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At least 793 records · Page 44

A transparent Pyrex μ-reactor for combined in situ optical characterization and photocatalytic reactivity measurements

A new Pyrex-based μ-reactor for photocatalytic and optical characterization experiments is presented. The reactor chamber and gas channels are microfabricated in a thin poly-silicon coated Pyrex chip that is sealed with a Pyrex lid by anodic bonding. The device is transparent to light in the UV-vis-near infrared range of wavelengths (photon energies between ∼0.4 and ∼4.1 eV). The absorbance of a photocatalytic film obtained with a light transmission measurement during a photocatalytic reaction is presented as a proof of concept of a photocatalytic reactivity measurement combined with in situ optical characterization. Diffuse reflectance measurements of highly scattering photocatalytic nanopowders in a sealed Pyrex μ-reactor are also possible using an integrating sphere as shown in this work. These experiments prove that a photocatalyst can be characterized with optical techniques after a photocatalytic reaction without removing the material from the reactor. The catalyst deposited in the cylindrical reactor chamber can be illuminated from both top and bottom sides and an example of application of top and bottom illumination is presented.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optical energy storage and reemission based weak localization of light and accompanying random lasing action in disordered Nd{sup 3+} doped (Pb, La)(Zr, Ti)O{sub 3} ceramics

Multi-mode random lasing action and weak localization of light were evidenced and studied in normally transparent but disordered Nd{sup 3+} doped (Pb,La)(Zr,Ti)O{sub 3} ceramics. Noticeable localized zone and multi-photon process were observed under strong pumping power. A tentative phenomenological physical picture was proposed by taking account of diffusive process, photo-induced scattering, and optical energy storage process as dominant factors in elucidating the weak localization of light observed. Both the decreased transmittance (increased reflectivity) of light and the observed long lasting fading-off phenomenon supported the physical picture proposed by us.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Inference of main ion particle transport coefficients with experimentally constrained neutral ionization during edge localized mode recovery on DIII-D

Abstract The plasma and neutral density dynamics after an edge localized mode are investigated and utilized to infer the plasma transport coefficients for the density pedestal. The Lyman-Alpha Measurement Apparatus (LLAMA) diagnostic provides sub-millisecond profile measurements of the ionization and neutral density and shows significant poloidal asymmetries in both. Exploiting the absolute calibration of the LLAMA diagnostic allows quantitative comparison to the electron and main ion density profiles determined by charge-exchange recombination, Thomson scattering and interferometry. Separation of diffusion and convection contributions to the density pedestal transport are investigated through flux gradient methods and time-dependent forward modeling with Bayesian inference by adaptation of the Aurora transport code and IMPRAD framework to main ion particle transport. Both methods suggest time-dependent transport coefficients and are consistent with an inward particle pinch on the order of 1 m s −1 and diffusion coefficient of 0.05 m 2 s −1 in the steep density gradient region of the pedestal. While it is possible to recreate the experimentally observed phenomena with no pinch in the pedestal, low diffusion in the core and high outward convection in the near scrape-off layer are required without an inward pedestal pinch.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A Ly{alpha} GALAXY AT REDSHIFT z = 6.944 IN THE COSMOS FIELD

Ly{alpha} emitting galaxies can be used to study cosmological reionization, because a neutral intergalactic medium (IGM) scatters Ly{alpha} photons into diffuse halos whose surface brightness falls below typical survey detection limits. Here, we present the Ly{alpha} emitting galaxy LAE J095950.99+021219.1, identified at redshift z = 6.944 in the COSMOS field using narrowband imaging and follow-up spectroscopy with the IMACS instrument on the Magellan I Baade telescope. With a single object spectroscopically confirmed so far, our survey remains consistent with a wide range of IGM neutral fraction at z Almost-Equal-To 7, but further observations are planned and will help clarify the situation. Meantime, the object we present here is only the third Ly{alpha}-selected galaxy to be spectroscopically confirmed at z {approx}> 7, and is {approx}2-3 times fainter than the previously confirmed z Almost-Equal-To 7 Ly{alpha} galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Surface slope probabilities from the spectra of weak radar echoes - Application to Mars

A method is described for stabilizing the inversion of the power spectra of comparatively weak radar echoes from Mars. It is noted that such stabilization is necessary for echoes with S/N power-spectral densities of order unity as well as for those with broad spectral distributions. The method is applied to the Martian surface, using two data sets obtained with radars of approximately 12.5-cm wavelength. The resulting slope probabilities are interpreted in terms of diffuse and quasi-specular scatter, and values of rms slope are calculated. The results for a sample of Martian locations clearly indicate extreme variations in the local nature of the surface and yield evidence for an apparent planetwide distribution of roughness that may be due to extreme slopes, surface or subsurface rock populations, or a combination of these.

