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At least 793 records · Page 44

Predicting the creep-rupture lifetime of a cast austenitic stainless steel using Larson-Miller and Wilshire parametric approaches

An experimental dataset of just over 100 creep tests of a cast austenitic stainless steel, CF8C-Plus, was analyzed by two temperature-compensated parametric models (Larson-Miller, Wilshire et al.) to predict long-term lifetimes as functions of temperature and stress. The dataset and associated regression analyses showed greater scatter than typically found in recent similar studies of wrought Ni-based alloys by the same two models and was attributed to the microstructural inhomogeneity of the cast stainless steel. Qualitatively, the Larson-Miller formalism showed greater lifetime prediction accuracy than the Wilshire approach, with the latter model's predictive ability being particularly degraded by the presence of two very significant outlier results. This observation suggests that the Larson-Miller approach is more robust when treating rupture-time datasets that show particularly wide experimental scatter. Despite the differences in the overall predictive ability, both models yielded similar predictions of the applied stress at which CF8C-Plus would have a creep-limited lifetime of 100,000 h when loaded below the yield point.

36 MATERIALS SCIENCE↗

In-Cell Thermal Creep Frame Capability: Out-of-Cell Construction and Subsized Sample Testing

This report describes the activities related to the construction of an in-cell thermal creep test facility for small-scale specimens in the irradiation-assisted stress-corrosion cracking (IASCC) hotcell located at the Fuels and Applied Science Building (FASB) at INL. The whole project includes three stages: (i) conceptual design; (ii) out-of-cell demonstration tests; and (iii) in-cell demonstration testing. During the current fiscal year (FY)-2022, materials and equipment required to construct the conceptual design outlined in a previous report were procured. Frames for conducting out-of-cell testing have been constructed, and testing plans have been developed to assess the operation of the newly constructed frames. Preliminary testing of flat subsized tensile specimens on ASTM creep frames has also been completed for two sample thicknesses: 0.75 mm and 1.0 mm.

36 MATERIALS SCIENCE↗

Pressure Dependence of Creep in Forsterite Olivine: Comparison of Measurements From the D-DIA and Griggs Apparatus

We present measurements of the creep strength of forsterite olivine at 1200°C from 1 to 7.5 GPa made using a Griggs apparatus at low pressures and a D-DIA apparatus at high pressures. The same starting material is used for all experiments allowing us to compare measurements made with the two instruments. We find that results from the two apparatus are comparable if the stress measurements made from the alumina piston in the D-DIA experiments are used as a proxy for the load that the olivine sample supports. The reproducibility of the D-DIA experiments are improved if microstructural observations of the post experimental integrity of the sample and piston are used to judge experimental validity. Interpretation of the joint dataset indicate that the pressure dependence of creep (ΔV*) for our sample material cannot be described by a constant value over this pressure range, but changes from ~15 cm 3 /mol at low pressure to closer to ~4 cm 3 /mol at high pressure. These results are consistent with changes in the mix of deformation mechanisms operating in forsterite as pressure increases.

58 GEOSCIENCES↗

Retardation of Small Creep–Fatigue Crack in Gr. 91 Steel Through the Combined Effects of Stress Relaxation, Microstructural Evolution, and Oxidation

This investigation reports an unusual effect of hold time (up to 10 seconds) on retardation in the growth of creep–fatigue small cracks at 550 °C in Grade 91 steel. The observed phenomenon was interpreted by elucidating multiple processes that are active in the plastic zone at the crack tip. To this effect, microstructural and mechanical responses of the crack tip plastic zone were compared with the mechanical and microstructural responses during low cycle fatigue/creep–fatigue. It is proposed that the stress relaxation that occurs during the hold time can reduce the stress intensity in the plastic zone of crack tip thus, contributing to retardation in the small crack growth rate. Aside from stress relaxation, stress intensity in the crack tip can be further reduced by the phenomenon of cyclic softening that occurs because of plasticity-induced microstructural coarsening. Separately, the contribution of oxidation-induced crack tip shielding is also considered to explain the observed effects of hold time on crack growth rates. Taken together, a combination of stress relaxation, enhanced rate of cyclic softening, and higher degree of oxidation with the introduction of a hold time is demonstrated to be responsible for reduction in the crack growth under creep–fatigue conditions.

