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At least 775 records · Page 43

Wide-temperature-spectrum self-lubricating coatings prepared by plasma spraying

Self-lubricating, multicomponent coatings, which lubricate over a wide range of operating conditions, are described. The coatings were successfully applied by plasma-spraying mixed powders onto superalloy substrates. They were evaluated in friction and wear experiments, and in sliding contact bearing tests. These coatings are wear resistant by virtue of their self lubricating characteristics rather than because of extreme hardness; a further benefit is low friction. Experiments with simple pin on disk sliding specimens and oscillating plain cylindrical bearing tests were performed to evaluate the tribological properties of the coatings. It was shown that coatings of nichrome, glass and calcium fluoride are self-lubricating from about 500 to 900 C, but give high friction at the lower temperatures. The addition of silver to the coating composition improved the low temperature bearing properties and resulted in coatings which are self-lubricating from cryogenic temperatures to at least 870 C; they are therefore, wide temperature spectrum, self-lubricating compositions.

Sliney, H. E.↗

Effect of fuel sprays on emissions

A research gas turbine combustor was operated under realistic conditions such that the influence of individual variables (in particular, fuel spray characteristics) on emissions could be determined. The special combustor allows independent control over drop size, fuel-air ratio, air inlet temperature, pressure, reference velocity, and residence time. Also, it lends itself to theoretical modeling and turbulent intensity measurements through use of laser velocimetry. Emission results for a range of operations are presented. A number of graphs show which show the variations of emissions levels with one variable at a time are included. In every case, the fuel is jet A, the pressure is atmospheric, and combustion is limited to a primary zone.

Nicholls, J. A.↗

Program for plasma-sprayed self-lubricating coatings

A method for preparing composite powders of the three coating components was developed and a procedure that can be used in applying uniform coatings of the composite powders was demonstrated. Composite powders were prepared by adjusting particle sizes of the components and employing a small amount of monoaluminum phosphate as an inorganic binder. Quantitative microscopy (image analysis) was found to be a convenient method of characterizing the composition of the multiphase plasma-sprayed coatings. Area percentages and distribution of the components were readily obtained by this method. The adhesive strength of the coating to a nickel-chromium alloy substrate was increased by about 40 percent by a heat treatment of 20 hours at 650 C.

Walther, G. C.↗

Plasma-sprayed coatings for lubrication of a titanium alloy in air at 430 deg C

Plasma sprayed coatings of pure silver and of composite materials containing silver were investigated as possible self lubricating coatings for titanium alloys in air at 430 C. Pure silver provided low friction but was prone to severe plastic deformation and excessive transfer except in coating thicknesses of 0.02 mm or less. Additions of nichrome, calcium fluoride, and glass to silver were all beneficial in reducing plastic deformation and otherwise improving the coatings. The longest coating wear life, low wear of Ti alloy pins in sliding contact with the coatings, and a steady friction coefficient of 0.19 were obtained with a four component coating of 0.17 mm thickness. The coating composition, in weight percent is 30 nichrome-30 Ag-25 CaF2-15 glass.

Sliney, H. E.↗

Plasma-sprayed zirconia gas path seal technology: A state-of-the-art review

The benefits derived from application of ceramic materials to high pressure turbine gas path seal components are described and the developmental backgrounds of various approaches are reviewed. The most fully developed approaches are those employing plasma sprayed zirconium oxide as the ceramic material. Prevention of cracking and spalling of the zirconium oxide under cyclic thermal shock conditions imposed by the engine operating cycle is the most immediate problem to be solved before implementation is undertaken. Three promising approaches to improving cyclic thermal shock resistance are described and comparative rig performance of each are reviewed. Advanced concepts showing potential for performance improvements are described.

