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At least 793 records · Page 44

Exploring the High Energy Universe: GLAST Mission and Science

GLAST, the Gamma-Ray Large Area Space Telescope, is NASA's next-generation high-energy gamma-ray satellite scheduled for launch in Autumn 2007. GLAST will allow measurements of cosmic gamma-ray sources in t he 10 MeV to 100 GeV energy band to be made with unprecedented sensi tivity. Amongst its key scientific objectives are to understand part icle acceleration in Active Galactic Nuclei, Pulsars and Supernovae Remnants, to provide high resolution measurements of unidentified ga mma-ray sources, to study transient high energy emission from objects such as gamma-ray bursts, and to probe Dark Matter and the early Uni verse. Dr. McEnery will present an overview of the GLAST mission and its scientific goals.

McEnery, Julie↗

Commercial Smallsat Data Acquisition Program: Airbus U.S. Synthetic Aperture Radar Quality Assessment Summary

Quality assessment of the Airbus X-band Synthetic Aperture Radar (SAR) satellite products was conducted by the Commercial Smallsat Data Acquisition (CSDA) program’s radar subject matter experts, following the Joint NASA/ESA (European Space Agency) assessment draft guidelines. All three Airbus SAR spacecraft (TerraSAR-X, TanDEM-X, and PAZ) are based on the TerraSAR-X platform, and each have an active phased array antenna that is 4.8 x 0.7 m in the along-track and cross-track dimensions, respectively. TerraSAR-X and TanDEM-X are in a helical orbit, creating a bistatic imaging geometry, in addition to being capable of independent monostatic observations. The PAZ mission follows TerraSAR-X and TanDEM-X in the same 11-day orbit with a 5.5-day lag. TerraSAR-X and TanDEM-X are designed, developed, and operated through a Public-Private Partnership, while PAZ is a dual-use mission (civil and defense agencies), funded and owned by the Spanish Ministry of Defense and managed by Hisdesat (Hisdesat Servicios Estratégicos, S.A.), a Spanish private communications company. The assessment presented in this document is divided into two main parts: documentation review and the assessment of test datasets. The documentation review in sections 2.1 through 2.4 includes the assessment of the Airbus documentation provided to the CSDA evaluation team. The grading of these documents is given in columns 1-4 of the maturity matrix shown in section 1.1. Section 2.5 summarizes the evaluation performed by NASA using the data purchased through the CSDA program. The grading for this is given in the last column of the maturity matrix. Section 3 provides more detailed explanations on the methods and the results of the data analysis performed by NASA. Only the documents provided by Airbus for the evaluation were considered for the review. Additional documentation with more detailed description of the calibration and validation procedures may be available online but were not considered for this evaluation. The product information provided in the available documentation (RD-1, RD-2) and the product metadata together provided adequate information to work with the data. The product details in the metadata included the required information to work with the data in the common XML file format. Metrological traceability documentation was not provided to CSDA. All relevant characterization of the SAR system and data were provided, and the metadata include all relevant ancillary information. Documentation provided to CSDA included limited pre-flight and post-launch calibration information.

Batuhan Osmanoglu↗

A Systematic Evidence Based Performance Approach to Regulation of Nuclear Sites in England and Wales - 20058

