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At least 775 records · Page 43

All sources NASA NTRS DOE OSTI

DOE OSTI2021

Liquid state properties and solidification features of the pseudo binary BaS-La 2 S 3

The high temperature thermodynamic properties of chalcogenides materials based on BaS remain elusive. Herein the pseudo binary BaS-La 2 S 3 is investigated above 1573 K. The liquid properties of BaS-La 2 S 3 are measured by means of high resolution in-situ visualization coupled with thermal arrest measurements in a thermal imaging furnace. This enables to report the first observation of such melts in a container-less setting. The melting points of BaS and La 2 S 3 are revisited at 2454 K and 2004 K respectively. La 2 S 3 demonstrates a high stability in its liquid state, in strike difference with the sublimation observed for BaS. BaS is however partially stabilized with the addition of few percents of La 2 S 3 . The remarkable chemical and thermal stability of La 2 S 3 -rich samples contrasts with the partial decomposition and high vapor pressure observed for BaS-rich samples. Observations and analysis of the solidified samples suggest three different solid solutions. Solid and liquid densities are investigated along the different compositions, supporting a first estimate of the volumetric thermal expansion coefficient for La 2 S 3 .

36 MATERIALS SCIENCE↗

NASA NTRS1989

Navier-Stokes analysis of solid propellant rocket motor internal flows

A multidimensional implicit Navier-Stokes analysis that uses numerical solution of the ensemble-averaged Navier-Stokes equations in a nonorthogonal, body-fitted, cylindrical coordinate system has been applied to the simulation of the steady mean flow in solid propellant rocket motor chambers. The calculation procedure incorporates a two-equation (k-epsilon) turbulence model and utilizes a consistently split, linearized block-implicit algorithm for numerical solution of the governing equations. The code was validated by comparing computed results with the experimental data obtained in cylindrical-port cold-flow tests. The agreement between the computed and experimentally measured mean axial velocities is excellent. The axial location of transition to turbulent flow predicted by the two-equation (k-epsilon) turbulence model used in the computations also agrees well with the experimental data. Computations performed to simulate the axisymmetric flowfield in the vicinity of the aft field joint in the Space Shuttle solid rocket motor using 14,725 grid points show the presence of a region of reversed axial flow near the downstream edge of the slot.

Sabnis, J. S.↗

NASA NTRS1983

Two hot, low-field magnetic DA white dwarfs

Two hot stars discovered in the Palomar Green survey which were found to exhibit peculiarly broad and strong Balmer lines possibly indicative of low magnetic fields are discussed. The stars, PG 1658+441 and PG 0136+251, were found to have extended trough-shaped Balmer and Lyman-alpha line profiles when compared to nonmagnetic dwarfs of similar temperatures. Further observations of PG 1658+441 show it to correspond to a 30,000 K pure hydrogen atmosphere and confirm its nature as a magnetic object with a longitudinal field strength of about 0.7 megagauss and a mean surface field of about 2.3 megagauss. PG 0136+251 is found to be a hotter star (40,000-50,000 K) with weaker lines. Although no strong evidence for magnetic line splitting was obtained, it is argued that neither a high surface gravity nor very rapid rotation can account for the Balmer line shapes. Results thus extend the range of magnetic degenerates to include very hot white dwarfs, and demonstrate the usefulness of line-widths as indicators of possible low-field magnetic sources.

Liebert, J.↗

DOE OSTI2025

A statistical and simulation-informed model for estimating permeability from pore size distribution in saturated geomaterials

Accurate permeability estimation is essential across subsurface engineering applications but remains challenging due to the complex pore structures of natural geomaterials. Traditional empirical methods and simplified theoretical models often inadequately capture the role of pore size distribution and connectivity. Here, this study develops a statistical and simulation-informed permeability model that collapses pore-scale complexity into a compact scaling of the form k = αϕμ d 2 , where ϕ is porosity, μ d is mean pore size, and α is a weakly varying coefficient. By combining pore network simulations with statistical analysis of unimodal and bimodal pore size distributions, we identify three key findings: (i) permeability is much more sensitive to mean pore size than to porosity; (ii) across extensive datasets, the ratio σ d /μ d (standard deviation to mean) clusters around a characteristic value ∼0.4, allowing the effects of the full pore size distribution to be represented by μ d and a narrowly varying α ≈ 0.05; and (iii) for bimodal systems, there exists a critical fraction of small pores ∼0.78 above which flow becomes small-pore dominated, enabling the definition of an effective flow-controlling pore population and facilitating simplified permeability estimation for such systems. The resulting model, which requires only porosity and a representative mean pore size as inputs, is validated against comprehensive experimental datasets (>1700 samples) spanning diverse soils and rocks and achieves good predictive accuracy. Overall, this work provides a physically grounded yet practically simple permeability estimator suitable for subsurface engineering, environmental protection, and resource management applications.