Bill, R. C.↗

Wide-temperature-spectrum self-lubricating coatings prepared by plasma spraying

Self-lubricating, multicomponent coatings, which lubricate over a wide range of operating conditions, are described. The coatings have been successfully applied by plasma-spraying mixed powders onto superalloy substrates. They have been evaluated in friction and wear experiments, and in sliding contact bearing tests. These coatings are wear resistant by virtue of their self-lubricating characteristics rather than because of extreme hardness; a further benefit is low friction. Experiments with simple pin on disk sliding specimens and oscillating plain cylindrical bearing tests were performed to evaluate the tribological properties of the coatings. It was shown that coatings of nichrome, glass and calcium fluoride are self-lubricating from about 500 to 900 C, but give high friction at the lower temperatures. The addition of silver to the coating composition improved the low temperature bearing properties and resulted in coatings which are self-lubricating from cryogenic temperatures to at least 870 C; they are therefore 'wide temperature spectrum,' self-lubricating compositions.

Sliney, H. E.↗

The effect of fuel sprays on emissions from a gas turbine combustor

A research gas turbine combustor which allows for independent control of drop size, fuel/air ratio, air inlet temperature, pressure, reference velocity, and residence time has been used to study the influence of fuel spray characteristics on primary zone emissions. Local concentrations of oxides of nitrogen, carbon monoxide and unburned hydrocarbons at various locations in the flow, local gas temperature, gas velocity, and the turbulence intensity (measured with laser velocimetry) are obtained. A comprehensive data analysis program to compute the local fuel/air ratio and the sum of the mole fractions of the species present confirms the validity of the emissions data. Increasing drop size is correlated with an increase in unburned hydrocarbons, while increasing residence time is associated with sharp decreases in hydrocarbons and carbon monoxide and an increase in oxides of nitrogen.

Nicholls, J. A.↗

Friction and wear of plasma-sprayed coatings containing cobalt alloys from 25 deg to 650 deg in air

Four different compositions of self-lubricating, plasma-sprayed, composite coatings with calcium fluoride dispersed throughout cobalt alloy-silver matrices were evaluated on a friction and wear apparatus. In addition, coatings of the cobalt alloys alone and one coating with a nickel alloy-silver matrix were evaluated for comparison. The wear specimens consisted of two, diametrically opposed, flat rub shoes sliding on the coated, cylindrical surface of a rotating disk. Two of the cobalt composite coatings gave a friction coefficient of about 0.25 and low wear at room temperature, 400 and 650 C. Wear rates were lower than those of the cobalt alloys alone or the nickel alloy composite coating. However, oxidation limited the maximum useful temperature of the cobalt composite coating to about 650 C compared to about 900 C for the nickel composite coating.

Sliney, H. E.↗

Plasma-sprayed dual density ceramic turbine seal system

Dual density, plasma sprayed ceramic coating systems were investigated for possible application as abradable turbine tip seal systems in small gas turbine engines. Abradability, erosion resistance, internal leakage, and microstructural characterization were investigated for polyester and cenosphere filled zirconium oxide composites. Results indicate the polyester system is more abradable but displays significantly less erosion resistance than the cenosphere system. It is also stated that the absence of significant blade tip damage during abradability testing of both systems suggests additional effort may result in a more nearly optimum balance of abradability and erosion resistance.

Clingman, D. L.↗

Program to develop sprayed, plastically deformable compressor shroud seal materials

A study of fundamental rub behavior for ten dense sprayed materials and eight current compressor clearance materials has been conducted. A literature survey of a wide variety of metallurgical and thermophysical properties was conducted and correlated to rub behavior. Based on these results, the most promising dense rub material was Cu-9Al. Additional studies on the effects of porosity, incursion rate, blade solidity and ambient temperature were carried out on aluminum bronze (Cu-9Al-1Fe) with and without a 515B Feltmetal underlayer.

Schwab, R. C.↗

Atomization of a liquid by a spray nozzle

The theory of atomization by mechanical and pneumatic (or vapor) spray nozzles is discussed. Basic design recommendations resulting from generalization of the material and confirmed by experiments are given. Sprayers which are widely used in the furnaces of stationary steam boilers, the combustion chambers of gas turbines, and industrial furnaces are examined.

