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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43

Stress dependence of ultrasonic velocity in unidirectional graphite/epoxy composites for longitudinal waves propagating along the direction of stress

Measurements of stress-induced velocity changes for propagation along the direction of applied stress in graphite/epoxy composites are presented. A linear relation between normalized velocity shift and stress is demonstrated for propagation and stress direction perpendicular to the fiber direction. The ratio of the SAC to the elastic compliance for this loading direction was assessed and found to have a value similar to that of numerous other materials which have very different linear elastic properties. Measurements with stress and propagation along the fibers yielded unusual behavior; the curves were very nonlinear and even shifted direction at higher loads.

Prosser, William H.↗

TEAMER: FOSWEC Mooring Modeling and Analysis, Post Access Report and Data

Floating oscillating surge wave energy converters (FOSWECs) offer several advantages over bottom-hinged oscillating surge wave energy converters, including large wave potential at deep-water sites with fewer permitting and environmental concerns outside territorial waters. As a team, Stevens Institute of Technology, Virginia Tech and Resolute Marine Energy are designing a 100 kW FOSWEC with DOE support (2020-2021) for the PacWave test site "PacWave". The proposed FOSWEC consists of a floating platform, two pivoting flaps, and an innovative power-take-off (PTO). The distance between the two flaps is around half the typical wavelength, resulting in out-of-phase motion and a reduction in motion of the frame and mooring loads. The overall goal of the project is to design, build, deploy and analyze a 1:2 scale (100-kW annual averaged electrical power output) device with reduced levelized cost of energy (LCOE) and peak-to-average power ratio, through the co-design and control of the PTO, WEC, and floating platform. This submission includes a Post Access Report and data for the project of Mooring Modeling and Analysis for Floating Oscillating Surge Wave Energy Converter that Powers Marine Aquaculture of RFTS2 (request for technical support). The data are used to generate all figures in the Post Access Report. Project was a collaboration between Virginia Tech and the National Renewable Energy Lab, with funding from TEAMER.

16 TIDAL AND WAVE POWER↗

The role of pre-existing heterogeneities in materials under shock and spall

There has been a challenge for many decades to understand how heterogeneities influence the behavior of materials under shock loading, eventually leading to spall formation and failure. Experimental, analytical, and computational techniques have matured to the point where systematic studies of materials with complex microstructures under shock loading and the associated failure mechanisms are feasible. This is enabled by more accurate diagnostics as well as characterization methods. As interest in complex materials grows, understanding and predicting the role of heterogeneities in determining the dynamic behavior becomes crucial. Early computational studies, hydrocodes, in particular, historically preclude any irregularities in the form of defects and impurities in the material microstructure for the sake of simplification and to retain the hydrodynamic conservation equations. Contemporary computational methods, notably molecular dynamics simulations, can overcome this limitation by incorporating inhomogeneities albeit at a much lower length and time scale. This review discusses literature that has focused on investigating the role of various imperfections in the shock and spall behavior, emphasizing mainly heterogeneities such as second-phase particles, inclusions, and voids under both shock compression and release. Pre-existing defects are found in most engineering materials, ranging from thermodynamically necessary vacancies, to interstitial and dislocation, to microstructural features such as inclusions, second phase particles, voids, grain boundaries, and triple junctions. This literature review explores the interaction of these heterogeneities under shock loading during compression and release. Systematic characterization of material heterogeneities before and after shock loading, along with direct measurements of Hugoniot elastic limit and spall strength, allows for more generalized theories to be formulated. Further, continuous improvement toward time-resolved, in situ experimental data strengthens the ability to elucidate upon results gathered from simulations and analytical models, thus improving the overall ability to understand and predict how materials behave under dynamic loading.

