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At least 775 records · Page 43

Classification of asteroid spectra using a neural network

The 52-color asteroid survey (Bell et al., 1988) together with the 8-color asteroid survey (Zellner et al., 1985) provide a data set of asteroid spectra spanning 0.3-2.5 micrometers. An artificial neural network clusters these asteroid spectra based on their similarity to each other. We have also trained the neural network with a categorization learning output layer in a supervised mode to associate the established clusters with taxonomic classes. Results of our classification agree with Tholen's classification based on the 8-color data alone. When extending the spectral range using the 52-color survey data, we find that some modification of the Tholen classes is indicated to produce a cleaner, self-consistent set of taxonomic classes. After supervised training using our modified classes, the network correctly classifies both the training examples, and additional spectra into the correct class with an average of 90% accuracy. Our classification supports the separation of the K class from the S class, as suggested by Bell et al. (1987), based on the near-infrared spectrum. We define two end-member subclasses which seem to have compositional significance within the S class: the So class, which is olivine-rich and red, and the Sp class, which is pyroxene-rich and less red. The remaining S-class asteroids have intermediate compositions of both olivine and pyroxene and moderately red continua. The network clustering suggests some additional structure within the E-, M-, and P-class asteroids, even in the absence of albedo information, which is the only discriminant between these in the Tholen classification. New relationships are seen between the C class and related G, B, and F classes. However, in both cases, the number of spectra is too small to interpret or determine the significance of these separations.

Howell, E. S.↗

Mineralogy and Ar-39 - Ar-40 of an old pristine basalt: Thermal history of the HED parent body

Previous investigations of mineral chemistry and Rb-Sr and Sm-Nd ages indicated that clast,84 from eucrite Yamato 75011 had preserved the pristine nature of its initial crystallization during an early stage of the HED parent body. Microscale mineralogy and Ar-39-Ar-40 ages of this clast, however, revealed local disturbance of microtextures and partially reset ages. This evidence suggests that, in addition to initial crystallization and rapid cooling, the Y75011,84 clast experienced shock deformation, reheating of short duration at higher temperature, and brecciation. These characteristics suggest two or more impact events. Fe-rich olivine filling fractures in pyroxene may have been introduced during the accompanying shock fracturing. The inferred Ar-39-Ar-40 degassing ages for Y75011 matrix and clast, 84 are 3.94 +/- 0.04 Ga and 3.98 +/- 0.03 Ga, respectively. The suggested degassing age for a clast from Y790020, believed to be paired with Y75011, is approximately 4.03 Ga, but could be younger. We consider it likely that all three samples experienced a common degassing event 3.95 +/- 0.05 Ga ago, but we cannot rule out two or more events spaced over a approximately 0.1 Ga interval. Higher temperature extractions of the two clast samples show significantly older apparent ages up to approximately 4.5 Ga and suggest that the time/temperature regime of this event was not sufficient to degas Ar totally. Most likely, the K-Ar ages were reset by thermal metamorphism associated with one or more impact events associated with shock fracturing, formation of Fe-rich olivine veins, and/or meteorite brecciation. The pyroxene annealing that commonly occurs in many eucrites is likely to be a much earlier process than the impact-produced textural changes and reset K-Ar ages observed in these meteorites. The existence of mineralogical and chronological evidence for metamorphism in an otherwise pristine eucrite suggests that the HED parent body experienced an extensive degree of early cratering.