36 MATERIALS SCIENCE↗

Influence of Melt-Pouring Temperature and Composition of Primary Coating of Shell Mold on Tensile Strength and Creep Resistance of Ni-Based Superalloy

Eight investment castings of Inconel 713C superalloy were fabricated, varying in the melt-pouring temperature, from 1400 to 1520 °C, and CoAl{sub 2}O{sub 4} inoculant content, 0 or 5 wt.%, in the primary coat. Their influence on grain size on tensile and creep properties was investigated. The best combination of yield stress (815 MPa) and elongation (A{sub 4} = 7.65%) at ambient temperature was obtained in surface-modified castings poured from 1520 °C. The longest time to rupture was for the unmodified castings (76.8 h) poured from 1520 °C, while for the modified variant, the time to rupture was lower around, 7.4 h, which was still a satisfactory value. During tensile testing, microcracks were formed in large eutectic γ′, carbides and borides, due to the accumulation of stress at interfaces with the matrix. During creep, N-type rafting of γ′ precipitates and phase transformation MC + γ → γ′ + M{sub 23}C{sub 6} took place.

36 MATERIALS SCIENCE↗

Microstructure Evolution and Improved Creep Behavior of Mg-Al-Si Alloy Matrix Composite Reinforced with SiC Nanoparticles

The Mg-9Al-1Si matrix composite reinforced with SiC nanoparticles is fabricated by semisolid stirring-assisted ultrasonic vibration, which contains finer grains and a more uniform microstructure compared to that of the Mg-9Al-1Si alloys. The sizes of the Mg{sub 17}Al{sub 12} and Mg{sub 2}Si phases decreased continuously as the volume fraction of n-SiCp increased from 0 to 1% and then increased apparently when the volume fraction of n-SiCp increased to 1.5%. The steady-creep rates of the 1 vol.% n-SiCp/Mg-9Al-1Si are approximately two times lower than those of the Mg-9Al-1Si matrix alloy at 200 °C under applied stress of 70 MPa due to the strengthening effect of the nanosized SiCp. The reason for the improved creep properties is mainly attributed to the obvious grain boundary strengthening, the Orowan strengthening mechanism, the load transfer effect, and the pinning effect of the n-SiCp and the refined Mg{sub 17}Al{sub 12} and Mg{sub 2}Si phases.

36 MATERIALS SCIENCE↗

Data-Driven Surrogate Modeling with Microstructure-Sensitivity of Viscoplastic Creep in Grade 91 Steel

Abstract To support the development of advanced steel alloys tailored to withstand extreme conditions, it is imperative to account for the mechanical performance of components, while considering the influence of local microstructure on the macroscopic response. To this end, this study focuses on the development of microstructure-sensitive constitutive models for the mechanical response of Grade 91 steel exposed to extreme thermo-mechanical environments. Polynomial chaos expansion (PCE) surrogates are used to emulate high-fidelity polycrystal simulations of the viscoplastic response of Grade 91 steel as a function of the microstructure fingerprint (e.g., dislocations and precipitates). To cover a wide temperature–stress domain, two separate PCE surrogates—one that captures softening and the other that captures hardening behavior—are combined using another (sparse) Gaussian process regression model. The resulting constitutive creep surrogate model is integrated within the MOOSE finite element framework to simulate the intricate effects of microstructure, in particular MX-phase precipitates, on a component with a graded microstructure. Surrogate sensitivity analysis is applied to quantify the relevant impact of spatially varying microstructure on the creep response in a test-case involving a Grade 91 alloy with a prototypical weld.

36 MATERIALS SCIENCE↗

Modern data analytics approach to predict creep of high-temperature alloys

A breakthrough in alloy design often requires comprehensive understanding in complex multi-component/multi-phase systems to generate novel material hypotheses. We introduce a modern data analytics workflow that leverages high-quality experimental data augmented with advanced features obtained from high-fidelity models. Herein, we use an example of a consistently-measured creep dataset of developmental high-temperature alloy combined with scientific alloy features populated from a high-throughput computational thermodynamic approach. Extensive correlation analyses provide ranking insights for most impactful alloy features for creep resistance, evaluated from a large set of candidate features suggested by domain experts. We also show that we can accurately train machine learning models by integrating high-ranking features obtained from correlation analyses. Consequently, the demonstrated approach can be extended beyond incorporating thermodynamic features, with input from domain experts used to compile lists of features from other alloy physics, such as diffusion kinetics and microstructure evolution.

