Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “plasma processing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 775 records · Page 43

Effects of Kinetic Processes in Shaping Io's Global Plasma Environment: A 3D Hybrid Model

The global dynamics of the ionized and neutral gases in the environment of Io plays an important role in the interaction of Jupiter s corotating magnetospheric plasma with Io. Stationary simulations of this problem have already been done using the magnetohydrodynamics (MHD) and the electrodynamics approaches. One of the major results of recent simplified two-fluid model simulations [Saur, J., Neubauer, F.M., Strobel, D.F., Summers, M.E., 2002. J. Geophys. Res. 107 (SMP5), 1-18] was the production of the structure of the double-peak in the magnetic field signature of the Io flyby. These could not be explained before by standard MHD models. In this paper, we present a hybrid simulation for Io with kinetic ions and fluid electrons. This method employs a fluid description for electrons and neutrals, whereas for ions a particle approach is used. We also take into account charge-exchange and photoionization processes and solve self-consistently for electric and magnetic fields. Our model may provide a much more accurate description for the ion dynamics than previous approaches and allows us to account for the realistic anisotropic ion velocity distribution that cannot be done in fluid simulations with isotropic temperatures. The first results of such a simulation of the dynamics of ions in Io s environment are discussed in this paper. Comparison with the Galileo IO flyby results shows that this approach provides an accurate physical basis for the interaction and can therefore naturally reproduce all the observed salient features.

Lipatov, Alexander S.↗

Spatiotemporal characterization of cerium monoxide in laser ablation plasmas using spectrally-resolved fast-gated imaging

The impact of oxidation chemistry on the emission characteristics and spatial structure of laser-produced Ce metal plasmas was investigated using laser-induced breakdown spectroscopy (LIBS) and time-resolved fast-gated imaging employing narrowband optical filters. Images of the plasma emission show that CeO coexists with atomic species in the periphery and vortex ring of the plasma plume. Image processing was also applied to combine independent monochromatic images of the plasma emission into a single merged image, culminating in a timelapse on the spatiotemporal evolution of atomic and molecular species within the plasma plume. The formation of CeO species was observed to proceed faster for plasmas generated in atmospheres containing larger concentrations of oxygen based on ratios of CeO-to-atomic emission intensities. Furthermore, these same ratios were shown to plateau and decrease at later times (≥25 μs), potentially indicating the depletion of CeO number densities in the plasma as the monoxide undergoes reactions to form higher polyatomic oxides. Altogether, these results provide fundamental insights into the chemical dynamics and intermixing between plasma-gas species in laser ablation cerium plasmas, advancing our understanding on optical signatures of nuclear-relevant materials to enable in-field measurement capabilities.

47 OTHER INSTRUMENTATION↗

Expansion-Driven Self-Magnetization of High-Energy-Density Plasmas

Understanding plasma self-magnetization is one of the fundamental challenges in both laboratory and astrophysical plasmas. Self-magnetization can modify plasma transport properties, altering the dynamical evolution of plasmas. Multiple high-energy-density (HED) experiments have observed the formation of ion-scale magnetic filaments of megagauss strength, though their origin remains debated. Here, in this study, we conduct 2D collisional particle-in-cell (PIC) simulations with a laser ray-tracing module for a fully self-consistent simulation of the plasma ablation, expansion, and magnetization. The simulations use a planar geometry, effectively suppressing the Biermann magnetic fields, to focus on anisotropy-driven instabilities. The laser intensity is varied between 10 13 and 10 14 W/cm 2 , which is relevant to HED and inertial fusion experiments where collisions must be considered. We find that, above a critical intensity, the plasma rapidly self-magnetizes via an expansion-driven Weibel process, producing a plasma beta of 100 (𝛽 = 8⁢𝜋⁢𝑘 𝐵 ⁢𝑛 𝑒 ⁢𝑇 𝑒 /𝐵 2 ) and Hall parameter 𝜔 ce ⁢𝜏 𝑒 >1 within the first few hundred picoseconds. The magnetic field is sufficiently strong to modify plasma heat transport, and simulations with an artificially suppressed magnetic field show noticeably different temperature profiles.

