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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

The NANOGrav 11 yr Data Set: Solar Wind Sounding through Pulsar Timing

The North American Nanohertz Observatory for Gravitational Waves (NANOGrav) has observed dozens ofmillisecond pulsars for over a decade. We have accrued a large collection of dispersion measure (DM)measurements sensitive to the total electron content between Earth and the pulsars at each observation. All lines ofsight cross through the solar wind (SW), which produces correlated DM fluctuations in all pulsars. We develop andapply techniques for extracting the imprint of the SW from the full collection of DM measurements in the recentlyreleased NANOGrav 11 yr data set. We filter out long-timescale DM fluctuations attributable to structure in theinterstellar medium and carry out a simultaneous analysis of all pulsars in our sample that can differentiate thecorrelated signature of the wind from signals unique to individual lines of sight. When treating the SW asspherically symmetric and constant in time, we find the electron number density at 1au to be 7.9 ± 0.2 cm(exp -3). Wefind our data to be insensitive to long-term variation in the density of the wind. We argue that our techniques pairedwith a high-cadence, low-radio-frequency observing campaign of near-ecliptic pulsars would be capable ofmapping out large-scale latitudinal structure in the wind.

Madison, D.R.↗
NASA NTRSDate not supplied

Airborne High Spectral Resolution Lidar-2 Measurements of Enhanced Depolarization in Marine Aerosols

Airborne NASA Langley Research Center (LaRC) High Spectral Resolution Lidar-2 (HSRL-2) measurements acquired during the recent NASA EVS-3 Aerosol Cloud Meteorology Interactions over the Western Atlantic Experiment (ACTIVATE) revealed enhanced particulate linear depolarization associated with aerosols within the marine boundary layer. These HSRL-2 observations were acquired off the east coast of the United States in February and March 2020 when this lidar was deployed on the NASA LaRC UC-12 aircraft. HSRL-2 measured profiles of aerosol backscattering, extinction,and depolarization at 355 and 532nm and aerosol backscattering and depolarization at 1064nm. Typically HSRL-2 measures low (<5%) linear particulate depolarization associated with marine sea salt aerosols. However, during several ACTIVATE flights, particularly those that occurred with outbreaks of cold, dry air, linear particulate depolarization exceeded 15-20% (532nm) for aerosols within a few hundred meters above the surface. These high values indicated that these particles were nonspherical. Elevated depolarization values were also observed at 355 and 1064 nm. HSRL-2 measured aerosol extinction/backscatter ratio (“lidar ratio”) values around 20-25 sr (355 and 532 nm) that are typically associated with sea salt particles. Coincident measurements of relative humidity from dropsondes released from the UC-12and in situ Diode Laser Hygrometer (DLH) measurements flown on the NASA HU-25 aircraft showed that highest depolarization values of these nonspherical particles were found when the relative humidity (RH)was below 50-60%.These lidar observations of elevated depolarization associated with sea salt aerosol are consistent with previous lidar measurements of sea salt aerosols in dry conditions. We discuss these HSRL-2 measurements also in the context of coincident airborne in situ measurements of particle size and composition acquired on the HU-25 aircraft. We also found that CALIOP satellite measurements observed elevated depolarization during some similar cold air outbreaks. In such cases, the operational CALIOP algorithms attributed the elevated depolarization to nonspherical dust particles rather than the more likely scenario of nonspherical sea salt particles associated with low RH.

aerosols↗
NASA NTRS2021

Microstructural Observations on Advanced Multilayer Protective Coatings for Nuclear Thermal Propulsion

