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All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

An Interim Set of TNT Curves for LOX/LNG Explosions

Space launch companies are actively developing, or in some cases have already developed, new vehicles that use large quantities of liquid oxygen (LOX) and liquid natural gas (LNG) propellants. This propellant mixture currently lacks sound/verified LOX/LNG explosive safety standards for use in explosive siting and flight safety analysis. In the U.S., multiple government and commercial organizations have conducted limited testing, or are preparing to conduct tests, intended to provide a sound technical basis for explosive standards applicable to space launch vehicle ground and flight operations. The limited testing and analysis conducted so far indicates the potential to produce extremely energetic explosions due to the miscibility of LOX/LNG (methane), a unique feature relative to previously used propellant mixtures such as hydrogen/oxygen or kerosene/oxygen. MOX is a homogenous mixture of methane and oxygen that is possible because of methane’s 100% miscibility in LOX. Preliminary testing by N2L, Inc. described in this paper shows that it is possible to form MOX with a variety of mixing methods, and that MOX is a sensitive high explosive capable of producing overpressures greater than comparable masses of C-4. The limited amount and quality of large-scale LOX/LNG explosive test data, and the potential formation of high-explosive MOX, create significant unknowns in the determination of hazard areas (cleared of the public) for ground operations (such as a static fire test) and flights of launch vehicles with LOX/LNG propellant. This paper will review the methods used by NASA to develop and validate the LOX/LH2 blast model using large-scale explosive test programs such as Project PYRO, the Hydrogen-Oxygen Vertical Impact (HOVI), and the Large-Scale Hydrogen-Oxygen Explosion (LSHOE) tests. This paper will describe how the same process was used to prepare an interim LOX/LNG blast model that applies to various LV failure scenarios and conservatively accounts for potential MOX formation. This paper also summarizes past and future testing and modeling efforts funded by a consortium of NASA, the US Federal Aviation Administration (FAA), and the US Space Force (USSF). These test programs should be concluded within the next 3 years and are intended to provide empirical data for model verification and validation.

Liquid Oxygen↗
DOE OSTI2017

Improvements to PHISICS/RELAP5-3D{sup C} Capabilities for Simulating HTGRs

Accurate, high-resolution full core simulations of prismatic high temperature reactors for burnup and transient analysis remain a challenge. The cores are geometrically large, but some features are quite small (tri-structural isotropic (TRISO) particles, burnable poison pellets). The treatment of both neutron scattering in graphite and resonance capture are complex and not adequately captured using the methods traditionally used in High Temperature Gas-cooled Reactors (HTGR) and commonly used in Light Water Reactors (LWR). For transient analysis, temperature feedback is a function of the TRISO fuel form, but full core models cannot resolve phenomena at this scale without averaging over space and energy. For burnup calculations, a second level of heterogeneity must be resolved to capture the local effects of fuel and burnable poisons, while accurately propagating their effects through and between blocks. The HTGR Methods and Simulation group has been utilizing the INL-developed PHISICS/RELAP5-3D{sup C} (P/R), code suite for participation in the Organization for Economic Cooperation and Development (OECD) Modular High Temperature Gas Cooled Reactor (MHTGR) Benchmark, funded by the US Department of Energy (DOE) under the Advanced Reactor Technologies (ART) program. The MHTGR-350 benchmark consists of several lattice, steady-state and transient exercises, and the P/R code has been successfully applied to most of the cases defined. In addition to this code-to-code verification activity, it is planned that P/R will be validated using data from several Loss of Forced Cooling (LOFC) tests performed at the High Temperature Test Reactor (HTTR) in a joint effort with Japan Atomic Energy Agency (JAEA) under the Civil Nuclear Energy Working Group (CNWG) project. These verification and validation simulations will identify code and model discrepancies, sensitivities, and establish the current state-of-the-art in HTGR simulation. The Department of Astronautical, Electrical and Energy Engineering (DIAEE), 'Sapienza' University has been involved in the development of P/R since 2014 through various graduate and PhD student projects. In the framework of this collaboration the P/R optimization for application on the OECD MHTGR-350 and HTTR models will be carried out.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2020

Fabrication of field-effect transistors with transfer-free nanostructured carbon as semiconducting channel material