The Environment Agency for England has developed a systematic evidence-based approach to pursue our strategic environmental objectives for the regulation of nuclear sites. We use an annual evidence review process to ensure effective and efficient targeting of limited resources to achieve those objectives. Over the last 8 years, we have been developing and refining this approach to ensure risk-based and value driven regulation. The approach comprises nuclear site and nuclear sector review processes known as Site Environment Review (SER) and Nuclear Environment Review (NER). This approach complements our regulation of nuclear site permit holders under the Environmental Permitting Regulations (EPR). We deliver our regulation of nuclear sites in England and Wales alongside the Office for Nuclear Regulation. The SER process involves the lead regulator for each nuclear site assessing the permit holder's environmental performance across 14 themes, set within the context of the site's main activities and associated waste disposals. Our themes include environmental leadership, resources and climate change, radioactive waste management, facility management and decommissioning, groundwater, and environmental radiological protection. We use evidence from site inspections and working within our subject matter groups to grade current and predicted future environmental performance. We are particularly interested in sustainability and the application of Best Available Techniques (BAT) to prevent the creation, and minimise the disposal, of radioactive wastes. We use risk analysis (strengths, weaknesses, threats and opportunities) to examine performance against our strategic environmental objectives, which are set out, in our 5-year Nuclear Delivery Plan (NDP). The output supports the targeting of our resources at each nuclear site. We consult the relevant permit holders on the SER priorities and use their feedback to refine our plans. We expect all permit holders to take account of our priorities when considering their own programmes of work, objectives and plans. The NER process brings together what we learn and achieve through regulation across the sector. It provides input to planning priorities, supported by qualitative and semi-quantitative evidence. It covers the 28 nuclear sites in England and Wales and spans the same 14 environmental themes. During the process we collate, compile and summarise evidence from the SERs and other sources such as inspection reports and evidence from our other nuclear work programmes. The output is the NER annual report. This provides a snapshot of the status of the nuclear sector and gives insights to enable us to regulate more efficiently and effectively. It also takes account of cross-cutting issues and risks such as changes in international standards, domestic policy, regulatory framework, domestic standards and guidance, learning from experience such as incidents, events and good practice, and innovation, research and development. It provides graphics that illustrate the grading of environmental performance for the nuclear sector across the fourteen environmental themes. This analysis allows benchmarking of nuclear site's environmental performance and the visualisation provides a convenient comparison of performance across themes, sites, and over time. We use this intelligence to inform our investment in training and development of our staff, and our cross-cutting engagement on strategic issues with government, the Nuclear Decommissioning Authority (NDA) and other corporate organisations. Adopting this approach can provide benefits with organisational reputation, stakeholder participation and ensuring value from the public investment. This paper describes the history of the SER/NER process, a selection of outputs from the process and ideas for improvement. The paper will be of interest to other regulators and organisations across the world that are interested in supporting continuous improvement. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Real-space observation of fluctuating antiferromagnetic domains

Magnetic domains play a fundamental role in physics of magnetism and its technological applications. Dynamics of antiferromagnetic domains is poorly understood, although antiferromagnets are expected to be extensively used in future electronic devices wherein it determines the stability and operational speed. Dynamics of antiferromagnets also features prominently in the studies of topological quantum matter. Real-space imaging of fluctuating antiferromagnetic domains is therefore highly desired but has never been demonstrated. We use coherent x-ray diffraction to obtain videos of fluctuating micrometer-scale antiferromagnetic domains in Ni 2 MnTeO 6 on time scales from 10 -1 to 10 3 s. In the collinear phase, thermally activated domain wall motion is observed in the vicinity of the Néel temperature. Unexpectedly, the fluctuations persist through the full range of the higher-temperature helical phase. These observations illustrate the high potential significance of the dynamic domain imaging in phase transition studies and in magnetic device research.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Nanostructure‐Derived Antireflectivity in Leafhopper Brochosomes

Understanding how insect‐derived biomaterials interact with light has led to new advances and interdisciplinary insights in entomology and physics. Leafhoppers are insects that coat themselves with highly ordered biological nanostructures known as brochosomes. Brochosomes are thought to provide a range of protective properties to leafhoppers, such as hydrophobicity and antireflectivity, which has inspired the development of synthetic brochosomes that mimic their structures. Despite recent progress, the high antireflective properties of brochosome structures are not fully understood. Herein, a combination of experiments and computational modeling is used to understand the structure‐, material‐, and polarization‐dependent optical properties of brochosomes modeled on the geometries found in three leafhopper species. The results qualitatively represent that light interference interaction with nanostructures naturally occurring in brochosomes is responsible for the spectral tuning and the asymmetric line shape of the reflectance spectra. Whereas prior work has focused on the computational modeling of idealized pitted particles, this work shows that light–matter interactions with brochosome structures can be tuned by varying the geometry of their cage‐like nanoscale features and by changing the arrangement of multiparticle assemblies. Broadly, this work establishes principles for the guided design of new optically active materials inspired by these unique insect nanostructures.

