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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Design of Multi-Stage Solvent Extraction Process for Separation of Rare Earth Elements

Flowsheet design and stage determination for the separation of rare earth elements (REEs) using solvent extraction (SX) is a challenging task because of the chemical similarity of the REEs. Low separation factors between the elements and complex equilibrium chemistry provide unique challenges to designing an efficient flowsheet for the separation of elements. The multi-stage nature of the SX process adds further complexity, making the assessment of products for a proposed design and stage combination difficult. Therefore, to develop a SX flowsheet, it is essential to quantify the performance for various design and separation conditions. This paper attempts to address the challenge by utilizing an equilibrium and process modeling approach. Results from a bench-scale study performed on a 10 g/L rare earth salt mixture were used in studying the extraction/stripping behavior and developing equilibrium models. DEHPA with TBP as a phase modifier was used as an extractant, while hydrochloric acid was utilized as a stripping agent. The results obtained were used in developing extraction/stripping models, which were integrated into a process framework of a SX train in a Matlab/Simulink environment. The models were programmed as a function block routine and used for developing a flowsheet, which was simulated for differing separation and design conditions. To identify optimum stage combinations, a particle swarm optimization (PSO) routine was developed and implemented for each SX train. Recovery and purity of elements of interest were used as objective function criteria. The stage combination leading to the minimization of the objective function was used to identify the optimum stage combination for a series of SX trains to attempt a balance of purity and recovery. The models and optimization method were implemented to separate a feed mixture containing REEs, which indicated that 99.52 and 85.41 percent purity is achievable for Yttrium and Lanthanum separation using 8-12-3 and 10-3-5 stage combination for loading, scrubbing, and striping. The model also indicated difficult separability between neodymium, praseodymium, and cerium.

Srivastava, Vaibhav (ORCID:0000000212645987)↗
NASA NTRS1972

Signal sequence detection given noisy, common background image sets.

The optimum processing (likelihood functional) is found for a set of M images, each the sum of a member of a signal sequence due to an object to be detected and its parameters estimated, a sample function of a noise field, and a sample function of a common background field. The noise fields are independent, zero mean, white Gaussian fields, all independent of the background field. The latter is assumed to be either (1) completely unknown or of known mean and covariance functions with (2) a certain fluctuation property or (3) Gaussian. Three equivalent forms of the optimum processing are found: (1) a summation of generalized matched filterings of the images, (2) a summation of matched filtering of certain generalized differences of the images, and (3) a summation of 'estimator-correlator' type filterings. The detection performance and optimum signal/image selection under the Neyman-Pearson criterion is given, and is shown that optimum processor and signal design can completely eliminate any effect of the background on detectability.

Harger, R. O.↗
NASA NTRS1973

Study of multiple cycles valves

A discussion is presented regarding valves which can be cycled repeatedly and are available from industry for application in the inlet system for the Pioneer Venus Probe mass spectrometer. Both solenoid type and latching type valves are considered. The study is divided into two principal areas: (1) preparation of a valve specification reflecting the requirements of the inlet system cyclic valves for the Pioneer Venus Probe mass spectrometer and the submittal of this specification to potential valve suppliers for their response and proposal; (2) preparation of a design layout of an optimum cyclic valve meeting all of the valve specification requirements.

Wichmann, H.↗
NASA NTRS1976

Analytical study of electrical disconnect system for use on manned and unmanned missions

The objective of this contract is to establish an optimum electrical disconnect system design(s) for use on manned and unmanned missions. The purpose of the disconnect system is to electrically mate and demate the spacecraft to subsystem module interfaces to accomplish orbital operations. The results of Task 1 and Task 2 of the effort are presented. Task 1 involves the definition of the functional, operational, and environmental requirements for the connector system to support the leading prototype candidate concepts. Task 2 involves the documentation review and survey of available existing connector designs.

Rosener, A. A.↗
NASA NTRS1976

Structural optimization via a design space hierarchy

Mathematical programming techniques provide a general approach to automated structural design. An iterative method is proposed in which design is treated as a hierarchy of subproblems, one being locally constrained and the other being locally unconstrained. It is assumed that the design space is locally convex in the case of good initial designs and that the objective and constraint functions are continuous, with continuous first derivatives. A general design algorithm is outlined for finding a move direction which will decrease the value of the objective function while maintaining a feasible design. The case of one-dimensional search in a two-variable design space is discussed. Possible applications are discussed. A major feature of the proposed algorithm is its application to problems which are inherently ill-conditioned, such as design of structures for optimum geometry.

