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Microstructural origin of high‐strength Tyranno SA4 SiC fiber studied by comparative Raman spectroscopy #

Tyranno SA4 grade SiC fiber is an emerging continuous fiber with excellent mechanical properties. The origin of the fiber's high-performance was studied by comparative Raman spectroscopy of four different grades of SiC fibers and reference SiC monolith. Analysis of the Raman spectra of fiber cross-sections, surface and homogeneity, and fibers under stress, revealed how differences in microstructure, such as crystalline order, size, and the presence of critical flaws, dictate mechanical properties. In conclusion, this information can help optimize SiC fiber manufacturing.

36 MATERIALS SCIENCE↗

A unified materials approach to mitigating optical nonlinearities in optical fiber. III. Canonical examples and materials road map

Abstract This paper, Part III in the Trilogy (Ballato, Cavillon, Dragic, 2018; Dragic, Cavillon, Ballato, et al ., 2018a,b), provides a road map for the development of simple core/clad optical fibers whose enhanced performance—in particular, marked reductions in optical nonlinearities—is achieved materially and not through the more conventional present routes of geometrically complex fiber design. More specifically, the material properties that give rise to Brillouin, Raman and Rayleigh scattering, transverse mode instabilities ( TMI ), and n 2 ‐mediated nonlinear effects are compiled and results on a wide range of optical fibers are discussed with a focus on trends in performance with glass composition. Furthermore, optical power scaling estimations as well as binary and ternary property diagrams associated with Rayleigh scattering, the Brillouin gain coefficient ( BGC ) and the thermo‐optic coefficient (d n /d T ) are developed and employed to graphically represent general trends with composition along with compositional targets for a single intrinsically low nonlinearity, silica‐based optical fiber that can achieve the power scaling goals of future high energy fiber laser applications. A foundational finding of this work is that the high‐silica content optical fibers fabricated using conventional chemical vapor deposition methods will not suffice to meet the power scaling demands of future high‐power and high‐energy fiber lasers.

36 MATERIALS SCIENCE↗

TU-F-BRE-01: A High Resolution Micro Fiber Scintillator Detector Optimized for SRS and SBRT in Vivo Real Time Treatment Verification

Purpose: We have built a high resolution real time scintillating fiber detector prototype to determine in real time the accuracy of stereotactic radiosurgery (SRS) and stereotactic body radiotherapy (SBRT) treatments when only a fraction of the planned dose was delivered. The motivation of this work is to enhance dose delivery accuracy and to achieve error free radiosurgery. Methods: A high density array of scintillating fibers and a high speed photo detectors array were integrated to implement a high resolution real time dosimeter that can sample with high resolution pulsed SRS and SBRT beams cross sections. The high efficiency of the developed system allows to read each linac pulse in real time and to compute the accumulated dose and dose errors when only a fraction of the beam was delivered. The fibers are highly packed in a substrate that is directly coupled to two 128 pixel arrays with a pitch matching the fiber spacing to achieve accurate spatial localization. The small cross section of the fiber array allows stacking multiple fiber arrays to measure independent angular profiles that are digitally processed in parallel for real time dosimetry. Results: We implemented a high density array detector prototype with a pitch of 0.5 mm, readout speed of 1.2 msec, and a response time of 0.5 usec. The fast reading speed has the capability to determining the dose in flattening free filter beams. The detector can be installed in transmission mode at the output port of a micro-MLC. Treatment deviations smaller than 3% are detected when less than 1/100 of the planned dose was delivered. Conclusions: We built a prototype of a high resolution fiber scintillator array detector for SRS and SBRT in vivo dosimetry. Results show that the developed detector has the potential to assure error free SRS and SBRT treatments.

