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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
NASA NTRS2024

Differential Absorption Lidar for Searching Water Sources on Mars

Water vapor has been detected in the Martian atmosphere by multiple orbiting instruments. The Atmospheric Chemistry Suite (ACS) on the ExoMars Trace Gas Orbiter (TGO) observed H2O mixing ratios reaching up to 50 ppmv at altitudes of 100-120 km during global dust storms, while levels remained low (<2 ppmv) during other seasons. The Neutral Gas and Ion Mass Spectrometer (NGIMS) on the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft revealed that water transported to the upper atmosphere is dissociated by ions, producing atomic hydrogen that escapes into space, contributing to Mars’ water loss. This transport is seasonal, peaking in southern summer and intensifying during dust storms. Additionally, the Mars Reconnaissance Orbiter’s (MRO) imaging spectrometer detected hydrated minerals on slopes, suggesting that liquid water may intermittently flow on present-day Mars. However, an observational gap exists between high-altitude water vapor and surface water due to limitations in spatial resolution and a lack of measurements in the lower atmosphere. To address this gap, we propose using an airborne differential absorption lidar (DIAL) to search for water sources. DIAL provides high-resolution measurements both day and night, bridging the observational gap between high-altitude water vapor and surface water, thus enhancing our understanding of water transport and loss on Mars. Absorption lines of water vapor in the 2.7 μm and 1.8 μm bands have been selected in this study. Simulations show that both lines are capable of detecting water vapor sources with reasonable system parameters.

lidar↗
DOE OSTI2020

Impact of climate change on water availability and its propagation through the Western U.S. power grid

Climate impact assessment for power systems has tended to focus on the effects of water availability on generation without explicitly considering how these impacts propagate through the interconnected grid to affect generation in other locations. We investigate the impact of projected water availability on the operations of the contemporary Western U.S. power grid, focusing specifically on regional interdependencies. Hydrologic simulations derived from three GCMs (CCSM4, INMCM4 and GFDL-CM3) and two radiative scenarios (RCP4.5 and RCP8.5) are used to force a large-scale, distributed water management model (MOSART-WM), which translates water availability into power generation constraints at hydropower plants and water-dependent thermo-electric plants. Power system dynamics are evaluated using the production cost model PLEXOS. We find that the inter-regional connections across the Western U.S. electricity infrastructure are key in managing drastic variations in regional water availability. Net generation in the Northwest and Northern California is substantially sensitive to local water availability. Generation from the Desert Southwest emerges as a critical resource to compensate for variations in water availability in those regions. Climate change impacts on Northwestern water availability therefore drive future changes in other regions’ generation and regional power flows. The large inter-annual hydrological variability of Northern California exacerbates grid stress arising from long-term changes in water availability in the Northwest. While the regional power flow directions seem insensitive to long-term variations in water availability, the analysis highlights the need to consider other compounding regional factors such as changes in Southern California net load or changes in regional fuel prices.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Impacts of water scarcity on agricultural production and electricity generation in the Middle East and North Africa

Incorporating the interdependencies between water, energy and food (WEF) within an integrated approach of planning and management could help nations worldwide to address sustainability concerns. This is a topic of great importance for the Middle East and North Africa (MENA) region, where water is a very limited resource. In this study, we develop an analytical framework to analyze the water-energy-food nexus in the MENA region to inform the formulation of integrated strategies for water, energy and food activities. Our approach is based on an integrated assessment model for the MENA region, which explicitly represents WEF sectors within an economic framework, in tandem with a set of relevant scenarios addressing three key dimensions (socioeconomics, climate and water-management). Using this framework, our study analyzes the current and projected status of water resources in the region, and the potential implications for the agriculture and electricity sectors. Our scenarios demonstrate that water scarcity worsens by the end of the 21st century in most MENA countries, mostly due to growing demands. The impacts of growing scarcity on agriculture are significant, with production projected to drop by 60 percent by 2050 in some countries. On the other hand, and to a lesser extent, water-saving technologies and fuel-switching in the power sector play a key role in mitigating the effects of water scarcity on electricity generation in some parts of the MENA region. Our analysis then underscores the need to reduce the dependence of MENA’s agricultural and energy sectors on water, and transition to renewable energies to reduce water scarcity.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2016