Permeability↗

DOE OSTI2021

Factors Governing Oxygen Vacancy Formation in Oxide Perovskites

The control of oxygen vacancy (V O ) formation is critical to advancing multiple metal-oxide-perovskite-based technologies. In this work, we report the construction of a compact linear model for the neutral V O formation energy in ABO 3 perovskites that reproduces, with reasonable fidelity, Hubbard-U-corrected density functional theory calculations based on the state-of-the-art, strongly constrained and appropriately normed exchange-correlation functional. We obtain a mean absolute error of 0.45 eV for perovskites stable at 298 K, an accuracy that holds across a large, electronically diverse set of ABO 3 perovskites. Our model considers perovskites containing alkaline-earth metals (Ca, Sr, and Ba) and lanthanides (La and Ce) on the A-site and 3d transition metals (Ti, V, Cr, Mn, Fe, Co, and Ni) on the B-site in six different crystal systems (cubic, tetragonal, orthorhombic, hexagonal, rhombohedral, and monoclinic) common to perovskites. Physically intuitive metrics easily extracted from existing experimental thermochemical data or via inexpensive quantum mechanical calculations, including crystal bond dissociation energies and (solid phase) reduction potentials, are key components of the model. Beyond validation of the model against known experimental trends in materials used in solid oxide fuel cells, the model yields new candidate perovskites not contained in our training data set, such as (Bi,Y)(Fe,Co)O 3 , which we predict may have favorable thermochemical water-splitting properties. The confluence of sufficient accuracy, efficiency, and interpretability afforded by our model not only facilitates high-throughput computational screening for any application that requires the precise control of V O concentrations but also provides a clear picture of the dominant physics governing V O formation in metal-oxide perovskites.

08 HYDROGEN↗

DOE OSTI2025

Cloud Feedback Uncertainty in the Equatorial Pacific Across CMIP6 Models

Cloud feedback is the largest uncertainty in estimating Equilibrium Climate Sensitivity. In this study we focus on the equatorial Pacific, where CMIP6 model cloud feedback spread is notably large. Cloud radiative effects in this region are relevant for the global climate. Our findings show that models predict a consistent shift towards the ascent regime in response to El Nino-like sea surface warming. Models diverge in terms of the radiative impact due to differences in cloud characteristics in ascent and subsidence regimes. Using the observed relationship between circulation regime and cloud radiative effect, we find a reduction in the regional mean cloud feedback estimate from 0.77 to 0.22 W m -2 K -1 , though this does not substantially lessen the model spread in total feedback. Pathways to reduce this spread include: improving confidence in the regional ocean warming pattern, and using observations and models to understand cloud type and circulation interactions.

CMIP6↗

DOE OSTI2024

Measurement of Thomson-scattering spectra with continuous angular resolution (invited)

Here, a novel Thomson-scattering diagnostic with continuous angular resolution over a span of 120° was developed for the characterization of plasmas produced at the Omega Laser Facility. Spectrally resolving light scattered from electron plasma wave features as a function of emission angle provides a means to efficiently probe a large range of plasma frequencies and k vectors. Together, these spectra contain critical constraints on the plasma-physics models used to interpret the data and enable experimental measurements of the electron-velocity distribution function over several orders of magnitude without assumptions about its mathematical form. Major components of the instrument include (1) a reflective collection objective that gathers light over a range of 120° × 12°; (2) a spatial-filter image relay for measurement localization; (3) cylindrical optics for producing a line image of the collection aperture; (4) a transmission grating spectrometer; and (5) a time-gated, image-intensified camera. Thomson-scattered light collected from an ~(50 – μM) 3 volume of plasma is recorded with 0.8-nm spectral and 1° angular resolution. Initial experiments examined the properties of the electron-velocity distribution in gas-jet-produced plasmas in the presence of heating via inverse bremsstrahlung absorption.