Banerjee, Progna↗

Long-term nitrogen loading alleviates phosphorus limitation in terrestrial ecosystems

Increased human-derived nitrogen (N) deposition to terrestrial ecosystems has resulted in widespread phosphorus (P) limitation of net primary productivity. However, it remains unclear if and how N-induced P limitation varies over time. Soil extracellular phosphatases catalyze the hydrolysis of P from soil organic matter, an important adaptive mechanism for ecosystems to cope with N-induced P limitation. In this study we show, using a meta-analysis of 140 studies and 668 observations worldwide, that N stimulation of soil phosphatase activity diminishes over time. Whereas short-term N loading (≤5 years) significantly increased soil phosphatase activity by 28%, long-term N loading had no significant effect. Nitrogen loading did not affect soil available P and total P content in either short- or long-term studies. Together, these results suggest that N-induced P limitation in ecosystems is alleviated in the long-term through the initial stimulation of soil phosphatase activity, thereby securing P supply to support plant growth. Our results suggest that increases in terrestrial carbon uptake due to ongoing anthropogenic N loading may be greater than previously thought.

59 BASIC BIOLOGICAL SCIENCES↗

Directing Traffic in the Rhizosphere: How Phage and Fauna Shape the Flow and Fate of Root Carbon through Microbial Pathways

The rhizosphere, the portion of soil directly influenced by plant roots, is an area of great biological activity and intense carbon (C) cycling. Interactions among the residents of the rhizosphere, such as bacteria, fungi, viruses, and fauna, result in transformation and transfer C from root exudates and root debris to biomass and developing soil organic matter. The primary object of this research project was to explore the complex interactions controlling C flow in the rhizosphere and the response of these interactions to soil water conditions. We used stable isotope techniques combined with molecular analyses to observe the flow of C as it is fixed by plants from the atmosphere, deposited into the soil through plant roots, and exchanged through multiple pathways of the soil food web. This technical report summarizes the achievements of this project from field, greenhouse, and lab experiments.

54 ENVIRONMENTAL SCIENCES↗

Development and Optimization of a Multi-Functional SCR-DPF Aftertreatment System for Heavy-Duty NOX and Soot Emission Reduction

The objective of this project is to develop a strategy for the integration of catalytic NOX emission control and particulate matter emission control into a single device for the successful application to heavy-duty on-road diesel engine exhaust aftertreatment. The critical attributes of such a device, for successful application to PACCAR fleet, are as follows: 1. Must have sufficient filtration efficiency and successfully demonstrate soot management strategies (i.e., oxidation) to be economically attractive and regulatory compliant for particulate matter abatement. 2. In particular, the integrated device must retain sufficiently high soot oxidation capacity with NO2 (i.e., passive soot oxidation) across an applicable engine test cycle to be economically attractive. 3. Must exhibit sufficient catalytic NOX reduction activity in an economically-attractive fashion that is regulatory compliant.

54 ENVIRONMENTAL SCIENCES↗

Polyphenylquinoxalines via Aromatic Nucleophilic Displacement

Polyphenylquinoxalines are produced by an aromatic nucleophilic displacement reaction involving an activated aromatic dihalide with an appropriate quinoxaline monomer. Polyphenylquinoxalines are high temperature thermoplastics used as adhesives, coatings, films and composite matrices. The novelty of this invention is threefold: (1) some of the quinoxaline monomers are new compositions of matter; (2) the phenylquinoxaline polymers which are the end products of the invention are new compositions of matter; and (3) the method of forming the polymers is novel, replacing a more costly prior art process, which is also limited in the kinds of products prepared therefrom.