60 APPLIED LIFE SCIENCES↗

SU-E-T-610: Phosphor-Based Fiber Optic Probes for Proton Beam Characterization

Purpose: To investigate feasibility of using fiber optics probes with rare-earth-based phosphor tips for proton beam radiation dosimetry. We designed and fabricated a fiber probe with submillimeter resolution (<0.5 mm3) based on TbF3 phosphors and evaluated its performance for measurement of proton beam including profiles and range. Methods: The fiber optic probe with TbF3 phosphor tip, embedded in tissue-mimicking phantoms was irradiated with double scattering proton beam with energy of 180 MeV. Luminescence spectroscopy was performed by a CCD-coupled spectrograph to analyze the emission spectra of the fiber tip. In order to measure the spatial beam profile and percentage depth dose, we used singular value decomposition method to spectrally separate the phosphors ionoluminescence signal from the background Cerenkov radiation signal. Results: The spectra of the TbF3 fiber probe showed characteristic ionoluminescence emission peaks at 489, 542, 586, and 620 nm. By using singular value decomposition we found the contribution of the ionoluminescence signal to measure the percentage depth dose in phantoms and compared that with measurements performed with ion chamber. We observed quenching effect at the spread out Bragg peak region, manifested as under-responding of the signal, due to the high LET of the beam. However, the beam profiles were not dramatically affected by the quenching effect. Conclusion: We have evaluated the performance of a fiber optic probe with submillimeter resolution for proton beam dosimetry. We demonstrated feasibility of spectral separation of the Cerenkov radiation from the collected signal. Such fiber probes can be used for measurements of proton beams profile and range. The experimental apparatus and spectroscopy method developed in this work provide a robust platform for characterization of proton-irradiated nanophosphor particles for ultralow fluence photodynamic therapy or molecular imaging applications.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

SU-E-T-672: Real-Time In Vivo Dosimeters Using LiPCDA and Optical Fibers

Purpose: To investigate dosimeter prototypes made with lithium pentacosa-10,12-diynoate (LiPCDA, the material used in GafChromic EBT films) and optical fibers for their suitability in real-time in vivo measurements. Methods: The prototypes, made with 500 µm plastic optical fibers and 8.5 µm thickness of LiPCDA at fiber tip, were irradiated with a 6 MV beam. To investigate the efficacy of pre-irradiation calibration, the probes were irradiated to 2 Gy twice, with 5 minutes in between. Net optical density values (netOD) around the main absorbance peak were compared, and effect of correcting second measurement by the first was assessed. Ageing was assessed by irradiating two prototypes to 2 Gy and comparing the netOD to that obtained for 15 prototypes from the same batch 12–14 months earlier. To measure angular dependence, the probes were pre-irradiated with beam perpendicular to fiber axis and then, 5 minutes later either perpendicular or parallel to fiber axes. The thickness-corrected netOD measurements were compared. Results: Standard deviation of netOD for probes of the same batch was measured to be 5–6%. When netOD was corrected for material thickness by using results from the first irradiation, the standard deviation decreased to 1.3%. This was comparable to the uncertainty in measurements observed with a single probe and is attributed to variations in light output, spectrometer noise and splitter-to-probe connection variations. Comparison of netOD values obtained a year apart failed to illustrate statistically significant decrease in sensitivity due to ageing (0.38 ± 0.03 and 0.3656 ± 0.0003). NetOD measured with MV beam parallel to fiber was within error of netOD measured with MV beam perpendicular to fiber. Conclusion: Current prototype construction allows for shelf life of at least one year. With material thickness corrected for, the prototypes can measure dose with an uncertainty below 2% at a given energy and dose rate. This work has been funded by the Ontario Centres of Excellence Market Readiness grant. The authors have no conflict of interest to declare.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

FiberFlex: Real-time FPGA-based Intelligent and Distributed Fiber Sensor System for Pedestrian Recognition