Takeda, Hiroshi↗

The 8-13 micron spectra of comets and the composition of silicate grains

We have analyzed the existing spectra of seven comets which show an emission feature at 7.8-13 micrometers. Most have been converted to a common calibration, taking into account the SiO feature in late-type standard stars. The spectra are compared with spectra of the Trapezium, interplanetary dust particles (IDPs), laboratory mineral samples, and small particle emission models. The emission spectra show a variety of shapes; there is no unique 'cometary silicate'. A peak at 11.20-11.25 micrometers, indicative of small crystalline olivine particles, is seen in only three comets of this sample, P/Halley, Bradfield 1987 XXIX, and Levy 1990 XX. The widths of the emission features range from 2.6 to 4.1 micrometers (FWHM). To explain the differing widths and the broad 9.8 micrometers maximum, glassy silicate particles, including both pyroxene and olivine compositions, are the most plausible candidates. Calculations of emission models confirm that small grains of glassy silicate well mixed with carbonaceous material are plausible cometary constituents. No single class of chondritic aggregate IDPs exhibits spectra closely matching the comet spectra. A mixture of IDP spectra, particularly the glass-rich aggregates, approximately matches the spectra of comets P/Halley, Levy, and Bradfield 1987 XXIX. Yet, if comets are simply a mix of IDP types, it is puzzling that the classes of IDPs are so distinct. None of the comet spectra match the spectrum of the Trapezium. Thus, the mineralogy of the cometary silicates is not the same as that of the interstellar medium. The presence of a component of crystalline silicates in comets may be evidence of mixing between high- and low-temperature regions in the solar nebula.

Hanner, Martha S.↗

Watson: A new link in the IIE iron chain

Watson, which was found in 1972 in South Australia, contains the largest single silicate rock mass seen in any known iron meteorite. A comprehensive study has been completed on this unusual meteorite: petrography, metallography, analyses of the silicate inclusion (whole rock chemical analysis, INAA, RNAA, noble gases, and oxygen isotope analysis) and mineral compositions (by electron microprobe and ion microprobe). The whole rock has a composition of an H-chondrite minus the normal H-group metal and troilite content. The oxygen isotope composition is that of the silicates in the IIE iron meteorites and lies along an oxygen isotope fractionation line with the H-group chondrites. Trace elements in the metal confirm Watson is a new IIE iron. Whole rock Watson silicate shows an enrichment in K and P (each approximately 2X H-chondrites). The silicate inclusion has a highly equilibrated igneous (peridotite-like) texture with olivine largely poikilitic within low-Ca pyroxene: olivine (Fa20), opx (Fs17Wo3), capx (Fs9Wo14)(with very fine exsolution lamellae), antiperthite feldspar (An1-3Or5) with less than 1 micron exsolution lamellae (An1-3Or greater than 40), shocked feldspar with altered stoichiometry, minor whitlockite (also a poorly characterized interstitial phosphate-rich phase) and chromite, and only traces of metal and troilite. The individual silicate minerals have normal chondritic REE patterns, but whitlockite has a remarkable REE pattern. It is very enriched in light REE (La is 720X C1, and Lu is 90X C1, as opposed to usual chonditic values of approximately 300X and 100-150X, respectively) with a negative Eu anomaly. The enrichment of whole rock K is expressed both in an unusually high mean modal Or content of the feldspar, Or13, and in the presence of antiperthite.

Olsen, Edward↗

Chemically anomalous, pre-accretionally irradiated grains in interplanetary dust -- interstellar grains?

Ultrafine-grained matrix is a unique and fundamental building block of chondritic porous (CP) interplanetary dust particles. Most IDPs so far determined to be of cometary origin belong to the CP class. The matrix in CP IDPs is not homogeneous but rather a loose mixture of discrete single crystals (e.g., olivine, pyroxene, Fe sulfides) and polyphase grains. The petrographic diversity observed among the polyphase grains suggest that they were formed under variable physiochemical conditions. One particular class of polyphase grains are a dominant component in cometary IDPs. Although their occurrence is well documented, the terminology used to describe them is confused. They have been called many names. Here they are simply called GEMS (Glass with Embedded Metal and Sulfides). The bulk compositions of GEMS are within a factor of 3 chondritic (solar) for all major elements except C. Quantitative thin-film X-ray (EDS) analyses have shown that GEMS are systematically depleted in Mg and Si, enriched in S, Fe, and Ni, and stoichiometrically enriched in O. Electron energy-loss spectroscopy (EELS) suggests that the excess O is present as hydroxyl (-OH) groups. These same chemical 'anomalies' were observed in solar-wind-irradiated amorphous rims on the surfaces of IDPs, suggesting that the compositions of GEMS reflect prior exposure to ionizing radiation. In order to test this hypothesis, a sample of Allende (CV3) matrix was exposed to proton flux. Radiation-damaged amorphous rims on olivine and pyroxene crystals in the Allende sample were found to be depleted in Mg and Ca, enriched in S, Fe, and Ni, and stoichiometrically enriched in O. Thus, the compositions of GEMS are indeed consistent with exposure to ionizing radiation. This study suggests that chemical as well as isotopic anomalies may be used to identify presolar interstellar grains in primitive meteoritic materials.