Lipa, B.↗

Ion and electron velocity distributions within flux transfer events

The detailed nature of the thermal and suprathermal ion and electron distributions within magnetic flux transfer events (FTEs) is examined. Examples of both magnetosheath FTEs and magnetospheric FTEs are discussed. The detailed distributions confirm that FTEs contain a mixture of magnetosheath and magnetospheric plasmas. To lowest order, the distributions are consistent with a simple superposition of the two interpenetrating populations, with no strong interactions between them. To first order, some interesting differences appear, especially in the electron distributions, suggesting that considerable pitch angle scattering and some electron energy diffusion are also occurring. These observations should provide a useful test of analytical and numerical studies of interpenetrating plasmas.

Thomsen, M. F.↗

Cosmic-ray-modified stellar winds. II - A perturbation approach

A perturbation method is developed to describe the modification of a stellar wind flow with termination shock by the Galactic cosmic rays. The perturbation parameter epsilon used in the analysis is the ratio of the galactic cosmic-ray pressure to the thermal gas pressure at a large distance from the star. The positive galactic cosmic-ray pressure gradient serves to brake the outflowing stellar wind gas, particularly just upstream of the termination shock of the wind. A one-fluid polytropic model is used to describe the thermal stellar wind gas, with the coupling between the cosmic rays and the thermal gas being determined by an average hydrodynamical diffusion coefficient kappa describing the scattering of cosmic rays by magnetohydrodynamic waves traveling in the background flow. The analysis takes into account cosmic-ray modifications of the critical point of the wind, the thermal gas entropy constants on both sides of the shock, and the fluid velocity profile.

Ko, C. M.↗

Refractive Index Effects on Radiation in an Absorbing, Emitting, and Scattering Laminated Layer

A simple set of equations is derived for predicting temperature radiative energy flow in a two-region semitransparent laminated layer in the limit of zero heat conduction. The composite is heated on its two sides by unequal amounts of incident radiation. The two layers of the composite have different refractive indices, and each material absorbs, emits, and isotropically scatters radiation. The interfaces are diffuse, and all interface reflections are included. To illustrate the thermal behavior that is readily calculated from the equations, typical results an given for various optical thicknesses and refractive indices of the layers. Internal reflections have a substantial effect on the temperature distribution and radiative heat flow.

Siegel, R.↗

Microgravity foam structure and rheology

Our long-range objective is to establish the fundamental interrelationship between the microscopic structure and dynamics of foams and their macroscopic stability and rheology. Foam structure and dynamics are to be measured directly and noninvasively through the use and development of novel multiple light scattering techniques such as diffusing-wave spectroscopy (DWS). Foam rheology is to be measured in a custom rheometer which allows simultaneous optical access for multiple light drainage of liquid from in between gas bubbles as the liquid:gas volume fraction in increased towards the rigidity-loss transition.

Durian, Douglas J.↗

Microgravity Foam Structure and Rheology

To exploit rheological and multiple-light scattering techniques, and ultimately microgravity conditions, in order to quantify and elucidate the unusual elastic character of foams in terms of their underlying microscopic structure and dynamics. Special interest is in determining how this elastic character vanishes, i.e. how the foam melts into a simple viscous liquid, as a function of both increasing liquid content and shear strain rate. The unusual elastic character of foams will be quantified macroscopically by measurement of the shear stress as a function of static shear strain, shear strain rate, and time following a step strain; such data will be analyzed in terms of a yield stress, a static shear modulus, and dynamical time scales. Microscopic information about bubble packing and rearrangement dynamics, from which these macroscopic non-Newtonian properties presumably arise, will be obtained non-invasively by novel multiple-light scattering diagnostics such as Diffusing-Wave Spectroscopy (DWS). Quantitative trends with materials parameters, such as average bubble size, and liquid content, will be sought in order to elucidate the fundamental connection between the microscopic structure and dynamics and the macroscopic rheology.

Durian, Douglas J.↗

Some Basic Concepts of Wave-Particle Interactions in Collisionless Plasmas

The physical concepts of wave-particle interactions in a collisionless plasma are developed from first principles. Using the Lorentz force, starting with the concepts of gyromotion, particle mirroring and the loss-cone, normal and anomalous cyclotron resonant interactions, pitch-angle scattering, and cross-field diffusion are developed.

wave-particle interactions Plasmas↗

Assessment of Mechanisms for Jovian Synchrotron Variability Associated with Comet SL-9

The impact comet SL-9 with Jupiter induced a number of variations in Jupiter's synchrotron radiation, including an increase in emission intensity, spectral changes, and a possible broadening in the latitudinal distribution of the emission. Considered are three potential mechanisms for inducing such effects (electron acceleration, radial diffusion, and pitch-angle scattering), and their consequences.