The present research discusses the microstructures of a new multilayered coating concept proposed to solve the “midrange corrosion” problem observed in NbC and ZrC-coated graphite (Gr) nuclear fuels during the NERVA/Rover programs. The concept envisions designing a compliant multilayered coatings architecture to accommodate the thermal expansion mismatch strains between the ZrC outer coating and the Gr/(U,Zr)C fuel matrix along with using a diffusion barrier to minimize carbon and hydrogen diffusion, respectively. Multilayered coatings were deposited on Gr substrates by chemical vapor deposition (CVD). Graphite disks, as well as the inner channels of a 19-hole hexagonal rod 152.4 mm long, were coated by CVD in proof-of concept process demonstration studies. Coated disk specimens were thermally-cycled between ambient and 1900 K for as long as 20 cycles with a 1h hold time at the temperature using both stepped and non-interrupted thermal cycling methods. Detailed cross-sectional microstructural analyses were conducted on the thermally-cycled coated disks. These results showed that the coatings were intact after 20 thermal cycles at 1900 K although the bonding of the overlay Mo coating appeared to be influenced by the oxygen content in the layer. Seven transverse sections were cut along the length from the coated hexagonal rod for microstructural studies. All the nineteen channels were observed to have been coated in all the sections. This paper reports the results of detailed microstructural analyses, compositional line scans and x-ray dot maps conducted on three coated channels from a mid-section of the rod. The measured values of carbon (C) were observed to be exceptionally high in all the specimens, which were attributed to hydrocarbon contamination of the specimen surfaces. It was observed that the oxygen (O) levels were high in all the coating layers even after approximately correcting for the observed high values of C. The source of O contamination of the CVD reactor system was attributed to either the presence of oxychloride impurities in the precursor salts or a pin hole leak in the coating system. It is concluded that high values of O result in poor bonding of the Mo overlay to the ZrC layer. These trials have established that it is possible to deposit multilayered coatings by CVD in 19-hole hexagonal rods 152.4 mm long similar to the NERVA fuel rod design although the quality of the coatings and the uniformity of their thicknesses require further improvement.

Nuclear thermal propulsion, multilayer coatings, m↗
NASA NTRS2020

Evidence for Ammonia-bearing Species on the Uranian Satellite Ariel Supports Recent Geologic Activity

We investigated whether ammonia-rich constituents are present on the surface of the Uranian moon Ariel by analyzing 32 near-infrared reflectance spectra collected over a wide range of sub-observer longitudes and latitudes. We measured the band areas and depths of a 2.2 μm feature in these spectra, which has been attributed to ammonia-bearing species on other icy bodies. Ten spectra display prominent 2.2 μm features with band areas and depths >2σ. We determined the longitudinal distribution of the 2.2 μm band, finding no statistically meaningful differences between Ariel’s leading and trailing hemispheres, indicating that this band is distributed across Ariel’s surface. We compared the band centers and shapes of the five Ariel spectra displaying the strongest 2.2 μm bands to laboratory spectra of various ammonia-bearing and ammonium-bearing species, finding that the spectral signatures of the Ariel spectra are best matched by ammonia-hydrates and flash frozen ammonia-water solutions. Our analysis also revealed that four Ariel spectra display 2.24 μm bands (>2σ band areas and depths), with band centers and shapes that are best matched by ammonia ice. Because ammonia should be efficiently removed over short timescales by ultraviolet photons, cosmic rays, and charged particles trapped in Uranus’ magnetosphere, the possible presence of this constituent supports geologic activity in the recent past, such as emplacement of ammonia-rich cryolavas and exposure of ammonia-rich deposits by tectonism, impact events, and mass wasting.

Richard J. Cartwright↗
DOE OSTI2025

Measurement report: A comparative analysis of an intensive incursion of fluorescing African dust particles over Puerto Rico and another over Spain

