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At least 775 records · Page 43

Automated Array Assembly, Phase 2

The solar cell module process development activities in the areas of surface preparation are presented. The process step development was carried out on texture etching including the evolution of a conceptual process model for the texturing process; plasma etching; and diffusion studies that focused on doped polymer diffusion sources. Cell processing was carried out to test process steps and a simplified diode solar cell process was developed. Cell processing was also run to fabricate square cells to populate sample minimodules. Module fabrication featured the demonstration of a porcelainized steel glass structure that should exceed the 20 year life goal of the low cost silicon array program. High efficiency cell development was carried out in the development of the tandem junction cell and a modification of the TJC called the front surface field cell. Cell efficiencies in excess of 16 percent at AM1 have been attained with only modest fill factors. The transistor-like model was proposed that fits the cell performance and provides a guideline for future improvements in cell performance.

Carbajal, B. G.↗

Aircraft control surface failure detection and isolation using the OSGLR test

The performance of the orthogonal series generalized likelihood ratio (OSGLR) test in detecting and isolating commercial aircraft control surface and actuator failures is evaluated. A modification to incorporate age-weighting which significantly reduces the sensitivity of the algorithm to modeling errors is presented. The steady-state implementation of the algorithm based on a single linear model valid for a cruise flight condition is tested using a nonlinear aircraft simulation. A number of off-nominal no-failure flight conditions including maneuvers, nonzero flap deflections, different turbulence levels and steady winds were tested. Based on the no-failure decision functions produced by off-nominal flight conditions, the failure detection and isolation performance at the nominal flight condition was determined. The extension of the algorithm to a wider flight envelope by scheduling on dynamic pressure and flap deflection is examined. Based on this testing, the OSGLR algorithm should be capable of detecting control surface failures that would affect the safe operation of a commercial aircraft. Isolation may be difficult if there are several surfaces which produce similar effects on the aircraft. Extending the algorithm over the entire operating envelope of a commercial aircraft appears feasible.

Bonnice, W. F.↗

The role of nonuniform internal heating in Triton's energy budget

Triton's large heliocentric distance and high albedo, combined with its unusually large silicate mass fraction, make internal heating more important in its energy budget than in that of any other icy satellite. Brown et al. have recently estimated that the average radiogenic heat flux (which is probably between 3.3 and 6.6 mW/sq m depending on core size and composition) may equal 5 to 20 pct. of the average absorbed insolation. On a global scale, this additional energy input appreciably increases the thermal emissivity required to be consistent with the observed surface temperature. Brown et al. also speculated that spatial variations of the internal flux may change the local sublimation deposition balance enough to lead to observable modifications of the distribution of volatiles on Triton's surface. An attempt is made to estimate the magnitude of internal heat flux variations due to the insulating effect of the polar caps, to mantle convection, and to cryovolcanism; the importance is evaluated of these variations in modifying the volatile distribution.

Kirk, R. L.↗

On the turbulent friction layer for rising pressure

Among the information presented are included displacement, momentum, and kinetic energy thicknesses, shearing stress distributions across boundary layer, and surface friction coefficients. The Gruschwitz method and its modifications are examined and tested. An energy theorem for the turbulent boundary layer is introduced and discussed but does not lead to a method for the prediction of the behavior of the turbulent boundary layer because relations for the shearing stress and the surface friction are lacking.

SKIN FRICTION - PLATES↗

Molecular Dynamics Simulations of Adhesion at Epoxy Interfaces

The effect of moisture on adhesives used in aerospace applications can be modeled with chemically specific techniques such as molecular dynamics simulation. In the present study, the surface energy and work of adhesion are calculated for epoxy surfaces and interfaces, respectively, by using molecular dynamics simulation. Modifications are made to current theory to calculate the work of adhesion at the epoxy-epoxy interface with and without water. Quantitative agreement with experimental values is obtained for the surface energy and work of adhesion at the interface without water. The work of adhesion agrees qualitatively with the experimental values for the interface with water: the magnitude is reduced 15% with respect to the value for the interface without water. A variation of 26% in the magnitude is observed depending on the water configuration at a concentration of 1.6 wt%. The methods and modifications to the method that are employed to obtain these values are expected to be applicable for other epoxy adhesives to determine the effects of moisture uptake on their work of adhesion.