In recent years, security monitoring of public places and critical infrastructure has heavily relied on the widespread use of cameras, raising concerns about personal privacy violations. To balance the need for effective security monitoring with the protection of personal privacy, we explore the potential of optical fiber sensors for this application. This article proposes FiberFlex, an intelligent and distributed fiber sensor system. Ultizing Field Programmable Gate Arrays (FPGA) high-level synthesis (HLS) acceleration, FiberFlex offers real-time pedestrian detection by co-designing the entire pipeline of optical signal acquisition, processing, and recognition networks based on the principles of optical fiber sensing. As a promising alternative to traditional camera-based monitoring systems, FiberFlex achieves pedestrian detection by analyzing the vibration patterns caused by pedestrian footsteps, enabling security monitoring while preserving individual privacy. FiberFlex comprises three modules: First , fiber-optic sensing system: A fiber-optic distributed acoustic sensing (DAS) system is built and used to measure the ground vibration waves generated by people walking. Second , algorithms: We first collect the training data by measuring the ground vibration waves, label the data, and use the data to train the neural network models to perform pedestrian recognition. Third , hardware accelerators: We use HLS tools to design hardware modules on FPGA for data collection and pre-processing and integrate them with the downstream neural network accelerators to perform in-line real-time pedestrian detection. The final detection results are sent back from FPGA to the host CPU. We implement our system FiberFlex with the in-house built DAS system and AMD/Xilinx Kintex7 FPGA KC705 board and verify the whole system using the real-world collected data. We conduct recognition tests on five test subjects of varying ages, heights, and weights in a fixed sensing area. Each subject experienced 20 real-time recognition tests using their daily walking habits, and the subjects were given adequate rest between tests. After 100 tests on five test subjects, the overall real-time recognition accuracy exceeded \(88.0\%\) . The whole system uses 55 W of power, 33 W in the optical DAS system and 22 W in the FPGA. Relying on its end-to-end interdisciplinary design, FiberFlex seamlessly combines fiber-optic sensors with FPGA accelerators to enable low-power real-time security monitoring without compromising privacy, making it a valuable addition to the existing security monitoring network. According to FiberFlex, more valuable research can be conducted in the future, such as fall monitoring for the elderly, migration of identification networks between different application scenarios, and improvement of anti-interference performance in more complex environments. In future perception networks, where the “eyes” are not feasible, let’s use fiber optic touch instead.

Distributed↗

Final Scientific and Technical Report - Practical Fiber Delivered Laser Ignition Systems for Vehicles

Research has characterized advanced kagome fiber optics for their use in laser ignition systems. In comparison to past fibers used in laser ignition, these fibers have the important advantage of being relatively bend-insensitivity, so that they can be bent and coiled without degradation of output energy or beam quality. The results are very promising for practical systems. For pulse durations of ~12 ns, the fibers could deliver >~10 mJ pulses before damage onset. A study of pulse duration showed that by using longer pulse duration (~20 – 30 ns), it is possible to carry even higher pulse energy (by factor of ~2-3) which also provides future opportunities to implement longer duration sources. Beam quality measurements showed nearly single-mode output from the kagome fibers (i.e. M2 close to 1) which is the optimum possible value and, combined with their high pulse energy, shows the suitability of the fibers for laser ignition. Research has also demonstrated laser ignition of an engine including reliable (100%) ignition of a single-cylinder gasoline engine using the laser ignition system with bent and coiled kagome fiber. The COV of IMEP was <2% which is favorable for stable engine operation. These research results, along with the continued reduction in cost of laser sources, support our commercial development of practical laser ignition systems.

ignition, laser ignition, vehicles, fiber optics↗

Radiological results for samples collected on paired glass- and cellulose-fiber filters at the Sandia complex, Tonopah Test Range, Nevada

