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At least 793 records · Page 44

Development of an X-ray surface analyzer for planetary exploration

An ultraminiature X-ray fluorescence spectrometer was developed which can obtain data on element composition not provided by present spacecraft instrumentation. The apparatus employs two radioisotope sources (Fe-55 and Cd-109) which irradiate adjacent areas on a soil sample. Fluorescent X-rays emitted by the sample are detected by four thin-window proportional counters. Using pulse-height discrimination, the energy spectra are determined. Virtually all elements above sodium in the periodic table are detected if present at sufficient levels. Minimum detection limits range from 30 ppm to several percent, depending upon the element and the matrix. For most elements, they are below 0.5 percent. Accuracies likewise depend upon the matrix, but are generally better than plus or minus 0.5 percent for all elements of atomic number greater than 14. Elements below sodium are also detected, but as a single group.

Clark, B. C.↗

Heterogeneous nucleation of gamma prime in Al-Ag and Al-Ag /Cd or Cu/ alloys.

Results of transmission electron microscopy studies of heterogeneous nucleation of the metastable gamma prime phase were made in binary and ternary alloys of Al-5 at. % Ag, Al-4.8 at. % Ag-0.15 at. % Cd, and Al-4.8 at. % Ag-0.2 at. % Cu. Heterogeneous nucleation of gamma prime was found to be associated with four types of dislocations, regardless of the quenching treatment or alloy additions which were used. Nucleation was found to occur on: (a) jogged dislocations; (b) helical dislocations; (c) dislocation loops; (d) heterogeneous climb sources. Only one nucleation mechanism was found to be unique to the ternary alloys: that of nucleation on heterogeneous climb sources.

Passoja, D. E.↗

Chemical fractionations in meteorites. V - Volatile and siderophile elements in achondrites and ocean ridge basalts.

Eighteen achondrites and 4 terrestrial basalts (3 ocean ridge, 1 continental) were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Co, Cs, Cu, Ga, In, Ir, Rb, Se, Tl and Zn. Samples included 7 eucrites, 5 howardites, 2 nakhlites, 2 shergottites, an angrite, and an aubrite. Light and dark portions of the gas-rich meteorites Kapoeta and Pesyanoe were analyzed separately. Nakhlites and shergottites have volatile element abundances similar to those in ocean ridge basalts; eucrites, howardites, and angrites show greater depletions by an order of magnitude and less similar abundance patterns. In terms of a two-component model of planetary accretion, the parent planets contained the following percentages of low-temperature material: eucrites 0.8, nakhlites 38, shergottites 28. Shergottites may be genetically related to L-chondrites. The siderophile element pattern of achondrites resembles that of the moon, but with less extreme depletions.

Laul, J. C.↗

Spectral compositional imaging of silicate rocks.

A technique is presented for the broad-scale mapping of gross compositional differences in silicate rocks from three medium-width (2 to 3 microns) spectral channels of thermal infrared scanner data. Ratios of radiances in two of the channels as measured by a two-element Hg:Cd:Te detector from an altitude of 1000 meters are calculated for 25 silicate rocks. The ratios are shown to be nearly linearly correlated with the position of the centers of gravity of the reststrahlen spectral emissivity features, as measured in the laboratory. Further, the ratios are shown to be generally correlated with SiO2 content of silicate rocks. A third channel is proposed for correction of temperature variations across the scene.

Vincent, R. K.↗

RKR Franck-Condon factors for blue and ultraviolet transitions of some molecules of astrophysical interest and some comments on the interstellar abundance of CH, CH+ and SiH+.

RKR Franck-Condon factors for thirteen of the blue and ultraviolet transitions of AlF, AlO, BH, BD, CH, CD, CH(+), SiO and SiH(+) have been calculated. The interstellar abundances of CH, CH(+) and SiH(+) are discussed with regard to recent laboratory measurements, our Franck-Condon factors, and observations of the sun and the interstellar medium.

Liszt, H. S.↗

A note on mass loss during collisions between galaxies and the formation of giant systems.

Stars will be liberated from the outer portions of galaxies which interact tidally. Using models based on the density distribution observed in the E1 galaxy NGC 3379, the mass loss is computed for hyperbolic collisions on an approximate but conservative basis. Binary collisions are then summed to show that large numbers of stars will be evaporated from elliptical members of dense clusters of galaxies. An estimate of one trillion solar masses is obtained for the amount of material dispersed in the Coma cluster, and in rich very dense systems (Morgan's Type I) the large amount of tidally dispersed debris may constitute the centrally located galaxies designated cD systems which often dominate these clusters.

Gallagher, J. S., III↗

N-type mercury-cadmium-telluride photoconductors in optical heterodyne communication systems.

Discussion of the performance of a photoconductive (Hg,Cd)Te detector/mixer in a carbon dioxide laser heterodyne communication system. The utility of computer simulation of the performance of an optical heterodyne detector/mixer is demonstrated. Certain unusual properties of this device are pointed out that, while having a substantial impact on device performance, have received little previous attention.

Cohen, S. C.↗

Performance of S-192 /Hg,Cd/Te arrays.

Very high performance (Hg,Cd)Te photoconductive detectors have been fabricated for use on the S-192 experiment, which is a multispectral scanner being built by Honeywell for the NASA Manned Space Center's Skylab. The S-192 will scan the earth from Skylab and record data in twelve near infrared spectral bands and one long wavelength band. These detectors demonstrate good uniformity in performance across an array. State-of-the-art fabrication techniques have been used to make detectors with good definition that are 5-10 microns thick with 25-micron spacing between elements.

Aldrich, N. C.↗

Evaluation of new plastic compression (Ziegler) type of seals for long life planetary batteries

A program was initiated to develop improved types of terminal seals for aerospace Ni-Cd batteries. The approach used has not involved attempts, such as employed elsewhere, to improve the ceramic-to-metal seal that is now extensively employed for this application. Rather the approach has been directed toward the development and evaluation of new types of seals. Of prime interest in this initial investigation has been the Ziegler type of compression seal and in particular the injection molded version developed by the Bell Telephone Laboratories (BTL). A number of these units were designed, fabricated, and evaluated on an accelerated life test under a simulated battery environment. Results have shown that there are no major problems involved in scaling up the BTL small-size (5-amp) seal to a larger size (up to 50-amp) seal suitable for most JPL flight batteries. Five out of five such seals successfully completed over 10 months of continuous thermal cycling without developing any leaks greater than 1.8 x to 10 to the minus 9th power atm-cc-He/s.

Frank, H. A.↗

The extralunar component in lunar soils and breccias.

Concentrations of Ni, Zn, Ga, Ge, Cd, In, and Ir in soils and breccias returned by Apollo 14 and Apollo 15 are reported. The integrated flux of extralunar material at each lunar landing site is estimated on the basis of the siderophilic elements Ni, Ge, Ir, and Au. It falls with time between 3.95 and 3.26 g.y. before the present. The flux versus time relationship indicated by the trace element data is consistent with estimates of the same relationship based on crater statistics and morphologies, as would be expected if the same populations of interplanetary objects were responsible for both properties. The data are consistent with the presence of two populations of material bombarding the moon early in its history, one with a short half-life that was dominant until about 3.8 g.y. ago, and another with a half-life of about 2.0 g.y. that dominated during the more recent era.

Baedecker, P. A.↗