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Space Shuttle cloud detection and earth feature classification experiment

The Feature Identification and Location Experiment (FILE) that is being designed for the detection and classification of four primary earth features (water, vegetation, bare land, and the clouds-snow-ice class) is described. Consideration is given to the FILE classification technology concept and the FILE instrument, which will use two solid-state CCD cameras operating at 0.65 and 0.85-micron center frequency wavelengths, with the camera outputs being functions of the earth surface material radiance. The classification is based on camera output radiance ratio values. The preliminary analysis of the data collected on the STS 41-G mission is discussed. The results demonstrated the suitability of using the two-channel-ratio detection technology and a simple (y = mx) algorithm to autonomously classify the four earth surface features. The technology is especially attractive as a cloud sensor, where, in advance of or during a mission, a threshold value for cloud cover percentage can be programmed and/or adaptively modified for use in the control of other remote sensors.

Sivertson, W. E., Jr.↗

Evaluation of Manganese Doped Ca5(PO4)3F as a Near Infrared (1-2 microns) Solid-State Laser Material

Tunable solid-state lasers are of enormous interest for applications including fundamental spectroscopy, remote sensing of the earth atmosphere, medical surgery, and optical communications. Efficient and widely tunable lasers have been developed for the 800-1100 nm region based on transition metal doped insulators like e.g. Ti:Sapphire. The development of transition metal lasers operating at longer wavelength, however, has been limited by the luminescence efficiency of existing materials. We are currently evaluating Mn doped Ca5(PO4)3F as a new solid-state laser material for the 1-2 micro-m region. Preliminary spectroscopic studies revealed that Mn:Ca5(PO4)3F exhibits an intense near infrared luminescence which extends from 1100-1300 nm. Based on lifetime measurements we estimated the luminescence quantum efficiency to be as high as 90 deg./0 at room temperature. The near infrared luminescence properties of Mn doped Ca5(PO4)3F and its potential for solid-state laser applications will be discussed in detail.

Turner, Matthew↗

Using the Moon and Mars as Giant Detectors for Strange Quark Nuggets

On the Earth, the detectability of small seismic signals is limited by pervasive seismic background noise, caused primarily by interactions of the atmosphere and oceans with the solid surface. Mars, with a very thin atmosphere and no ocean is expected to have a noise level at least an order of magnitude lower than the Earth, and the airless Moon is even quieter still. These pristine low-vibration environments are ideal for searching for nuggets of "strange quark matter." Strange quark matter was postulated by Edward Witten [Phys. Rev. D30, 272, 1984] as the lowest possible energy state of matter. It would be made of up, down, and strange quarks, instead of protons and neutrons made only of up and down quarks. It would have nuclear densities, and hence be difficult to detect. Micron-sized nuggets would weigh in the ton range. As suggested by de Rujula and Glashow [Nature 312 (5996): 734, 1984], a massive strange quark nugget can generate a trail of seismic waves, as it traverses a celestial body. We discuss the mission concept for deploying a network of sensitive seismometers on Mars and on the Moon for such a search.

Chui, Talso↗

Integrated low carbon H 2 conversion with in situ carbon mineralization from aqueous biomass oxygenate precursors by tuning reactive multiphase chemical interactions

Meeting our rising demand for clean energy carriers such as H 2 from renewable biomass resources is challenged by the co-emission of CO 2 and CH 4 . To address this challenge, we design novel reactive separation pathways that integrate multiphase chemical reactions by harnessing Ca and Mg bearing minerals as a sorbent to capture CO 2 released during the hydrothermal deconstruction of aqueous biomass oxygenates to produce H 2 and solid carbonates via low temperature aqueous phase reforming and thermodynamically downhill carbon mineralization. Earth abundant catalysts such as Ni/Al 2 O 3 are effective in producing H 2 yields as high as 79% and 74% using ethylene glycol and methanol in the presence of Ca(OH) 2 as an alkaline sorbent, without contaminating or deactivating the catalyst. H 2 yields with in situ carbon mineralization using a Ni or Pt/Al 2 O 3 catalyst are enhanced based on the following order of reactivity: acetate < glycerol < methanol < formate < ethylene glycol. These studies demonstrate that the multiphase chemical interactions can be successfully tuned to enhance H 2 yields through the selective cleavage of C–C bonds using Ni/Al 2 O 3 catalysts to deconstruct biomass oxygenates for producing H 2 and CO 2 , and in situ carbon mineralization by harnessing abundant alkaline materials, as demonstrated using ladle slag. This approach unlocks new scientific possibilities for harnessing multiple emissions including abundant organic-rich wastewater streams and alkaline industrial residues to co-produce low carbon H 2 and carbonate-bearing materials for use in construction by using renewable solar thermal energy resources.