Multi-Model Assessment of Global Hydropower and Cooling Water Discharge Potential Under Climate Change

Worldwide, 98% of total electricity is currently produced by thermoelectric power and hydropower. Climate change is expected to directly impact electricity supply, in terms of both water availability for hydropower generation and cooling water usage for thermoelectric power. Improved understanding of how climate change may impact the availability and temperature of water resources is therefore of major importance. Here we use a multi-model ensemble to show the potential impacts of climate change on global hydropower and cooling water discharge potential. For the first time, combined projections of streamflow and water temperature were produced with three global hydrological models (GHMs) to account for uncertainties in the structure and parametrization of these GHMs in both water availability and water temperature. The GHMs were forced with bias-corrected output of five general circulation models (GCMs) for both the lowest and highest representative concentration pathways (RCP2.6 and RCP8.5). The ensemble projections of streamflow and water temperature were then used to quantify impacts on gross hydropower potential and cooling water discharge capacity of rivers worldwide. We show that global gross hydropower potential is expected to increase between +2.4% (GCM-GHM ensemble mean for RCP 2.6) and +6.3% (RCP 8.5) for the 2080s compared to 1971-2000. The strongest increases in hydropower potential are expected for Central Africa, India, central Asia and the northern high-latitudes, with 18-33% of the world population living in these areas by the 2080s. Global mean cooling water discharge capacity is projected to decrease by 4.5-15% (2080s). The largest reductions are found for the United States, Europe, eastern Asia, and southern parts of South America, Africa and Australia, where strong water temperature increases are projected combined with reductions in mean annual streamflow. These regions are expected to affect 11-14% (for RCP2.6 and the shared socioeconomic pathway (SSP)1, SSP2, SSP4) and 41-51% (RCP8.5-SSP3, SSP5) of the world population by the 2080s.

global hydrological models↗
NASA NTRS2020

Monitoring Water-Related Ecosystems with Earth Observation Data in Support of Sustainable Development Goal (SDG) 6 Reporting

Lack of national data on water-related ecosystems is a major challenge to achieving the Sustainable Development Goal (SDG) 6 targets by 2030. Monitoring surface water extent, wetlands, and water quality from space can be an important asset for many countries in support of SDG 6 reporting. We demonstrate the potential for Earth observation (EO) data to support country reporting for SDG Indicator 6.6.1, ‘Change in the extent of water-related ecosystems over time’ and identify important considerations for countries using these data for SDG reporting. The spatial extent of water-related ecosystems, and the partial quality of water within these ecosystems is investigated for seven countries. Data from the Moderate Resolution Imaging Spectroradiometer (MODIS) and Landsat 5, 7, and 8 with Shuttle Radar Topography Mission (SRTM) are used to measure surface water extent at 250 m and 30 m spatial resolution, respectively, in Cambodia, Jamaica, Peru, the Philippines, Senegal, Uganda, and Zambia. The extent of mangroves is mapped at 30 m spatial resolution using Landsat 8 Operational Land Imager (OLI), Sentinel-1, and SRTM data for Jamaica, Peru, and Senegal. Using Landsat 8 and Sentinel 2A imagery, total suspended solids and chlorophyll-a are mapped over time for a select number of large surface water bodies in Peru, Senegal, and Zambia. All of the EO datasets used are of global coverage and publicly available at no cost. The temporal consistency and long time-series of many of the datasets enable replicability over time, making reporting of change from baseline values consistent and systematic. We find that statistical comparisons between different surface water data products can help provide some degree of confidence for countries during their validation process and highlight the need for accuracy assessments when using EO-based land change data for SDG reporting. We also raise concern that EO data in the context of SDG Indicator 6.6.1 reporting may be more challenging for some countries, such as small island nations, than others to use in assessing the extent of water-related ecosystems due to scale limitations and climate variability. Country-driven validation of the EO data products remains a priority to ensure successful data integration in support of SDG Indicator 6.6.1 reporting. Multi-country studies such as this one can be valuable tools for helping to guide the evolution of SDG monitoring methodologies and provide a useful resource for countries reporting on water-related ecosystems. The EO data analyses and statistical methods used in this study can be easily replicated for country-driven validation of EO data products in the future.