Measurements during episodes of African dust, made with two wideband integrated bioaerosol spectrometers (WIBSs), one on the northeastern coast of Puerto Rico and the other in the city of León, Spain, show unmistakable, bioaerosol-like fluorescing aerosol particles (FAPs) that can be associated with these dust episodes. The Puerto Rico event occurred during a major incursion of African dust during June 2020. The León event occurred in the late winter and spring of 2022, when widespread, elevated layers of dust inundated the Iberian Peninsula. Satellite and back-trajectory analyses confirm that dust from northern Africa was the source of the particles during both events. The WIBSs measure the size of individual particles in the range from 0.5 to 30 µm, derive a shape factor, and classify seven types of fluorescence from the FAPs. In general, it is not possible to directly determine the specific biological identity from fluorescence signatures; however, measurements of these types of bioaerosols in laboratory studies allow us to compare ambient fluorescence patterns with whole microbial cells measured under controlled conditions. Here we introduce some new metrics that offer a more quantitative approach for comparing FAP characteristics derived from particles measured under different environmental conditions. The analysis highlights the similarities and differences at the two locations and reveals differences that can be attributed to the age and history of the dust plumes, e.g., the amount of time that the air masses were in the mixed layer and the frequency of precipitation along the air mass trajectory.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Total Column Infrared Trace Species in Baltimore Field Campaign Report

The U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) User Facility Coast-Urban-Rural Atmospheric Gradient Experiment (CoURAGE), including the first ARM Mobile Facility (AMF1), occurred during 2025 at a site in Baltimore, Maryland owned by Morgan State University. Our goal was to supplement the measurements taken by locating a Bruker EM27/SUN spectrometer at the site to make total column measurements of trace gases in the near-infrared. This EM27 location was one of six locations in the Washington, D.C./Maryland region during the summer of 2025, and the network of observations was intended to help us better understand emissions in the region, as well as how emissions interact with meteorology to affect air quality and other atmospheric attributes.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1995

Analysis of ocean color components within stratified and well-mixed waters of the western English Channel

In situ pigment and dissolved organic carbon (DOC) data from two distinct hydrographic regions of the western English Channel are used to explore the possible marine DOC contamination of the past satellite estimates of phytoplankton biomass. To compare with field measurements, the individual spectral contributions of DOC, pigments, and water to the total diffuse attenuation coefficient, K(sub par), are summed on a quantum basis within stratified waters near Plymouth, England; and for the spectrally averaged diffuse attenuation coefficient, K(sub d), on an energy basis within tidally mixed waters near Roscoff, France. In addition, coastal zone color scanner (CZCS) images from 1979 to 1986 were used to compute DOC concentrations for comparison with in situ values. Our analysis suggests that almost 50% of the color signal of satellite-sensed pigments may be attributed to absorption by marine colored DOC (CDOC) within the English Channel. These results compare favorably to the in situ DOC measurements off Plymouth, but not to off-Roscoff measurements, suggesting that there may be more CDOC in the stratified waters and more nonabsorbing DOC in the tidally mixed waters.

Hochmann, Herschel T.↗
NASA NTRS2014

High-Energy X-Ray Imaging of the Pulsar Wind Nebula MSH 15-52: Constraints on Particle Acceleration and Transport

We present the first images of the pulsar wind nebula (PWN) MSH 15−52 in the hard X-ray band (8 keV), as measured with the Nuclear Spectroscopic Telescope Array (NuSTAR). Overall, the morphology of the PWN as measured by NuSTAR in the 3-7 keV band is similar to that seen in Chandra high-resolution imaging. However, the spatial extent decreases with energy, which we attribute to synchrotron energy losses as the particles move away from the shock. The hard-band maps show a relative deficit of counts in the northern region toward the RCW 89 thermal remnant, with significant asymmetry. We find that the integrated PWN spectra measured with NuSTAR and Chandra suggest that there is a spectral break at 6 keV, which may be explained by a break in the synchrotron emitting electron distribution at approximately 200 TeV and/or imperfect cross calibration. We also measure spatially resolved spectra, showing that the spectrum of the PWN softens away from the central pulsar B1509−58, and that there exists a roughly sinusoidal variation of spectral hardness in the azimuthal direction. We discuss the results using particle flow models. We find non-monotonic structure in the variation with distance of spectral hardness within 50 of the pulsar moving in the jet direction, which may imply particle and magnetic-field compression by magnetic hoop stress as previously suggested for this source. We also present two-dimensional maps of spectral parameters and find an interesting shell-like structure in the N(sub H) map. We discuss possible origins of the shell-like structure and their implications.