Lezhnin, K. V. [Princeton Plasma Physics Laborator↗

Orientation-dependent etching of silicon by fluorine molecules: A quantum chemistry computational study

Anisotropic etching is a widely used process in semiconductor manufacturing, in particular, for micro- and nanoscale texturing of silicon surfaces for black silicon production. The typical process of plasma-assisted etching uses energetic ions to remove materials in the vertical direction, creating anisotropic etch profiles. Plasmaless anisotropic etching, considered here, is a less common process that does not use ions and plasma. The anisotropy is caused by the unequal etching rates of different crystal planes; the etching process, thus, proceeds in a preferred direction. In this paper, we have performed quantum chemistry modeling of gas-surface reactions involved in the etching of silicon surfaces by molecular fluorine. The results confirm that orientation-dependent etch rates are the reason for anisotropy. The modeling of F 2 dissociative chemisorption on F-terminated silicon surfaces shows that Si–Si bond breaking is slow for the Si(111) surface, while it is fast for Si(100) and Si(110) surfaces. Both Si(100) and Si(110) surfaces incorporate a larger number of fluorine atoms resulting in Si–Si bonds having a larger amount of positive charge, which lowers the reaction barrier of F 2 dissociative chemisorption, yielding a higher etch rate for Si(100) and Si(110) surfaces compared to Si(111) surfaces. Molecular dynamics modeling of the same reactions has shown that the chosen reactive bond order potential does not accurately reproduce the lower reaction barriers for F 2 dissociative chemisorption on Si(100) and Si(100) surfaces. Furthermore, reparameterization is necessary to model the anisotropic etching process that occurs at lower temperatures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Kinetic Space Weather: Toward a Global Hybrid Model of the Polar Ionosphere-Lower Magnetosphere Plasma Transport

During the indicated period of performance, we had a number of publications concerned with kinetic polar ionosphere-lower magnetosphere plasma transport. For the IUGG 1991-4 Quadrennial Report, we reviewed aspects of U.S. accomplishments concerned with polar plasma transport, among other issues. In another review, we examined the computer simulations of multiple-scale processes in space plasmas, including polar plasma outflow and transport. We also examined specifically multiscale processes in ionospheric outflows. We developed a Generalized Semi-Kinetic(GSK) model for the topside-lower magnetosphere which explored the synergistic action of wave heating and electric potentials in the formation of auroral Ion conics, in particular the "pressure cooker" mechanism. We extended the GSK model all the way down to 120 km and applied this code to illustrate the response of the ionosphere- magnetosphere to soft-electron precipitation and convection-driven frictional ion heating, respectively. Later, the convection-driven heating work was extended to a paper for the Journal of Geophysical Research. In addition to the above full published papers, we also presented the first developments of the coupled fluid-semikinetic model for polar plasma transport during this period. The results from a steady-state treatment were presented, with the second presentation being concerned with the effects of photo-electrons on the polar wind, and the first garnering an outstanding student paper award from the American Geophysical Union. We presented the first results from a time-dependent version of this coupled fluid-semikinetic model.

Horwitz, James L.↗

Experimental and computational investigation into the hydrodynamics and chemical dynamics of laser ablation aluminum plasmas