water-related ecosystems; surface water extent; ma↗
DOE OSTI2022

Natural and anthropogenic controls on lake water‐level decline and evaporation‐to‐inflow ratio in the conterminous United States

Abstract Lake water levels are integral to lake function, but hydrologic changes from land and water management may alter lake fluctuations beyond natural ranges. We constructed a conceptual model of multifaceted drivers of lake water levels and evaporation‐to‐inflow ratio (Evap : Inflow). Using a structural equation modeling framework, we tested our model on (1) a national subset of lakes in the conterminous United States with minimal water management to describe natural drivers of lake hydrology and (2) five ecoregional subsets of lakes to explore regional variation in water management effects. Our model fits the national and ecoregional datasets and explained up to 47% of variation in Evap : Inflow, 38% of vertical water level decline, and 79% of horizontal water level decline (littoral exposure). For lakes with minimal water management, Evap : Inflow was related to lake depth ( β = −0.31) and surface inflow ( β = −0.44); vertical decline was related to annual climate (e.g., precipitation β = −0.18) and water management ( β = −0.21); and horizontal decline was largely related to vertical decline ( β = 0.73) and lake morphometry (e.g., depth β = −0.18). Anthropogenic effects varied by ecoregion and likely reflect differences in regional water management and climate. In the West, water management indicators were related to greater vertical decline ( β = 0.38), whereas in the Midwest, these indicators were related to more stable and full lake levels ( β = −0.22) even during drought conditions. National analyses show how human water use interacts with regional climate resulting in contrasting impacts to lake hydrologic variation in the United States.

Fergus, C. Emi↗
DOE OSTI2025

Side-Chain and Ring-Size Effects on Permeability in Artificial Water Channels

Artificial water channels (AWCs) have emerged as a promising framework for stable water permeation, with water transport rates comparable to aquaporins (3.4–40.3 × 10 8 H 2 O/channel/s). In this study, we probe the influence of ring-size and side-chain length on the water permeability observed within a class of AWCs termed ligand-appended pillar[n]arenes (LAPs) that have an adjustable ring-size (m) and side-chain length (n). Through all-atom molecular dynamics simulations, we calculate the permeability of these channels using the collective diffusion model and find their permeabilities. We characterize the mechanistic influence of pillar[n]arene ring-size and side-chain length on the channel water permeability by analyzing the characteristics of the internal permeating water-wire and the surrounding channel structure. We observe that water permeability decreases as a function of increasing ring-size due to increases in hydrophilic contacts between the permeating water-wire and the oxygen groups on the channel wall. Further, we observe an increase in water permeability as a function of side-chain length due to increased partitioning of the channel terminal groups into the hydrophilic blocks of the surrounding bilayer. For the LAP6 channel, with increase in side-chain length, the distance between terminal groups increases and leads to an increase in pore size, thereby enhancing water permeability. In the case of LAP5, as side-chain length increases, the channel displays a compensatory effect between tilt and bend angle due to the flexible side-chains. Such flexibility leads to higher terminal group partitioning in the hydrophilic blocks of the bilayer and extends the permeating water-wire. Furthermore, this increase in water-wire length and hydrophilic block access overcomes the nonmonotonic pore size trend in pillar[5]arene channels.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Molecular Structure and Thermodynamics of CO 2 and Water Adsorption on Mica