Airborne particulates are collected at U.S. Department of Energy sites that exhibit radiological contamination on the soil surface to help assess the potential for wind to transport radionuclides from the contamination sites. Collecting these samples was originally accomplished by drawing air through a cellulose-fiber filter. These filters were replaced with glass-fiber filters in March 2011. Airborne particulates were collected side by side on the two filter materials between May 2013 and May 2014. Comparisons of the sample mass and the radioactivity determinations for the side-by-side samples were undertaken to determine if the change in the filter medium produced significant results. The differences in the results obtained using the two filter types were assessed visually by evaluating the time series and correlation plots and statistically by conducting a nonparametric matched-pair sign test. Generally, the glass-fiber filters collect larger samples of particulates and produce higher radioactivity values for the gross alpha, gross beta, and gamma spectroscopy analyses. However, the correlation between the radioanalytical results for the glass-fiber filters and the cellulose-fiber filters was not strong enough to generate a linear regression function to estimate the glass-fiber filter sample results from the cellulose-fiber filter sample results.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Validation of Material Models For Automotive Carbon Fiber Composite Structures Via Physical And Crash Testing (VMM Composites Project)

As automotive fuel economy requirements increase, the push for reducing overall vehicle weight will likely include the consideration of materials that have not previously been part of mainstream vehicle design and manufacturing, including carbon fiber composites. Vehicle manufacturers currently rely on computer-aided engineering (CAE) methods as part of the design and development process, so going forward, the ability to accurately and predictably model carbon fiber composites will be necessary. If composites are to be used for structural components, this need applies to both, crash and quasi-static modeling. This final report covers the results of a five-year, $6.89M, 50% cost-shared research project between Department of Energy (DOE) and the US Advanced Materials Partnership (USAMP) under Cooperative Agreement DE-EE-0005661 known as “Validation of Material Models for Automotive Carbon Fiber Composite Structures Via Physical and Crash Testing (VMM).” The objective of the VMM Composites Project was to validate and assess the ability of physics-based material models to predict crash performance of automotive primary load-carrying carbon fiber composite structures. Simulation material models that were evaluated included micro-mechanics based meso-scale models developed by the University of Michigan (UM) and micro-plane models by Northwestern University (NWU) under previous collaborations with the DOE and Automotive Composites Consortium/USAMP, as well as five commercial crash codes: LS-DYNA, RADIOSS, VPS/PAM-CRASH, Abaqus, and GENOA-MCQ. CAE predictions obtained from seven organizations were compared with experimental results from quasi-static testing and dynamic crash testing of a thermoset carbon fiber composite front-bumper and crush-can (FBCC) system gathered under multiple loading conditions. This FBCC design was developed to demonstrate progressive crush, virtual simulation, tooling, fabrication, assembly, non-destructive evaluation and crash testing advances in order to assess the correlation of the predicted results to the physical tests. The FBCC was developed to meet a goal of 30-35% mass reduction while aiming for equivalent energy absorption as a steel component for which baseline experimental results were obtained from testing in the same crash modes. The project also evaluated crash performance of thermoplastic composite structures fabricated from commercial prepreg materials and low cost carbon fiber sourced from Oak Ridge National Laboratory. The VMM Project determined that no set of predictions from a CAE supplier were found to be universally accurate among all the six crash modes evaluated. In general, crash modes that were most dependent on the properties of the prepreg were more accurate than those that were dependent on the behavior of the joints. The project found that current CAE modeling methods or best practices for carbon fiber composites have not achieved standardization, and accuracy of CAE is highly reliant on the experience of its users. Coupon tests alone are not sufficient to develop an accurate material model, but it is necessary to bridge the gap between the coupon data and performance of the actual structure with a series of subcomponent level tests. Much of the unreliability of the predictions can be attributed to shortcomings in our ability to mathematically link the effects of manufacturing and material variability into the material models. This is a subject of ongoing research in the industry. The final report is organized by key technical tasks to describe how the validation project developed, modeled and compared crash data obtained on the composite FBCC to the multiple sets of CAE predictions. Highlights of the report include a discussion of the quantitative comparison between predictions and experimental data, as well as an in-depth discussion of remaining technological gaps that exist in the industry, which are intended to spur innovations and improvements in CAE technology.