Bradley, J. P.↗

CM chondrites exhibit the complete petrologic range from type 2 to 1

Recognition and characterization of the different CM lithologies as components in all meteorites could reveal details of the nature and chronology of alteration and brecciation events on hydrous asteroids. The CM chondrites are of particular interest, as they are the most common carbonaceous chondrites and are found as clasts within other types of meteorites, which suggests that the CM parent asteroids are (or were) widespread in the sections of the asteroid belt providing samples to Earth. Some CM2s, including EET 90047, ALH 83100, and Y 82042, are more 'extensively' altered, and are distinguished by a high proportion of Mg-rich phyllosilicates and Ca-Mg carbonates, frequently in rounded aggregates, and near absence of olivine or pyroxene. 'Completely' altered CMs, called CM1s, essentially lack olivine or pyroxene; these include EET 83334, ALH 88045, and the CM1 clasts in Kaidun. Cold Bokkeveld and EET 84034, both highly brecciated CMs, consist of both extensively and completely altered lithologies. We describe how these lithologies further cosntrain physicochemical conditions on hydrous asteroids. We conclude that CM chondrites exhibit the petrologic range 2 through 1, and that progressive alteration on the parent hydrous asteroid(s) was accompanied by significant increases in temperature (to a peak of approximately 450 C), fO2, water-rock ratio, and (locally) degree of chemical leaching, all well beyond the conditions recorded by CM2s.

Zolensky, M. E.↗

Roosevelt County 075: A petrologic chemical and isotopic study of the most unequilibrated known H chondrite

Roosevelt County (RC) 075 was recovered in 1990 as a single 258-gram stone. Classification of this meteorite is complicated by its highly unequilibrated nature and its severe terrestrial weathering, but we favor H classification. This is supported by O isotopes and estimates of the original Fe, Ni metal content. The O isotopic composition is similar to that of a number of reduced ordinary chondrites (e.g., Cerro los Calvos, Willaroy), although RC 075 exhibits no evidence of reduced mineral compositions. Chondrule diameters are consistent with classification as an L chondrite, but large uncertainties in chondrule diameters of RC 075 and poorly constrained means of H, L and LL chondrites prevent use of this parameter for reliable classification. Other parameters are compromised by severe weathering (e.g., siderophile element abundances) or unsuitable for discrimination between unequilibrated H, L and LL chondrites (e.g., Co in kamacite delta C-13). Petrologic subtype 3.2 +/- 0.1 is suggested by the degree of olivine heterogeneity, the compositions of chondrule olivines, the thermoluminescence sensitivity, the abundances and types of chondrules mapped on cathodoluminescence mosaics, and the amount of presolar SiC. The meteorite is very weakly shocked (S2), with some chondrules essentially unshocked and, thus, is classified as an H3.2(S2) chondrite. Weathering is evident by a LREE enrichment due to clay contamination, reduced levels of many siderophile elements, the almost total loss of Fe, Ni metal and troilite, and the reduced concentrations of noble gases. Some components of the meteorite (e.g., type IA chondrules, SiC) appear to preserve their nebular states, with little modification from thermal metamorphism. We conclude that RC 075 is the most equilibrated H chondrite yet recovered and may provide additional insights into the origin of primitive materials in the solar nebula.