36 MATERIALS SCIENCE↗

Integrated Resource and System Plannning Based on Energy Costs and Emission Analysis for a Sustainable Future

Efficient integration of renewable energy sources (RES) - such as wind, solar, geothermal, tidal, and wave - into the electric power grids can help improve energy security and contribute toward a sustainable energy future. To date, however, electric power grids are critically dependent on conventional sources, such as fossil fuels. Given the increasing penetration of RES and dynamic loads, there is a need to thoroughly reanalyze the performance of power grids in terms of cost, efficiency, and energy security. This paper presents a comprehensive analysis in terms of energy costs and emissions estimates of dynamic power grids incorporating various power-generating sources.

distributed energy resources↗

High-power generation in IMPATT devices in the 100-200-GHz range

A silicon double-drift IMPATT diode with high uniform doping levels was simulated. Simulation results show that it is possible for silicon IMPATT diodes to generate extremely high pulsed output power for frequencies above 100 GHz under high current-density operation. The highest output power matched to a 1-ohm load resistance obtained at 150 GHz is 37.7 W, with a dc current density of 200 kA/sq cm, although the calculated power conversion efficiency is low. It is also shown that the low-power conversion efficiency limits the diode's continuous wave power operation.

Chen, Chien-Chung↗

Coupled multi-disciplinary composites behavior simulation

The capabilities of the computer code CSTEM (Coupled Structural/Thermal/Electro-Magnetic Analysis) are discussed and demonstrated. CSTEM computationally simulates the coupled response of layered multi-material composite structures subjected to simultaneous thermal, structural, vibration, acoustic, and electromagnetic loads and includes the effect of aggressive environments. The composite material behavior and structural response is determined at its various inherent scales: constituents (fiber/matrix), ply, laminate, and structural component. The thermal and mechanical properties of the constituents are considered to be nonlinearly dependent on various parameters such as temperature and moisture. The acoustic and electromagnetic properties also include dependence on vibration and electromagnetic wave frequencies, respectively. The simulation is based on a three dimensional finite element analysis in conjunction with composite mechanics and with structural tailoring codes, and with acoustic and electromagnetic analysis methods. An aircraft engine composite fan blade is selected as a typical structural component to demonstrate the CSTEM capabilities. Results of various coupled multi-disciplinary heat transfer, structural, vibration, acoustic, and electromagnetic analyses for temperature distribution, stress and displacement response, deformed shape, vibration frequencies, mode shapes, acoustic noise, and electromagnetic reflection from the fan blade are discussed for their coupled effects in hot and humid environments. Collectively, these results demonstrate the effectiveness of the CSTEM code in capturing the coupled effects on the various responses of composite structures subjected to simultaneous multiple real-life loads.

Singhal, Surendra N.↗

Backscatter Modeling at 2.1 Micron Wavelength for Space-Based and Airborne Lidars Using Aerosol Physico-Chemical and Lidar Datasets

Space-based and airborne coherent Doppler lidars designed for measuring global tropospheric wind profiles in cloud-free air rely on backscatter, beta from aerosols acting as passive wind tracers. Aerosol beta distribution in the vertical can vary over as much as 5-6 orders of magnitude. Thus, the design of a wave length-specific, space-borne or airborne lidar must account for the magnitude of 8 in the region or features of interest. The SPAce Readiness Coherent Lidar Experiment under development by the National Aeronautics and Space Administration (NASA) and scheduled for launch on the Space Shuttle in 2001, will demonstrate wind measurements from space using a solid-state 2 micrometer coherent Doppler lidar. Consequently, there is a critical need to understand variability of aerosol beta at 2.1 micrometers, to evaluate signal detection under varying aerosol loading conditions. Although few direct measurements of beta at 2.1 micrometers exist, extensive datasets, including climatologies in widely-separated locations, do exist for other wavelengths based on CO2 and Nd:YAG lidars. Datasets also exist for the associated microphysical and chemical properties. An example of a multi-parametric dataset is that of the NASA GLObal Backscatter Experiment (GLOBE) in 1990 in which aerosol chemistry and size distributions were measured concurrently with multi-wavelength lidar backscatter observations. More recently, continuous-wave (CW) lidar backscatter measurements at mid-infrared wavelengths have been made during the Multicenter Airborne Coherent Atmospheric Wind Sensor (MACAWS) experiment in 1995. Using Lorenz-Mie theory, these datasets have been used to develop a method to convert lidar backscatter to the 2.1 micrometer wavelength. This paper presents comparison of modeled backscatter at wavelengths for which backscatter measurements exist including converted beta (sub 2.1).