Hergenrother, Paul M.↗

Theoretical and Observational Studies of the Central Engines of AGN

In Active Galactic Nuclei (AGN) the luminosity is so intense that the effect of radiation pressure on a particle may exceed the gravitational attraction. It was shown that when such luminosities are reached, relatively cold (not completely ionized) thermal matter clouds may form in the central engines of AGN, where most of the luminosity originates. We show that the spectrum of emission from cold clouds embedded in hot relativistic matter is similar to the observed spectrum. We also show that within the hot relativistic matter, cold matter moves faster than the speed of sound or the Alfven speed, and shocks form. The shocks provide a mechanism by which a localized perturbation can propagate throughout the central engine. The shocked matter can emit the observed luminosity, and can explain the flux and spectral variability. It may also provide an efficient mechanism for the outward transfer of angular momentum and provide the outward flow of winds. With observations from X-ray satellites, emission features from the cold and hot matter may be revealed. Our analysis of X-ray data from the Seyfert 1 galaxy MCG - 6-30-15 over five years using detectors on the Ginga and Rosat satellites, revealed some interesting variable features. A source with hot matter emits non-thermal radiation which is Compton reflected from cold matter and then absorbed by warm (partially ionized) absorbing matter in the first model, which can be fit to the data if both the cold and warm absorbers are near the central engine. An alternative model in which the emission from the hot matter is partially covered by very warm matter (in which all elements except Iron are mostly ionized) is also successful. In this model the cold and warm matter may be at distances of up to 100 times the size of the central engine, well within the region where broad optical lines are produced. The flux variability is more naturally explained by the second model. Our results support the existence of cold matter in, or near, the central engine of MCG -6-30-15. Cold matter in the central engine, and evidence of the effects of shocks, is probably forthcoming with future X-ray satellites.

Sivron, Ran↗

The Badhwar-O'Neill 2020 Model

The Badhwar-O'Neill (BON) model has been used for some time to describe the galactic cosmic ray (GCR) environment encountered in deep space by astronauts and sensitive electronics. The most recent version of the model, BON2014, was calibrated to available measurements to reduce model errors for particles and energies of significance to astronaut exposure. Although subsequent studies showed the model to be reasonably accurate for such applications, modifications to the sunspot number (SSN) classification system and a large number of new high precision measurements suggested the need to develop an improved and more capable model. In this work, the BON2020 model is described. The new model relies on daily integral flux from the Advanced Composition Explorer Cosmic Ray Isotope Spectrometer (ACE/CRIS) to describe solar activity. For time periods not covered by ACE/CRIS, the updated international SSN database is used. Parameters in the new model are calibrated to available data, which includes the new Alpha Magnetic Spectrometer (AMS-02) and Payload for Antimatter Matter Exploration and Light-nuclei Astrophysics (PAMELA) high-precision measurements. It is found that the BON2020 model is a significant improvement over BON2014. Systematic errors associated with BON2014 have been removed. The average relative error of the BON2020 model compared to all available measurements is found to be <1%, and BON2020 is found to be within ±15% of a large fraction of the available measurements (26,269 of 27,646 → 95%).

Slaba, Tony C.↗

The Badhwar-O'Neill 2020 Model

The Badhwar-O’Neill (BON) model has been used for some time to describe the galactic cosmic ray (GCR) environment encountered in deep space by astronauts and sensitive electronics. The most recent version of the model, BON2014, was calibrated to available measurements to reduce model errors for particles and energies of significance to astronaut exposure. Although subsequent studies showed the model to be reasonably accurate for such applications, modifications to the sunspot number (SSN) classification system and a large number of new high-precision measurements suggested the need to develop an improved and more capable model. In this work, the BON2020 model is described. The new model relies on daily integral flux from the Advanced Composition Explorer Cosmic Ray Isotope Spectrometer (ACE/CRIS) to describe solar activity. For time periods not covered by ACE/CRIS, the updated international SSN database is used. Parameters in the new model are calibrated to available data, which includes the new Alpha Magnetic Spectrometer (AMS-02) and Payload for Antimatter Matter Exploration and Light-nuclei Astrophysics (PAMELA) high-precision measurements. It is found that the BON2020 model is a significant improvement over BON2014. Systematic errors associated with BON2014 have been removed. The average relative error of the BON2020 model compared to all available measurements is found to be <1%, and BON2020 is found to be within +15% of a large fraction of the available measurements (26,269 of 27,646  95%.

