Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Co”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Droplet Growth in Undercooled Cu-Co Alloys

High undercooling usually leads to the refinement of microstructures, while an opposite tendency occurs in liquid immiscible alloys. In the Cu-Co system, there is a metastable liquid miscibility gap which may allow the study of droplet nucleation and growth by undercooling experiments. In the present work, two alloys of Cu50Co50 and Cu68Co32 (atomic) were undercooled using a melt fluxing technique in which the liquid separation temperature could be directly measured. It was observed that after separation the resultant melts were further undercooled by 315 K prior to solidification. The relationship between the largest droplet radius and undercooling was found to exhibit three regimes: a power law growth, linear growth, and saturation stage. In addition to dendrites and droplet-like morphology reported previously, an interconnected structure was formed for the Cu50Co50 alloy at intermediate undercooling. It played a crucial role in droplet coarsening at high undercooling.

Robinson, Michael B.↗
NASA NTRS1971

Selective Detection of Ambient CO with a Mercury Replacement Analyzer

A commercial available ambient CO analyzer based on low yield mercury replacement is described. Measurements of the effects of interfering reactions are reported. Hydrogen interferes to the extent of less than 10%. Selective detection of ambient carbon monoxide is verified.

Palanos, Paul N.↗
NASA NTRS1997

CO and the Temperature Structure of the Solar Atmosphere

The surface layers of the Sun provide a crucial boundary condition for many of the processes that occur in the deep interior. The stratification of the outer solar atmosphere once was thought to be well understood. However, studies of thermally sensitive molecular absorptions in the infrared revealed puzzling anomalies. Strong lines of the CO fundamental vibration-rotation bands near 5 microns showed very cool temperatures at the extreme limb, and remarkable off-limb emissions extending well into the supposedly hot chromosphere. The conflicting pictures of the photosphere/chromosphere interface, from the widely separated wavelength regimes, has raised suspicions that those "layers" of the atmosphere are much more inhomogeneous than previously suspected. One proposal is that the low chromosphere is dominated by cool gas--the "COmosphere," if you will--which is threaded by a network of persistent small-scale hot magnetic filaments and occasionally disrupted by localized acoustic disturbances. The COmosphere is capped by the merged fields of the network elements in the chromospheric "canopy." I will describe the evidence in favor of that model, including recent work at the NSO McMath-Pierce telescope (including use of the new "Phoenix" spectrometer) and translimb far-UV spectroscopy by SOHO/SUMER.

Ayres, Thomas R.↗
NASA NTRS1999

Co-Seismic Mass Dislocation and Its Effect on Earth's Rotation and Gravity

Mantle processes often involve large-scale mass transport, ranging from mantle convection, tectonic motions, glacial isostatic adjustment, to tides, atmospheric and oceanic loadings, volcanism and seismicity. On very short time scale of less than an hour, co-seismic event, apart from the "shaking" that is the earthquake, leaves behind permanent (step-function-like) dislocations in the crust and mantle. This redistribution of mass changes the Earth's inertia tensor (and hence Earth's rotation in both length-of-day and polar motion), and the gravity field (in terms of spherical harmonic Stokes coefficients). The question is whether these effects are large enough to be of any significance. In this paper we report updated calculation results. The calculation uses the normal mode summation scheme, applied to 15,814 major earthquakes that occurred during 1976-1998, according to source mechanism solutions given by the Harvard Central Moment Tensor catalog. Compared to the truly large ones earlier in the century, the earthquakes we study are individually all too small to have left any discernible signature in geodetic records of Earth rotation or global gravity field. However, their collective effects continue to exhibit an extremely strong statistical tendencies. For example, earthquakes conspire to decrease J(sub 2) and J(sub 22) while shortening LOD, resulting in a rounder and more compact Earth. Strong tendency is also seen in the earthquakes trying to "nudge" the Earth rotation pole towards about 140 degree E, roughly opposite to the observed polar drift direction. The geophysical significance and implications will be further studied.

Chao, Benjamin F.↗
NASA NTRS2000

High Resolution Emission Spectroscopy of the Alpha Pi-1 - Chi Sigma-1(+) Fourth Positive Band System of CO from Electron Impact

We report electron-impact induced fluorescence spectra [300 mA full width at half maximum (FWHM)] of CO for 20 and 100 eV impact energies of the spectral region of 1300 to 2050 A and high resolution spectra (FWHM) of the v'=5 to v"=l and the v'=3 to v"=O bands showing that the rotational structure of the band system are modeled accurately. The excitation function of the (0,1) band (1597 A) was measured from electron impact in the energy range from threshold to 750 eV and placed on an absolute scale from modem calibration standards.