Srivastava, V.↗

Tunable Electromechanical Liquid Crystal Elastomer Actuators

Liquid crystal elastomers (LCE) are soft materials which anisotropically shape morph in response to external stimuli. Herein, a method to produce large‐area carbon nanotube–LCE nanocomposite films with exceptional electrostrictive properties is examined. A methodology to produce telechelic precursor oligomeric composites at scale (>100 g) is presented along with the continuous casting and photocuring process. The carbon nanotubes are well‐aligned and well‐dispersed in the films, which exhibit exceptional anisotropic thermomechanical, optical, and thermal shape change characteristics. When an electric field is applied through the film thickness, the material quickly and reversibly contracts along the alignment direction. As an example, a compliant carbon nanotube–LCE film contracts >4% against a 140 kPa load, roughly comparable to the blocking force of many natural muscular tissues. Furthermore, it is demonstrated that this tunable contraction is dependent upon the electric field strength, and that the contraction mimics the form function of the input electric field (e.g., a sine wave). These compliant actuators are excellent candidates for incorporation into soft and/or biological systems.

36 MATERIALS SCIENCE↗

From force chains to nonclassical nonlinear dynamics in cemented granular materials

In this letter, we present evidence for a mechanism responsible for the nonclassical nonlinear dynamics observed in many cemented granular materials that are generally classified as mesoscopic nonlinear elastic materials. We demonstrate numerically that force chains are created within the complex grain-pore network of these materials when subjected to dynamic loading. The interface properties between grains along with the sharp and localized increase of the stress occurring at the grain-grain contacts leads to a reversible decrease of the elastic properties at macroscopic scale and peculiar effects on the propagation of elastic waves when grain boundary properties are appropriately considered. These effects are observed for relatively small amplitudes of the elastic waves, i.e., within tens of microstrain, and relatively large wavelengths, i.e., orders of magnitude larger than the material constituents. The mechanics are investigated numerically using the hybrid finite-discrete-element method and match those observed experimentally using nonlinear resonant ultrasound spectroscopy.

36 MATERIALS SCIENCE↗

Method for Coupled Electromagnetic and Circuit Simulations to Evaluate Surge Arrester Performance in Protecting Equipment Against E1 HEMP

Surge arrester behavioral modeling for realistic systems embedded in an E1 high-altitude electromagnetic pulse environment inherently encompasses three interconnected complications: (1) the need to account for signal propagation across two domains, electromagnetics and electrical; (2) the need to include both linear and nonlinear circuit components in the analysis; and (3) the need to understand that the over-current and over-voltage mitigation performance is dependent not only on the properties of the surge arrester and protected load but also on the topology of the overall electrical network. This study presents a framework to address these challenges in a systematic manner to consider the effectiveness of protective measures for a common class of equipment in power generation facilities. Full-wave simulations were carried out to derive circuit-domain (i.e., lumped element–based) equivalent models for the excitation waveform and the physical components of the system. Then, these equivalent models were imported to a circuit solver and combined with a high-frequency surge arrester model to evaluate mitigation performance. The methodology outlined is general enough such that it can be applied for other electromagnetic interference problems that involve E2/E3 HEMP or microwave emissions.

42 ENGINEERING↗

Effect of Cavity Injection on Wall Drag in a Supersonic Flow with Reflecting Shocks

The wall drag test tunnel at NASA Langley Research Center was used to evaluate simulated scramjet fuel injection into a wall cavity. In this tunnel, one wall consists of interchangeable aluminum plates attached to an air bearing suspension system. The plates were equipped with load cells to measure drag forces and static taps to determine pressure distributions. The plates were exposed to a Mach 2 air stream at a total pressure of 115 psia (793 kPa). This flow field contained a train of weak unsteady, reflecting shock waves that were produced in the nozzle assembly located upstream of the test section.