T C Slaba↗

Satellite-Assisted Particulate Matter (SAPM) for the Models, In situ, and Remote Sensing of Aerosols (MIRA) Working Group

Models, In situ, and Remote sensing of Aerosols (MIRA) is an international working group that provides a forum for collaborations amongst these three atmospheric aerosol communities. MIRA consists of a collection of interdisciplinary and independently funded Topic/Project groups with clear goals and generally characterized by requests for additional scientific data. The Satellite-Assisted Particulate Matter (SAPM) Topic group focuses on the study of fine particulate matter (PM2.5), as it is a major contributor to air pollution and negatively impacts human health. Our group aims to provide intercomparisons of various methods and techniques for estimating surface PM2.5 assisted by satellite remote sensors (passive and active), global aerosol models, and in situ aerosol measurements. The overall motivation of our work is to enhance PM2.5 coverage beyond in situ ground stations, which can be limited. In this presentation, we provide an overview of various PM2.5 estimation approaches by current SAPM team members, as each approach has its own strengths and limitations. One approach uses near-surface aerosol extinction retrievals from the spaceborne Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and an assumed value of mass extinction efficiency to derive PM2.5 concentrations (Toth et al 2019). A study using this method found a promising agreement (R=0.60; slope=0.89) with U.S. Environmental Protection Agency (EPA) in situ PM2.5 measurements over the contiguous United States (CONUS) for a 12-year (2007-2018) period (Toth et al 2022). In a different approach combining spaceborne lidar and a model, the Cloud Aerosol Transport System (CATS) lidar and Goddard Earth Observing System (GEOS) model are blended in an ensemble variational assimilation scheme to retrieve aerosol extinction and convert speciated mass concentrations to total PM2.5. A recent study (Matus et al in prep.) found agreement within 2 μg/m3 over the CONUS on the 2016 annual mean when compared to EPA ground-based measurements. Another study explored trends in city aerosol optical depth (AOD) from a spaceborne passive remote sensor, Moderate Resolution Imaging Spectroradiometer (MODIS), and found that these trends agree well with trends in city surface PM2.5, which provides confidence in the use of city AOD for city PM2.5 trend studies (Vohra et al 2021). In a follow-on study, steep and significant trends (~2.5 to 7.8% a-1) in AOD are found for several South Asian cities (e.g., Bangalore and Hyderabad), suggesting rapid growth in PM2.5 (Vohra et al 2022). Also in this presentation, we report results on our current collective SAPM study of India, a country that exhibits high levels of PM2.5 pollution. We show the temporal (i.e., seasonal) and spatial variability of PM2.5 over India using the CALIOP and CATS+model approaches, comparisons between the estimated PM2.5 from the retrieval schemes, and validation with in situ PM2.5 ground-based observations from the Central Pollution Control Board in India. This region provides us with an excellent case study to test our PM2.5 retrievals in heavily polluted scenes and over a complex and varying topography. The SAPM Topic group actively seeks international participants/collaborators in our group, including those working with in situ aerosol measurements (e.g., ACTRIS). We are interested in aerosol datasets in order to either improve our PM2.5 estimates from various approaches (e.g., using in situ mass scattering/absorption coefficient and aerosol hygroscopic properties for various aerosol species) and/or validate the PM2.5 estimates (e.g., using in situ ground-based PM2.5 concentrations).