Laser ablation plasma chemistry is governed by a complex interplay between hydrodynamic plasma-gas mixing processes, thermodynamics, and rapid high-temperature chemical reactions. Here, in this work, we investigate the gas-phase oxidation chemistry of ns-laser ablation aluminum plasmas in air using optical spectroscopy combined with advanced multi-physics modeling. Experimental measurements demonstrate the formation of AlO in the plasma plume as early as 1 μs while computational results reveal that several Al x O y species are distributed in the periphery of the plume at even earlier times (<20 ns) in the presence of large temperature gradients and strong shockwaves. Interactions with the ablation crater during rapid plume expansion are shown to initiate vortex formation, followed by mixing dynamics that work to pull AlO into the vortices to react with gas-phase Al to form Al 2 O. Oxygen and several aluminum oxides are simultaneously pulled up through the stem of the fireball, encouraging further intermixing between reacting species and enhanced molecular formation. This work concludes that chemical dynamics in laser ablation plasmas is driven by diffusion processes, concentration gradients, and plume hydrodynamics while strong shockwaves generated during laser ablation do not impede chemical reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pulsed power to control growth of silicon nanoparticles in low temperature flowing plasmas

Low-temperature plasmas have seen increasing use for synthesizing high-quality, mono-disperse nanoparticles (NPs). Recent work has highlighted that an important process in NP growth in plasmas is particle trapping—small, negatively charged nanoparticles become trapped by the positive electrostatic potential in the plasma, even if only momentarily charged. In this article, results are discussed from a computational investigation into how pulsing the power applied to an inductively coupled plasma (ICP) reactor may be used for controlling the size of NPs synthesized in the plasma. The model system is an ICP at 1 Torr to grow silicon NPs from an Ar/SiH 4 gas mixture. This system was simulated using a two-dimensional plasma hydrodynamics model coupled to a three-dimensional kinetic NP growth and trajectory tracking model. The effects of pulse frequency and pulse duty cycle are discussed. We identified separate regimes of pulsing where particles become trapped for one pulsed cycle, a few cycles, and many cycles—each having noticeable effects on particle size distributions. For the same average power, pulsing can produce a stronger trapping potential for particles when compared to continuous wave power, potentially increasing particle mono-dispersity. Pulsing may also offer a larger degree of control over particle size for the same average power. Experimental confirmation of predicted trends is discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Rotating Alfvén waves in rotating plasmas

Angular momentum coupling between a rotating magnetized plasma and torsional Alfvén waves carrying orbital angular momentum (OAM) is examined. It is demonstrated not only that rotation is the source of Fresnel–Faraday rotation – or orbital Faraday rotation effects – for OAM-carrying Alfvén waves, but also that angular momentum from an OAM-carrying Alfvén wave can be transferred to a rotating plasma through the inverse process. For the direct process, the transverse structure angular rotation frequency is derived by considering the dispersion relation for modes with opposite OAM content. For the inverse process, the torque exerted on the plasma is derived as a function of wave and plasma parameters.

Physics↗

A deficiency of O III in the Io plasma torus

Evidence for a deficiency of O III ions in the Io plasma torus is reported and implications of this deficiency for the physical processes controlling the plasma are considered. Observations of the O III 5007-A as well as Cl III and S III emissions from the Io plasma torus were made by a ground-based echelle spectrograph and intensified Reticon detector in February and May, 1981. The O III observations allow an upper limit of 4/cu cm to be placed on torus O III abundance, which is inconsistent with expectations for a low density plasma controlled by electron collisions. The inclusion of ion-ion and ion-atom charge exchange reactions and a depleted high energy electron component in the model is found to suppress O III levels, however observed limiting values are only achieved if it is assumed that the O III is kinetically hot. In addition, the charge-exchange model developed is inconsistent with previous observations of the kinetics of the S II-S III system. The present observations also establish upper limits of 2 R on 5518-A and 5538-A Cl III emission, and an emission rate of 58 + or - 40 R for the S III 6312-A line in the hot torus.

Brown, R. A.↗

Global simulation of the solar wind-magnetosphere interaction - The importance of its numerical validity

This paper examines the global interaction of the solar wind with the geomagnetic field, using a newly developed three-dimensional high-precision MHD simulation code which employs the fourth-order Runge-Kutta-Gill scheme in time and the direct finite-difference method in space, and which allows much less numerical error than the conventional code. The simulation reveals in detail the formation processes of the magnetosphere and the bow shock, as well as the plasma sheet formation process. It is shown that, contrary to the conventional understanding, no Kelvin-Helmholtz instability occurs along the magnetopause in an ideal MHD.