Castiglone, L. A.↗

Dynamic Load Balancing for Adaptive Unstructured Grids

Dynamic mesh adaptation on unstructured grids is a powerful tool for computing unsteady three-dimensional problems that require grid modifications to efficiently resolve solution features. By locally refining and coarsening the mesh to capture phenomena of interest, such procedures make standard computational methods more cost effective. Highly refined meshes are required to accurately capture shock waves, contact discontinuities, vortices, and shear layers in fluid flow problems. Adaptive meshes have also proved to be useful in several other areas of computational science and engineering like computer vision and graphics, semiconductor device modeling, and structural mechanics. Local mesh adaptation provides the opportunity to obtain solutions that are comparable to those obtained on globally-refined grids but at a much lower cost. Additional information is contained in the original extended abstract.

Biswas, Rupak↗

Computational Fluid Dynamics Study of a Cross-Flow Marine Hydrokinetic Turbine and the Combined Influence of Struts and Helical Blades: Preprint

A computational fluid dynamics study was performed for a cross-flow marine hydro-kinetic turbine. The analysis was done in three dimensions and used the unsteady Reynolds averaged Navier-Stokes solver in the commercial code STAR-CCM+. The base turbine configuration is the RivGen® Turbine, designed by the Ocean Renewable Power Company (ORPC). A convergence and uncertainty analysis was performed for both the spatial and temporal discretization; this was done using the base configuration which features support struts and helical foils. The proposed study aims to compare the impact of the struts on both power performance and blade loading for helical and straight blades.

CFD↗

Oxidation of Ammonia Catalyzed by a Molecular Iron Complex: Translating Chemical Catalysis to Mediated Electrocatalysis

Abstract Ammonia is a promising candidate in the quest for sustainable, clean energy. With its capacity to serve as an energy carrier, the oxidation of ammonia opens avenues for carbon‐neutral approaches to address worldwide growing energy needs. We report the catalytic chemical oxidation of ammonia by an Earth‐abundant transition metal complex, trans ‐ [LFe II (MeCN) 2 ][PF 6 ] 2 , where L is a macrocyclic ligand bearing four N ‐heterocyclic carbene (NHC) donors. Using triarylaminium radical cations in MeCN, up to 182 turnovers of N 2 per Fe were obtained from chemical catalysis with an extremely low loading of the Fe catalyst (0.043 mM, 0.004 mol % catalyst). This chemical catalysis was successfully transitioned to mediated electrocatalysis for the oxidation of ammonia. Molecular electrocatalysis by the Fe catalyst and the mediator ( p ‐MeOC 6 H 4 ) 3 N exhibited a catalytic half‐wave potential ( E cat/2 ) of 0.18 V vs [Cp 2 Fe] +/0 in MeCN, and achieved 9.3 turnovers of N 2 at an applied potential of 0.20 V vs [Cp 2 Fe] +/0 at −20 °C in controlled‐potential electrolysis, with a Faradaic efficiency of 75 %. Based on computational results, the catalyst undergoes sequential oxidation and deprotonation steps to form [LFe IV (NH 2 ) 2 ] 2+ , and thereafter bimetallic coupling to form an N−N bond.

Liu, Liang↗

Oxidation of Ammonia Catalyzed by a Molecular Iron Complex: Translating Chemical Catalysis to Mediated Electrocatalysis

Abstract Ammonia is a promising candidate in the quest for sustainable, clean energy. With its capacity to serve as an energy carrier, the oxidation of ammonia opens avenues for carbon‐neutral approaches to address worldwide growing energy needs. We report the catalytic chemical oxidation of ammonia by an Earth‐abundant transition metal complex, trans ‐ [LFe II (MeCN) 2 ][PF 6 ] 2 , where L is a macrocyclic ligand bearing four N ‐heterocyclic carbene (NHC) donors. Using triarylaminium radical cations in MeCN, up to 182 turnovers of N 2 per Fe were obtained from chemical catalysis with an extremely low loading of the Fe catalyst (0.043 mM, 0.004 mol % catalyst). This chemical catalysis was successfully transitioned to mediated electrocatalysis for the oxidation of ammonia. Molecular electrocatalysis by the Fe catalyst and the mediator ( p ‐MeOC 6 H 4 ) 3 N exhibited a catalytic half‐wave potential ( E cat/2 ) of 0.18 V vs [Cp 2 Fe] +/0 in MeCN, and achieved 9.3 turnovers of N 2 at an applied potential of 0.20 V vs [Cp 2 Fe] +/0 at −20 °C in controlled‐potential electrolysis, with a Faradaic efficiency of 75 %. Based on computational results, the catalyst undergoes sequential oxidation and deprotonation steps to form [LFe IV (NH 2 ) 2 ] 2+ , and thereafter bimetallic coupling to form an N−N bond.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High-resolution vibrational predissociation spectroscopy of I - ·H 2 O by single-mode CW infrared excitation in a 3D cryogenic ion trap