Carbon nanostructures as active channel material in field effect transistors (FETs) are appealing in microelectronics for their improved performance such as high speed and low energy dissipation. However, these devices require the incorporation of nanostructure transfer steps in the fabrication process flow, which makes difficult its application in large scale integration circuits. Here we present a novel method for the fabrication of FETs with nanostructured carbon in the channel with p-type semiconducting properties and intermediate drain-source current (IDS) on/off ratio. The method is based on the use of Ni nanoparticles in the source-drain gap region as seed material for the formation of carbon nanostructures in the FET channel. FETs without Ni nanoparticles in the channel showed no modulation of IDS as a function of gate voltage. The device fabrication process does not require any carbon nanostructure transfer steps since it directly forms carbon nanostructures electrically connected to the device's source and drain electrodes via electron-beam evaporation of carbon and conventional lithographic processes. Since all device fabrication steps are compatible with Si technology processes, they are capable of being further optimized following process development protocols practiced by the semiconductor industry.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2019

An Investigation of Hydrometeor Latent Cooling upon Convective Cold Pool Formation, Sustainment, and Properties

Downdrafts extending from convective clouds can produce cold pools that propagate outward, sometimes initiating new convection along their leading edges. Models operating at scales requiring convective parameterizations usually lack representation of this detail, and thus fail to predict this convective regeneration and longer episodes of convective activity. Developing such parameterizations requires an improved understanding of the physical drivers of cold pools, and detailed studies of the roles of all the contributing microphysical processes have been lacking. This study utilizes a set of 12 simulations conducted within a single convective environment, but with variability in the microphysical fields produced by varying parameters influencing warm-rain or ice processes. Time-integrated microphysical budgets quantify the contribution of each hydrometeor type to the total latent cooling occurring in the downdrafts that form and sustain the cold pool. The timing of the onset of the cold pool is earlier in cases with a stronger warm rain process, but both graupel and rain were equally as likely to be the dominant hydrometeor in the downdraft first forming the cold pool. Graupel sublimation is the dominant term in sustaining the cold pool in all simulations, but the evaporation of rain has the strongest correlation to the cold pool expansion rate, depth, and intensity. Reconciling the current results with past studies elucidates the importance of considering: graupel sublimation, the latent cooling only in downdrafts contributing to the cold pool, and latent cooling in those downdrafts at altitudes that may be significantly higher than the melting level.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Optimizing and Quantifying CO 2 Storage Resource in Saline Formations and Hydrocarbon Reservoirs

In an effort to reduce carbon dioxide (CO 2 ) emissions from large stationary sources, carbon capture and storage (CCS) is being investigated as one approach. This work assesses CO 2 storage resource estimation methods for deep saline formations (DSFs) and hydrocarbon reservoirs undergoing CO 2 enhanced oil recovery (EOR). Project activities were conducted using geologic modeling and simulation to investigate CO 2 storage efficiency. CO 2 storage rates and efficiencies in DSFs classified by interpreted depositional environment were evaluated at the regional scale over a 100-year time frame. A focus was placed on developing results applicable to future widespread commercial-scale CO 2 storage operations in which an array of injection wells may be used to optimize storage in saline formations. The results of this work suggest future investigations of prospective storage resource in closed or semiclosed formations need not have a detailed understanding of the depositional environment of the reservoir to generate meaningful estimates. However, the results of this work also illustrate the relative importance of depositional environment, formation depth, structural geometry, and boundary conditions on the rate of CO 2 storage in these types of systems. CO 2 EOR occupies an important place in the realm of geologic storage of CO 2 , as it is likely to be the primary means of geologic CO 2 storage during the early stages of commercial implementation, given the lack of a national policy and the viability of the current business case. This work estimates CO 2 storage efficiency factors using a unique industry database of CO 2 EOR sites and 18 different reservoir simulation models capturing fluvial clastic and shallow shelf carbonate depositional environments for reservoir depths of 1219 and 2438 meters (4000 and 8000 feet) and 7.6-, 20-, and 64-meter (25-, 66,- and 209-foot) pay zones. The results of this work provide practical information that can be used to quantify CO 2 storage resource estimates in oil reservoirs during CO 2 EOR operations (as opposed to storage following depletion) and the uncertainty associated with those estimates.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Queued Up: Characteristics of Power Plants Seeking Transmission Interconnection As of the End of 2020

