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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 793 records · Page 44
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Study on the Microstructure, Mechanical Properties and Corrosion Behavior of Mg-Zn-Ca Alloy Wire for Biomaterial Application

Due to their excellent biocompatibility and biodegradability, magnesium alloy wires have attracted much attention for biomaterial applications including orthopedic K-wires and sutures in wound closure. In this study, Mg-3Zn-0.2Ca alloy wires were prepared by cold drawing combined with proper intermediate annealing process. Microstructures, texture, mechanical properties and corrosion behavior of Mg-3Zn-0.2Ca alloy wire in a simulated body fluid were investigated. The results showed that the secondary phase and average grain size of the Mg-3Zn-0.2Ca alloy were refined in comparison with the as-extruded alloy and a strong (0002)<10-10>//DD basal fiber texture system was formed after multi-pass cold drawing. After the annealing, most of the basal planes were tilted to the drawing direction (DD) by about 35°, presenting the characteristics of random texture, and the texture intensity decreased. The as-annealed wire shows good mechanical properties with the ultimate tensile strength (UTS), yield strength (YS) and elongation of 253 ± 8.5 MPa, 212 ± 11.3 MPa and 9.2 ± 0.9%, respectively. Electrochemical and hydrogen evolution measurements showed that the corrosion resistance of the Mg-3Zn-0.2Ca alloy wire was improved after the annealing. The immersion test indicated that the Mg-3Zn-0.2Ca wire exhibited uniform corrosion behavior during the initial period of immersion, but then exhibited local corrosion behavior.

36 MATERIALS SCIENCE↗
DOE OSTI2018

X-ray Diffraction Investigation of Annealing Behavior of Peened Surface Deformation Layer on Precipitation Hardening Stainless Steel

In order to investigate the recrystallization behavior of peened surface deformation layer of precipitation hardening stainless steel, a classic x-ray diffraction line profile analysis, Voigt method, was carried out on peened 17-4PH with different isothermal annealing temperatures. The activation energy of domain boundary migration (Q{sub a}) and the activation energy of microstrain relaxation (Q{sub b}) were calculated by regression analysis in different annealing temperature conditions. The results show that the value of Q{sub a} decreases with annealing temperature increasing, which is due to the influence of precipitation (ε-Cu) size on the movements of grain and subgrain boundaries. The maximum growth rate of ε-Cu particles occurs during 400 to 500 °C interval. Compared with growth behavior of domain size, microstrain relaxation behavior is less sensitive to precipitation particle size. The effects of annealing temperature and time on dislocation density are both significant when annealing temperature is lower than 500 °C. However, the effect of annealing temperature on dislocation density becomes insignificant when annealing temperature is higher than 500 °C. 300 °C annealing temperature only leads to the microstrain relaxation but nearly cannot lead to the domain size growth even if prolonging annealing time. Microstructure enhancement effect still exists in plastic deformation layer when 300 °C annealing temperature lasts for 60 min but nearly disappears when 600 °C annealing temperature lasts for 20 min.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Prediction of the Stress–Strain Behavior of Open-Cell Aluminum Foam under Compressive Loading and the Effects of Various RVE Boundary Conditions

The prediction of the mechanical behavior of metallic foams with realistic microstructure and the effects of various boundary conditions on the mechanical behavior is an important and challenging issue in modeling representative volume elements (RVEs). A numerical investigation is conducted to determine the effects of various boundary conditions and cell wall cross sections on the compressive mechanical properties of aluminum foam, including the stiffness, plateau stress and onset strain of densification. The open-cell AA6101-T6 aluminum foam Duocel is used in the analyses in this study. Geometrical characteristics including the cell size, foam relative density, and cross-sectional shape and thickness of the cell walls are extracted from images of the foam. Then, the obtained foam microstructure is analyzed as a 2D model. The ligaments are modeled as shear deformable beams with elastic-plastic material behavior. To prevent interpenetration of the nodes and walls inside the cells with large deformations, self-contact-type frictionless interaction is stipulated between the internal surfaces. Sensitivity analyses are performed using several boundary conditions and cells wall cross-sectional shapes. The predicted results from the finite element analyses are compared with the experimental results. Finally, the most appropriate boundary conditions, leading to more consistent results with the experimental data, are introduced.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Electrochemical Behavior Assessment of As-Cast Mg-Y-RE-Zr Alloy in Phosphate Buffer Solutions (X Na{sub 3}PO{sub 4} + Y Na{sub 2}HPO{sub 4}) Using Electrochemical Impedance Spectroscopy and Mott–Schottky Techniques