Beegle, Luther W.↗
NASA NTRS2000

Purification of Restriction Endonuclease EcoRII and its Co-Crystallization

Restriction endonuclease EcoRII (EcoRII) is a homodimeric DNA-binding protein. It belongs to the type II family of restriction-modification enzymes (subclass IIe). EcoRII recognizes the nucleotide sequence 5'-CCWGG (W=A or T) and cleaves the phosphodiester bond preceding the first cytosine. Methylation at C5 of the second cytosine inhibits cleavage. The enzyme has a unique ability to search for the presence of two substrate sites before cleavage. To the best of our knowledge no other subclass IIe restriction endonuclease has been crystallized yet, without or with a DNA-substrate. We have recently grown and characterized the crystals of this enzyme (1) Here we report on the result of co-crystallization experiments of EcoRII with an 11 b.p. oligonucleotide substrate. The dissociation constant (Kd) EcoRII: 11 b.p. was determined earlier (unpublished results). The needle-like crystals of oligonucleotide-EcoRII protein complex were obtained with this substrate by the technique of vapor diffusion hanging drops. The crystals obtained were washed and dissolved in an aliquot of 10 mM Tris-HCl buffer, pH=7.5. Running a portion of this solution on the SDS-get indicated the presence of endonuclease in the solution. A UV-spectrophotometric test of a second portion confirmed the presence of DNA. We are now working on improvement of the DNA-EcoRII protein crystals. Results obtained from these and ongoing efforts will be reported.

Karpova, E. A.↗
NASA NTRS2000

Genetic Network Inference: From Co-Expression Clustering to Reverse Engineering

Advances in molecular biological, analytical, and computational technologies are enabling us to systematically investigate the complex molecular processes underlying biological systems. In particular, using high-throughput gene expression assays, we are able to measure the output of the gene regulatory network. We aim here to review datamining and modeling approaches for conceptualizing and unraveling the functional relationships implicit in these datasets. Clustering of co-expression profiles allows us to infer shared regulatory inputs and functional pathways. We discuss various aspects of clustering, ranging from distance measures to clustering algorithms and multiple-duster memberships. More advanced analysis aims to infer causal connections between genes directly, i.e., who is regulating whom and how. We discuss several approaches to the problem of reverse engineering of genetic networks, from discrete Boolean networks, to continuous linear and non-linear models. We conclude that the combination of predictive modeling with systematic experimental verification will be required to gain a deeper insight into living organisms, therapeutic targeting, and bioengineering.

Dhaeseleer, Patrik↗
NASA NTRS2000

BOREAS TGB-5 CO2, CH4 and CO Chamber Flux Data Over the NSA

The BOReal Ecosystem-Atmosphere Study Trace Gas Biogeochemistry (BOREAS TGB-5) team collected a variety of trace gas concentration and flux measurements at several NSA sites. This data set contains carbon dioxide (CO2), methane (CH4), and carbon monoxide (CO) chamber flux measurements conducted in 1994 at upland forest sites that experienced stand-replacement fires. These measurements were acquired to understand the impact of fires on soil biogeochemistry and related changes in trace gas exchange in boreal forest soils. Relevant ancillary data, including data concerning the soil temperature, solar irradiance, and information from nearby un-burned control sites, are included to provide a basis for modeling the regional impacts of fire and climate changes on trace gas biogeochemistry. The data are provided in tabular ASCII files.

Burke, Roger↗
NASA NTRS2001

Systematics of Ni, Co, Cr and V in Olivine from Planetary Melt Systems: Martian Basalts

Secondary Ion Mass Spectrometry (SIMS) data for Ni, Co, Cr, and V in olivine in martian basalts is compared to data from lunar and terrestrial basalts. We use experimentally-derived and published D values to calculate as-yet unsampled, olivine-bearing, non-cumulus melt compositions. Additional information is contained in the original extended abstract.

Herd, C. D. K.↗
NASA NTRS1994

Global Dipole Moment Function for the X1 Sigma+ Ground State of CO

We have studied the dipole moment function (DMF) for the X(sup 1)Sigma(sup +) state of CO as a function of the completeness of the one- and n-particle treatments. Our best DMF is obtained using an augmented correlation-consistent quadruple-zeta basis set with external correlation included using the averaged-coupled-pair functional (ACPF) approach from a complete-active-space self-consistent-field zeroth-order reference. The DMF evaluated using the finite-field approach is in far better agreement with the experimentally deduced DMF than all previous theoretical determinations, but systematic differences still remain in the DMF at larger internuclear distances that give rise to significant discrepancies between the theoretical and experimental Einstein coefficients for transitions involving vibrational quantum numbers above about Upsilon=15.