The adsorption of CO 2 and water on clay surfaces plays a key role in applications, such as gas storage in saline aquifers and depleted hydrocarbon reservoirs, but is not yet fully understood. Here, we study the adsorption of CO 2 and water vapor using Grand Canonical Monte Carlo and molecular dynamics simulations. At a bulk pressure of 100 bar, pure CO 2 adsorbs strongly on mica and forms extensive layers next to it. CO 2 adsorption is lowered substantially if introducing water vapor above mica and is largely eliminated when the relative humidity (RH) approaches about 60%. When pure water vapor is introduced above a mica surface, a subnanometer thick liquid water film develops on it to form apparent liquid–solid and liquid–vapor interfaces simultaneously. Using the identification of truly interfacial molecules (ITIM) analysis, we delineate how individual water layers develop in this film as RH increases. We highlight that the water film is spatially heterogeneous and the true liquid–vapor interface emerges only at an RH of 60–80%. Introducing 100 bar of CO 2 into the water vapor above the mica surface modulates water adsorption nonlinearly: at RH = 0.01%, the water adsorption is reduced by ∼30%; as RH increases, the reduction is weakened, and eventually, enhancement of water adsorption by about 7% occurs at RH = 90%. These variations are attributed to the interplay of film thinning by high-pressure CO 2 , competition of mica surface sites by CO 2 molecules, and energetic and entropic stabilization of interfacial water by CO 2 molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Decision making for implementing non-traditional water sources: a review of challenges and potential solutions

Abstract The effects of climate change, population growth, and future hydrologic uncertainties necessitate increased water conservation, new water resources, and a shift towards sustainable urban water supply portfolios. Diversifying water portfolios with non-traditional water sources can play a key role. Rooftop harvested rainwater (RHRW), atmospheric and condensate harvesting, stormwater, recycled wastewater and greywater, and desalinated seawater and brackish water are all currently utilized and rapidly emerging non-traditional water sources. This review explores the status and trends around these non-traditional water sources, and reviews approaches and models for prioritizing, predicting, and quantifying metrics of concern. The analysis presented here suggests that understanding the challenges of location specific scenarios, socioeconomic knowledge gaps, water supply technologies, and/or water management structure is the crucial first step in establishing a model or framework approach to provide a strategy for improvement going forward. The findings of this study also suggest that clear policy guidance and onsite maintenance is necessary for variable water quality concerns of non-traditional sources like harvested rainwater and greywater. In addition, use of stormwater or reuse of wastewater raises public health concerns due to unknown risks and pathogen levels, thus rapid monitoring technologies and transparent reporting systems can facilitate their adoption. Finally, cost structure of desalination varies significantly around the world, largely due to regulatory requirements and local policies. Further reduction of its capital cost and energy consumption is identified as a hurdle for implementation. Overall, models and process analyses highlight the strength of comparative assessments across scenarios and water supply options.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

All-atom molecular dynamics simulations of weak polyionic brushes: influence of charge density on the properties of polyelectrolyte chains, brush-supported counterions, and water molecules

All atom molecular dynamics (MD) simulations of planar Na+-counterion-neutralized polyacrylic acid (PAA) brushes are performed for varying degrees of ionization (and thereby varying charge density) and varying grafting density. Variation in the PE charge density (or degree of ionization) and grafting density leads to massive changes of the properties of the PE molecules (quantified by the changes in the height and the mobility of the PE brushes) as well as the local arrangement and distribution of the brush-supported counterions and water molecules within the brushes. The effect on the counterions is manifested by the corresponding variation of the counterion mobility, counterion concentration, extent of counterion binding to the charged site of the PE brushes, water-in-salt-like structure formation, and counterion-water–oxygen radial distribution function within the PE brushes. On the other hand, the effect on water molecules is manifested by the corresponding variation of water–oxygen–water–oxygen RDF, local water density, water–water and water–PE functional group hydrogen bond networks, static dielectric constant of water molecules, orientational tetrahedral order parameter, and water mobility. Enforcing such varying degree of ionization of weak polyelectrolytes is possible by changing the pH of the surrounding medium. Thus, our results provide insights into the changes in microstructure (at the atomistic level) of weak polyionic brushes at varying pH. Finally, we anticipate that this knowledge will prove to be vital for the efficient design of several nano-scale systems employing PE brushes such as nanomechanical gates, current rectifiers, etc.