Kutateladze, S. S.↗

InP and GaAs characterization with variable stoichiometry obtained by molecular spray

Both InP and GaAs surfaces were studied in parallel. A molecular spray technique was used to obtain two semiconductor surfaces with different superficial compositions. The structures of these surfaces were examined by electron diffraction. Electron energy loss was measured spectroscopically in order to determine surface electrical characteristics. The results are used to support conclusions relative to the role of surface composition in establishing a Schottky barrier effect in semiconductor devices.

Massies, J.↗

Friction and wear of plasma-sprayed coatings containing cobalt alloys from 25 deg to 650 deg in air

Four different compositions of self-lubricating, plasma-sprayed, composite coatings with calcium fluoride dispersed throughout cobalt alloy-silver matrices were evaluated on a friction and wear apparatus. In addition, coatings of the cobalt alloys alone and of one coating with a nickel alloy-silver matrix were evaluated for comparison. The wear specimens consisted of two, diametrically opposed, flat rub shoes sliding on the coated, cylindrical surface of a rotating disk. Two of the cobalt composite coatings gave a friction coefficient of about 0.25 and low wear at room temperature, 400 and 650 C. Wear rates were lower than those of the cobalt alloys alone or the nickel alloy composite coating. However, oxidation limited the maximum useful temperature of the cobalt composite coating to about 650 C compared to about 900 C for the nickel composite coating.

Sliney, H. E.↗

Program to develop sprayed, plastically deformable compressor shroud seal materials

A study of fundamental rub behavior for 10 dense, sprayed materials and eight current compressor clearance materials was conducted. A literature survey of a wide variety of metallurgical and thermophysical properties was conducted and correlated to rub behavior. Based on the results, the most promising dense rub material was Cu-9A1. Additional studies on the effects of porosity, incursion rate, blade solidity, and ambient temperature were carried out on aluminum bronze (Cu-9Al-1Fe) with and without a 515B Feltmetal underlayer. A further development effort was conducted to assess the property requirements of a porous, aluminum bronze, seal material. Strength, thermal cycle capabilities, erosion and oxidation resistance, machinability, and abradability at several porosity levels were examined.

Schell, J. D.↗

Measurement of fuel spray vaporisation by laser techniques

Comparison of fuel spray structures in heated and in cold environments is made by using a new laser tomographic technique and laser anemometry. The tomography technique is shown to give accurate and rapid 'point' measurements of droplet sizes and concentrations. Experimental results show acceleration of droplets to the local gas velocity, preferential vaporisation of the smallest droplets and the dispersion of droplets by the turbulence.

Yule, A. J.↗

Sodium Spray Would Speed Silicon Production

Production rate of solar-grade silicon in sodium/silicon tetrafluoride reactor increase by spray feed. Liquid-sodium droplet size is controlled by pressure of argon gas and by nozzle design. Baffle helps to prevent reactor opening from becoming clogged by reaction products.

Sancier, K. M.↗

Process Sprays Uniforms Plasma Coatings

Composite-powder processing procedure developed along with plasma-spray parameters to achieve homogeneous, well-bonded, low-porosity, self-lubricating coatings. Multicomponent plasma coatings are applied without segretation of components.

Sliney, H. E.↗

Effects of arc current on the life in burner rig thermal cycling of plasma sprayed ZrOsub2-Ysub2Osub3

An analysis of thermal cycle life data for four sets of eight thermal barrier coated specimens representing arc currents (plasma gun power) of 525, 600, 800, or 950 amps is presented. The ZrO2-8Y2O3/NiCrAlY plasma spray coated Rene 41 rods were thermal cycled to 1040 C in a Mach 0.3-Jet A/air burner flame. The experimental results indicate the existance of a minimum or threshold power level which coating life expectancy is less than 500 cycles. Above the threshold power level, coating life expectancy more than doubles and increases with arc current.

Hendricks, R. C.↗