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Smart Methane Emission Detection System Development (Final Report)

Working with the Department of Energy's National Energy Technology Laboratory, Southwest Research Institute® (SwRI®) developed a system to identify methane leaks reliably, accurately, and autonomously at critical midstream sections of the natural gas distribution network in real-time for the purpose of mitigating methane emissions using Optical Gas Imaging (OGI) cameras. SwRI's Smart Leak Detection – Methane (SLED/M) adds a high degree of automation to the process of methane leak detection to minimize sources of human error, minimize response time to a leak event, and maximize midstream visibility. Furthermore, SwRI has been working towards integrating Quantitative OGI (QOGI) capabilities into this existing technology. By leveraging Deep Learning, SwRI now has the capability to estimate fugitive emission leak rates quickly and reliably, which allows operators to detect emissions, quantify leak rate, prioritize repairs, and validate the repairs in a single instrument. The next generation QOGI technology leverages the same cameras used in Leak Detection and Repair (LDAR) programs, with improvements in safety and speed for traditional quantification-based repairs, ultimately leading to less overhead cost for the operators. The goals for this research were to develop two types of models with the following goals: Run in real-time on the edge (≥ 12 Hz), Classification: Achieve less than 5% false positive detection, Classification: Achieve ≥ 95% methane plume detection rate, Regression: achieve ≤ 10 standard cubic feet per hour (scfh) prediction > 70% of the time. In order to achieve these results, multiple infrared (IR) and other sensors were investigated in tandem with the midwave IR (MWIR) OGI to provide additional information to train the underlying models. Information on atmospheric conditions including humidity, temperature, pressure, and solar radiation was provided by a weather station. Several machine learning and deep learning architectures and methods, including looking at quantized classification networks and regressions networks, were explored. As further data was collected, curated, and labeled, it allowed for more refined regressive networks to be adequately trained, leading to better insight into the true flow rates being observed. An important valuable deliverable of this research effort was the development of an advanced network which underwent multiple iterations capable of giving a continuous output. The current network has a predicted mean average percentage error (MAPE) of 12.3% just outside our target goal of 10.00%, but an accuracy of 97.78% at ±50 scfh, well within the overall goal for the Department of Energy (DOE) program. Upon closer inspection, it was observed that more than 10% of datapoints contributing to the MAPE predictions were the result of low flow rate predictions and are beyond the sensitivity of instrument measurement as a result of normal operational variation and noise.

03 NATURAL GAS↗

Updated Application of Frequency of Detection Methods for the INL Site Ambient Air Monitoring Network

This report presents a quantitative assessment of the current INL Site air monitoring network using frequency of detection (FD) methods. The first assessment of the INL network was performed in 2015 and made recommendations for improving the network. As a result of changes made in response to the recommendations and the addition of new source locations, the network was modified and reassessed in 2017. Since 2017, administration of the air sampling program has been consolidated under one contractor, which resulted in additional changes to the network (sampler numbers and locations) and changes in radionuclide detection levels. As a result of these changes and others, an updated assessment of the INL Site ambient air monitoring network was performed. The same two exposure scenarios used in previous assessments were used for this assessment: a resident scenario and a shepherd/rancher scenario. The resident was assumed to be continuously present at their residence/business/farm operation outside the INL Site boundary while the shepherd/rancher was assumed to be present 24-hours at the nearest INL grazing allotment boundary in each of the 22.5-degree sectors along the sector centerline from each source. Updates to both the resident and shepherd/rancher receptor locations were included. Other changes include updates to flow rates for stack sources, expansion of the list of important radionuclides based on the most recent National Emission Standards for Hazardous Pollutants (NESHAPs) analysis, and updated dose coefficients. The assessment was conducted to determine whether the current INL monitoring network is capable of detecting releases of important radionuclides from INL Site sources that have the potential to exceed a conservative dose threshold for the two exposure scenarios. The assessment revealed that for the resident scenario, the current network meets the desired performance objective (FD = 95%) for all radionuclides and sources except for Cl-36 from the TRA-770 stack (94.4%). For the shepherd/rancher scenario, the FD performance objective is met for all radionuclides and sources except tritium from MFC-774 and TAN 679 (91% for both). An investigation of reported emissions for the past three years revealed that Cl 36 is not emitted from TRA-770, and routine tritium emissions from MFC-774 and TAN-679 are very small and the sources are likely incapable of emitting enough tritium to cause a release that should be detectable by the monitoring network. This assessment is based on a conservative dose threshold. This coupled with fact that the FD for Cl 36 is only slightly less than the performance objective and Cl-36 is not emitted from TRA-770, modifying the network (i.e. adding another sampler, increasing sampler flow rate, moving samplers) to meet the 95% performance objective for this radionuclide/source/receptor scenario is not warranted. Similarly, because tritium emissions from MFC-774 and TAN-679 are very small and these two sources are likely incapable of causing a dose due to tritium release that should be detectable by the network, modifications to increase tritium detection for these sources is also unwarranted at this time. However, if it is required to meet the performance objective for tritium for all sources and receptor scenarios, additional analysis determined the FD could be raised from 91% to > 99% for both sources by adding two tritium samplers to the network.