09 BIOMASS FUELS↗

Deuterium and tritium from solar flares at approximately 10 MeV per nucleon

It is indicated that the observations with the high-resolution solid-state charged-particle telescopes of the IMP-5 and IMP-6 earth satellites have resolved all the hydrogen and helium isotopes of solar-flare origin in groups of solar flares during the period from September, 1969, through November, 1972. The values obtained for the average isotope ratios are given and are compared with previous values. It is concluded that the observed high yields of H(2), H(3) and He(3) can be explained only by high-energy nuclear interactions and that an acceleration process must have taken place in the chromosphere at that time.

Anglin, J. D.↗

Influence of convection on eutectic microstructure

When the MnBi-Bi eutectic is directionally solidified, it forms fibers of MnBi in a matrix of bismuth. When the material solidified in space at rates of 30 and 50 cm/hr, the average fiber spacing lambda was about one half of the value obtained in cases in which the same material solidified on earth. Neither an altered temperature gradient nor a fluctuating freezing rate are apparently responsible for the change in lambda, and the possibility is studied that natural convection increases lambda on earth by perturbing the compositional field in the melt ahead of the growing solid. A theoretical analysis is conducted along with some experiments. On the basis of the theoretical results for lamellar growth, it is concluded that the spacing lambda increases with increasing stirring, especially at small freezing rates. The experiments indicate that at low growth rates the cross-sectional area of the MnBi blades increases with increased stirring and with decreased growth rate.

Baskaran, V.↗

Study of meteoroid impact craters on various materials (AO 138-1). Attempt at dust debris collection with stacked detectors (AO 138-2)

Part of the Long Duration Exposure Facility (LDEF) tray allocated to French experiments, known as FRECOPA payload, was devoted to the study of dust particles. Two passive experiments were flown: one composed of a set of glass and metallic samples and one composed of multilayer thin foils detectors. In addition to these experiments, a broad variety of materials were exposed to the bombardment of microparticles and provide more data. Thick target experiment comprises selected metallic (Al, Au, Cu, W, Stainless Steel) 250 microns thick and glass surfaces 1.5 mm thick. Crater size distribution from these thick target experiments enable, with the aid of lab calibrations by solid particle accelerators, the evaluation of the incident microparticle flux in the near earth environment. The aim of the multiple foil penetration and collection experiment is primarily to study the feasibility of multilayer thin film detectors acting as energy sorters in order to collect micrometeoroids, if not in their original shape, at least as 'breakup' fragments suitable for chemical analysis. Foil thicknesses range from 0.75 to 5 microns of Al.

Mandeville, Jean Claude↗

Analytical Simulations of Energy-Absorbing Impact Spheres for a Mars Sample Return Earth Entry Vehicle

Nonlinear dynamic finite element simulations were performed to aid in the design of an energy-absorbing impact sphere for a passive Earth Entry Vehicle (EEV) that is a possible architecture for the Mars Sample Return (MSR) mission. The MSR EEV concept uses an entry capsule and energy-absorbing impact sphere designed to contain and limit the acceleration of collected samples during Earth impact without a parachute. The spherical shaped impact sphere is composed of solid hexagonal and pentagonal foam-filled cells with hybrid composite, graphite-epoxy/Kevlar cell walls. Collected Martian samples will fit inside a smaller spherical sample container at the center of the EEV's cellular structure. Comparisons were made of analytical results obtained using MSC.Dytran with test results obtained from impact tests performed at NASA Langley Research Center for impact velocities from 30 to 40 m/s. Acceleration, velocity, and deformation results compared well with the test results. The correlated finite element model was then used for simulations of various off-nominal impact scenarios. Off-nominal simulations at an impact velocity of 40 m/s included a rotated cellular structure impact onto a flat surface, a cellular structure impact onto an angled surface, and a cellular structure impact onto the corner of a step.