In the present study, electrochemical behavior of as-cast Mg-Y-RE-Zr alloy (RE: rare-earth alloying elements) was investigated using electrochemical tests in phosphate buffer solutions (X Na{sub 3}PO{sub 4} + Y Na{sub 2}HPO{sub 4}). X-ray diffraction techniques and Scanning electron microscopy equipped with energy dispersive x-ray spectroscopy were used to investigate the microstructure and phases of the experimental alloy. Different electrochemical tests such as potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS) and Mott–Schottky (M–S) analysis were carried out in order to study the electrochemical behavior of the experimental alloy in phosphate buffer solutions. The PDP curves and EIS measurements indicated that the passive behavior of the as-cast Mg-Y-RE-Zr alloy in phosphate buffer solutions was weakened by an increase in the pH, which is related to formation of an imperfect and less protective passive layer on the alloy surface. The presence of the insoluble zirconium particles along with high number of intermetallic phases of RE elements mainly Mg{sub 24}Y{sub 5} in the magnesium matrix can deteriorate the corrosion performance of the alloy by disrupting the protective passive layer that is formed at pH values over 11. These insoluble zirconium particles embedded in the matrix can detrimentally influence the passivation. The M–S analysis revealed that the formed passive layers on Mg-Y-RE-Zr alloy behaved as an n-type semiconductor. An increase in donor concentration accompanying solutions of higher alkalinity is thought to result in the formation of a less resistive passive layer.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Corrosion Behavior of Wire Electrical Discharge Machined Surfaces of P91 Steel

The extensive usage of P91 steel in certain reactor components requires its precision fabrication by wire electrical discharge machining (WEDM). The WEDM cut surfaces consist of primarily re-melted and solidified layer (recast layer) of 2-8 µm. The recast layer is a result of fast removal of heat by unaffected metallic substrate and dielectric medium leading to rapid cooling. The WEDM surface is expected to affect the component performance in terms of its corrosion properties. The microstructural changes taking place due to EDM cutting of P91 steel bring about a drastic change in the electrochemical response of surface as compared to that for bulk P91 steel. The surface microstructure is shown to alter the passivation behavior and resistance to localized corrosion. Electrochemical polarization studies were done to evaluate passivation, pitting and intergranular corrosion (IGC) behavior and field emission gun—scanning electron microscopy was used for microstructural characterization of P91 steel surfaces. The passivation behavior for P91 steel WEDM cut surfaces was better than that for diamond polished surface. But pitting corrosion resistance decreased for the P91 steel WEDM surface which is a result of inhomogeneities in the microstructure of recast layer. The IGC resistance though increased due to the decreased grain size in the surface layer.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Microstructure and Ratcheting Behavior of Additive Manufactured 4043 Aluminum Alloy