36 MATERIALS SCIENCE↗

Fully Distributed Acoustic and Magnetic Field Monitoring Via a Single Fiber Line for Optimized Production of Unconventional Resource Plays

This is the final technical report for the Virginia Tech Center for Photonics Technology (VT-CPT) research project entitled “Fully Distributed Acoustic and Magnetic Field Monitoring Via a Single Fiber Line for Optimized Production of Unconventional Resource Plays”. In the the four-year effort, VT-CPT collaborated with the Departments of Mathmatics at VT and Sentek Instrument, LLC (Sentek) to develop a fiber-optic sensing system capable of real-time simultaneous distributed measurement of multiple subsurface, drilling, and production parameters. The ultra-sensitive fiber optic distributed acoustic sensing technology, picoDAS, developed by Sentek was integrated with a novel multi-material optical sensing fiber fabricated by CPT-VT to obtain distributed acoustic and magnetic field measurements with ultrahigh sensitivity and high spatial resolution. The sensing technology successfully developed and demonstrated under this research program is truly unique has application beyond subsurface imaging to include carbon storage and electrical grid monitoring, as well as healthcare and nuclear fusion. The project, sponsored by the Advanced Technology Program, began in 2019 and had the original goal of developing the next generation of harsh environment sensing systems. Exhaustive theoretical modeling was performed to optimize the multi-material optical fiber design. VT developed the processing techniques employed to successfully fabricate single mode fibers with metal cladding wires. Sensing fibers with nickel and Metglas cladding wires were fully characterized, inscribed with sensors, and fully integrated with the picoDAS system. Laboratory scale testing was performed to demonstrate performance upon exposure to lateral and transverse magnetic fields. Preliminary field trials were performed for prototype magnetic and acoustic sensing systems upon near surface deployment at VT. The distributed acoustic and magnetic field sensing system was advanced from a (Technology Readiness Level) TRL=2 to a TRL=5 via laboratory scale system validation in relevant environments. The truly one-of-its kind distributed magnetic and acoustic sensing system is expected to find immediate applications that require subsurface monitoring, to include carbon storage site monitoring, and has the potential to be a distributive technology in healthcare and electric grid markets. The technologies developed by Virginia Tech’s Center for Photonics Technology will support the mission of the National Energy Technology Laboratory (NETL) to drive innovation and deliver solutions for an environmentally sustainable and prosperous energy future by ensuring affordable, abundant, and reliable energy that drives a robust economy and national security. Technical accomplishments during the program are summarized briefly here and described in detail in the remainder of the report.

02 PETROLEUM↗

The hygrothermal performance of continuous and cavity wood fiber insulation

Wood fiber insulation is an emerging material known for its effective thermal performance and moisture management properties, making it a compelling alternative to conventional insulation. Its vapor permeability and ability to regulate indoor humidity contribute to improved building durability and comfort, particularly in varying climate conditions. The goal of this project is to characterize the hygrothermal performance of a new wood fiber insulation product line in U.S. climate zones and to facilitate the design and construction of the product in residential and light commercial building envelopes. This study investigates the thermal and hygrothermal performance of wood fiber insulation, both as continuous and cavity insulation. The research employs an exhaustive simulation task and an environmental chamber test of a wood fiber insulation. Over 400 simulations were conducted to study the hygrothermal characteristics of bio-based wood fiber insulation in various building envelope configurations across four climate zones. Environmental chamber tests were conducted under controlled winter conditions representative of Climate Zone 5A (Chicago, IL) to complement the simulation results. The chamber tests focused on the hygrothermal performance of the wood fiber insulation and the sheathing board to assess the insulation's ability to manage moisture in a cold climate. Simulation and environmental chamber test results were analyzed to evaluate the insulation's consistency and efficacy across diverse climatic zones. Results show that with a proper moisture control strategy, both cavity and continuous wood fiber insulation can work properly in both new and retrofit constructions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