Travis D Toth↗

Developing an Energy Service Interface Specification

Developing an Energy Service Interface (ESI) specification requires engaging a community of stakeholders including grid operators, Information and Communication Technology implementors, integrators, and finally standards bodies who will define an interface that respects and boundaries of ownership and roles of responsibility in order to activate millions of Distributed Energy Resource for the provision of grid services. By applying Interoperability Maturity Model Criteria and ESI principles to common grid-DER service use cases, the Grid Modernization Lab Consortium team will engage subject matter experts to develop a specification, with an eventual goal of informing development of ESI compliant profiles or standards. The ESI Specification is intended to specify the characteristics, attributes, or qualities that need to be addressed in ESI compliant standards or profiles. This includes addressing interoperability criteria and the service-performance style of the interface.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

X-Ray Polarization Measurement of the Gold Standard of Radio-Quiet Active Galactic Nuclei: NGC 1068

Context.NGC 1068 is the most observed radio-quiet active galactic nucleus (AGN) in polarimetry, yet its high-energy polarization has never been probed before due to a lack of dedicated polarimeters.Aims.Using the first X-ray polarimeter sensitive enough to measure the polarization of AGNs, we want to probe the orientation and geometric arrangement of (sub)parsec-scale matter around the X-ray source. Methods. We used the Imaging X-ray Polarimetry Explorer (IXPE) satellite to measure, for the first time, the 2–8 keV polarization of NGC 1068.We pointed IXPE at the target for a net exposure time of 1.15 Ms, in addition to using two Chandra snapshots of∼10 ks each in order to account for the potential impact of several ultraluminous X-ray sources (ULXs) within IXPE’s field of view. Results. We measured a 2–8 keV polarization degree of 12.4%±3.6% and an electric vector polarization angle of 101◦±8◦at a 68% confidence level. If we exclude the spectral region containing bright Fe K lines and other soft X-ray lines where depolarization occurs, the polarization fraction rises to 21.3%±6.7% in the 3.5–6.0 keV band, with a similar polarization angle. The observed polarization angle is found to be perpendicular to the parsec-scale radio jet. Using a combined Chandra and IXPE analysis plus multiwavelength constraints, we estimated that the circum nuclear“torus” may sustain a half-opening angle of 50–55◦(from the vertical axis of the system). Conclusions. Thanks to IXPE, we have measured the X-ray polarization of NGC 1068 and found comparable results, both in terms of the polarization angle orientation with respect to the radio jet and the torus half-opening angle, to the X-ray polarimetric measurement achieved for the other archetypal Compton-thick AGN: the Circinus galaxy. Probing the geometric arrangement of parsec-scale matter in extragalactic objects is now feasible thanks to X-ray polarimetry

active galaxies↗

High Spectral Resolution Datasets of in Situ Aquatic Inherent and Apparent Optical Properties

Light emerging from natural water bodies and measured by remote sensing radiometers contains information about the local type and concentrations of phytoplankton, non-algal particles and colored dissolved organic matter in the underlying waters. An increase in spectral resolution in forthcoming satellite and airborne remote sensing missions is expected to lead to new or improved capabilities to characterize aquatic ecosystems. Such upcoming missions include NASA’s Plankton, Aerosol, Cloud, ocean Ecosystem PACE Mission; the NASA Surface Biology and Geology observable mission; and NASA Airborne Visible / Infrared Imaging Spectrometer (AVIRIS) - Next Generation airborne missions. In anticipation of these missions, we present a dataset of geographically diverse, quality-controlled, high spectral resolution inherent and apparent optical property (IOP/AOP) aquatic data. The data are intended to be of use to increase our understanding of aquatic optical properties, to develop aquatic remote sensing data product algorithms, and to perform calibration and validation activities for forthcoming aquatic-focused imaging spectrometry missions. The dataset is comprised of contributions from several investigators and investigating teams collected over a range of geographic areas and water types, including inland water, estuaries and oceans. Specific in situ measurements include particulate absorption, particulate attenuation, non-algal particulate or detritus absorption, colored dissolved organic matter absorption, phytoplankton absorption, total absorption, total attenuation, particulate backscattering, total backscatter, remote sensing reflectance, and irradiance reflectance. The dataset can be downloaded from PANGAEA: (https://www.pangaea.de/TBD ).