In this paper, 4043 aluminum alloy was printed using additive manufacturing (AM) with robot cold metal transfer (CMT) technology. The microstructure and mechanical properties of different parts, including the bottom, middle and upper portions of the printed AM 4043 aluminum alloy, were analyzed. Ratcheting tests were performed using an asymmetric load, and the tensile properties of the pre-ratcheting and un-ratcheted specimens were tested. The results indicate that the dendrites in the middle region are larger than those at the top and bottom regions and that the coarse microstructure associated with the interlayer junction resulted in the decline of the mechanical properties. The tensile strength of the AM specimens is 165 MPa, and the yield strength is 50 MPa. The printed 4043 aluminum alloy exhibits mechanical properties similar to those for conventional cast and welded aluminum alloys. The ratcheting behavior indicates that an increase in the mean stress or stress amplitude leads to an increase in the ratcheting strain, and the accumulation of ratcheting strain causes plastic damage to the materials. Pre-ratcheting behavior causes the tensile and yield strengths to increase compared to the behavior of the un-ratcheted specimens.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Variation of the Corrosion Behavior Prior to Crack Initiation of E690 Steel Fatigued in Simulated Seawater with Various Cyclic Stress Levels

The electrochemical process and corrosion behavior prior to crack initiation of E690 steel fatigued in simulated seawater are investigated under different cyclic stress levels by methods of electrochemical impedance spectroscopy, cyclic current response, electrochemical noise and morphology observation. The results show that the electrochemical behavior changes with the peak stress of cyclic loading and the corrosion behavior transforms as the peak stress increases over the proof strength. The charge transfer resistance (R{sub ct}) decreases with elevated peak stress. Continuous decreasing R{sub ct} with cycling number under peak stress of 1.02 σ{sub p0.2} indicates that continuous fresh metal induced by work-softening is exposed to the seawater, which is also proved by cyclic current response induced by cyclic stress and contact angle test. As a result, the corrosion type of E690 steel changes from general corrosion to pitting corrosion with the peak stress close to and above the proof strength. That induces the corrosion fatigue crack initiation mechanism to change correspondingly.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Effect of Tempering and Rolling on Fatigue Crack Growth Behavior of Modified 9Cr-1Mo Steel

In the present work, fatigue crack growth (FCG) behavior of modified 9Cr-1Mo steel has been investigated near fatigue threshold and Paris regime at room temperature (RT) and 650 °C. The modified 9Cr-1Mo steel was subjected to normalizing at 1050 °C followed by tempering (650-750 °C) and warm rolling at 550 °C followed by tempering in order to improve its precipitation state and refine microstructure. The microstructural parameters such as grain size, block size, lath width and precipitate size were examined and correlated with FCG and tensile properties of investigated samples. The results showed that decreasing tempering temperature significantly reduces the fatigue threshold at RT while increases the yield strength at elevated temperature (i.e., 650 °C). Increase in fatigue threshold is found to increase with the increase in block size, whereas high density of fine precipitates contributed the high temperature strength. The FCG rate in Paris regime was less affected by heat treatment and rolling process at RT. However, rolled sample tested at 650 °C shows a decrease in FCG rate as compared to heat-treated samples. In terms of higher FCG resistance and yield strength, warm rolling followed by tempering at low temperature (i.e., 700 °C) can be considered optimum. For the numerical simulation of FCG behavior, extended finite element method (XFEM) along with Paris law has been implemented in ABAQUS using python script. The simulated FCG behavior is found in good agreement with the experimental results.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Constitutive Modeling for Hot Deformation Behavior of Al-5083 + SiC Composite

In the present research, isothermal hot deformation behavior of aluminum 5083 alloy + 15 (wt.%) SiC composite was obtained through compression test on INSTRON 8801 universal tensile testing machine (UTM) under a wide temperature range of 473-773 K and strain rate range of 0.01-10 s{sup −1}. The experimental true stress–strain data were employed to establish constitutive equations based on modified Johnson–Cook (JC) model and modified Zerilli–Armstrong (ZA) model to predict the hot flow behavior of the composite. The flow stress values obtained from these two models were plotted against the experimental flow curves to check the accuracy of these models. Suitability of the models was evaluated by comparing correlation coefficient (R), average absolute relative error and relative errors of prediction. The results show that the hot flow stresses of the present material depend on temperature and strain rate significantly. Both the models give good description of the hot deformation behavior of the composite. The prediction accuracy is found to be higher for modified ZA model compared to modified JC model, though the number of materials constants involved and time needed to evaluate them to establish the model are lower for modified JC model.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Dry Sliding Wear Behavior and Mechanism of a Hot-Dip Aluminized Steel as a Function of Sliding Velocity