Billings, Marcus Dwight↗

A Bootstrap Approach to Martian Manufacturing

In-Situ Resource Utilization (ISRU) is an essential element of any affordable strategy for a sustained human presence on Mars. Ideally, Martian habitats would be extremely massive to allow plenty of room to comfortably live and work, as well as to protect the occupants from the environment. Moreover, transportation and power generation systems would also require significant mass if affordable. For our approach to ISRU, we use the industrialization of the U.S. as a metaphor. The 19th century started with small blacksmith shops and ended with massive steel mills primarily accomplished by blacksmiths increasing their production capacity and product size to create larger shops, which produced small mills, which produced the large steel mills that industrialized the country. Most of the mass of a steel mill is comprised of steel in simple shapes, which are produced and repaired with few pieces of equipment also mostly made of steel in basic shapes. Due to this simplicity, we expect that the 19th century manufacturing growth can be repeated on Mars in the 21st century using robots as the primary labor force. We suggest a "bootstrap" approach to manufacturing on Mars that uses a "seed" manufacturing system that uses regolith to create major structural components and spare parts. The regolith would be melted, foamed, and sintered as needed to fabricate parts using casting and solid freeform fabrication techniques. Complex components, such as electronics, would be brought from Earth and integrated as needed. These parts would be assembled to create additional manufacturing systems, which can be both more capable and higher capacity. These subsequent manufacturing systems could refine vast amounts of raw materials to create large components, as well as assemble equipment, habitats, pressure vessels, cranes, pipelines, railways, trains, power generation stations, and other facilities needed to economically maintain a sustained human presence on Mars.

Dorais, Gregory A.↗

Data Analysis for GOPEX Laser Communications Experiment

This paper describes the data analysis based on the image frames received at the Solid State Imaging camera of the Galileo Optical-communications from an Earth-based Transmitter demonstration conducted between December 9 and December 16 of 1992.

SSI Galileo GOPEX laser communication↗

Easing into Reality: Experimental Impacts into Slopes and Layers

Impact cratering is the dominant geo-logic process affecting the surfaces of solid bodies throughout our solar system. Because large impacts are (luckily) rare on Earth, the process is studied through experiments, observations of existing structures, numerical modeling, and theory, most of which make the simplifying assumptions that the target is homogeneous, with no substantial topography. Craters do not always form on level targets com-posed of homogeneous loose material. Rather (Fig. 1), they often form on sloped surfaces and in layered tar-gets, both of which significantly influence the excavation and ejecta deposition processes. Such craters are common on the Moon and asteroids. We are investigating crater formation in two separate suites of experiments using sloped and layered targets (Fig. 2) at the Experimental Impact Laboratory at NASA Johnson Space Center. An experiment was also performed in a flat, homogenous target to serve as a reference.

Ebel, J. M.↗

The absence of convective stability in incongruent crystal growth on Earth

It is often assumed that convection can be excluded in materials processing by avoiding horizontal temperature gradients, and employing top-heating and horizontal interfaces. Model calculations for vapor transport processes show that this supposition holds only for strictly congruent vapor-solid transitions. This result can be generalized to all fluid-solid phase transitions. Due to the omnipresence of impurity segregation, it is concluded that convective stability is practically unattainable in materials processing on Earth.

Rosenberger, F. E.↗

Sound Velocity and Grüneisen Parameter in Shock‐Melted Silica at Deep Earth Pressures

Silica is a primary component of rocky planet interiors and its melt properties are important for understanding planetary formation and differentiation, magma oceans, and the deep mantle. Although well understood in the solid state, the high-pressure behavior of liquid silica is poorly constrained at lower mantle pressures. Using laser interferometry to measure shock wave profiles, we report measured stress-density states and longitudinal sound speeds in shock-synthesized stishovite, from fused silica staring material, and across the solid-liquid phase boundary up to 154 GPa. Our results constrain completion of melt at 80 GPa and show that at pressures relevant to the deep mantles of Earth-sized, rocky planets, the Grüneisen parameter for liquid silica increases with compression. This finding is consistent with a continuous increase in Si-O coordination above six for liquid silica at core-mantle boundary relevant pressures and temperatures.

Ocampo, I. K. [Princeton University, NJ (United St↗

Synthesizing Lithium Sorbents Using Acid Mine Drainage Solids

In this study, we prepared HMO from coal mine drainage (CMD) solids and examined the practicability of recovering Li from oil and gas produced waters and geothermal brines. We aim to innovate high-value added products from the existing extract REEs and CMs processing chain of legacy byproducts associated with coal production. CMD solids, which are precipitates collected from exhausted limestone gravels of passive CMD treatment beds, are enriched in rare earth elements (REEs) and other critical minerals (CMs), and therefore, considered as a viable alternative source for REEs/CMs to supply the Nation’s demands. A patented extraction process developed by NETL (TREE) has been demonstrated as a cost-effective and efficient approach to recover REEs/CMs from CMD solids. Here, we selected residuals of CMD solids from the TREE process that are enriched in manganese (Mn) (&gt;20% w/w) and successfully prepared LMO using a solid-state method modified from Yoshizuka et al. (2002).