61 RADIATION PROTECTION AND DOSIMETRY↗

Comparison of Sub-Ppm Instrument Response Suggests Higher Detection Limits Could Be Used to Quantify Methane Emissions from Oil and Gas Infrastructure

Quantifying and controlling fugitive methane emissions from oil and gas facilities remains essential for addressing climate goals, but the costs associated with monitoring millions of production sites remain prohibitively expensive. Current thinking, supported by measurement and simple dispersion modelling, assumes single-digit parts-per-million instrumentation is required. To investigate instrument response, the inlets of three trace-methane (sub-ppm) analyzers were collocated on a facility designed to release gas of known composition at known flow rates between 0.4 and 5.2 kg CH 4 h –1 from simulated oil and gas infrastructure. Methane mixing ratios were measured by each instrument at 1 Hertz resolution over nine hours. While mixing ratios reported by a cavity ring-down spectrometer (CRDS)-based instrument were on average 10.0 ppm (range 1.8 to 83 ppm), a mid-infrared laser absorption spectroscopy (MIRA)-based instrument reported short-lived mixing ratios far larger than expected (range 1.8 to 779 ppm) with a similar nine-hour average to the CRDS (10.1 ppm). We suggest the peaks detected by the MIRA are likely caused by a micrometeorological phenomenon, where vortex shedding has resulted in heterogeneous methane plumes which only the MIRA can observe. Further analysis suggests an instrument like the MIRA (an optical-cavity-based instrument with cavity size ≤10 cm3 measuring at ≥2 Hz with air flow rates in the order of ≤0.3 slpm at distances of ≤20 m from the source) but with a higher detection limit (25 ppm) could detect enough of the high-concentration events to generate representative 20 min-average methane mixing ratios. Even though development of a lower-cost, high-precision, high-accuracy instrument with a 25 ppm detection threshold remains a significant problem, this has implications for the use of instrumentation with higher detection thresholds, resulting in the reduction in cost to measure methane emissions and providing a mechanism for the widespread deployment of effective leak detection and repair programs for all oil and gas infrastructure.

03 NATURAL GAS↗

Deep Learning and Photogrammetric Reconstruction for Automated Crack Detection and Dimensional Measurement in Mining Operations