Mccoy, T. J.↗

Petrogenesis of lunar troctolites

Models of petrogenesis for lunar troctolites are severely constrained by the high Mg(*) (greater than 88) values of the most primitive members of the Mg-rich suite. Melts derived by partial melting of olivine cumulates to the lunar magma ocean have high Mg(*) but are strongly undersaturated with respect to plagioclase. Assimilation of lunar crust cannot bring these melts to the plagioclase liquious without unduly reducing the Mg(*) values of olivine. Partial melts derived by melting a lherzolite primitive interior have higher normative plagioclase contents but require sources with Mg(*) greater than 90. More terrestrial-like Mg(*) (approximately 88) values are permitted if rising thermal plumes are capable of entraining the most Mg-rich cumulates of the magma ocean. The Mg(*) values of lunar troctolites may, therfore, reflect a hybrid source composed of primitive mantle and Mr-rich cumulates of the magma ocean. Higher Mg(*) values may also arise from the reducction of small amounts of FeO to Fe. Alternatively, the parent magmas to lunar troctolites may be impact melts of the anorthositic crust and the Mg-rich dunites cumulates of the magma ocean; the latter were brought to the upper mantle during the overturn of the unstable cumulate pile of the magma ocean.

Hess, Paul C.↗

Igneous inclusions from ordinary chondrites: High temperature cumulates and a shock melt

We report microprobe, instrumental neutron activation analysis, and radiochemical neutron activation analysis data for three large igneous inclusions in the Yamato (Y-)75097, Y-793241, and Y-794046 ordinary chondrites. The inclusions in the first two chondrites are troctolitic cumulates that have undergone appreciable reactions with their hosts either during emplacement and/or cooling. Olivine-spinel Fe-Mg exchange pairs in these two inclusions record equilibration temperatures of about 710 C, and these temperatures are similar to those exhibited by mineral pairs in the Y-75097 and Y-793241 hosts. The inclusion in Y-794046 is texturally unique, consisting of fine-grained, randomly distributed olivines, coarse (approximately 2 mm) fascicular pyroxene laths, and angular pockets of maskelynite/plagioclase feldspar. The phase compositions are readily interpreted as having resulted from extremely rapid, essentially isochemical cooling to temperatures less than 1000 C of a melt with an initial temperature greater than 1670 C. We suggest that this igneous inclusion formed in-situ by shock.

Sack, Richard O.↗

Small main-belt asteroid spectroscopic survey: Initial results

The spectral characterization of small asteroids is important for understanding the evolution of their compositional and mineralogical properties. We report the results of a CCD spectroscopic survey of small main-belt asteroids which we call the Small Main-belt Asteroid Spectroscopic Survey (SMASS). Spectra of 316 asteroids were obtained, with wavelength coverage ranging from 4000 to 10000 A (0.4 to 1 micrometers). More than half of the objects in our survey have diameters less than 20 km. Survey results include the identification of the first object resembling ordinary chondrite meteorites among the main-belt asteroids (Binzel, R. P., et al, 1993) and observations of more than 20 asteroids showing basaltic achondrite spectral absorption features that strongly link Vesta as the parent body for the basaltic achondrite meteorites (Binzel, R. P., and S. Xu 1993). A potential Mars-crossing asteroid analog to ordinary chondrite meteorites (H chondrites), 2078 Nanking, is reported here. Through a principal component analysis, we have assigned classifications to the members of our sample. The majority of the small main-belt asteroids belong to S and C classes, similar to large asteroids. Our analysis shows that two new classes are justified which we label as J and O. Small asteroids display more diversity in spectral absorption features than the larger ones, which may indicate a greater variation of compositions in the small asteroid population. We found a few candidates for olivine-rich asteroids within the S class. Although the total number of olivine-rich candidates is relatively small, we present evidence suggesting that such objects are more prevalent at smaller sizes.

Xu, Shui↗

Trace Element Geochemistry of Martian Iddingsite in the Lafayette Meteorite

The Lafayette meteorite contains abundant iddingsite, a fine-grained intergrowth of smectite clay, ferrihydrite, and ionic salt minerals. Both the meteorite and iddingsite formed on Mars. Samples of iddingsite, olivine, and augite pyroxene were extracted from Lafayette and analyzed for trace elements by instrumental neutron activation. Our results are comparable to independent analyses by electron and ion microbeam methods. Abundances of most elements in the iddingsite do not covary significantly. The iddingsite is extremely rich in Hg, which is probably terrestrial contamination. For the elements Si, Al, Fe, Mn, Ni, Co, and Zn, the composition of the iddingsite is close to a mixture of approximately 50% Lafayette olivine + approximately 40% Lafayette siliceous glass + approximately 1O% water. Concordant behavior among these elements is not compatible with element fractionations between smectite and water, but the hydrous nature and petrographic setting of the iddingsite clearly suggest an aqueous origin. These inferences are both consistent, however, with deposition of the iddingsite originally as a silicate gel, which then crystallized (neoformed) nearly isochemically. The iddingsite contains significantly more magnesium than implied by the model, which may suggest that the altering solutions were rich in Mg(2+).