We describe the integration of a tunable, single-mode, continuous wave infrared laser into a cryogenic ion spectroscopy experiment to measure the rovibrational spectrum of the I - ∙H 2 O complex in the OH stretching region. These upper levels lie about 300 cm -1 above the dissociation threshold. The measurements are carried out by loading the ions in a radiofrequency ion trap at 10 Hz and cooling them to 5 K with pulsed He buffer gas. IR photodissociation (PD) of the I - ∙H 2 O complex is monitored by recording the I - product yield by time-of-flight mass spectrometry as a function of laser wavelength. Very narrow (Δν~75 MHz) rotational lines are observed throughout the spectrum, indicating long (ca. 2 ns) lifetimes for the excited metastable rovibrational levels. Rotational analysis of the band arising from the K”=1 to K’=2 transition of the free OH stretching fundamental yields the structure of the complex for the first time. Over 50% of the trapped ion ensemble in the trap can be photodissociated upon excitation of a single rotational line. This enables very high signal-to-noise in the PD spectrum, and is traced to a mechanism in which the ground state rotational levels are rapidly equilibrated by collisions with the buffer gas.

74 ATOMIC AND MOLECULAR PHYSICS↗

Finite Element Development of Honeycomb Panel Configurations with Improved Transmission Loss

The higher stiffness-to-mass ratio of a honeycomb panel compared to a homogeneous panel results in a lower acoustic critical frequency. Above the critical frequency the panel flexural wave speed is acoustically fast and the structure becomes a more efficient radiator with associated lower sound transmission loss. Finite element models of honeycomb sandwich structures are presented featuring areas where the core is removed from the radiating face sheet disrupting the supersonic flexural and shear wave speeds that exist in the baseline honeycomb panel. These modified honeycomb panel structures exhibit improved transmission loss for a pre-defined diffuse field sound excitation. The models were validated by the sound transmission loss of honeycomb panels measured in the Structural Acoustic Loads and Transmission (SALT) facility at the NASA Langley Research Center. A honeycomb core panel configuration is presented exhibiting a transmission loss improvement of 3-11 dB compared to a honeycomb baseline panel over a frequency range from 170 Hz to 1000 Hz. The improved transmission loss panel configuration had a 5.1% increase in mass over the baseline honeycomb panel, and approximately twice the deflection when excited by a static force.

Grosveld, Ferdinand W.↗

General Testing Setup for Hyperelastic Transducers-DEEC-Tec & Marine Renewable Energy: Preprint

Distributed embedded energy conversion technologies (DEEC-Tec), an emerging domain for ocean wave energy conversion technology, is showing promise for a range of applications. Research is being conducted at the National Renewable Energy Laboratory that leverages this domain to investigate the potential of ocean wave energy converters (WECs) constructed from hyperelastic forms of distributable and embeddable energy transducers. These transducers are available in forms such as disks, rectangles, or hexagons and can be combined in various ways to form energy-producing metamaterials and flexible WECs. DEEC-Tec, therefore, could open doors that enhance ocean wave energy conversion in ways not previously thought possible by allowing for many WEC topologies and morphologies. However, the same diversity and adaptability pose challenges for the development of these DEEC-Tec-oriented hyperelastic transducers. A commercial tensile testing setup was not found that was adaptable enough to accommodate the varied transducers while providing precise force control, range of motion, and noncontact data collection. Because of this lack, a comprehensive test rig was designed in house to be used with a 3D laser scanning device-providing contactless measurements while also allowing for different geometries and various uniaxial loadings. This paper and presentation will discuss these unique challenges and the processes for overcoming them to provide a robust and general testing setup for hyperelastic transducers, of any form, for the DEEC-Tec marine renewable energy domain.

DEEC-Tec↗