Surface crack detection and dimensional measurement at active mining sites present significant safety and operational challenges. Manual inspection methods are labor-intensive, spatially incomplete, and expose personnel to hazardous environments, while existing automated approaches have been developed primarily for concrete civil infrastructure and have not been validated on the complex, variable surfaces characteristic of mining environments. This dissertation presents an automated pipeline that integrates deep learning semantic segmentation with Structure-from-Motion photogrammetry to detect surface cracks and measure their aperture, length, and vertical displacement from standard RGB imagery acquired during routine Uncrewed Aerial Vehicle (UAV) survey operations, without requiring additional sensor hardware or manual measurement. The pipeline combines a U-Net architecture with an EfficientNet-B0 encoder, pretrained on the SDNET2018 concrete crack dataset and fine-tuned on a mining-specific dataset spanning laboratory concrete specimens, coal refuse impoundment embankments, and post-blast limestone quarry benches. Photogrammetric reconstruction is performed using COLMAP Structure-from-Motion and Multi-View Stereo, with crack segmentation masks projected into the reconstructed point cloud to enable three-dimensional vertical displacement measurement through local plane fitting and bimodal surface detection. The pipeline was validated across 36 controlled laboratory specimens at three imaging distances and four vertical displacement levels, achieving aperture measurement RMSE of 0.047 cm and R² of 0.954, and vertical displacement RMSE of 0.140 cm and R² of 0.966, against independent caliper measurements. Field application at a coal refuse impoundment in southwestern Pennsylvania detected 71 crack components across the embankment crest, with a dominant longitudinal crack exhibiting aperture values reaching 28 cm and a 95th percentile vertical displacement of 35.53 cm, consistent in magnitude and spatial distribution with simultaneously acquired LiDAR-derived estimates. Application across four post-blast limestone quarry bench datasets in California successfully characterized blast-induced fracture networks at ground sampling distances ranging from 0.59 to 1.23 cm/pixel, with detected crack geometries physically consistent with observable surface conditions at each site. The results demonstrate that deep learning-based crack detection and photogrammetric measurement can be integrated into routine UAV inspection workflows at mining sites, providing repeatable, scalable, and quantitative crack characterization across surface types, crack scales, and displacement magnitudes not previously addressed in the literature. The pipeline requires no dedicated surveying equipment beyond the UAV platforms already deployed at mine sites for survey and monitoring purposes, supporting practical adoption within existing operational workflows.

Crack detection, Dimensional Measurement↗

MINIMAL PROSPECTS FOR RADIO DETECTION OF EXTENSIVE AIR SHOWERS IN THE ATMOSPHERE OF JUPITER

One possible approach for detecting ultra-high-energy cosmic rays and neutrinos is to search for radio emission from extensive air showers created when they interact in the atmosphere of Jupiter, effectively utilizing Jupiter as a particle detector. We investigate the potential of this approach. For searches with current or planned radio telescopes we find that the effective area for detection of cosmic rays is substantial (∼3 × 10{sup 7} km{sup 2}), but the acceptance angle is so small that the typical geometric aperture (∼10{sup 3} km{sup 2} sr) is less than that of existing terrestrial detectors, and cosmic rays also cannot be detected below an extremely high threshold energy (∼10{sup 23} eV). The geometric aperture for neutrinos is slightly larger, and greater sensitivity can be achieved with a radio detector on a Jupiter-orbiting satellite, but in neither case is this sufficient to constitute a practical detection technique. Exploitation of the large surface area of Jupiter for detecting ultra-high-energy particles remains a long-term prospect that will require a different technique, such as orbital fluorescence detection.

79 ASTRONOMY AND ASTROPHYSICS↗

RADIO DETECTION PROSPECTS FOR A BULGE POPULATION OF MILLISECOND PULSARS AS SUGGESTED BY FERMI-LAT OBSERVATIONS OF THE INNER GALAXY

The dense stellar environment of the Galactic center has been proposed to host a large population of as-yet undetected millisecond pulsars (MSPs). Recently, this hypothesis has found support in an analysis of gamma-rays detected using the Large Area Telescope onboard the Fermi satellite, which revealed an excess of diffuse GeV photons in the inner 15 deg about the Galactic center. The excess can be interpreted as the collective emission of thousands of MSPs in the Galactic bulge, with a spherical distribution strongly peaked toward the Galactic center. In order to fully establish the MSP interpretation, it is essential to find corroborating evidence in multi-wavelength searches, most notably through the detection of radio pulsations from individual bulge MSPs. Based on globular cluster observations and gamma-ray emission from the inner Galaxy, we investigate the prospects for detecting MSPs in the Galactic bulge. While previous pulsar surveys failed to identify this population, we demonstrate that upcoming large-area surveys of this region should lead to the detection of dozens of bulge MSPs. Additionally, we show that deep targeted searches of unassociated Fermi sources should be able to detect the first few MSPs in the bulge. The prospects for these deep searches are enhanced by a tentative gamma-ray/radio correlation that we infer from high-latitude gamma-ray MSPs. Such detections would constitute the first clear discoveries of field MSPs in the Galactic bulge, with far-reaching implications for gamma-ray observations, the formation history of the central Milky Way, and strategy optimization for future deep radio pulsar surveys.