42 ENGINEERING↗
DOE OSTI2025

The possibility of hydrogen-water demixing in Uranus, Neptune, K2-18 b and TOI-270 d

Context. The internal structures of Uranus and Neptune remain unknown. In addition, sub-Neptunes are now thought to be the most common type of exoplanets. Improving our understanding of the physical processes that govern the interiors of such planets is therefore essential. Phase separation between planetary constituents may occur, in particular, hydrogen-water immiscibility in cold, water-rich intermediate-mass planets. Aims. We assess whether hydrogen-water demixing could occur in Uranus, Neptune, K2-18 b and TOI-270 d, and investigate its effect on the planetary evolution and inferred internal structure. Methods. We couple planetary evolution models with recent ab initio calculations of the hydrogen-water phase diagram, allowing for temperature shifts to account for uncertainties in miscibility gaps. Results. We find that demixing may occur and could lead to a complete depletion of water in the outermost regions of Uranus and Neptune. Temperature offsets of up to 1100 K lead to a depleted region comprising as much as 16% of the planet’s mass, and an increase in planetary radius by nearly 20%. For K2-18 b, our models suggest that hydrogen-water demixing is ongoing and may explain the absence of water features in its JWST spectrum. A temperature offset of 500 K is required to get a complete depletion of water in the atmosphere of K2-18b. TOI-270d may also have experienced hydrogen-water demixing. When applying a similar temperature offset on the phase diagram as for K2-18 b, we find a partial depletion of water in the atmosphere of TOI-270 d, consistent with JWST’s detection of water. Conclusions. Hydrogen-water immiscibility may play a key role in shaping the structure and evolution of both Solar System giant planets like Uranus and Neptune, and cold/temperate exoplanets such as K2-18 b and TOI-270 d. Accounting for such internal processes is crucial to accurately interpret atmospheric observations from current (e.g., JWST) and upcoming (e.g., ARIEL) missions.

planets and satellites: composition↗
DOE OSTI2021

Self-interaction correction in water–ion clusters

We study the importance of self-interaction errors in density functional approximations for various water–ion clusters. We have employed the Fermi-Löwdin orbital self-interaction correction (FLOSIC) method in conjunction with LSDA, PBE, and SCAN to describe binding energies of hydrogen-bonded water–ion clusters, i.e., water–hydronium, water– hydroxide, water–halide, as well as non-hydrogen-bonded water–alkali clusters. In the hydrogen-bonded water–ion clusters, the building blocks are linked by hydrogen atoms, although the links are much stronger and longer-ranged than the normal hydrogen bonds between water molecules, because the monopole on the ion interacts with both permanent and induced dipoles on the water molecules. We find that self-interaction errors overbind the hydrogen-bonded water– ion clusters and that FLOSIC reduces the error and brings the binding energies into closer agreement with higher–level calculations. Here, the non-hydrogen-bonded water–alkali clusters are not significantly affected by self-interaction errors. Self-interaction corrected PBE predicts the lowest mean unsigned error in binding energies (≤ 50 meV/H 2 O) for hydrogen-bonded water–ion clusters. Self-interaction errors are also largely dependent on the cluster size, and FLOSIC does not accurately capture the subtle variation in all clusters, indicating the need for further refinement.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Hydropower representation in water and energy system models: a review of divergences and call for reconciliation

Abstract Reservoir-based hydropower systems represent key interactions between water and energy systems and are being transformed under policy initiatives driven by increasing water and energy demand, the desire to reduce environmental impacts, and interacting effects of climate change. Such policies are often guided by complex system models, whereby divergence in system representations can potentially translate to incompatible planning outcomes, thereby undermining any planning that may rely on them. We review different approaches and assumptions in hydropower representation in water and energy systems. While the models and issues are relevant globally, the review focuses on applications in California given its extensive development of energy and water models for policy planning, but discusses the extent to which these observations apply to other regions. Structurally, both water-driven and energy-driven management models are similar. However, in energy models, hydropower is often represented as a single-priority output. Water management models typically allocate water for competing priorities, which are generally uninformed by dynamic electricity load demand, and often result in a lower priority for hydropower. In water models, constraints are increasingly resolved for non-energy components (e.g. inflow hydrology and non-energy water demand); few analogues exist for energy models. These limitations may result in inadequate representations of each respective sector, and vastly different planning outcomes for the same facilities between the two different sectors. These divergent modeling approaches manifest themselves in California where poorly reconciled outcomes may affect decisions in hydropower licensing, electricity grid flexibility and decarbonization, and planning for environmental water. Fully integrated water-energy models are computationally intensive and specific to certain regions, but better representation of each domain in respective efforts would help reconcile divergences in planning and management efforts related to hydropower across energy and water systems.