Frankland, Sarah-Jane V.↗

The Topography and Basin Deposits of the Equatorial Highlands: A MGS-Viking Synergistic Study

One of the greatest unresolved issues concerns the evolution of Mars early in its history; during the time period that accretion was winding down but the frequency of impacting debris was still heavy. Ancient cratered terrain that has only been moderately modified since the period of heavy bombardment covers about a quarter of the planet's surface but the environment during its formation is still uncertain. This terrain was dominantly formed by cratering. But unlike on the airless Moon, the impacting craters were strongly modified by other contemporary surface processes that have produced distinctive features such as: 1) dendritic channel networks, 2) rimless, flatfloored craters, 3) obliteration of most craters smaller than a few kilometers in diameter (except for post heavy-bombardment impacts), and 4) smooth intercrater plains. The involvement of water in these modification processes seems unavoidable, but interpretations of the surface conditions on early Mars range from the extremes of: 1) the "cold" model which envisions a thin atmosphere and surface temperatures below freezing except for local hydrothermal springs; and 2) the "warm" model, which invokes a thick atmosphere, seasonal temperatures above freezing in temperate and equatorial regions, and at least occasional precipitation as part of an active hydrological cycle. The nature of hydrologic cycles, if they occurred on Mars, would have been critically dependent on the environment. The resolution of where along this spectrum the actual environment of early Mars occurred is clearly a major issue, particularly because the alternate scenarios have much different implications about the possibility that life might have evolved on Mars. Additional information is contained in the original extended abstract.

Moore, J. M.↗

Topographic Evaluation of Mars 2001 Candidate Landing Sites: A MGS-Viking Synergistic Study

One of the greatest unresolved issues concerns the evolution of Mars early in its history; during the time period that accretion was winding down but the frequency of impacting debris was still heavy. Ancient cratered terrain that has only been moderately modified since the period of heavy bombardment covers about a quarter of the planet's surface but the environment during its formation is still uncertain. This terrain was dominantly formed by cratering. But unlike on the airless Moon, the impacting craters were strongly modified by other contemporary surface processes that have produced distinctive features such as 1) dendritic channel networks, 2) rimless, flatfloored craters, 3) obliteration of most craters smaller than a few kilometers in diameter (except for post heavy-bombardment impacts), and 4) smooth intercrater plains. The involvement of water in these modification processes seems unavoidable, but interpretations of the surface conditions on early Mars range from the extremes of 1) the "cold" model which envisions a thin atmosphere and surface temperatures below freezing except for local hydrothermal springs; and 2) the "warm" model, which invokes a thick atmosphere, seasonal temperatures above freezing in temperate and equatorial regions, and at least occasional precipitation as part of an active hydrological cycle. The nature of hydrologic cycles, if they occurred on Mars, would have been critically dependent on the environment. The resolution of where along this spectrum the actual environment of early Mars occurred is clearly a major issue, particularly because the alternate scenarios have much different implications about the possibility that life might have evolved on Mars.

Moore, J. M.↗

Correction factory techniques for improving aerodynamic prediction methods

A method for correcting discrete element lifting surface theory to reflect given experimental data is presented. Theoretical pressures are modified such that imposed constraints are satisfied while minimizing the changes to the pressures. Several types of correction procedures are presented and correlated; (1) scaling of pressures; (2) scaling of downwash values; and (3) addition of an increment to the downwash that is proportioned to pressure. Some special features are included in these methods and they include: (1) consideration of experimental data from multiple deflection modes, (2) limitation of the amplitudes of the correction factors, and (3) the use of correction factor mode shapes. These methods are correlated for cases involving all three Mach Number ranges using a FORTRAN IV computer program. Subsonically, a wing with an oscillating partial span control surface and a wing with a leading edge droop are presented. Transonically a two-dimensional airfoil with an oscillating flap is considered. Supersonically an arrow wing with and without camber is analyzed. In addition to correction factor methods an investigation is presented dealing with a new simplified transonic modification of the two-dimensional subsonic lifting surface theory. Correlations are presented for an airfoil with an oscillating flap.

Giesing, J. P.↗

Tuning the surface reactivity of oxides by peroxide species

The Mars–van Krevelen mechanism is the foundation for oxide-catalyzed oxidation reactions and relies on spatiotemporally separated redox steps. Herein, we demonstrate the tunability of this separation with peroxide species formed by excessively adsorbed oxygen, thereby modifying the catalytic activity and selectivity of the oxide. Using CuO as an example, we show that a surface layer of peroxide species acts as a promotor to significantly enhance CuO reducibility in favor of H 2 oxidation but conversely as an inhibitor to suppress CuO reduction against CO oxidation. Together with atomistic modeling, we identify that this opposite effect of the peroxide on the two oxidation reactions stems from its modification on coordinately unsaturated sites of the oxide surface. By differentiating the chemical functionality between lattice oxygen and peroxide, these results are closely relevant to a wide range of catalytic oxidation reactions using excessively adsorbed oxygen to activate lattice oxygen and tune the activity and selectivity of redox sites.