79 ASTRONOMY AND ASTROPHYSICS↗

On the Prospects of Gamma-Ray Burst Detection in the TeV Band

A gamma-ray burst (GRB) jet running into an external medium is expected to generate luminous GeV–TeV emission lasting from minutes to several hours. The high-energy emission results from inverse Compton upscattering of prompt and afterglow photons by shock-heated thermal plasma. At its peak the high-energy radiation carries a significant fraction of the power dissipated at the forward shock. We discuss in detail the expected TeV luminosity, using a robust “minimal” emission model. Then, using the statistical properties of the GRB population (luminosity function, redshift distribution, afterglow energy), we simulate the expected detection rates of GRBs by current and upcoming atmospheric Cherenkov instruments. We find that GRBs exploding into a low-density interstellar medium must produce TeV emission that would have already been detected by the currently operating Cherenkov telescopes. The absence of detections is consistent with explosions into a dense wind of the GRB progenitor. If, as suggested by the recent analysis of Fermi LAT data, the typical environment of long GRBs is a Wolf–Rayet progenitor wind with the density parameter A∼10{sup 11} g cm{sup −1}, then 10%–20% of the bursts that trigger the space-borne detectors should also be detectable by the upcoming Cherenkov Telescope Array (CTA) under favorable observing conditions. Since absorption by the extragalactic background light limits the detectability above 0.1 TeV for all but the most nearby bursts (z≲1), the reduced energy threshold of CTA is the key improvement over current instruments, which should increase the number of detectable bursts by at least a factor of 3 compared with currently operating facilities.

79 ASTRONOMY AND ASTROPHYSICS↗

Detection of Galactic and Extragalactic Millimeter-wavelength Transient Sources with SPT-3G

High angular resolution cosmic microwave background experiments provide a unique opportunity to conduct a survey of time-variable sources at millimeter wavelengths, a population that has primarily been understood through follow-up measurements of detections in other bands. Here we report the first results of an astronomical transient survey with the South Pole Telescope (SPT) using the SPT-3G camera to observe 1500 deg 2 of the southern sky. The observations took place from 2020 March to November in three bands centered at 95, 150, and 220 GHz. This survey yielded the detection of 15 transient events from sources not previously detected by the SPT. The majority are associated with variable stars of different types, expanding the number of such detected flares by more than a factor of two. Additionally, the stellar flares are unpolarized and bright, in some cases exceeding 1 Jy, and have durations from a few minutes to several hours. Another population of detected events last for 2–3 weeks and appear to be extragalactic in origin. Though data availability at other wavelengths is limited, we find evidence for concurrent optical activity for two of the stellar flares. Future data from SPT-3G and forthcoming instruments will provide real-time detection of millimeter-wave transients on timescales of minutes to months.

79 ASTRONOMY AND ASTROPHYSICS↗

ARE WE THERE YET? TIME TO DETECTION OF NANOHERTZ GRAVITATIONAL WAVES BASED ON PULSAR-TIMING ARRAY LIMITS

Decade-long timing observations of arrays of millisecond pulsars have placed highly constraining upper limits on the amplitude of the nanohertz gravitational-wave stochastic signal from the mergers of supermassive black hole binaries (∼10{sup −15} strain at f = 1 yr{sup −1}). These limits suggest that binary merger rates have been overestimated, or that environmental influences from nuclear gas or stars accelerate orbital decay, reducing the gravitational-wave signal at the lowest, most sensitive frequencies. This prompts the question whether nanohertz gravitational waves (GWs) are likely to be detected in the near future. In this Letter, we answer this question quantitatively using simple statistical estimates, deriving the range of true signal amplitudes that are compatible with current upper limits, and computing expected detection probabilities as a function of observation time. We conclude that small arrays consisting of the pulsars with the least timing noise, which yield the tightest upper limits, have discouraging prospects of making a detection in the next two decades. By contrast, we find large arrays are crucial to detection because the quadrupolar spatial correlations induced by GWs can be well sampled by many pulsar pairs. Indeed, timing programs that monitor a large and expanding set of pulsars have an ∼80% probability of detecting GWs within the next 10 years, under assumptions on merger rates and environmental influences ranging from optimistic to conservative. Even in the extreme case where 90% of binaries stall before merger and environmental coupling effects diminish low-frequency gravitational-wave power, detection is delayed by at most a few years.