Langhoff, Stephen R.↗
NASA NTRS1997

Global Transport of Aerosol and CO: Initial 3-D Simulations of MAPS, TOMS, and AVHRR

Carbon monoxide concentrations and aerosol properties provide the tracers of global tropospheric perturbation by humankind that are most easily observed from satellite platforms. Aircraft field observations are additionally needed for us to simulate and understand the patterns observed. We report on our accumulating experience in making detailed, situation-specific, 3-D simulations of these tropospheric constituents as observed from the MAPS CO sensor, the Advanced Very High Resolution Radiometer (AVHRR) aerosol scattering data, and the Total Ozone Mapping Spectrometer (TOMS) absorbing-aerosol information. We have found a strong complimentarity of satellite and aircraft data in this effort, and recommend modelers use: (1) satellite data to pose initial questions; (2) aircraft data for modelers' first detailed simulations; and (3) a return to satellite data for global generalization. This work provides one example. Our main tools are the MM5 numerical model for meteorological assimilation and GRACES, our NASA Ames tracer-chemistry model, which incorporates emissions estimates. We report on several six-week simulations of global biomass burning effects as observed in the MAPS October 1994 dataset, and show the usefulness of two aircraft datasets, the TRACE-A (1992) and PEM-Tropics missions of NASA's Global Tropospheric Experiment. Additional information is contained in the original extended abstract.

Chatfield, Robert B.↗
NASA NTRS2002

H2, CO and Dust Emission Around Low Mass Stars

We model the thermal balance, the chemistry, and the radiative transfer in dusty disks orbiting young, low mass stars. These models are motivated by observations of infrared and ultraviolet transitions of H2 from protoplanetary disks, as well as millimeter and submillimeter observations of other molecules such as CO, and infrared continuum observations of the dust. The dust grains are heated primarily by the stellar radiation and the infrared radiation field produced by the dust itself. The gas is heated by collisions with warmer dust grains, X-rays from the region close to the stellar surface, UV pumping of hydrogen molecules, and the grain photoelectric heating mechanism initiated by UV photons from the central star. We treat cases where the gas to dust ratio is high, because the dust has settled to the midplane and coagulated into relatively large objects. We discuss situations in which the infrared emission from H2 can be detected, and how the comparison of the observations with our models can deduce physical parameters such as the mass and the density and temperature distribution of the gas.

Hollenbach, David↗
NASA NTRS2002

H2, CO and Dust Emission Around Low Mass Stars

We model the thermal balance, the chemistry, and the radiative transfer in dusty disks orbiting young, low mass stars. These models are motivated by observations of infrared and ultraviolet transitions of H2 from protoplanetary disks, as well as millimeter and submillimeter observations of other molecules such as CO, and infrared continuum observations of the dust. The dust grains are heated primarily by the stellar radiation and the infrared radiation field produced by the dust itself. The gas is heated by collisions with warmer dust grains, X-rays from the region close to the stellar surface, UV (ultraviolet) pumping of hydrogen molecules, and the grain photoelectric heating mechanism initiated by UV photons from the central star. We treat cases where the gas to dust ratio is high, because the dust has settled to the midplane and coagulated into relatively large objects. We discuss situations in which the infrared emission from H2 can be detected, and how the comparison of the observations with our models can deduce physical parameters such as the mass and the density and temperature distribution of the gas.

Hollenbach, David↗
NASA NTRS2002

MPL-Net Measurements of Aerosol and Cloud Vertical Distributions at Co-Located AERONET Sites