Vanderplaats, G. N.↗
NASA NTRS1977

F-8 supercritical wing flight pressure, Boundary layer, and wake measurements and comparisons with wind tunnel data

Data for speeds from Mach 0.50 to Mach 0.99 are presented for configurations with and without fuselage area-rule additions, with and without leading-edge vortex generators, and with and without boundary-layer trips on the wing. The wing pressure coefficients are tabulated. Comparisons between the airplane and model data show that higher second velocity peaks occurred on the airplane wing than on the model wing. The differences were attributed to wind tunnel wall interference effects that caused too much rear camber to be designed into the wing. Optimum flow conditions on the outboard wing section occurred at Mach 0.98 at an angle of attack near 4 deg. The measured differences in section drag with and without boundary-layer trips on the wing suggested that a region of laminar flow existed on the outboard wing without trips.

Montoya, L. C.↗
NASA NTRS1974

Fractional watt Vuillemier cryogenic refrigerator program engineering notebook. Volume 1: Thermal analysis

The cryogenic refrigerator thermal design calculations establish design approach and basic sizing of the machine's elements. After the basic design is defined, effort concentrates on matching the thermodynamic design with that of the heat transfer devices (heat exchangers and regenerators). Typically, the heat transfer device configurations and volumes are adjusted to improve their heat transfer and pressure drop characteristics. These adjustments imply that changes be made to the active displaced volumes, compensating for the influence of the heat transfer devices on the thermodynamic processes of the working fluid. Then, once the active volumes are changed, the heat transfer devices require adjustment to account for the variations in flows, pressure levels, and heat loads. This iterative process is continued until the thermodynamic cycle parameters match the design of the heat transfer devices. By examing several matched designs, a near-optimum refrigerator is selected.

Miller, W. S.↗
NASA NTRS1978

Trajectory module of the NASA Ames Research Center aircraft synthesis program ACSYNT

A program was developed to calculate trajectories for both military and commercial aircraft for use in the aircraft synthesis program, ACSYNT. The function of the trajectory module was to calculate the changes in the vehicle's flight conditions and weight, as fuel is consumed, during the flying of one or more missions. The trajectory calculations started with a takeoff, followed by up to 12 phases chosen from among the following: climb, cruise, acceleration, combat, loiter, descent, and paths. In addition, a balanced field length was computed. The emphasis was on relatively simple formulations and analytic expressions suitable for rapid computation since a prescribed trajectory had to be calculated many times in the process of converging an aircraft design, or finding an optimum configuration. The trajectory module consists of about 2500 cards and operational on a CDC 7600 computer.

Tauber, M. E.↗
NASA NTRS1979

Data System Implications Derived from User Application Requirements for Satellite Data

An investigation of the data system needs as driven by users of space acquired Earth observation data is documented. Two major categories of users, operational and research, are identified. Limiting data acquisition alleviates some of the delays in processing thus improving timeliness of the delivered product. Trade offs occur between timeliness and data distribution costs, and between data storage and reprocessing. The complexity of the data system requirements to apply space data to users' needs is such that no single analysis suffices to design and implement the optimum system. A series of iterations is required with analyses of the salient problems in a general way, followed by a limited implementation of benefit to some users with a continual upgrade in system capacity, functions, and applications served. The resulting most important requirement for the data system is flexibility to accommodate changing requirements as the system is implemented.

Neiers, J.↗
NASA NTRS1981

The CMG Nickel Electrode

The development and design of the Controlled Microgeometry electrode are described. Advantages of the electrode over others in existance include a higher number of ampere hours per kilogram and the ability to make them over a wide range of thicknesses. The parameters that control the performance of the electrode can be individually controlled over a wide range. Therefore, the electrode may be designed to give the optimum performance for a given duty cycle.

Depaul, R. A.↗
NASA NTRS1980

CCD data processor for maximum likelihood feature classification

The paper describes an advanced technology development which utilizes a high speed analog/binary CCD correlator to perform the matrix multiplications necessary to implement onboard feature classification. The matrix manipulation module uses the maximum likelihood classification algorithm assuming a Gaussian probability density function. The module will process 16 element multispectral vectors at rates in excess of 500 thousand multispectral vector elements per second. System design considerations for the optimum use of this module are discussed, test results from initial device fabrication runs are presented, and the performance in typical processing applications is described

Benz, H. F.↗
NASA NTRS1983

The Voyager Mission - Encounters with Saturn

The trajectories of Voyager 1 and Voyager 2 through the Saturnian system were selected in such a way that the observations would be complementary. The Voyager 1 trajectory provided a close encounter with Titan, making possible atmospheric occultations, a search for an intrinsic Titanian magnetic field, and studies of the interaction of Titan with either the solar wind or the Saturnian magnetosphere. The trajectory was also designed to provide an optimum geometry for the transmission of S and X band radio waves from the spacecraft through the rings; in this way, the attenuation and scattering of 3.6- and 13-cm waves by the ring particles could be observed. Besides this, Voyager 1 provided radio and ultraviolet occultation studies of Saturn's atmosphere as well as close approaches to three of the moderate-sized icy satellites (Mimas, Dione, and Rhea) and to a number of minor satellites. The much later arrival of Voyager 2 and the Saturn flyby distance were chosen in such a way as to make possible a gravity-assisted continuation on to Uranus and Neptune.