79 ASTRONOMY AND ASTROPHYSICS↗

Investigating the Efficacy of CubeSats for Asteroid Detection

A simulation to examine the potential of a network of CubeSats for detecting Near Earth Objects is discussed, in terms of goals, methods used and initial results obtained. By designing a basic optical system and the orbital parameters of the satellites in this network, their effectiveness for detecting asteroids is examined, with a small sample of cataloged asteroids considered.The conditions to be satisfied for detection cover both the geometrical aspects of astronomy such as field of view and line of sight, along with more technical optics-based conditions such as resolution and sensitivity of our telescopes. Of special interest to us in this work is the region of the sky between 45 deg. and 90 deg. from the Sun, as seen from the Earth. This part of the sky is currently unobservable by ground-based surveys and so provides the primary reason to consider a space-based one. There exist a number of issues with the simulation which call these results into question, but an eort has been made to remove those results which exceed the possible capabilities of the satellite network, and identify those aspects of the mission which should be examined in order to provide an in-depth assessment of it's performance. With these filters applied to the overall data, a tentative result of 1458 total detections over an 85 year period has been obtained, with 14 of the 22 asteroids in the sample being detected at least once. A number of ways in which the simulation could be improved are also proposed, both in-terms of addressing the aforementioned issues, as well as how to improve on the accuracy of the simulation and capture as many aspects of a space-based optical astronomy mission as possible,with the possible nal form of the simulation being a tool for assessing the performance of any space-based optical mission to detect asteroids.

Near Earth Objects↗

Improving Nocturnal Fire Detection with the VIIRS Day-Night Band

Building on existing techniques for satellite remote sensing of fires, this paper takes advantage of the day-night band (DNB) aboard the Visible Infrared Imaging Radiometer Suite (VIIRS) to develop the Firelight Detection Algorithm (FILDA), which characterizes fire pixels based on both visible-light and infrared (IR) signatures at night. By adjusting fire pixel selection criteria to include visible-light signatures, FILDA allows for significantly improved detection of pixels with smaller and/or cooler subpixel hotspots than the operational Interface Data Processing System (IDPS) algorithm. VIIRS scenes with near-coincident Advanced Spaceborne Thermal Emission and Reflection (ASTER) overpasses are examined after applying the operational VIIRS fire product algorithm and including a modified "candidate fire pixel selection" approach from FILDA that lowers the 4-μm brightness temperature (BT) threshold but includes a minimum DNB radiance. FILDA is shown to be effective in detecting gas flares and characterizing fire lines during large forest fires (such as the Rim Fire in California and High Park fire in Colorado). Compared with the operational VIIRS fire algorithm for the study period, FILDA shows a large increase (up to 90%) in the number of detected fire pixels that can be verified with the finer resolution ASTER data (90 m). Part (30%) of this increase is likely due to a combined use of DNB and lower 4-μm BT thresholds for fire detection in FILDA. Although further studies are needed, quantitative use of the DNB to improve fire detection could lead to reduced response times to wildfires and better estimate of fire characteristics (smoldering and flaming) at night.

Day-night band↗

GRB 191016A: A Long Gamma-Ray Burst Detected by TESS

The Transiting Exoplanet Survey Satellite (TESS) exoplanet-hunting mission detected the rising and decaying optical afterglow of GRB 191016A, a long gamma-ray burst (GRB) detected by Swift-BAT but without prompt XRT or UVOT follow-up due to proximity to the Moon. The afterglow has a late peak at least 1000 s after the BAT trigger, with a brightest-detected TESS data point at 2589.7 s post-trigger. The burst was not detected by Fermi-LAT, but was detected by Fermi-GBM without triggering, possibly due to the gradual nature of the rising light curve. Using ground-based photometry, we estimate a photometric redshift of z(sub phot) = 3.29 ± 0.40. Combined with the high-energy emission and optical peak time derived from TESS, estimates of the bulk Lorentz factor Γ(sub BL) range from 90 to 133. The burst is relatively bright, with a peak optical magnitude in ground-based follow-up of R = 15.1 mag. Using published distributions of GRB afterglows and considering the TESS sensitivity and sampling, we estimate that TESS is likely to detect ∼1 GRB afterglow per year above its magnitude limit.