In the early 1990s, the first small, eye-safe, and autonomous lidar system was developed, the Micropulse Lidar (MPL). The MPL acquires signal profiles of backscattered laser light from aerosols and clouds. The signals are analyzed to yield multiple layer heights, optical depths of each layer, average extinction-to-backscatter ratios for each layer, and profiles of extinction in each layer. In 2000, several MPL sites were organized into a coordinated network, called MPL-Net, by the Cloud and Aerosol Lidar Group at NASA Goddard Space Flight Center (GSFC) using funding provided by the NASA Earth Observing System. tn addition to the funding provided by NASA EOS, the NASA CERES Ground Validation Group supplied four MPL systems to the project, and the NASA TOMS group contributed their MPL for work at GSFC. The Atmospheric Radiation Measurement Program (ARM) also agreed to make their data available to the MPL-Net project for processing. In addition to the initial NASA and ARM operated sites, several other independent research groups have also expressed interest in joining the network using their own instruments. Finally, a limited amount of EOS funding was set aside to participate in various field experiments each year. The NASA Sensor Intercomparison and Merger for Biological and Interdisciplinary Oceanic Studies (SIMBIOS) project also provides funds to deploy their MPL during ocean research cruises. All together, the MPL-Net project has participated in four major field experiments since 2000. Most MPL-Net sites and field experiment locations are also co-located with sunphotometers in the NASA Aerosol Robotic Network. (AERONET). Therefore, at these locations data is collected on both aerosol and cloud vertical structure as well as column optical depth and sky radiance. Real-time data products are now available from most MPL-Net sites. Our real-time products are generated at times of AERONET aerosol optical depth (AOD) measurements. The AERONET AOD is used as input to our processing routines, which calculate the aerosol layer top height and extinction profile, and our MPL calibration value. A variety of other data products are available or under development. We present an overview of the MPL-Net project and discuss data products useful to the AERONET community. Results from several sites and field experiments will be presented.

Welton, Ellsworth J.↗
NASA NTRS2002

Co-Seismic Mass Dislocation and its Effect on Earth's Rotation and Gravity

Mantle processes often involve large-scale mass transport, ranging from mantle convection, tectonic motions, glacial isostatic adjustment, to tides, atmospheric and oceanic loadings, volcanism and seismicity. On very short time scale of less than an hour, co-seismic event, apart from the shaking that is the earthquake, leaves behind permanent (step-function-like) dislocations in the crust and mantle. This redistribution of mass changes the Earth's inertia tensor (and hence Earth's rotation in both length-of-day and polar motion), and the gravity field (in terms of spherical harmonic Stokes coefficients). The question is whether these effects are large enough to be of any significance. In this paper we report updated calculation results based on Chao & Gross (1987). The calculation uses the normal mode summation scheme, applied to nearly twenty thousand major earthquakes that occurred during 1976-2002, according to source mechanism solutions given by the Harvard Central Moment Tensor catalog. Compared to the truly large ones earlier in the century, the earthquakes we study are individually all too small to have left any discernible signature in geodetic records of Earth rotation or global gravity field. However, their collective effects continue to exhibit an extremely strong statistical tendencies. For example, earthquakes conspire to decrease J2 and J22 while shortening LOD, resulting in a rounder and more compact Earth. Strong tendency is also seen in the earthquakes trying to nudge the Earth rotation pole towards approximately 140 degrees E, roughly opposite to the observed polar drift direction. The geophysical significance and implications will be further studied.

Chao, B. F.↗
NASA NTRS2002

UV photoabsorption cross sections of CO, N2, and SO2 for studies of the ISM and planetary atmospheres

We report high-resolution laboratory measurements of photoabsorption cross sections of CO, N2, and SO2 in the wavelength range 80 to 320 nm. The motivation is to provide the quantitative data that are needed to analyze observations of absorption by, and to model photochemical processes in, the interstellar medium and a number of planetary atmospheres. Because of the high resolution of the spectrometers used, we can minimize distortion of the spectrum that occurs when instrument widths are greater than the widths of spectral features being measured. In many cases, we can determine oscillator strengths of individual rotational lines - a unique feature of our work.

Smith, Peter L.↗
NASA NTRS2003

Co-Seismic Energy Changes Induced by Earthquakes on a Rotating, Gravitating Earth

Besides operating its own energy budget, an earthquake acts as an agent transferring a much greater amount of energy among the Earth's rotation, elastic field, gravitational field and internal heat. We compute the co-seismic, globally integrated gravitational and rotation changes induced by some 20,000 large earthquakes that occurred in the last quarter century, according to Chao et al. (1995, GJI, 122,776- 783,784-789) and using the Harvard CMT catalog. The result confirms an extremely strong tendency for the earthquakes to decrease the global gravitational energy and to increase the spin energy. It is found that energy is being extracted from the Earth's gravitational field by the action of earthquakes at an average rate of about approx. 2 TeraW during the studied period, larger by far than the approx. 7 GigaW for the average rate of the earthquake-induced rotational energy increase and the approx. 5 GigaW for the seismic energy release. Based on energetics considerations and assuming the inability of the Earth to build up elastic energy continuously over time, it is argued that earthquakes, by converting gravitational energy, may make a significant contribution to the global hedflow.

Chao, Benjamin F.↗