Proposed large-scale electric generation and storage projects must apply for interconnection to the bulk power system via interconnection queues. While many projects that apply for interconnection are not subsequently built, data from these queues nonetheless provide a general indicator for mid-term trends in developer interest. Berkeley Lab compiled and analyzed data from all seven ISOs/RTOs in concert with 35 non-ISO utilities, representing an estimated 85% of all U.S. electricity load. We include all "active" projects in these generation interconnection queues through the end of 2020, as well as data on "completed" and "withdrawn" projects for five of the ISOs (CAISO, ISO-NE, MISO, NYISO, PJM). We find that the total capacity active in the queues is growing year-over-year, with over 750 GW of generation and an estimated 200 GW of storage capacity as of the end of 2020. Solar (462 GW) accounts for a large – and growing – share of generator capacity in the queues. Substantial wind (209 GW) capacity is also in development, 29% of which is for offshore projects (61 GW). In total, about 680 GW of zero-carbon capacity is currently seeking transmission access, as is 74 GW of natural gas capacity. Hybrids now comprise a large – and increasing – share of proposed projects, particularly in CAISO and the non-ISO West. 159 GW of solar hybrids (primarily solar+battery) and 13 GW of wind hybrids are currently active in the queues. However, much of this proposed capacity will not ultimately be built. Among a subset of queues for which data are available, only 24% of the projects seeking connection from 2000 to 2015 have subsequently been built. Completion percentages appear to be declining, and are even lower for wind and solar than other resources. Additionally, wait times are on the rise: in four ISOs, the typical duration from connection request to commercial operation increased from ~1.9 years for projects built in 2000-2009 to ~3.5 years for those built in 2010-2020. There are growing calls for queue reform to reduce cost, lead times, and speculation.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Pool-Based Tow System for Testing Tethered Hydrokinetic Devices Being Developed to Harvest Energy From Ocean Currents

Abstract The immense potential for ocean current energy harvesting is being actively explored as the push for renewable energy becomes more urgent. This paper demonstrates a tow testing platform built to examine and validate mathematical models related to the performance of tethered, underwater, hydrokinetic devices in development to harvest energy from ocean currents, and presents experimental results illustrating how such a system can be used. The platform has been modularly designed to allow for the testing of various tethered, underwater energy-generation systems, including kite-based systems, coaxial turbines, and duct sails. Previous research on tethered energy-generating systems has primarily been focused on airborne systems. Additionally, the limited experimental research on tethered, underwater energy-generation systems has relied on a rigid rod for mechanical and electrical connections between the test articles and instrumentation. The tow testing platform presented in this paper accomplishes the mechanical and electrical connection through a dual-function tether, featuring internal conductors and an external sheath to support towing loads. The goal of this platform was to enable the emulation of ocean currents, which are largely unidirectional, and to retrofit a regular pool into a cost-effective, adaptable, small-scale tow tank test bed. The capabilities of the system include two-way communication with tethered devices, multiple towing profiles in order to emulate different flow regimes, real-time control, and differential velocities via dual winch operation.

Engineering↗
NASA NTRS2019

Next-Generation Optical Sensing Technologies for Exploring Ocean Worlds - NASA FluidCam, MiDAR, and NeMO-Net

We highlight three emerging NASA optical technologies that enhance our ability to remotely sense, analyze, and explore ocean worlds–FluidCam and fluid lensing, MiDAR, and NeMO-Net. Fluid lensing is the first remote sensing technology capable of imaging through ocean waves without distortions in 3D at sub-cm resolutions. Fluid lensing and the purpose-built FluidCam CubeSat instruments have been used to provide refraction-corrected 3D multispectral imagery of shallow marine systems from unmanned aerial vehicles (UAVs). Results from repeat 2013 and 2016 airborne fluid lensing campaigns over coral reefs in American Samoa present a promising new tool for monitoring fine-scale ecological dynamics in shallow aquatic systems tens of square kilometers in area. MiDAR is a recently-patented active multispectral remote sensing and optical communications instrument which evolved from FluidCam. MiDAR is being tested on UAVs and autonomous underwater vehicles (AUVs) to remotely sense living and non-living structures in light-limited and analog planetary science environments. MiDAR illuminates targets with high-intensity narrowband structured optical radiation to measure an object’s spectral reflectance while simultaneously transmitting data. MiDAR is capable of remotely sensing reflectance at fine spatial and temporal scales, with a signal-to-noise ratio 10-10(exp 3) times higher than passive airborne and spaceborne remote sensing systems, enabling high-framerate multispectral sensing across the ultraviolet, visible, and near-infrared spectrum. Preliminary results from a 2018 mission to Guam show encouraging applications of MiDAR to imaging coral from airborne and underwater platforms whilst transmitting data across the air-water interface. Finally, we share NeMO-Net, the Neural Multi-Modal Observation & Training Network for Global Coral Reef Assessment. NeMO-Net is a machine learning technology under development that exploits high-resolution data from FluidCam and MiDAR for augmentation of low-resolution airborne and satellite remote sensing. NeMO-Net is intended to harmonize the growing diversity of 2D and 3D remote sensing with in situ data into a single open-source platform for assessing shallow marine ecosystems globally using active learning for citizen-science based training. Preliminary results from four-class Q17 coral classification have an accuracy of 94.4%. Together, these maturing technologies present promising scalable, practical, and cost-efficient innovations that address current observational and technological challenges in optical sensing of marine systems.