Gamma-ray bursts↗

Revolution in Detection Affairs

The detection of nuclear or radioactive materials for homeland or national security purposes is inherently difficult. This is one reason detection efforts must be seen as just one part of an overall nuclear defense strategy which includes, inter alia, material security, detection, interdiction, consequence management and recovery. Nevertheless, one could argue that there has been a revolution in detection affairs in the past several decades as the innovative application of new technology has changed the character and conduct of detection operations. This revolution will likely be most effectively reinforced in the coming decades with the networking of detectors and innovative application of anomaly detection algorithms.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Smart Methane Emission Detection System Development (Final Report)

Working with the Department of Energy’s National Energy Technology Laboratory, Southwest Research Institute® (SwRI®) developed a system to identify methane leaks reliably, accurately, and autonomously at critical midstream sections of the natural gas distribution network in real- time for the purpose of mitigating methane emissions using Optical Gas Imaging (OGI) cameras. SwRI’s Smart Leak Detection – Methane (SLED/M) adds a high degree of automation to the process of methane leak detection to minimize sources of human error, minimize response time to a leak event, and maximize midstream visibility. Furthermore, SwRI has been working towards integrating Quantitative OGI (QOGI) capabilities into this existing technology. By leveraging Deep Learning, SwRI now has the capability to estimate fugitive emission leak rates quickly and reliably, which allows operators to detect emissions, quantify leak rate, prioritize repairs, and validate the repairs in a single instrument. The next generation QOGI technology leverages the same cameras used in Leak Detection and Repair (LDAR) programs, with improvements in safety and speed for traditional quantification-based repairs, ultimately leading to less overhead cost for the operators. The goals for this research were to develop two types of models with the following goals: 1. Run in real-time on the edge (≥ 12 Hz) 2. Classification: Achieve less than 5% false positive detection 3. Classification: Achieve ≥ 95% methane plume detection rate 4. Regression: achieve ≤ 10 standard cubic feet per hour (scfh) prediction > 70% of the time In order to achieve these results, multiple infrared (IR) and other sensors were investigated in tandem with the midwave IR (MWIR) OGI to provide additional information to train the underlying models. Information on atmospheric conditions including humidity, temperature, pressure, and solar radiation was provided by a weather station. Several machine learning and deep learning architectures and methods, including looking at quantized classification networks and regressions networks, were explored. As further data was collected, curated, and labeled, it allowed for more refined regressive networks to be adequately trained, leading to better insight into the true flow rates being observed. An important valuable deliverable of this research effort was the development of an advanced network which underwent multiple iterations capable of giving a continuous output. The current network has a predicted mean average percentage error (MAPE) of 12.3% just outside our target goal of 10.00%, but an accuracy of 97.78% at ±50 scfh, well within the overall goal for the Department of Energy (DOE) program. Upon closer inspection, it was observed that more than 10% of datapoints contributing to the MAPE predictions were the result of low flow rate predictions and are beyond the sensitivity of instrument measurement as a result of normal operational variation and noise.

03 NATURAL GAS↗

Detecting Process Equipment Failures Using Acoustic Data and Machine Learning

Nuclear power plant (NPP) process equipment such as fans, motors, valves, and pumps generate frequent or continuous noise, and deviations from the normal operational sounds made by this equipment can indicate potential issues. These deviations can be identified via automated acoustic anomaly detection, which involves using acoustic sensors (i.e., microphones) alongside detection algorithms to continuously monitor for changes in acoustic signatures. This task is made challenging by the substantial background noise that exists, such as operators opening and closing doors, manipulating valves, and conversing—in addition to typical plant noises. In collaboration with a nuclear power utility partner, this effort assessed the efficacy of acoustic anomaly detection when using a specific acoustic sensor that compresses data into a fixed set of features that are transferable over a standard Internet of Things communication protocol, thereby improving usability but potentially degrading detection performance. Two methods of performing automated acoustic anomaly detection were evaluated: one-class support vector machine (OC-SVM) and isolation forest (iForest). To enable the use of high-quality acoustic data encompassing both normal and anomalous conditions, the study utilized the publicly available Malfunctioning Industrial Machine Investigation and Inspection dataset, which includes real measured acoustic sensor data for a range of equipment types, model numbers, and signal-to-noise ratios (SNRs), along with a benchmark set of detection results. Using this dataset, the methods were tested and then compared against the benchmark results. The results indicated that although the specific acoustic sensor did not enable as rich a feature set extraction, the proposed methods with the limited feature set performed just as well. This provides solid justification for both the methods and the use of the proposed acoustic sensor.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Hyper Spectral Anomaly Detection