Fe-Al intermetallic coatings were prepared on AISI 1045 steel by hot-dip aluminizing and subsequent high-temperature diffusion. The dry sliding wear tests were performed for the aluminized steel with various substrate hardnesses in the velocity range of 0.75-4 m/s on a pin-on-disk configuration. The dry sliding wear behavior and mechanisms of the aluminized steel under various velocities were explored. It was found that the wear rate decreased substantially with an increase in sliding velocity from 0.75 to 1.5 and then slightly varied in the velocity range of 1.5-4 m/s. The wear behavior and mechanisms of the aluminized steel were noticed to be closely related with tribo-layers. As tribo-layers contained more oxides with Fe{sub 2}O{sub 3}, the wear resistance of the aluminized steel was markedly improved because of their protective function. The substrate hardness also changed the wear behavior of the aluminized steel by affecting the stability of tribo-layers because the substrate hardness was inversely proportional to the thermal stability of the substrate structure. Under a low velocity of 0.75 m/s, adhesive wear and abrasive wear prevailed owing to the metal-on-metal contact, resulting in a higher wear rate. At 1.5-4 m/s, mild oxidative wear prevailed due to the stable existence of tribo-oxides layers. However, at 1.5 and 4 m/s for the substrate hardness of 45 HRC, the wear rate was slightly increased because the protection of tribo-layers was weakened by a double-layered structure or more cracks in tribo-layers and coatings.

36 MATERIALS SCIENCE↗
DOE OSTI2019

An Integrated Numerical Method to Predict the Strain Sensing Behavior of Flexible Conductive Fibers under Electric–Thermal Conditions

Flexible conductive textiles have attracted an increasing amount of attention due to being flexible and stretchable with multi-functions, in addition to the strain sensing function. In this paper, an integrated numerical method is established to predict the strain sensing behavior of PPy-coated flexible conductive fibers. Based on our previous investigation on the strain sensing behavior of the PPy-coated elastic conductive fibers, it has been known that the main strain sensing mechanisms of the conductive fibers are micro-cracks opening under stretching and closing under unloading. Therefore, in the numerical approach, extended finite element method is used to simulate the multi-crack initiation and propagation. Then, by establishing a representative element model including a single crack, the resistance variation with the increase in crack width/depth can be obtained using the electric–thermal package in ABAQUS software. Combining the relationship between crack width and strain, the relationship between fractional increment in resistance (ΔR/R{sub 0}) and the strain can be obtained. The prediction of the fractional increment in resistance (ΔR/R{sub 0}) versus strain is consistent with the experimental results of PPy-coated Lycra fibers. The new integrated method is further verified by experimental results of PPy-coated XLA fibers, showing that the integrated numerical approach can capture the complicated strain sensing mechanisms of PPy-coated elastic fibers and predict the strain sensing behavior of flexible conductive fibers. This approach will make it possible to shorten the period, and reduce the cost in R&D of the PPy-coated electrically conductive fibers, comparing with the corresponding experimental work.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Nanoindentation Creep Behavior of CoCrFeNiMn High-Entropy Alloy under Different High-Pressure Torsion Deformations

CoCrFeNiMn high-entropy alloy (HEA) has gained increasing attention in recent years. In this work, CoCrFeNiMn HEA was prepared by arc melting and casting method; and high-pressure torsion (HPT) technology was used to refine the grains. A series of nanoindentation experiments was used to investigate the effect of different loading rates and deformations on the nanoindentation creep behavior of the CoCrFeNiMn HEA. The results show that the grain size of the CoCrFeNiMn HEA refines to the nanoscale after HPT. However, grain refinement is not obvious with further increasing HPT rotation. The loading rate and HPT rotations have an obvious effect on the nanoindentation creep behaviors of the CoCrFeNiMn HEA. The creep behaviors of the as-cast and HPT-treated CoCrFeNiMn HEA may be controlled by dislocations and the collective effect of GB sliding and dislocations, respectively.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Characterization and Modeling of Hot Deformation Behavior of a Copper-Bearing High-Strength Low-Carbon Steel Microalloyed with Nb