Rheinheimer, David E. (ORCID:0000000315259069)↗
DOE OSTI2024

Quantification of Residual Water in Spent Fuel Dry Storage Canisters Using Mass Spectrometry

The purpose of this report is to document updates on the apparatus to simulate commercial vacuum drying procedures at the Nuclear Energy Work Complex at Sandia National Laboratories. Validation of the extent of water removal in a dry spent nuclear fuel storage system based on drying procedures used at nuclear power plants is needed to close existing technical gaps. Operational conditions leading to incomplete drying may have potential impacts on the fuel, cladding, and other components in the system during subsequent storage and disposal, such as fuel degradation; cladding corrosion, embrittlement, or breaching; and the creation of a flammable environment via radiolysis of water. A general lack of data suitable for model validation of commercial nuclear canister drying processes necessitates well-designed investigations of drying process efficacy and water retention. Scaled tests that incorporate relevant physics and well-controlled boundary conditions are essential to provide insight and guidance to the simulation of prototypic systems undergoing drying processes. This report documents details on the quantification of residual water in the Advanced Drying Cycle Simulator (ADCS), an apparatus built to simulate commercial drying procedures and quantify the amount of residual water remaining in a pressurized water reactor (PWR) fuel assembly after drying. The ADCS was constructed with a prototypic 17×17 PWR fuel skeleton and waterproof heater rods to simulate decay heat. The ADCS is outfitted with thermocouples to measure the thermal response of the ADCS to simulated decay heats and internal helium fill pressures relevant to commercial drying procedures. The ADCS is also instrumented with pressure transducers to measure the pressures and vacuum levels observed during simulated commercial drying. The most unique instrumentation used for quantifying residual water in the ADCS is a Hiden Analytical HPR-30 mass spectrometer (MS), which measures gas compositions of the ADCS internal free volume, based on partial pressures calculated from relative proportions of gas molecules detected by the MS. This report details the methodology used to implement MS measurements in quantifying residual water in the ADCS. This methodology includes the calibration of the HPR-30 MS to a Buck Research Instruments CR-4 chilled mirror hygrometer, which itself is calibrated to a NIST-traceable standard. Data collected by both the MS and the chilled mirror hygrometer from water/helium mixtures ranging from 150 to 500,000 ppmv water in helium were used to generate calibration curves, establishing a source of verification of MS measured water contents. Details regarding water content measurement uncertainties are included in this report, defining the accuracy and verifiability of the HPR-30 MS in measuring residual water content in simulated dry storage canister environments.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1976

Evaluation of surface water resources from machine-processing of ERTS multispectral data

The surface water resources of a large metropolitan area, Marion County (Indianapolis), Indiana, are studied in order to assess the potential value of ERTS spectral analysis to water resources problems. The results of the research indicate that all surface water bodies over 0.5 ha were identified accurately from ERTS multispectral analysis. Five distinct classes of water were identified and correlated with parameters which included: degree of water siltiness; depth of water; presence of macro and micro biotic forms in the water; and presence of various chemical concentrations in the water. The machine processing of ERTS spectral data used alone or in conjunction with conventional sources of hydrological information can lead to the monitoring of area of surface water bodies; estimated volume of selected surface water bodies; differences in degree of silt and clay suspended in water and degree of water eutrophication related to chemical concentrations.