K A Casey↗

One thousand soils for molecular understanding of belowground carbon cycling

While significant progress has been made in understanding global carbon (C) cycling, the mechanisms regulating belowground C fluxes and storage are still uncertain. New molecular technologies have the power to elucidate these processes, yet we have no widespread standardized implementation of molecular techniques. To address this gap, we introduce the Molecular Observation Network (MONet), a decadal vision from the Environmental Molecular Sciences Laboratory (EMSL), to develop a national network for understanding the molecular composition, physical structure, and hydraulic and biological properties of soil and water. These data are essential for advancing the next generation of multiscale Earth systems models. In this paper, we discuss the 1000 Soils Pilot for MONet, including a description of standardized sampling materials and protocols and a use case to highlight the utility of molecular-level and microstructural measurements for assessing the impacts of wildfire on soil. While the 1000 Soils Pilot generated a plethora of data, we focus on assessments of soil organic matter (SOM) chemistry via Fourier-transform ion cyclotron resonance-mass spectrometry and microstructural properties via X-ray computed tomography to highlight the effects of recent fire history in forested ecosystems on belowground C cycling. We observed decreases in soil respiration, microbial biomass, and potential enzyme activity in soils with high frequency burns. Additionally, the nominal oxidation state of carbon in SOM increased with burn frequency in surface soils. This results in a quantifiable shift in the molecular signature of SOM and shows that wildfire may result in oxidation of SOM and structural changes to soil pore networks that persist into deeper soils.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of Engineered Barrier Systems (FY19 Report)

This report describes research and development (R&D) activities conducted during fiscal year 2019 (FY19) specifically related to the Engineered Barrier System (EBS) R&D Work Package in the Spent Fuel and Waste Science and Technology (SFWST) Campaign supported by the United States (U.S.) Department of Eneregy (DOE). The R&D activities focus on understanding EBS component evolution and interactions within the EBS, as well as interactions between the host media and the EBS. A primary goal is to advance the development of process models that can be implemented directly within the Genreric Disposal System Analysis (GDSA) platform or that can contribute to the safety case in some manner such as building confidence, providing further insight into the processes being modeled, establishing better constraints on barrier performance, etc.The FY19 EBS activities involved not only modeling and analysis work, but experimental work as well. The report documents the FY19 progress made in seven different research areas as follows: (1) thermal analysis for the disposal of dual purpose canisters (DPCs) in sedimentary host rock using the semianalytical method, (2) tetravalent uranium solubility and speciation, (3) modeling of high temperature, thermal-hydrologic-mechanical-chemical (THMC) coupled processes, (4) integration of coupled thermalhydrologic- chemical (THC) model with GDSA using a Reduced-Order Model, (5) studying chemical controls on montmorillonite structure and swelling pressure, (6) transmission x-ray microscope for in-situ nanotomography of bentonite and shale, and (7) in-situ electrochemical testing of uranium dioxide under anoxic conditions. The R&D team consisted of subject matter experts from Sandia National Laboratories, Lawrence Berkeley National Laboratory (LBNL), Los Alamos National Laboratory (LANL), Pacific Northwest National Laboratory (PNNL), the Bureau de Recherches Géologiques et Minières (BRGM), the University of California Berkeley, and Mississippi State University. In addition, the EBS R&D work leverages international collaborations to ensure that the DOE program is active and abreast of the latest advances in nuclear waste disposal. For example, the FY19 work on modeling coupled THMC processes at high temperatures relied on the bentonite properties from the Full-scale Engineered Barrier EXperiment (FEBEX) Field Test conducted at the Grimsel Test Site in Switzerland. Overall, significant progress has been made in FY19 towards developing the modeling tools and experimental capabilities needed to investigate the performance of EBS materials and the associated interactions in the drift and the surrounding near-field environment under a variety of conditions including high temperature regimes.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