Treiman, Allan H.↗

Experimental Constraints on the Origin of Lunar High-Ti Ultramafic Glasses

Phase equilibria and dissolution rate experiments are used to develop a petrogenetic model for the high-Ti lunar ultramafic glasses. Near-liquidus phase relations of the Apollo 14 black glass, the most Ti-rich lunar ultramafic glass, are determined to 2.2-GPa. The liquidus is saturated with Cr-spinel at 1-atm, olivine between approximately 0.5- and 1.5-GPa, and low-Ca pyroxene + Cr-spinel above 1.5-GPa. Ilmenite does not crystallize near the liquidus and implies that high-Ti ultramafic glasses are not produced by melting of an ilmenite-saturated source. We infer that high-Ti ultramafic magmas are derived from low-Ti ultramafic parent magmas by assimilation of ilmenite +/- clinopyroxene +/- urKREEP +/- pigeonite in the shallow lunar interior. Heat is provided by adiabatic ascent of the low-Ti ultramafic primary magmas from the deeper lunar interior and crystallization of olivine during assimilation. The assimilation reaction is modeled by mass balance and requires that ilmenite and high-Ca pyroxene are assimilated in a approximately 3:1 ratio, a much higher ratio than the proportion in which these minerals are thought to exist in the lunar interior. In an effort to understand the kinetic controls on this reaction, the dissolution of ilmenite is examined experimentally in both low- and high-Ti lunar magmas. We find that ilmenite dissolves incongruently to Cr-spinel and a high-Ti melt. The dissolution reaction proceeds by a diffusion-controlled mechanism. An assimilation model for the origin of high-Ti melts is developed that leaves the magma ocean cumulates in their initial stratigraphic positions and obviates source hybridization models that require lunar overturn.

Wagner, T. P.↗

Raman Spectroscopy as a Method for Mineral Identification on Lunar Robotic Exploration Missions

The sharp, nonoverlapping Raman bands for plagioclase, pyroxene, and olivine would be advantageous for on-surface, active mineralogical analysis of lunar materials. A robust, light-weight, low-power, rover-based Raman spectrometer with a laser exciting source, entirely transmission-mode holographic optics, and a charge-coupled device (CCD) detector could fit within a less than 20 cm cube. A sensor head on the end of an optical fiber bundle that carried the laser beam and returned the scattered radiation could be placed against surfaces at any desired angle by a deployment mechanism; otherwise, the instrument would need no moving parts. A modem micro-Raman spectrometer with its beam broadened (to expand the spot to 50-micrometer diameter) and set for low resolution (7/cm in the 100-1400/cm region relative to 514.5-nm excitation), was used to simulate the spectra anticipated from a rover instrument. We present spectra for lunar mineral grains, less than 1 mm soil fines, breccia fragments, and glasses. From frequencies of olivine peaks, we derived sufficiently precise forsterite contents to correlate the analyzed grains to known rock types and we obtained appropriate forsterite contents from weak signals above background in soil fines and breccias. Peak positions of pyroxenes were sufficiently well determined to distinguish among orthorhombic, monoclinic, and triclinic (pyroxenoid) structures; additional information can be obtained from pyroxene spectra, but requires further laboratory calibration. Plagioclase provided sharp peaks in soil fines and most breccias even when the glass content was high.