Mausel, P. W.↗
NASA NTRS1986

Defining reclaimed water potability requirements

Water used during previous space missions has been either carried or made aloft. Future human space endeavors will probably have to utilize some form of water reclamation and recycling. There is little applied experience in either the US or foreign space programs with this technology. Water reclamation and recycling constitutes an engineering challenge of the broadest nature and will require an intensive research and development effort if this technology is to mature in time for practical use on the proposed US spacestation. In order for this to happen, reclaimed/recycled water specification will need to be devised to guide engineering development. Perhaps the most strigent specifications will involve water to be consumed. NASA's present Potable Water Specifications are not applicable to reclaimed or recycled potable water. No specifications for reclaimed or recycled potable water presently exist either inside or outside NASA. NASA's past experience with potable water systems is reviewed, limitations of the present Potable Water Specifications are examined, present world expertise with potable water reclamation/recycling systems and system analogs is reviewed, and an approach to developing pertinent Reclaimed/Recycled Potable Water Specifications for spacecraft is presented.

Janik, D. S.↗
NASA NTRS1992

SPE water electrolyzers in support of the lunar outpost

During the 1970s, the SPE water electrolyzer, which uses ion exchange membranes as its sole electrolyte, was developed for nuclear submarine metabolic oxygen production. These developments included SPE water electrolyzer operation at up to 3,000 psia and at current densities in excess of 1,000 amps per square foot. The SPE water electrolyzer system is now fully qualified for both the U.S. and U.K. Navies with tens of thousands of system hours accumulated at sea. During the 1980s, the basic SPE water electrolyzer cell structure developed for the Navies was incorporated into several demonstrations for NASA's Space Station Program. Among these were: the SPE regenerative fuel cell for electrical energy storage; the SPE water electrolyzer for metabolic oxygen production; and the high pressure SPE water electrolyzer for reboost propulsion reactant production. In the 1990s, one emphasis will be the development of SPE water electrolyzers for the Lunar Outposts Currently defined potential Lunar Outpost applications for the SPE water electrolyzer include: SPE water electrolyzers for metabolic oxygen and potable water production from reclaimed water; and SPE water electrolyzers operating at high pressure as part of stationary and mobile surface energy storage systems.

Mcelroy, J. F.↗
NASA NTRS1993

Physiological water model development

The water of the human body can be categorized as existing in two main compartments: intracellular water and extracellular water. The intracellular water consists of all the water within the cells and constitutes over half of the total body water. Since red blood cells are surrounded by plasma, and all other cells are surrounded by interstitial fluid, the intracellular compartment has been subdivided to represent these two cell types. The extracellular water, which includes all of the fluid outside of the cells, can be further subdivided into compartments which represent the interstitial fluid, circulating blood plasma, lymph, and transcellular water. The interstitial fluid surrounds cells outside of the vascular system whereas plasma is contained within the blood vessels. Avascular tissues such as dense connective tissue and cartilage contain interstitial water which slowly equilibrates with tracers used to determine extracellular fluid volume. For this reason, additional compartments are sometimes used to represent these avascular tissues. The average size of each compartment, in terms of percent body weight, has been determined for adult males and females. These compartments and the forces which cause flow between them are presented. The kidneys, a main compartment, receive about 25 percent of the cardiac output and filters out a fluid similar to plasma. The composition of this filtered fluid changes as it flows through the kidney tubules since compounds are continually being secreted and reabsorbed. Through this mechanism, the kidneys eliminate wastes while conserving body water, electrolytes, and metabolites. Since sodium accounts for over 90 percent of the cations in the extracellular fluid, and the number of cations is balanced by the number of anions, considering the renal handling sodium and water only should sufficiently describe the relationship between the plasma compartment and kidneys. A kidney function model is presented which has been adapted from a previous model of normal renal function in man. To test the validity of the proposed kidney model, results predicted by the model will be compared to actual data involving injected or ingested fluids and subsequent urine flow rates. Comparison of the model simulation to actual data following the ingestion of 1 liter of water is shown. The model simulation is also shown with actual data following the intravenous infusion of hypertonic saline.

Doty, Susan↗