36 MATERIALS SCIENCE↗

Irradiation induced creep in nanocrystalline high entropy alloys

Irradiation induced creep (IIC) compliance in NiCoFeCrMn high entropy alloys is measured as a function of grain size (30 < x < 80 nm) and temperature (23–500 °C). For 2.6 MeV Ag 3+ irradiation at a dose rate of 1.5×10 – 3 dpa – 1 s – 1 the transition from the recombination to sink limited regimes occurs at ~ 100 °C. In the sink-limited regime, the IIC compliance scales inversely with grain size, consistent with a recently proposed model for grain boundary IIC. The thermal creep rate is also measured; it does not become comparable to the IIC rate, however, until ~ 650 °C. Here, the results are discussed in context of defect kinetics in irradiated HEA systems.

36 MATERIALS SCIENCE↗

Effect of Zr and Sc additions on coarsening- and creep resistance of AlSi10Mg fabricated by laser powder bed fusion

Microstructure and creep properties are studied in a eutectic AlSi10Mg alloy modified with Zr and Sc additions (Al-9.8Si-0.32Mg-0.70Zr-0.23Sc, wt%) manufactured through laser powder-bed fusion (L-PBF). Three types of Zr/Sc-bearing powders - elemental, master-alloy, and pre-alloyed - are employed in the fabrication process, with the pre-alloyed powders providing the highest incorporation of Zr and Sc in the Al matrix. Here, the as-printed alloy exhibits a fine cellular Al-Si eutectic structure which fragments and coarsens into micron-sized Si particles during aging at 300 ºC, leading to a steady drop in alloy microhardness between 0.1 and 1000 h. Coarsening of the eutectic Si phase during aging is not measurably affected by Zr and Sc in solid solution, which precipitate during aging and increases strength, compensating weakening from Si coarsening between 1 and 200 h at 300 ºC. Atom-probe analysis in the peak-aged condition (96 h/300 °C) confirms the presence of Al 3 (Sc,Zr) secondary nano-precipitates with an average radius of 1.0 nm and some Si solubility. Micron-sized grains are present throughout the alloy, with ultra-fine-grained regions at the melt pool boundaries, neither of which coarsen during long-term aging at 300 ºC. Under creep conditions at 300 °C, the Zr/Sc-bearing alloy with Al 3 (Sc,Zr) nano-precipitates exhibits power-law behavior, with a high apparent stress exponent (n a = 9) and a high threshold stress (σ th = 43 MPa), exhibiting nearly double the strength of a Zr/Sc-free AlSi10Mg control alloy (σ th = 22 MPa).

36 MATERIALS SCIENCE↗

THE DEVELOPMENT OF MICROSTRUCTURAL DAMAGE DURING HIGH TEMPERATURE CREEP-FATIGUE OF A NICKEL ALLOY

Alloy 617 is the leading candidate material for an Intermediate Heat Exchanger (IHX) of the Very High Temperature Reactor (VHTR). To evaluate the behavior of this material in the expected service conditions, strain-controlled cyclic tests that include hold times up to 9000 s at maximum tensile strain were conducted at 950 degrees C. The fatigue resistance decreased when a hold time was added at peak tensile strain, owing to the mechanisms resulting in a change in fracture mode from transgranular in pure fatigue to intergranular in creep–fatigue. Increases in the tensile hold duration beyond an initial value were not detrimental to the creep–fatigue resistance. An analysis of the evolving failure modes was facilitated by interrupting tests during cycling for ex situ microstructural investigation.