This study investigates hot deformation behavior of a newly developed Cu-bearing high-strength low-carbon steel microalloyed with Nb (Nb-HSLC). A computational method based on experimental data was employed to design the chemical composition of the alloy. Compression tests were carried out in the temperature range of 850-1100 °C as well as strain rates of 0.001-10 s{sup −1} using BAHR Dil 805 A/D thermo-analyzer equipment. The Arrhenius-type constitutive equations were used to model the hot working behavior of the designed steel. Effects of friction and temperature rise during deformation were corrected to obtain the actual stresses. The results showed that the peak flow stress was increased with increasing Zener–Hollomon parameter. The obtained flow curves at strain rates lower than 0.1 s{sup −1} and temperatures above 950 °C represented the typical dynamic recrystallization (DRX) behavior, while the flow curves at temperatures lower than 950 °C at all strain rates were associated with continuous strain hardening. This feature is in good agreement with the precipitation temperature range of Nb(C, N) particles, i.e., 800-1000 °C. Moreover, the flow curves showed the serrations during hot deformation at strain rates of 0.001 and 0.01 s{sup −1}, indicating that the dynamic strain aging (DSA) phenomenon occurred at low strain rates. The best fit between “peak stress” and “deformation conditions” was obtained by a hyperbolic sine-type equation (R{sup 2} = 0.993). Therefore, the average activation energy was determined as 348 kJ mol{sup −1}. The agreement between the achieved model and experimental flow data was verified using the results of additional tests at a strain rate of 5 s{sup −1}. The maximum difference between the measured and predicted “peak stresses” was calculated as 5 Mpa.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Corrosion and Tribocorrosion Behavior of Ti-B{sub 4}C Composites Joined with TiCuNi Brazing Alloy

Corrosion behavior of joined Ti-B{sub 4}C composites was evaluated in 9 g/L NaCl solution using cyclic polarization and electrochemical impedance spectroscopy. Tribocorrosion behavior was investigated by sliding against an alumina ball under open-circuit potential and potentiodynamic polarization. The results showed that joining did not negatively affect the corrosion behavior of the composites. Regarding tribocorrosion, while joining did not significantly influence the coefficient of friction and total wear volume loss, it resulted in slightly increased electrochemical activity under sliding. These results showed that brazing may be considered as a simple and low-cost technique for joining Ti-B{sub 4}C composites to be operated in tribocorrosive environments.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Strain-Hardening Behavior of Dual-Phase Steel under Multistress States

The complexity and nonuniformity of microdeformation in high-strength dual-phase (DP) steels make it difficult to accurately predict the deformation processes in stamping. Here, in situ experiments under three kinds of stress states and a crystal plasticity finite element (CPFE) model were used to predict the strain-hardening behavior of DP steel. The microdeformation in various deformation stages was extracted from metallographs captured during in situ experiments to calculate the strain partitioning functions of each phase. Then, the multistress state mechanical behavior of DP steel was calculated based on the CPFE model combined with the strain partitioning functions of ferrite and martensite. The calculation results showed that (1) the CPFE model could accurately describe the load–stroke curves of the three experiments and that (2) the stress state had a significant effect on the strain partition ratio and the initial critical resolved shear stress of the material. In addition, the stress–strain curves of DP800 steel were predicted under six stress states; these curves did not coincide and had obvious deviations. Finally, the activity of the grain slip systems and the dislocation evolution were analyzed and discussed to predict the microdeformation and stress state effects on strain-hardening behavior.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Effects of Environmental Conditions on the Mechanical and Degradation Behavior of Polyurethane Foam Subjected to Various Deformation Histories