47 OTHER INSTRUMENTATION↗

DOE OSTI2020

Anisotropic magnetocaloric effect and critical behavior in CrCl 3

We report anisotropic magnetocaloric effect and magnetic critical behavior in the van der Waals crystal CrCl 3 . The maximum magnetic entropy change $-ΔS^{max}_M ~ 14.6 J kg -1 K -1 and the relative cooling power RCP ~ 340.3 J kg -1 near T c with a magnetic field change of 5 T are much larger when compared to CrI 3 or CrBr 3 . The rescaled ΔS M (T, H) curves collapse onto a universal curve, confirming the second-order ferromagnetic transition. Finally, further critical behavior analysis around T c presents a set of critical exponents β = 0.28 (1) with T c = 19.4 (2) K, γ = 0.89 (1) with T c = 18.95 (8) K, and δ = 4.6 (1) at T c = 19 K , which are close to those of the theoretical tricritical mean-field model.

2-dimensional systems↗

NASA NTRS1972

Liapunov stability analysis of hybrid dynamical systems with multi-elastic domains.

This paper presents a Liapunov stability theory applicable to hybrid systems with multi-elastic domains. The mathematical formulation consists of a simultaneous set of ordinary and partial differential equations. A new stability theorem, particularly suited to such hybrid systems, is introduced. To predict the system stability by means of the theorem, it is necessary to construct a functional k, where k is free of spatial derivatives and bounding the Hamiltonian H from below. The conditions under which the construction of such a functional is possible are shown. As an application of the theory, the attitude stability of an earth-pointing satellite with multi-elastic domains is investigated and closed-form stability criteria derived.

Meirovitch, L.↗

NASA NTRS1972

Observations of prominences at 3.5 millimeter wavelength.

At 3.5 mm wavelength, absorption features are observed in correspondence with H-alpha dark filaments on the disk; beyond the limb, the prominences correspond to emissive regions. The absorption features are larger than the corresponding H-alpha dark filaments; the emissive regions at the limb have similar angular sizes. The emissive regions at the limb have electron temperatures of 5500 (plus or minus 500) K; the amount of absorption observed on the disk leads to mean electron densities of about 50 billion per cu cm.

Kundu, M. R.↗

NASA NTRS1975

A superfluid helium system for an LST IR experiment

The results are presented of a study program directed toward evaluating the problems associated with cooling an LST instrument to 2 K for a year by using superfluid helium as the cooling means. The results include the parametric analysis of systems using helium only, and systems using helium plus a shield cryogen. A baseline system, using helium only is described. The baseline system is sized for an instrument heat leak of 50 mw. It contains 71 Kg of superfluid helium and has a total, filled weight of 217 Kg. A brief assessment of the technical problems associated with a long life, spaceborne superfluid helium storage system is also made. It is concluded that a one year life, superfluid helium cooling system is feasible, pending experimental verification of a suitable low g vent system.

Breckenridge, R. W., Jr.↗

NASA NTRS1978

One-millimeter brightness temperatures of the planets

Results are reported for a bolometric determination of the relative brightness at a wavelength of 1 mm of Mercury, Venus, Mars, Jupiter, Saturn, Uranus, and Neptune. The relative measurements are converted to absolute temperatures by using a thermal model for Mars, which was checked by observations of Mars and Jupiter at two different epochs. The mean planetary disk temperatures are found to be 320 + or 16 K for Mercury, 276 + or - 14 K for Venus, 145 + or - 7 K for Saturn, 168 + or - 8 K for Jupiter, 87 + or - 7 K for Uranus, and 96 + or - 10 K for Neptune. These results are compared with previous determinations at other wavelengths, and some aspects of the observations of the individual planets are briefly discussed.

Werner, M. W.↗

NASA NTRS1982

The upper atmosphere of Uranus - A critical test of isotropic turbulence models

Observations of the August 15, 1980, Uranus occultation of KM 12, obtained from Cerro Tololo InterAmerican Observatory, European Southern Observatory, and Cerro Las Campanas Observatory, are used to compare the atmospheric structure at points separated by approximately 140 km along the planetary limb. The results reveal striking, but by no means perfect correlation of the light curves, ruling out isotropic turbulence as the cause of the light curve spikes. The atmosphere is strongly layered, and any acceptable turbulence model must accommodate the axial ratios of greater than about 60 which are observed. The mean temperature of the atmosphere is 150 plus or minus 15 K for the region near number density 10 to the 14th per cu cm. Derived temperature variations of vertical scale approximately 130 km and amplitude plus or minus 5 K are in agreement for all stations, and correlated spikes correspond to low-amplitude temperature variations with a vertical scale of several kilometers.