36 MATERIALS SCIENCE↗

Creep anisotropy modeling and uncertainty quantification of an additively manufactured Ni-based superalloy

The advantages offered by additive manufacturing over traditional processes has driven a great deal of industrial and academic interest in recent years. However, the process is relatively new and requires additional investigation to become sufficiently mature for wide scale industrial adoption. Electron beam melting powder bed fusion is one technology that has shown promise for fabricating high temperature resistant materials such as nickel based superalloys. The resulting microstructures typically exhibit a strong fiber texture in the build direction giving rise to anisotropic time-dependent deformation behavior. In order to accelerate the qualification of these materials for industrial adoption accurate numerical models are needed for simulating their behavior. In this work a crystal plasticity model including non-Schmid effects is presented for capturing creep anisotropy observed in additively manufactured IN738LC. The model is calibrated via a probabilistic framework where model parameters are treated as random variables. An iterative sequential design strategy is utilized to efficiently identify the probability density of the unknown model parameters. As a case study the model is utilized to investigate the behavior of randomly oriented equiaxed grain clusters sometimes observed embedded in the additively manufactured columnar structure. A synthetic realization is simulated and uncertainty is propagated through to the full-field response. Results indicate that these features are the source of significant creep relaxation and strain accumulation which partially explains observed grain boundary decohesion at these locations.

36 MATERIALS SCIENCE↗

On the irradiation creep by climb-enabled glide of dislocations

The plastic deformation is defined by the proportional to stress elastic deflections of pinned dislocations in climb-enabled glide models of irradiation creep. Here, we argue that this relation is incorrect; instead, as in other pinning-unpinning-type models, the dislocations move from one set of obstacles to another, so that the inter-obstacle spacing determines creep rate, whereas the dependence on the applied stress is only implicit in the unpinning time.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Cell structure in cold worked and creep deformed phosphorus alloyed copper

Transmission electron microscopy (TEM) examinations on as-received, cold worked, as well as cold worked and creep tested phosphorus-alloyed oxygen-free copper (Cu-OFP) have been carried out to study the role of the cell structure. The cell size decreased linearly with increasing plastic deformation in tension. The flow stress in the tests could also be correlated to the cell size. The observed relation between the flow stress and the cell size was in excellent agreement with previously published results. The dense dislocation walls that appeared after cold work in tension is likely to be the main reason for the dramatic increase in creep strength. The dense dislocation walls act as barriers against dislocation motion and their presence also reduces the recovery rate due to an unbalanced dislocation content.

36 MATERIALS SCIENCE↗

Dislocation density evolution in the process of high-temperature treatment and creep of EK-181 steel

X-ray diffraction has been used to study the dislocation structure in ferrite-martensite high-chromium steel EK-181 in the states after heat treatment and high-temperature creep. The influence of heat treatment and stress on evolution of lath martensite structure was investigated by and electron back-scattered diffraction. The effect of nitrogen content on the total dislocation density, fraction of edge and screw dislocation segments are analyzed. - Highlights: •Fraction of edge dislocation in quenched state depends on nitrogen concentration. •Nitrogen affects the character of dislocation structure evolution during annealing. •Edge dislocations fraction influences on dislocation density after aging and creep.

36 MATERIALS SCIENCE↗

Examining the creep strengthening nanoprecipitation in novel highly reinforced heat resistant steels

Here we studied the creep strengthening nanoprecipitation in novel heat resistant steels strengthened by a high density of stable nanoprecipitates. The results show that the high number density of MX nanoprecipitates within the martensitic laths in these steels comes from the great amount of MX former elements present in their chemical compositions and the high dislocation density generated by the martensitic transformation that takes place during cooling after austenitization. These dislocations act as nucleation sites for these nanoprecipitates during the tempering applied after the austenitization and quenching. Atom probe tomography measurements show that these nanoprecipitates are rich in Nb, V, Cr and N for the HDSN1 and HDSN2 steels and V, Cr and N for the HDSN3 steel. The distribution of the nanoprecipitates within the martensitic laths suggests that the creep strengthening produced by the Nb, V, Cr and N nanoprecipitates in the HDSN1 and HDSN2 steels is more effective at pinning dislocations at high temperature than that obtained in the HDSN3 steel by the V, Cr and N nanoprecipitates. However, the high amount of W in the HDSN3 steel enhances the solid solution strengthening at high temperatures, resulting in a similar high temperature strength for all HDSN steels.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On creep of trapped flux near T c in MgB 2 and CaKFe 4 As 4

Here, we present flux creep data taken at different temperatures on single crystals of known, ambient pressure, superconductors, CaKFe 4 As 4 and MgB 2 , taken using the protocol that is common for trapped flux measurements. Using our results, we show that the time dependence of the magnetic moment in H 3 S is remarkably similar to the magnetization relaxation rates observed in established superconductors at ambient pressure, where in the latter cases this can be unambiguously assigned to flux creep.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