Watanabe, K.↗

Weld Pool Stability in the Flat Position

The Soft Plasma Arc (SPA) process was devised to avoid interactions between backshield and full penetration mode plasma jet in welding 2195 aluminum-lithium alloy. Occasional sudden and mysterious losses in penetration were encountered in flat position SPA welding. To understand what was happening a model of the dynamics of the molten metal meniscus at the root of the weld was worked out. When the power input to the weld P(sub in) exceeds the power leakage P(sub out) the difference in power is absorbed by an increase in the molten weld pool volume V, Rho X L(SUB m) X (d(V)/dt)) = P(sub in) - P(sub out) where rho is the density and L(sub m) the specific heat of the weld metal.

Nunes, A. C., Jr.↗

Fabrication of High Temperature Cermet Materials for Nuclear Thermal Propulsion

Processing techniques are being developed to fabricate refractory metal and ceramic cermet materials for Nuclear Thermal Propulsion (NTP). Significant advances have been made in the area of high-temperature cermet fuel processing since RoverNERVA. Cermet materials offer several advantages such as retention of fission products and fuels, thermal shock resistance, hydrogen compatibility, high conductivity, and high strength. Recent NASA h d e d research has demonstrated the net shape fabrication of W-Re-HfC and other refractory metal and ceramic components that are similar to UN/W-Re cermet fuels. This effort is focused on basic research and characterization to identify the most promising compositions and processing techniques. A particular emphasis is being placed on low cost processes to fabricate near net shape parts of practical size. Several processing methods including Vacuum Plasma Spray (VPS) and conventional PM processes are being evaluated to fabricate material property samples and components. Surrogate W-Re/ZrN cermet fuel materials are being used to develop processing techniques for both coated and uncoated ceramic particles. After process optimization, depleted uranium-based cermets will be fabricated and tested to evaluate mechanical, thermal, and hot H2 erosion properties. This paper provides details on the current results of the project.

Hickman, Robert↗

The terrestrial plasma source - A new perspective in solar-terrestrial processes from Dynamics Explorer

The geospace environment has been viewed as a mixing bowl for plasmas of both solar and terrestrial origin. The present perspective on the nature of the supply mechanisms has undergone a radical evolution over the past decade, particularly during the five years of the Dynamics Explorer mission. During this period, the terrestrial source has increased in importance in both magnitude and character of ionospheric outflow. These outflows include the classical polar wind, the cleft ion fountain, the auroral ion fountain, and the polar cap. The earth can be envisioned as a multifaceted fountain which ejects particles from different spatial locations spread around the globe. These particles exhibit a range of masses from 1 to 32 amu and a range of energies from 1 eV to 10 keV. The total flux of this ionospheric outflow is very large: adequate to supply the entire magnetospheric particle population. And the implications of the outflow are significant across a broad spectrum of solar-terrestrial processes ranging from sources of magnetospheric plasmas, to influences on ionospheric density and temperature structure, to energy transfer in phenomena such as stable auroral red arcs. The Dynamics Explorer mission has made a major contribution in the characterization of the terrestrial plasma source.

Chappell, Charles R.↗

Outstanding questions in magnetospheric plasma physics: The pollenzo view

Based on discussions held at a workshop in Bra-Pollenzo, Italy, this paper elaborates upon 19 outstanding questions of plasma physics in the Earth's magnetosphere. The questions are grouped according to (a) driving processes, (b) radiation belt and ring current issues, (c) auroral physics, (d) internal plasma processes, and (e) magnetosphere-ionosphere mapping issues. Future needs for magnetospheric plasma physics (measurements, techniques, simulations, theories, studies) are outlined.

79 ASTRONOMY AND ASTROPHYSICS↗