HDG-1 Fiber Bragg grating data analysis

The main goal of the High dose graphite 1 Advanced test reactor experiment was to study nuclear grade graphite at high fluences. Additional supplementary optical fiber instrumentation was added to this long duration experiment for instrumentation development purposes. The supplementary instrumentation consisted of two pure silica core, fluorine doped cladding optical fibers each etched with 9 fiber Bragg gratings, one fiber being heat treated for 9 hours at 750 C and 16 hours at 750 C, the other being heat treated for 24 hours at 550 C and 48 hours at 650 C. Fiber Bragg gratings are known to have issues of measurement drift when in high temperature and high radiation environments like what is encountered in the Advanced test reactor. At the culmination of this experiment, the optical fibers saw ~1.3E21 n/cm2 total fluence, which is at the highest fluences that fiber Bragg gratings have been studied to date. Reported here is the analysis of this data including radiation induced shift and changes in sensitivity.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Ethanol Production from Corn Fiber Separated after Liquefaction in the Dry Grind Process

Conversion of corn fiber to ethanol in the dry grind process can increase ethanol yields, improve coproduct quality and contribute to process sustainability. This work investigates the use of two physio-chemical pretreatments on corn fiber and effect of cellulase enzyme dosage to improve ethanol yields. Fiber separated after liquefaction of corn was pretreated using (I) hot water pretreatment (160 °C for 5, 10 or 20 min) and (II) wet disk milling and converted to ethanol. The conversion efficiencies of hot water pretreated fiber were higher than untreated fiber, with highest increase in conversion (10.4%) achieved for 5 min residence time at 160 °C. Disk milling was not effective in increasing conversion compared to other treatments. Hydrolysis and fermentation of untreated fiber with excess cellulase enzymes resulted in 33.3% higher conversion compared to untreated fiber.

09 BIOMASS FUELS↗

State-of-the-Art Organic- and Inorganic-Based Hollow Fiber Membranes in Liquid and Gas Applications: Looking Back and Beyond

The aggravation of environmental problems such as water scarcity and air pollution has called upon the need for a sustainable solution globally. Membrane technology, owing to its simplicity, sustainability, and cost-effectiveness, has emerged as one of the favorable technologies for water and air purification. Among all of the membrane configurations, hollow fiber membranes hold promise due to their outstanding packing density and ease of module assembly. Herein, this review systematically outlines the fundamentals of hollow fiber membranes, which comprise the structural analyses and phase inversion mechanism. Furthermore, illustrations of the latest advances in the fabrication of organic, inorganic, and composite hollow fiber membranes are presented. Key findings on the utilization of hollow fiber membranes in microfiltration (MF), nanofiltration (NF), reverse osmosis (RO), forward osmosis (FO), pervaporation, gas and vapor separation, membrane distillation, and membrane contactor are also reported. Moreover, the applications in nuclear waste treatment and biomedical fields such as hemodialysis and drug delivery are emphasized. Subsequently, the emerging R&D areas, precisely on green fabrication and modification techniques as well as sustainable materials for hollow fiber membranes, are highlighted. Last but not least, this review offers invigorating perspectives on the future directions for the design of next-generation hollow fiber membranes for various applications. As such, the comprehensive and critical insights gained in this review are anticipated to provide a new research doorway to stimulate the future development and optimization of hollow fiber membranes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Bit Error Rate Performance of a Free Space Optical Link Using Double Clad Fibers

Mobile and embedded applications are emerging in the growing field of free space optical links (FSOL). Some mobile applications for FSOL include spacecraft, aircraft, and automotive. These applications by nature require low size weight and power (SWaP) solutions. The main challenge with any FSOL system is the strict pointing requirements. Common solutions to pointing and alignment of FSOL include gimbals, fast steering mirrors, and adaptive optics. All of which provide viable solutions at the cost of increased SWaP. Previously, we presented the use of both large core fibers and double clad fibers (DCF) to interface FSOL transmit and receive optics with small form factor pluggable optical transceivers (SFP). Double clad fibers have been shown to enable a common optical path by transmitting through a single mode core and receiving through a large inner cladding. This enables a single set of symmetric transmit and receive optics, which decreases the SWaP. In addition, using DCF increases the received power stability of the link relative to a multi-mode fiber (MMF) transmitting. To determine the viability of the system, bit error rate performance needs to be investigated. The results of this paper show that at a bit rate of 10 Gbps, double clad fibers offer similar bit error rate performance to single mode fibers when transmitting and multi-mode fibers when receiving enabling a symmetric duplex FSOL reducing SWaP.