Stone, E. C.↗
NASA NTRS1984

Optimization and mechanisms of mistuning in cascades

In the present inverse design procedure for the optimum mistuning of a high bypass ratio shroudless fan that is modeled as a cascade of blades (each with a single torsional degree-of-freedom), linearized supersonic aerodynamic theory is used to compute the unsteady aerodynamic forces in the 'influence coefficient' form at a typical blade section. The mistuning pattern is then numerically optimized in order to achieve a specified increase in the aeroelastic stability margin with a minimum amount of mistuning. If the blades are self-damped, an optimized mistuning pattern can be found that achieves a given stability margin for a much lower level of mistuning than required for the alternate mistuning pattern, which requires only two blade frequencies and is relatively insensitive to implementation errors.

Crawley, E. F.↗
NASA NTRS1987

An aerodynamic comparison of blown and mechanical high lift airfoils

Short takeoff and landing (STOL) performance utilizing a circulation control airfoil was successfully demonstrated on the A-6 CCW (circulation control wing). Controlled flight at speeds as slow as 67 knots was demonstrated. Takeoff ground run and liftoff speed reductions in excess of 40 and 20 percent respectively were achieved. Landing ground roll and approach speeds were similarly reduced. The technology demonstrated was intended to be useable on modern high performance aircraft. STOL performance would be achieved through the combination of a 2-D vectored nozzle and a circulation control type of high lift system. The primary objective of this demonstration was to attain A-6 CCW magnitude reductions in takeoff and landing flight speed and ground distance requirements using practical bleed flow rates from a modern turbofan engine for the blown flap system. Also, cruise performance could not be reduced by the wing high lift system. The A-6 was again selected as the optimum demonstration vehicle. The procedure and findings of the study to select the optimum high lift wing design are documented. Some findings of a supercritical airfoil and a comparison of 2-D and 3-D results are also described.

Carr, John E.↗
NASA NTRS1988

Trellis-coded MPSK modulation techniques for MSAT-X(sup)1

Various trellis-coded modulated phase shift keying (MPSK) modulation techniques for transmitting 4.8 kbps over a 5 kHz RF channel are considered. The tradeoffs between coherent versus differentially coherent types of demodulation, and interleaving are discussed as well as optimum trellis-codes designed for fading channels. Simulation results are presented.

Divsalar, Dariush↗
NASA NTRS1988

Effects of maneuver dynamics on drag polars of the X-29A forward-swept-wing aircraft with automatic wing camber control

The camber control loop of the X-29A FSW aircraft was designed to furnish the optimum L/D for trimmed, stabilized flight. A marked difference was noted between automatic wing camber control loop behavior in dynamic maneuvers and in stabilized flight conditions, which in turn affected subsonic aerodynamic performance. The degree of drag level increase was a direct function of maneuver rate. Attention is given to the aircraft flight drag polar effects of maneuver dynamics in light of wing camber control loop schedule. The effect of changing camber scheduling to better track the optimum automatic camber control L/D schedule is discussed.

Hicks, John W.↗
NASA NTRS1989

Guidance and Control strategies for aerospace vehicles

A neighboring optimal guidance scheme was devised for a nonlinear dynamic system with stochastic inputs and perfect measurements as applicable to fuel optimal control of an aeroassisted orbital transfer vehicle. For the deterministic nonlinear dynamic system describing the atmospheric maneuver, a nominal trajectory was determined. Then, a neighboring, optimal guidance scheme was obtained for open loop and closed loop control configurations. Taking modelling uncertainties into account, a linear, stochastic, neighboring optimal guidance scheme was devised. Finally, the optimal trajectory was approximated as the sum of the deterministic nominal trajectory and the stochastic neighboring optimal solution. Numerical results are presented for a typical vehicle. A fuel-optimal control problem in aeroassisted noncoplanar orbital transfer is also addressed. The equations of motion for the atmospheric maneuver are nonlinear and the optimal (nominal) trajectory and control are obtained. In order to follow the nominal trajectory under actual conditions, a neighboring optimum guidance scheme is designed using linear quadratic regulator theory for onboard real-time implementation. One of the state variables is used as the independent variable in reference to the time. The weighting matrices in the performance index are chosen by a combination of a heuristic method and an optimal modal approach. The necessary feedback control law is obtained in order to minimize the deviations from the nominal conditions.

Hibey, J. L.↗