Since its development, polyurethane foam (PUF) has been widely used as an insulator, including in the marine industry. Liquefied natural gas (LNG) carriers have the highest market share in the LNG-related shipbuilding industry. PUF is used as an insulator in membrane-type cargo containment systems (CCSs) as one of the most important components of LNG carriers. Because PUF is subjected to constant load and deformation when used in insulation for LNG CCSs and is exposed to the cryogenics of the seawater environment for extended times, it is essential to evaluate the mechanical behavior of PUF in such environments. In this study, to investigate the effects of applying an initial strain and of immersion in various media on the mechanical properties of PUF, compression tests were carried out at ambient and cryogenic temperature using a universal testing machine. The mechanical behavior of PUF after deformation recovery upon subjection to various initial strain levels was estimated experimentally. In addition, the microstructure of the PUF specimen prior to testing was analyzed to investigate the effects of the initial strain level and immersion in different media on the mechanical behavior of PUF.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Impact of Cryogenic Treatment on Mechanical Behavior and Microstructure of Ti-6Al-4V ELI Biomaterial

Ti-6Al-4V with its ELI variant is a potential biomaterial for structural implants. However, its poor resistance to plastic shearing results in poor tribological properties that hinders its widespread use in biomedical implants. Cryogenic treatment being an established technique for improving wear resistance and other mechanical properties of ferrous materials is applied on Ti-6Al-4V ELI alloy. To ensure comprehensive investigations, the widely studied microstructures of Ti-6Al-4V ELI, i.e., lamellar, martensite, two variants of bimodal and mill annealed are considered in this work. Deep cryogenic treatment at the soaking temperature (− 196 °C) for 24 h soaking time followed by tempering has been applied. The impact of cryogenic treatment has been assessed in terms of changes in the mechanical behavior including wear resistance, hardness, tensile properties and impact strength. The alterations in mechanical behavior due to cryogenic treatment are correlated with microstructure evolution. Cryogenic treatment has caused significant improvement in mechanical behavior of Ti-6Al-4V ELI alloy.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Constitutive Modeling for Hot Working Behavior of SP-700 Titanium Alloy

In this paper, the constitutive modeling and hot deformation behavior of SP-700 titanium alloy was investigated by performing isothermal hot compression tests in the temperature range of 700-950 °C and strain rates of 0.001, 0.1, and 1 s{sup −1}. The flow curves of the alloy indicated that the yield point phenomenon occurs at strain rates of 0.1 and 1 s{sup −1}. The friction, adiabatic heating, and stroke-rate controlling effects were eliminated from the raw data. Then, three types of phenomenological constitutive models, considering the compensation of strain, were used to predict the flow stresses of the alloy. The correlation coefficients (R{sup 2}) of the measured and predicted results for the power-law, hyperbolic-sine law, and dynamic softening models were found to be 0.9790, 0.9883, and 0.9877, respectively. The corresponding average absolute relative errors (AARE) were 6.3, 5.9, and 7.45%, respectively. The flow softening behavior of SP-700 alloy was modeled using the combined hyperbolic-sine law and dynamic softening model approach. The predicted flow stresses were in a good agreement with the experimental data, indicated that the developed models can accurately characterize flow behavior of the alloy. In addition, the strain-rate sensitivity (m) distribution map of the alloy was obtained by plotting the m-value against temperature and strain rate in the form of a contour map. There was the maximum of m-value (0.36) in the temperature ranges of 700-715 and 837-875 °C, and strain rates of 0.001-0.006 s{sup −1}. The microstructure of hot deformed at 700 °C mainly consists of globularized and lamellar α phase, while dynamic globularization was completed at 800 °C. The hot deformation activation energy of the alloy in α/β region (305.5 kJ mol{sup −1}) was higher than that in single-phase β region (165.2 kJ mol{sup −1}) due to the globularization of lamellar α.

36 MATERIALS SCIENCE↗