function of composition using a 'grain boundary groove' technique. The solid-liquid interfacial free energy of the two phases are evaluated directly from the eutectic interface. The phase diagram for the system, the heat of fusion as a function of composition, and the density as a function of composition are measured. The shape of the eutectic interface is controlled mainly by the solid-liquid and solid-solid interfacial free energy relationships at the interface and by the temperature gradient present, rather than by interlamellar diffusion in the liquid at the interface, over the range of growth rates studied.

Kaukler, W. F. S.↗
NASA NTRS1983

Design considerations for FET-gated power transistors

An FET-bipolar combinational power transistor configuration (tested up to 300 V, 20 A at 100 kHz) is described. The critical parameters for integrating the chips in hybrid form are examined, and an effort to optimize the overall characteristics of the configuration is discussed. Chip considerations are examined with respect to the voltage and current rating of individual chips, the FET surge capability, the choice of triple diffused transistor or epitaxial transistor for the bipolar element, the current tailing effect, and the implementation of the bipolar transistor and an FET as single chip or separate chips. Package considerations are discussed with respect to package material and geometry, surge current capability of bipolar base terminal bonding, and power losses distribution.

Chen, D. Y.↗
NASA NTRS1985

Effect of simulated hyperemia on the flow field in a mildly atherosclerotic coronary artery casting of man

Changes in an arterial flow field due to mild atherosclerosis were determined using a main coronary artery casting with a maximum obstruction of about 50 percent by area. Local pressure changes were measured using six pressure tap holes along the wall of the casting. The test-fluid was a 33 percent sugar-water solution of approximately the same viscosity as human blood. Flow visualization results were obtained by injecting blue-dye through the pressure tap holes. Measurement of local pressure demonstrated a significant Reynolds number effect. At Reynolds numbers of 80-710, a local pressure rise was observed downstream of the mild atherosclerotic constriction due to momentum changes. The Reynolds number necessary for flow separation in the divergent region of the coronary casting was about 330. The experimental results can be used to obtain a quantitative relation between coronary morphology and the fluid dynamic consequences of mild diffuse disease under conditions of maximum cardiac demand i.e., higher coronary flow rates and Reynolds numbers associated with space and atmospheric flight.

Cho, Y. I.↗