Wang, Alian↗

Abundant Cool Magnesium-Rich Pyroxene Crystals in Comet Hale-Bopp

Modeling of the observed dust emission from Comet Hale-Bopp over a large range of heliocentric distances (2.8 AU - 0.93 AU -1.7 AU) led to the discovery of Mg-rich pyroxene crystals in the coma These pyroxene crystals are apparent in the 10 micron spectrum only when the comet is close to perihelion (r(sub h) = 1.2 AU) because they are cooler than the other silicate minerals. The pyroxene crystals are cooler than the other species because of their high Mg-content. They do not absorb as efficiently as the other silicate minerals. Given the same high Mg content of Mg/(Mg + Fe) = 0.9, radiative equilibrium computations show that pyroxene crystals are expected to be 150 K cooler than olivine crystals. The pyroxene crystals are also about 10x more abundant than the other silicate mineral species. Their high Mg content and relatively large abundance are in agreement with the preponderance of pyroxene interplanetary dust particles (IDPs) and the recent reanalysis of the PUMA-I flyby of Comet Halley. Before Hale-Bopp, only olivine crystals were detected spectroscopically in comets, probably because the pyroxene crystals are less optically active, hence significantly cooler and harder to detect in contrast to the warmer silicate species. Determining the relative abundances of silicate minerals depends on their Mg contents. If the pyroxene crystals in Comet Hale-Bopp are solar nebula condensates, then they probably had to form during the early FU Orionis epoch when the inner disk was hot enough and be transported out to the region of formation of icy planetesimals without being reheated. Reheating events appear to reincorporate Fe back into the crystals or form Fe-rich rims, which are not consistent with the high-Mg-content crystals. The condensation of Mg-rich pyroxene crystals is expected from solar nebula thermal equilibrium computations. However, their subsequent transport to the outer solar nebula unaltered has yet to be theoretically demonstrated. The discovery of Mg-rich crystals in Comet Hale-Bopp and in AGB stars opens the possibility that these crystals are relic interstellar grains. One-third of IDPs have been shown to have significant deuterium enrichments, thus indicating that they contain presolar material. By spectroscopic analogy to IDPs the Mg-rich pyroxene crystals in Comet Hale-Bopp may be presolar grains. If so, then the comet contains largely ISM silicates. ISM grains may have been the dominant source of dust in the outer early solar nebula.

Wooden, D. H.↗

Experimental Study of Lunar and SNC Magmas

The research described in this progress report involved the study of petrological, geochemical and volcanic processes that occur on the Moon and the SNC parent body, generally accepted to be Mars. The link between these studies is that they focus on two terrestrial-type parent bodies somewhat smaller than earth, and the fact that they focus on the role of volatiles in magmatic processes and on processes of magma evolution on these planets. The work on the lunar volcanic glasses has resulted in some exciting new discoveries over the years of this grant. During the tenure of the present grant, we discovered a variety of metal blebs in the A17 orange glass. Some of these Fe-Ni metal blebs occur in the glass; others were found in olivine phenocrysts which we find make up about 2 vol % of the orange glass magma. The importance of these metal spheres is that they fix the oxidation state of the parent magma during the eruption, and also indicate changes during the eruption. They also yield important information about the composition of the gas phase present, the gas which drove the lunar fire-fountaining. In an Undergraduate senior thesis project, Nora Klein discovered a melt inclusion that remained in a glassy state in one of the olivine phenocrysts. Analyses of this inclusion gave additional information on the CO2, CO and S contents of the orange glass magma prior to its reaching the lunar surface. The composition of lunar volcanic gases has long been one of the puzzles of lunar magmatic processes. One of the more exciting findings in our research over the past year has been the study of magmatic processes linking the SNC meteorite source magma composition with the andesitic composition rocks found at the Pathfinder site. In this project, graduate student Michelle Minitti showed that there was a clear petrologic link between these two magma types via fractional removal of crystals from the SNC parent melt, but the process only worked if there was at least 1 wt % dissolved water in the melt.

Rutherford, Malcolm J.↗

Possible Bacteria in Nakhla

Mars Agueous Alteration Nakhla contains alteration products in an extensive network of which fill cracks, veins, and void spaces, composed of smectite, although in some cases they are amorphous and gel-like. Strong evidence presented show that these alteration products developed on Mars: some veins are offset by impact faulting of olivine followed by annealing of the olivine, and veins near the fusion crust show partial vesicle development suggesting heating and volatile liberation. The smectite-containing cracks and veins are interpreted as low temperature aqueous alteration on Mars. We have been studying these veins with optical microscopy and high resolution SEM.

McKay, David S., Jr.↗