French, R. G.↗

NASA NTRS1985

Vuilleumier cycle cryocooler operating below 8 K

This paper describes the design and development of a Vuilleumier cycle cryocooler (VM cooler) operating below 8 K, for the application of small superconducting devices. Liquid nitrogen has been used as a heat sink of the hot displacer. The annular gap between the phenolic displacer and SUS 304 stainless cylinder has been used as a gap regenerator. In order to obtain the cooling temperature below 3 K, we designed a single stage VM cooler which is precooled to 10 K by another two stage VM cooler. The effect of the mean operating pressure, cycle speed and phase difference between the hot and cold displacer of each VM cooler will be also discussed, including the experimental results.

Matsubara, Y.↗

NASA NTRS1988

Dual-frequency and dual-polarization VLBI observations of the stellar system Algol

Results of multiepoch VLBI observations of the stellar system Algol are presented, including dual-polarization and dual-frequency measurements at 2.3 and 8.4 GHz. The brightness temperature of the radio source is generally between 3 x 10 to the 8th K and 5 x 10 to the 9th K and is consistent with gyrosynchrotron emission from energetic electrons with mean energy less than 1 MeV in an active coronal region. Two exceptional events were observed: a high-brightness, broad-band outburst occurring simultaneously at 2.3 and 8.4 GHz, and a short-duration, highly polarized and high-brightness temperature outburst at 1.66 GHz. A simple physical model which includes all three types of emission is suggested.

Lestrade, Jean-Francois↗

NASA NTRS1990

Fluid/electrolyte balance and cardiovascular responses - Head-down tilted rats

Results are presented on cardiovascular and fluid/electrolyte balance responses of rats to a 7-day-long whole-body suspension (WBS) with about 20-deg head-down tilt (HDT), followed by 7 days of recovery. Compared with horizontally positioned (N-HDT) rats serving as controls, the Na intake of HDT rats was significantly reduced during the first 3 days of HDT, and urinary and fecal Na loss exceeded the Na intake during days 5 and 6. Changes during the days of recovery showed adjustments and reestablishment of Na balance. Urinary K losses increased progressively during the 7 days of HDT, but, with the exception of days 1-3 of HDT, when the K intake was significantly reduced, the K balance was retained. Changes in cardiac responses (including elevations in mean, diastolic, and systolic arterial pressures) paralleled changes in fluid and electrolyte balance during the HDT period.

Musacchia, X. J.↗

NASA NTRS1996

Quantum Cohesion Oscillation of Electron Ground State in Low Temperature Laser Plasma

The development of radically new technological and economically efficient methods for obtaining chemical products and for producing new materials with specific properties requires the study of physical and chemical processes proceeding at temperature of 10(exp 3) to 10(exp 4) K, temperature range of low temperature plasma. In our paper, by means of Wigner matrix of quantum statistical theory, a formula is derived for the energy of quantum coherent oscillation of electron ground state in laser plasma at low temperature. The collective behavior would be important in ion and ion-molecule reactions.

Zhao, Qingxun↗

NASA NTRS2003

High-Frequency Planetary Waves in the Polar Middle Atmosphere as seen in a data Assimilation System

This study examines the winter southern hemisphere vortex of 1998 using four times daily output from a data assimilation system to focus on the polar 2-day, wave number 2 component of the 4-day wave. The data assimilation system products are from a test version of the finite volume data assimilation system (fvDAS) being developed at Goddard Space Flight Center (GSFC) and include an ozone assimilation system. Results show that the polar 2-day wave dominates during July 1998 at 70 degrees. The period of the quasi 2-day wave is somewhat shorter than 2 days (about 1.7 days) during July 1998 with an average perturbation temperature amplitude for the month of over 2.5 K. The 2-day wave propagates more slowly than the zonal mean zonal wind, consistent with Rossby wave theory, and has EP flux divergence regions associated with regions of negative horizontal potential vorticity gradients, as expected from linear instability theory. Results for the assimilation-produced ozone mixing ratio show that the 2-day wave represents a major source of ozone variation in this region. The ozone wave in the assimilation system is in good agreement with the wave seen in the POAM (Polar Ozone and Aerosol Measurement) ozone observations for the same time period. Some differences with linear instability theory are noted as well as spectral peaks in the ozone field, not seen in the temperature field, that may be a consequence of advection.

Coy, L.↗