36 MATERIALS SCIENCE↗

Chemical structure–property relationships in nanocelluloses

Abstract Nanocelluloses, nanoscale cellulosic particles or fibrils, are an appealing class of nanomaterials with enormous potential for sustainable development. They have great promise to target some of the 17 Sustainable Development Goals outlined by the United Nations. Nanocelluloses are derived from the most abundant biopolymer in the world, cellulose, which have multiple hydroxyl groups on their surface, enabling a vast range of chemical modifications. The interplay between the chemical structure and physicochemical properties of nanocelluloses is crucial to engineering the next generation of green, functional nanomaterials. In this review paper, we provide a comprehensive account of the structure–property relationships in nanocelluloses, which may establish the basis for the design of precision bio‐based materials. Chemical modifications of nanocelluloses, including hydrolysis, oxidation, esterification, amidation, and polymer grafting, provide an array of chemical and physical properties that open opportunities in a diverse spectrum of applications. We review how chemical modifications affect the physicochemical properties of nanocelluloses, such as thermal stability, hydrophobicity, and dispersibility in nonpolar media. Understanding nanocellulose chemical structure–property relationships is integral to the development of sustainable material platforms based on the most renewable biopolymer on earth.

59 BASIC BIOLOGICAL SCIENCES↗

Novel nucleocytoplasmic protein O -fucosylation by SPINDLY regulates diverse developmental processes in plants

Here, in metazoans, protein O-fucosylation of Ser/Thr residues was only found in secreted or cell surface proteins, and this post-translational modification is catalyzed by ER-localized protein O-fucosyltransferases (POFUTs) in the GT65 family. Recently, a novel nucleocytoplasmic POFUT, SPINDLY (SPY), was identified in the reference plant Arabidopsis thaliana to modify nuclear transcription regulators DELLAs, revealing a new regulatory mechanism for gene expression. The paralog of AtSPY, SECRET AGENT (SEC), is an O-link-N-acetylglucosamine (GlcNAc) transferase (OGT), which O-GlcNAcylates Ser/Thr residues of target proteins. Both AtSPY and AtSEC are tetratricopeptide repeat-domain-containing glycosyltransferases in the GT41 family. The discovery that AtSPY is a POFUT clarified decades of miss-classification of AtSPY as an OGT. SPY and SEC play pleiotropic roles in plant development, and the interactions between SPY and SEC are complex. SPY-like genes are conserved in diverse organisms, except in fungi and metazoans, suggesting that O-fucosylation is a common mechanism in modulating intracellular protein functions.

59 BASIC BIOLOGICAL SCIENCES↗

A family of tubular pili from harmful algal bloom forming cyanobacterium Microcystis aeruginosa

Cyanobacteria are vital photosynthetic prokaryotes, but some form harmful algal blooms (cyanoHABs) that disrupt ecosystems and produce toxins. The mechanisms by which these blooms form have yet to be fully understood, particularly the role of extracellular components. Here, we present a 2.4 Å cryo-EM structure of a pilus, termed the cyanobacterial tubular (CT) pilus, found in the cyanoHAB-forming Microcystis aeruginosa. The pilin exhibits a unique protein fold, forming a tubular pilus structure with tight, double-layer anti-parallel β-sheet interactions. We show that CT pili are essential for buoyancy by facilitating the formation of micro-colonies, which increases drag force and prevents sinking. The CT pilus surface is heavily glycosylated with ten monosaccharide modifications per pilin. Furthermore, CT pili can enrich microcystin, potentially enhancing cellular resilience, and co-localize with iron-enriched extracellular matrix components. Thus, we propose that this pilus plays an important role in the proliferation of cyanoHABs. This just discovered pilus family appears to be widely distributed across several cyanobacterial orders. Our structural and functional characterization of CT pili provide insights into cyanobacterial cell morphology, physiology, and toxin interactions, and identify potential targets for disrupting bloom formation.