Ved Chirayath↗
NASA NTRSDate not supplied

Openet: Applications of Satellite-Based Evapotranspiration Data for Water Resources Management in the Western United States

Advancing water security in overallocated river basins globally requires consistent and reproducible information on consumptive use of water that can anchor the development of data-driven solutions to the challenge of balancing water supply and demand. OpenET is a fully automated system for field-scale (30 m), satellite-based mapping of evapotranspiration (ET) at daily, monthly and annual timesteps. OpenET currently provides spatially contiguous data throughout the 23 westernmost states in the continental US, and includes both current information as well as multi-year timeseries of ET. The OpenET consortium has implemented an ensemble of satellite-based ET models (ALEXI/DisALEXI, eeMETRIC, PT-JPL, geeSEBAL, SIMS and SSEBop) on Google Earth Engine, which provides a shared computing platform for collaboration on processing of data from Landsat and other satellites, land cover and meteorological inputs, leading to increased consistency and accuracy across the ensemble of models. Earth Engine also facilitates hosting and distribution of data via open data collections and an application programming interface. We provide updates on the OpenET framework, open data services and data access tools, approach to geographic expansion, recent accuracy assessments, and describe how a user-driven design approach has facilitated successful applications of OpenET data for a wide range of water resource management activities. Applications to date include: use of ET data to improve quantification of ET and consumptive use in Oregon, Utah and the Upper Colorado River Basin; streamlining of water use reporting requirements in the California Delta; support for calculation of water budgets for the implementation of the Sustainable Groundwater Management Act in California; and integration into decision support tools for irrigation management. The use cases demonstrate how satellite-derived ET data that are easily accessed and seen as broadly accepted can accelerate adoption of innovative water management practices at scale, and support advances in the sustainability of water supplies. Uptake and use of data by the OpenET science community has also led to advances in our understanding of the impacts of landcover change, irrigation intensification and wildfire events on hydrology and the water security.

Applications↗
DOE OSTI2019

Development of low-cost sodium-aqueous polysulfide hybrid batteries

There has been increasing interest in sodium-sulfur (Na-S) batteries as an option for low-cost grid-scale energy storage. Yet, traditional Na-S batteries operate at high temperatures, raising concerns about long-term maintenance costs and safety. On the other hand, room-temperature Na-S batteries have their own limitations, including Na dendrite formation, polysulfide shuttling, and low utilization of active material. To overcome these issues, we introduce here a novel low-cost room-temperature sodium-aqueous polysulfide (Na-APS) hybrid battery system with a Na-metal anode, Na+-ion solid electrolyte separator, and an aqueous polysulfide catholyte. The solid electrolyte blocks Na dendrites and polysulfide shuttling while simultaneously protecting the reactive Na metal anode from the aqueous catholyte. The redox kinetics of the APS catholyte is improved with a rational development of a freestanding CuS-CNT catalytic electrode. The improvements with the Na-APS hybrid battery compared to the traditional Na-S battery systems are discussed. The Na-APS hybrid battery displays excellent performance under a 418 mA h g -1 of sulfur capacity-restricted cycling. The battery achieves an energy efficiency of 90% over 100 cycles at 0.5 mA cm -2 current density.