Anomaly detection is a common machine learning (ML) task with growing importance in the fields of imaging, quality assurance, and multiple security related disciplines. Anomaly detection is more difficult than traditional machine learning methods due to the inherent unlabeled nature of the datasets. Existing anomaly detection architectures commonly face challenges with explainability, retaining information related to the relational structure of the data, and false positive rates. Hyperspectral Imaging Anomaly Detection (HSI) is a statistical model that employs vertex and edge weighted graphs to preserve the data’s relationships on different topographical scales. The model is able to generalize from anomaly detection in 2D images to novel datasets related to cyber-security. Furthermore, the use of multi-spectral and other filtering methods results in fewer false positives and increases the explainability of model predictions. When applying HSI to cyber-security datasets, we are able to successfully detect malicious activity with a relatively high degree of accuracy.

97 - MATHEMATICS AND COMPUTING↗

Light-Duty Vehicle Trip Classification Using One-Class Novelty Detection and Exhaustive Feature Extraction

Travel mode classification within travel survey data sets, especially light-duty vehicle (LDV) trips, is foundational, though nontrivial, to emerging mobility systems, travel behavior analysis, and fuel consumption estimation. Current travel mode detection approaches require well-sampled and balanced data sets with ground truth travel mode labels. The detection approaches are rarely applied and validated on large-scale, real-world data sets, which may not satisfy the dataset requirements. This work proposes an LDV trip detection model as a supplement to current travel mode detection methods, for the case when the training set is highly (and/or completely) unbalanced, to the extent that classical machine-learning approaches become difficult or impossible to deploy. The proposed model uses a novelty detection technique - one-class support vector machines (OCSVMs) - and a novel exhaustive feature extraction (EFE) technique on continuous time series data (i.e., Global Positioning System [GPS] speed profiles) for single-mode trip trajectories. Training and validation of the model are conducted on a large-scale, real-world data set. The proposed method accurately identifies LDV trips from a broad set of multimodal trips by leveraging a wealth of preexisting in-vehicle GPS travel data. Additional sensitivity analysis sheds light on the optimal training size and feature selection, which will benefit applications limited by highly imbalanced data. The paper also discusses performance comparison with regular machine-learning approaches, the model's robustness, and the potential to extend the proposed model to multi-modal trip prediction.

33 ADVANCED PROPULSION SYSTEMS↗

Phosphodiesterase (PDE5) inhibition assay for rapid detection of erectile dysfunction drugs and analogs in sexual enhancement products

Abstract Products marketed as dietary supplements for sexual enhancement are frequently adulterated with phosphodiesterase‐5 (PDE5) inhibitors, which are erectile dysfunction drugs or their analogs that can cause adverse health effects. Due to widespread adulteration, a rapid screening assay was developed to detect PDE5 inhibitors in adulterated products. The assay employs fluorescence detection and is based on measuring inhibition of PDE5 activity, the pharmacological mechanism shared among the adulterants. Initially, the assay reaction scheme was established and characterized, followed by analysis of 9 representative PDE5 inhibitors ( IC 50 , 0.4–4.0 ng mL –1 ), demonstrating sensitive detection in matrix‐free solutions. Next, dietary supplements serving as matrix blanks ( n = 25) were analyzed to determine matrix interference and establish a threshold value; there were no false positives. Finally, matrix blanks were spiked with 9 individual PDE5 inhibitors, along with several mixtures. All 9 adulterants were successfully detected (≤ 5 % false negative rate; n = 20) at a concentration of 1.00 mg g –1 , which is over 5 times lower than concentrations commonly encountered in adulterated products. A major distinction of the PDE5 inhibition assay is the ability to detect adulterants without prior knowledge of their chemical structures, demonstrating a broad‐based detection capability that can address a continuously evolving threat of new adulterants. The PDE5 inhibition assay can analyze over 40 samples simultaneously within 15 minutes and involves a single incubation step and simple data analysis, all of which are advantageous for combating the widespread adulteration of sex‐enhancement products.

Santillo, Michael F.↗