Cryoelectron microscopy↗

The clouds of Venus. II - An investigation of the influence of coagulation on the observed droplet size distribution

An approximate numerical technique is used to investigate the influence of coagulation, sedimentation and turbulent motions on the observed droplet size distribution in the upper layers of the Venus clouds. If the cloud mass mixing ratio is less than 0.000001 at 250 K or the eddy diffusivity throughout the cloud is greater than 1,000,000 sq cm per sec, then coagulation is unimportant. In this case, the observed droplet size distribution is the initial size distribution produced by the condensation of the droplets. It is found that all cloud models with droplet formation near the cloud top (e.g., a photochemical model) must produce the observed droplet size distribution by condensation without subsequent modification by coagulation. However, neither meteoritic or surface dust can supply sufficient nucleating particles to account for the observed droplet number density. If the cloud droplets are formed near the cloud bottom, the observed droplet size distribution can be produced solely by the interaction of coagulation and dynamics; all information about the initial size distribution is lost. If droplet formation occurs near the cloud bottom, the lower atmosphere of Venus is oxidizing rather than reducing.

Rossow, W. B.↗

Silicon Solar Cell Process Development, Fabrication and Analysis, Phase 1

Solar cells from RTR ribbons, EFG (RF and RH) ribbons, dendritic webs, Silso wafers, cast silicon by HEM, silicon on ceramic, and continuous Czochralski ingots were fabricated using a standard process typical of those used currently in the silicon solar cell industry. Back surface field (BSF) processing and other process modifications were included to give preliminary indications of possible improved performance. The parameters measured included open circuit voltage, short circuit current, curve fill factor, and conversion efficiency (all taken under AM0 illumination). Also measured for typical cells were spectral response, dark I-V characteristics, minority carrier diffusion length, and photoresponse by fine light spot scanning. the results were compared to the properties of cells made from conventional single crystalline Czochralski silicon with an emphasis on statistical evaluation. Limited efforts were made to identify growth defects which will influence solar cell performance.

Yoo, H. I.↗

Computerized three-dimensional aerodynamic design of a lifting rotor blade

A three-dimensional, inviscid, full-potential lifting rotor code was used to demonstrate that pressure distributions on both advancing and retreating blades could be significantly improved by perturbing local airfoil sections. The perturbations were described by simple geometric shape functions. To illustrate the procedure, an example calculation was made at a forward flight speed of 85 m/sec (165 knots) and an advance ratio of 0.385. It was found that a minimum of three shape functions was required to improve the pressures without producing undesirable secondary effects in high-speed forward flight on a hypothetical modern rotor blade initially having an NLR-1 supercritical airfoil. Reductions in the shock strength on the advancing blade could be achieved, while simultaneously lessening leading-edge pressure gradients on the retreating blade. The major blade section modifications required were blunting of the upper surface leading edge and some reshaping of the blade's upper surface resulting in moderately thicker airfoils.

Tauber, M. E.↗

Aerodynamic mission concepts for the Mars sample return mission

Future plans for the continued exploration of Mars call for a sample return mission. This plan proposes bringing a distributed, selected sample of Mars material from several locales on Mars back to earth. The mission options studied to date utilize an extensive number of aerodynamic concepts not previously planned in past planetary exploration programs. These include various modes of orbit modification using atmospheric braking, aeromaneuvering to effect precision surface landing, very low ballistic entry for a network of surface penetrators, low flying hydrazine powered airplanes, balloons, ascent vehicles and direct entry of the samples on return to earth. This paper will discuss the concepts and their feasibility along with technology problems associated with them as surveyed from the reference material. The paper focuses primarily on the aerocapture technique as it relates to Mars orbit modification. Remaining orbit modification techniques are also discussed briefly for comparison.

Cruz, M. I.↗

A case study of the energy dissipation of the gravity wave field based on satellite altimeter measurements

Wave breaking is proposed as the primary energy dissipation mechanism for the gravity wave field. The energy dissipation rate is calculated based on the statistical model proposed by Longuet-Higgins (1969) with a modification of the breaking criterion incorporating the surface stress according to Phillips and Banner (1974). From this modified model, an analytic expression is found for the wave attenuation rate and the half-life time of the wave field which depend only on the significant slope of the wave field and the ratio of friction velocity to initial wave phase velocity. These expressions explain why the freshly generated wave field does not last long, but why swells are capable of propagating long distances without substantial change in energy density. It is shown that breaking is many orders of magnitude more effective in dissipating wave energy than the molecular viscosity, if the significant slope is higher than 0.01. Limited observational data from satellite and laboratory are used to compare with the analytic results, and show good agreement.

Huang, N. E.↗