Cheng, Chin-Min↗

Planet Formation by Gas-assisted Accretion of Small Solids

We compute the accretion efficiency of small solids, with radii 1 cm ≤ R s ≤ 10 m, on planets embedded in gaseous disks. Planets have masses 3 ≤ M p ≤ 20 Earth masses (M ⊕ ) and orbit within 10 au of a solar mass star. Disk thermodynamics is modeled via 3D radiation-hydrodynamics calculations that typically resolve the planetary envelopes. Both icy and rocky solids are considered, explicitly modeling their thermodynamic evolution. The maximum efficiencies of 1 ≤ R s ≤ 100 cm particles are generally ≲10%, whereas 10 m solids tend to accrete efficiently or be segregated beyond the planet’s orbit. A simplified approach is applied to compute the accretion efficiency of small cores, with masses M p ≤ 1 M ⊕ and without envelopes, for which efficiencies are approximately proportional to $M^{2/3}_{p}$. The mass flux of solids, estimated from unperturbed drag-induced drift velocities, provides typical accretion rates dM p /dt ≲ 10 -5 M ⊕ yr -1 . In representative disk models with an initial gas-to-dust mass ratio of 70–100 and total mass of 0.05–0.06 M ⊙ , the solids’ accretion falls below 10 -6 M ⊕ yr -1 after 1–1.5 Myr. The derived accretion rates, as functions of time and planet mass, are applied to formation calculations that compute dust opacity self-consistently with the delivery of solids to the envelope. Assuming dust-to-solid coagulation times of ≈0.3 Myr and disk lifetimes of ≈3.5 Myr, heavy-element inventories in the range 3–7 M ⊕ require that ≈90–150 M ⊕ of solids cross the planet’s orbit. The formation calculations encompass a variety of outcomes, from planets a few times M ⊕ , predominantly composed of heavy elements, to giant planets. The peak luminosities during the epoch of the solids’ accretion range from ≈10 -7 to ≈10 -6 L ⊙ .

79 ASTRONOMY AND ASTROPHYSICS↗

Synthesis of Amino Acid Precursors with Organic Solids in Planetesimals with Liquid Water

Amino acids are important ingredients of life that would have been delivered to Earth by extraterrestrial sources, e.g., comets and meteorites. Amino acids are found in aqueously altered carbonaceous chondrites in good part in the form of precursors that release amino acids after acid hydrolysis. Meanwhile, most of the organic carbon (greater than 70 weight %) in carbonaceous chondrites exists in the form of solvent insoluble organic matter (IOM) with complex macromolecular structures. Complex macromolecular organic matter can be produced by either photolysis of interstellar ices or aqueous chemistry in planetesimals. We focused on the synthesis of amino acids during aqueous alteration, and demonstrated one-pot synthesis of a complex suite of amino acids simultaneously with IOM via hydrothermal experiments simulating the aqueous processing

Kebukawa, Y↗

Implications of the iron oxide phase transition on the interiors of rocky exoplanets

The discovery of an extraordinary number of extrasolar planets, characterized by an unexpected variety of sizes, masses and orbits, challenges our understanding of the formation and evolution of the planets in the Solar System and the perception of the Earth as the prototypical habitable world. Many exoplanets appear to be rocky and yet more massive than the Earth, with expected pressures and temperatures of hundreds of gigapascal and thousands of Kelvin in their deep interiors. At these conditions, the properties of bridgmanite and ferropericlase, expected to dominate their mantles, are largely unconstrained, limiting our knowledge of their interior structure. Here we used nano-second X-ray diffraction and dynamic compression to experimentally investigate the atomic structure and density of iron oxide (FeO), one of the end-members of the (Mg,Fe)O ferropericlase solid solution, up to 700 GPa, a pressure exceeding the core–mantle boundary of a 5 Earth masses planet. Our data document the stability of the high-pressure cesium-chloride B2 structure above 300 GPa, well below the pressure required for magnesium oxide (MgO) to adopt the same phase. These observations, complemented by the calculation of the binary MgO–FeO phase diagram, reveal complex stratification and rheology inside large terrestrial exoplanets.

58 GEOSCIENCES↗

Performance of Surface-Mount Ceramic and Solid Tantalum Capacitors for Cryogenic Applications

Low temperature electronics are of great interest for space exploration programs. These include missions to the outer planets, earth-orbiting and deep-space probes, remote-sensing and communication satellites. Terrestrial applications would also benefit from the availability of low temperature electronics. Power components capable of low temperature operation would, thus, enhance the technologies needed for the development of advanced power systems suitable for use in harsh environments. In this work, ceramic and solid tantalum capacitors were evaluated in terms of their dielectric properties as a function of temperature and at various frequencies. The surface-mount devices were characterized in terms of their capacitance stability and dissipation factor in the frequency range of 50 Hz to 100 kHz at temperatures ranging from room temperature (20 deg. C) to about liquid nitrogen temperature (-190 deg. C). The results are discussed and conclusions made concerning the suitability of the capacitors investigated for low temperature applications.

Patterson, Richard L.↗