25 ENERGY STORAGE↗
NASA NTRS2010

Investing American Recovery and Reinvestment Act Funds to Advance Capability, Reliability, and Performance in NASA Wind Tunnels

The National Aeronautics and Space Administration's (NASA) Aeronautics Test Program (ATP) is implementing five significant ground-based test facility projects across the nation with funding provided by the American Recovery and Reinvestment Act (ARRA). The projects were selected as the best candidates within the constraints of the ARRA and the strategic plan of ATP. They are a combination of much-needed large scale maintenance, reliability, and system upgrades plus creating new test beds for upcoming research programs. The projects are: 1.) Re-activation of a large compressor to provide a second source for compressed air and vacuum to the Unitary Plan Wind Tunnel at the Ames Research Center (ARC) 2.) Addition of high-altitude ice crystal generation at the Glenn Research Center Propulsion Systems Laboratory Test Cell 3, 3.) New refrigeration system and tunnel heat exchanger for the Icing Research Tunnel at the Glenn Research Center, 4.) Technical viability improvements for the National Transonic Facility at the Langley Research Center, and 5.) Modifications to conduct Environmentally Responsible Aviation and Rotorcraft research at the 14 x 22 Subsonic Tunnel at Langley Research Center. The selection rationale, problem statement, and technical solution summary for each project is given here. The benefits and challenges of the ARRA funded projects are discussed. Indirectly, this opportunity provides the advantages of developing experience in NASA's workforce in large projects and maintaining corporate knowledge in that very unique capability. It is envisioned that improved facilities will attract a larger user base and capabilities that are needed for current and future research efforts will offer revenue growth and future operations stability. Several of the chosen projects will maximize wind tunnel reliability and maintainability by using newer, proven technologies in place of older and obsolete equipment and processes. The projects will meet NASA's goal of integrating more efficient, environmentally safer, and less energy consuming hardware and processes into existing tunnel systems. These include Environmental Protection Agency-approved refrigerants, energy efficient motors, and faster, flexible tunnel data systems.

Sydnor, Goerge H.↗
DOE OSTI2019

CRAGE enables rapid activation of biosynthetic gene clusters in undomesticated bacteria

Advances in the prediction of biosynthetic gene clusters (BGCs) from genomic and metagenomic data have made the large-scale identification of candidate secondary metabolite biosynthesis pathways routine. However, most predicted BGCs cannot be successfully expressed in the limited range of expression hosts currently available, which prevents the identification and characterization of their respective products. Here we show that parallelized use of a phylogenetically and physiologically diverse panel of purpose-engineered chassis strains offers a versatile strategy for the rapid activation of BGCs. We domesticated an ensemble of 25 diverse ?-proteobacteria from 11 different genera by integrating a unified landing pad that enables efficient introduction of large BGCs into their genome. We deployed this chassis-independent recombinase-assisted genome engineering (CRAGE) strategy to express several previously posited but experimentally elusive non-ribosomal peptide synthase (NRPS) and NRPSpolyketide synthase (PKS) hybrid BGCs from Photorhabdus luminescens. Successful activation of 6 BGCs identified 21 products, including several with likely roles in host-microbe interactions. Taken together, we illustrate how the regulatory and physiological diversity naturally present across bacteria can be harnessed for the exploration of novel bioproducts and provide a sizable panel of domesticated chassis strains to enable this strategy.

applied microbiology, genetic engineering, industr↗
DOE OSTI2017

First Look Fund - An Early-Stage Aligned Intermediary to Enhance the Flow of Private Capital into Energy Companies (Final Technical Report)