Jupiter Jovian synchrotron variability synchrotron↗

Geology of the Lachesis Tessera Quadrangle (V-18), Venus

The Lachesis Tessera Quadrangle (V-18) lies between 25deg and 50deg north, 300deg and 330deg east. Most of the quadrangle consists of "regional plains" (1) of Sedna and Guinevere Planitiae. A first draft of the geology has been completed, and the tentative number of mapped units by terrain type is: Tesserae - 2; plains - 4; ridge belts - 1; fracture belts - 1 (plus embayed fragments of possible additional belts); coronae - 3; central volcanoes - 1; shield flows - 2; paterae - 1; impact craters - 1; undifferentiated flows - 1; bright materials - 1. By far the areally most extensive materials are regional plains. These are mapped as two units, based on radar backscatter ("radar brightness"). The brighter unit appears to be younger than the darker unit. This inference is based on the common presence within the lighter unit of circular or nearly circular inliers of material with radar backscatter characteristic of the darker unit. The circular inliers are most likely low shield volcanoes, which are commonly present on the darker unit, that were only partially covered by the brighter unit. Clear cut examples of wrinkle ridges and fractures superposed on the darker unit but truncated by the brighter unit have not been found to date. These relationships indicate that the brighter unit is superposed on the darker unit, but that the difference in age between them is very small. Because they are so widespread, the regional plains are a convenient relative age time "marker." The number of impact craters superposed on these plains is too small to measure age differences (2), and thus we cannot estimate how much time elapsed between the emplacement of the darker and brighter regional plains units. More local plains units are defined by significantly lower radar backscatter or by a texture that is mottled at scores to hundreds of kilometers scale. A plains-like unit with a homogenous, bright diffuse backscatter is present as scattered exposures in the eastern part of the quadrangle. These exposures have been mapped as "bright material," but it is not clear at present if this is a valid unit or if it is part of the brighter regional plains unit. Tessera terrain is primarily found along the western border of the quadrangle, where Lachesis Tessera refers to the southern exposures, and Zirka Tessera refers to northern exposures. A second tessera unit has been mapped with the symbol "t?." This unit appears to be deformed by the requisite 2 sets of closely spaced structures, but it is so extensively flooded by regional plains materials that the structural fabric is partially obscured. Tessera terrain is present in the adjacent V-17 quadrangle, where both Lachesis Tessera and Zirka Tessera are areally more extensive than in V-18. Ridge and fracture belts are both present, but not as extensive as is the case in, for example, the Pandrosos Dorsa (3) and Lavinia Planitia (4) quadrangles. As is commonly the case, it is difficult to determine if the materials of these belts are older or younger than regional plains. A recent study using radar properties (5) demonstrated that at least most ridge belts appear to be older than regional plains. The materials of fracture belts probably are also older than regional plains, but the fractures themselves can be both older and younger than regional plains (e.g., 3).

McGill, George E.↗

Direct Correlation of the Salt-Reduced Diffusivities of Organic Solvents with the Solvent’s Mole Fraction

We report that lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in organic solvents (especially propylene carbonate) has demonstrated extraordinary pseudocapacitive performance as an electrolyte in the supercapacitor configuration. However, the influence of the solvated ions on the diffusivity of the solvent molecules is yet to be understood. We examine the impact of LiTFSI on the diffusivity in five organic solvents: acetonitrile (ACN), tetrahydrofuran (THF), methanol (MeOH), dimethyl sulfoxide (DMSO), and propylene carbonate (PC) using a combination of neutron scattering, conductivity measurements, and molecular dynamics simulations. The extent of the diffusivity reduction in the concentration regime of ≤1 M directly correlates with the solvent mole fraction at which the solvation shells around Li + ions are of similar size in all the solvents, resulting in a universal ~50% reduction in the solvent diffusivity. These results provide guidance for formulation of the new electrolytes to enhance the performance of energy storage devices.

conductivity↗

A Hydrodynamic Theory for Spatially Inhomogeneous Semiconductor Lasers: Microscopic Approach

Starting from the microscopic semiconductor Bloch equations (SBEs) including the Boltzmann transport terms in the distribution function equations for electrons and holes, we derived a closed set of diffusion equations for carrier densities and temperatures with self-consistent coupling to Maxwell's equation and to an effective optical polarization equation. The coherent many-body effects are included within the screened Hartree-Fock approximation, while scatterings are treated within the second Born approximation including both the in- and out-scatterings. Microscopic expressions for electron-hole (e-h) and carrier-LO (c-LO) phonon scatterings are directly used to derive the momentum and energy relaxation rates. These rates expressed as functions of temperatures and densities lead to microscopic expressions for self- and mutual-diffusion coefficients in the coupled density-temperature diffusion equations. Approximations for reducing the general two-component description of the electron-hole plasma (EHP) to a single-component one are discussed. In particular, we show that a special single-component reduction is possible when e-h scattering dominates over c-LO phonon scattering. The ambipolar diffusion approximation is also discussed and we show that the ambipolar diffusion coefficients are independent of e-h scattering, even though the diffusion coefficients of individual components depend sensitively on the e-h scattering rates. Our discussions lead to new perspectives into the roles played in the single-component reduction by the electron-hole correlation in momentum space induced by scatterings and the electron-hole correlation in real space via internal static electrical field. Finally, the theory is completed by coupling the diffusion equations to the lattice temperature equation and to the effective optical polarization which in turn couples to the laser field.

Li, Jianzhong↗