Small Form-Factor Pluggable Optical Transceiver↗

Bit Error Rate Performance of a Free Space Optical Link Using Double Clad Fibers

Mobile and embedded applications are emerging in the growing field of free space optical links (FSOL). Some mobile applications for FSOL include spacecraft, aircraft, and automotive. These applications by nature require low size weight and power (SWaP) solutions. The main challenge with any FSOL system is the strict pointing requirements. Common solutions to pointing and alignment of FSOL include gimbals, fast steering mirrors, and adaptive optics. All of which provide viable solutions at the cost of increased SWaP. Previously, we presented the use of both large core fibers and double clad fibers (DCF) to interface FSOL transmit and receive optics with small form factor pluggable optical transceivers (SFP). Double clad fibers have been shown to enable a common optical path by transmitting through a single mode core and receiving through a large inner cladding. This enables a single set of symmetric transmit and receive optics, which decreases the SWaP. In addition, using DCF increases the received power stability of the link relative to a multi-mode fiber (MMF) transmitting. To determine the viability of the system, bit error rate performance needs to be investigated. The results of this paper show that at a bit rate of 10 Gbps, double clad fibers offer similar bit error rate performance to single mode fibers when transmitting and multi-mode fibers when receiving enabling a symmetric duplex FSOL reducing SWaP.

Double Clad Fiber↗

Carbon fibers derived from commodity polymers: A review

Carbon fiber composites are prohibitively expensive for a wide array of applications that would greatly benefit from their superior specific strength and specific stiffness. Replacing the market-dominant carbon fiber precursor material, polyacrylonitrile, with a low-cost alternative would significantly reduce the cost of carbon fiber production. Commodity polymers may provide such an alternative thanks to their abundance and ease of production into fibers. Furthermore, this review presents state-of-the-art carbon fiber production from polyacrylonitrile, an overview of melt-spinnable alternative precursors broadly, and an in-depth review of the latest advances in the synthesis of carbon fibers from low-cost, commodity thermoplastics such as polyethylene, polyamide, polystyrene, polyester, and poly(vinyl chloride).

36 MATERIALS SCIENCE↗

Comparative Analysis of Radial and Random Microstructures of Mesophase Pitch Carbon Fibers

Carbon fibers (CF) with radial and random microstructures are produced. Here, these fibers are subjected to identical treatment before being mechanically tested and analyzed with Weibull analysis, with the results revealing a statistically significant difference in tensile strengths of 2.23 GPa for random CF and 1.69 GPa for radial CF. Raman mapping probed the crystalline structure perpendicular to the fiber axis and found a uniform structure, while wide‐angle X‐ray diffraction showed a significant difference of 7.5 Å in the crystallites’ basal lengths parallel to the fiber. Small‐angle X‐ray scattering is completed parallel to the fiber for the first time. A cross‐section Guinier plot of the 1D azimuthal integration is generated assuming symmetric scattering, and the parallel scatterers are found to have a similar length scale to the crystallite's length, validating the testing method. Finally, transmission electron microscopy is completed on the longitudinal cross‐section of each fiber. The radial carbon fiber is found to have a core–shell structure, as evidenced further by fast Fourier transform images. Through all studies, it is shown that the structure developed during mesophase pitch spinning altered the microstructure, thus impacting the mechanical properties, confirming a direct relationship between processing, structure, and properties.

Scherschel, Alexander [Univ. of Virginia, Charlott↗