The technologies required to advance society into a cleaner, better future will come from a broad range of scientific disciplines including materials science, chemistry, physics, and biology. The innovations will rely on scientific breakthroughs rather than software innovation and can be referred to as “hardtech.” These new technology developments will have vast implications across most industrial sectors: energy, materials, manufacturing, electronics, life sciences, etc. The majority of these scientific breakthroughs will be produced and developed by startup companies, which are best suited for high-risk, early-stage development work. However, a large funding gap exists between lab-scale scientific research of the startup world and industrial-scale commercialization. Activate Global, Inc (Activate), a 501(c)3 nonprofit, fills one part of this gap with the Activate Fellowship program1.To fully bridge the gap between lab and market, additional and aligned capital sources are needed. Through this project, Activate’s goals were: Research the recent history (2005-2015) of hardtech investing to discover the driving forces behind positive and negative outcomes from the viewpoint of investors.; Create a database of “technology pathways” categorized by specific technology areas and showing what technology milestones would be needed to be attractive to a partner or acquirer and what resources were available to achieve those goals.; Build a financial model supported by the data acquired that would show attractive returns were possible in early-stage hardtech investing.; Create an investment thesis around the financial model to show how attractive returns could be achieved in an early-stage hardtech-focused fund.; Publish a paper with a qualitative comparative analysis to help investors better understand driving factors of outcomes.; Share these findings with asset managers not currently investing in early-stage hardtech to attract partners to execute the investment strategy.; Implement the investment strategy and begin investing in early-stage hardtech companies through a new vehicle: First Look Fund. Through this research, Activate created a database of nearly 200 hardtech companies that exited via an M&A transaction between 2005 and 2015. Much of the data Activate obtained was nonpublic information and therefore, the database was anonymized. Activate also created the technology pathways database to help new early-stage hardtech companies define milestones, technology objectives and potential resources. Activate created a financial model with a legal structure showing that market-rate returns were possible, created an investment thesis around that model, and then shared these findings with potential partners. Finally, Activate’s research was used to publish a paper with Stanford on driving factors behind financial outcomes that will help investors better guide their portfolios. While Activate was not able to launch the First Look Fund during the project timeline, mostly due to the fallout from COVID-19 (global economic shocks decreasing interest in first time funds, inability to meet potential investors in person), the research has created enough interest for Activate to continue pursuing the goals of the project, showing the potential feasibility of the endeavor. Regardless of Activate’s ability to execute on the investment strategy, the resulting research has been downloaded, viewed, and referenced by investors and becomes another tool to encourage investment in the early-stage hardtech space.

14 SOLAR ENERGY↗
DOE OSTI2020

Powering the Blue Economy: Progress Exploring Marine Renewable Energy Integration With Ocean Observations

The blue economy is a dynamic and rapidly growing movement that captures the interplay between economic, social, and ecological sustainability of the ocean and encompasses numerous maritime sectors and activities (e.g., commerce and trade; living resources; renewable energy; minerals, materials, and freshwater; and ocean health and data). The demand for ocean data to inform scientific, risk reduction, and national security needs is leading to a large increase in the number of deployed ocean observation and monitoring systems, most of which require increased power. Because ocean observation systems are often placed in remote locations, they primarily rely on energy storage (or in some cases in situ energy generation) to power instruments and equipment, which imposes limits on sampling rates, deployment times, and spatiotemporal resolution of data. The U.S. Department of Energy Water Power Technologies Office is exploring the potential for marine renewable energy (MRE) devices (largely wave and tidal energy converters) to provide power to support multiple blue economy opportunities. A portion of these opportunities focus on power at sea markets for providing power in off-grid and offshore locations to support a variety of ocean-based activities, including ocean observation and navigation, underwater vehicle charging, marine aquaculture, marine algae farming, and seawater mining. Initially, research has focused on better understanding how and where MRE can provide a consistent source of reliable power to extend ocean observing missions, including operation of autonomous underwater vehicles. Online surveys as well as phone and inperson interviews were conducted with experts in the field of ocean observing systems and observatories to gather end-user requirements, determine energy needs, identify opportunities for codevelopment, and pinpoint constraints for MRE to meet those needs. The surveys and interviews provided feedback on the potential for powering devices and vehicles using MRE, including identifying common themes and challenges that will inform foundational research and development steps needed to advance the integration of MRE with ocean observing systems. In most cases, additional power generation on the order of watts was identified as significantly beneficial to enhancing ocean observations capabilities.

marine renewable energy, powering the blue economy↗
DOE OSTI2014

Direct Utilization of Coal Syngas in High Temperature Fuel Cells

This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that the extent of steam and current load accelerate the degradation caused by PH3. A unique filtering technique has been proposed to reduce the effect of PH3. In addition, various cell materials have been proposed to reduce the rate of degradation caused by H2S. Furthermore, a three-dimensional, transient multi-physics model has been formulated to describe primary transport processes and electro-chemical reactions occurring within the cell. This model has been validated using data gathered from accelerated tests. The validated model then has been used to study the degradation rates under a range of operating conditions and impurity levels. This has resulted in a procedure that uses both experiments and simulations to predict the life-time of a cell operating with syngas with known concentration of trace impurities. Finally all the experience and knowledge gained has been disseminated via 39 journal papers and 43 presentations/posters/conference papers.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2022

An Updated Review of Hypotheses Regarding Bat Attraction to Wind Turbines

Patterns of bat activity and mortalities at wind energy facilities suggest that bats are attracted to wind turbines based on bat behavioral responses to wind turbines. For example, current monitoring efforts suggest that bat activity increases post-wind turbine construction, with bats making multiple passes near wind turbines. We separated the attraction hypothesis into five previously proposed explanations of bat interactions at or near wind turbines, including attraction based on noise, roost sites, foraging and water, mating behavior, and lights, and one new hypothesis regarding olfaction, and provide a state of the knowledge in 2022. Our review indicates that future research should prioritize attraction based on social behaviors, such as mating and scent-marking, as this aspect of the attraction hypothesis has many postulates and remains the most unclear. Relatively more data regarding attraction to wind turbines based on lighting and noise emission exist, and these data indicate that these are unlikely attractants. Analyzing attraction at the species-level should be prioritized because of differences in foraging, flight, and social behavior among bat species. Lastly, research assessing bat attraction at various scales, such as the turbine or facility scale, is lacking, which could provide important insights for both wind turbine siting decisions and bat mortality minimization strategies. Identifying the causes of bat interactions with wind turbines is critical for developing effective impact minimization strategies.

17 WIND ENERGY↗
DOE OSTI2013

RESEARCH AND DEVELOPMENT ACTIVITIES AT SAVANNAH RIVER SITE'S H CANYON FACILITY

The Savannah River Site's (SRS) H Canyon Facility is the only large scale, heavily shielded, nuclear chemical separations plant still in operation in the U.S. The facility's operations historically recovered uranium-235 (U-235) and neptunium-237 (Np-237) from aluminum-clad, enriched-uranium fuel tubes from Site nuclear reactors and other domestic and foreign research reactors. Today the facility, in conjunction with HB Line, is working to provide the initial feed material to the Mixed Oxide Facility also located on SRS. Many additional campaigns are also in the planning process. Furthermore, the facility has started to integrate collaborative research and development (R&D) projects into its schedule. H Canyon can serve as the appropriate testing location for many technologies focused on monitoring the back end of the fuel cycle, due to the nature of the facility and continued operation. H Canyon, in collaboration with the Savannah River National Laboratory (SRNL), has been working with several groups in the DOE complex to conduct testing demonstrations of novel technologies at the facility. The purpose of conducting these demonstrations at H Canyon will be to demonstrate the capabilities of the emerging technologies in an operational environment. This paper will summarize R&D testing activities currently taking place in H Canyon and discuss the possibilities for future collaborations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2019

Hillslope Hydrology in Global Change Research and Earth System Modeling

Earth System Models (ESMs) are essential tools for understanding and predicting global change, but they cannot explicitly resolve hillslope-scale terrain structures that have been long recognized by hydrologists as the fundamental organizers of water, energy, and biogeochemical stores and fluxes. Here, we bring together hydrologists, Critical Zone scientists and ESM developers, to explore how hillslope structures may modulate ESM grid-level water, energy and biogeochemical fluxes. In contrast to the traditional one-dimensional (1D), vertical, 2-3m deep, and free-draining soil hydrology in current ESM land models, we argue that 3D, lateral ridge-to-valley flow through shallow and deep paths, and insolation contrasts between sunny and shady slopes, are the top two basic, long-acknowledged, and readily quantifiable organizers of water and energy (and hence vegetation) within an ESM grid cell. We argue that these two processes will be most consequential where (and when) water and/or energy are limiting. We further hypothesize that if they are implemented in ESM land models, they will increase continental water storage and residence time, buffering land ecosystems against seasonal and interannual droughts. We explore efficient ways to capture these mechanisms in ESMs and identify critical knowledge gaps preventing us from scaling up hillslope to global processes. One such gap is our extremely limited view of the subsurface, where water is stored to support vegetation and released to stream baseflow and aquatic ecosystems. We conclude with a call for global syntheses activities and model experiments to assess the impact of hillslope hydrology on global change predictions.

Fan, Ying↗