individual objects: G320.4-1.2↗
DOE OSTI2025

A simulation pipeline for fast neutron imaging and spectroscopy using quantified detector attributes

Radiation imaging capabilities, essential in the nuclear nonproliferation regime, facilitate source localization and, in certain cases, spectroscopy. Scatter-based neutron cameras, which can measure the neutron signatures from special nuclear material, hold particular interest. Systems incorporating organic scintillators can extract neutron energy spectra, potentially distinguishing fission neutron sources from others, such as alpha-neutron sources. The development and testing of a scatter-based neutron imager, however, can be challenging without having an accurate simulation model or first constructing a prototype. This work describes a simulation pipeline that takes output from MCNPX-PoliMi simulations and creates the expected back-projection neutron images and neutron energy spectra. This pipeline was developed to improve the modeling of fast neutron imagers and bridge the current gap in literature, which predominantly focuses on gamma-ray Compton imager models. This work also reports on the significance of various real-world system considerations and their effects on the simulated detector responses. The pipeline was verified and validated with experimental data collected using a 252 Cf spontaneous fission source using a fast neutron scattering imager developed at the University of Michigan.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Evaluating the WFIP2 updates to the HRRR model using scanning Doppler lidar measurements in the complex terrain of the Columbia River Basin

The wind-energy (WE) industry relies on numerical weather prediction (NWP) forecast models as foundational or base models for many purposes, including wind-resource assessment and wind-power forecasting. During the Second Wind Forecast Improvement Project (WFIP2) in the Columbia River Basin of Oregon and Washington, a significant effort was made to improve NWP forecasts through focused model development, to include experimental refinements to the High Resolution Rapid Refresh (HRRR) model physics and horizontal grid spacing. In this study, the performance of an experimental version of HRRR that includes these refinements is tested against a control version, which corresponds to that of the operational HRRR run by National Oceanic and Atmospheric Administration/National Centers for Environmental Protection at the outset of WFIP2. Furthermore, the effects of horizontal grid resolution were also tested by comparing wind forecasts from the HRRR (with 3-km grid spacing) with those from a finer-resolution HRRR nest with 750-m grid spacing. Model forecasts are validated against accurate wind-profile measurements by three scanning, pulsed Doppler lidars at sites separated by a total distance of 71 km. Model skill and improvements in model skill, attributable to physics refinements and improved horizontal grid resolution, varied by season, by site, and during periods of atmospheric phenomena relevant to WE. In general, model errors were the largest below 150 m above ground level (AGL). Experimental HRRR refinements tended to reduce the mean absolute error (MAE) and other error metrics for many conditions, but degradation in skill (increased MAE) was noted below 150 m AGL at the two lowest-elevation sites at night. Finer resolution was found to produce the most significant reductions in the error metrics.

17 WIND ENERGY↗
DOE OSTI2023

Revealing Deformation Mechanisms in Polymer-Grafted Thermoplastic Elastomers via In Situ Small-Angle X-ray Scattering

The tunable properties of thermoplastic elastomers (TPEs), through polymer chemistry manipulations, enable these technologically critical materials to be employed in a broad range of applications. The need to “dial-in” the mechanical properties and responses of TPEs generally requires the design and synthesis of new macromolecules. In these designs, TPEs with nonlinear macromolecular architectures outperform the mechanical properties of their linear copolymer counterparts, but the differences in the deformation mechanism providing enhanced performance are unknown. Here, in situ small-angle X-ray scattering (SAXS) measurements during uniaxial extension reveal distinct deformation mechanisms between a commercially available linear poly(styrene)–poly(butadiene)–poly(styrene) (SBS) triblock copolymer and the grafted SBS version containing grafted poly(styrene) (PS) chains from the poly(butadiene) (PBD) midblock. The neat SBS (φ SBS = 100%) sample deforms congruently with the macroscopic dimensions, with the domain spacing between spheres increasing and decreasing along and transverse to the stretch direction, respectively. At high extensions, end segment pullout from the PS-rich domains is detected, which is indicated by a disordering of SBS. Conversely, the PS-grafted SBS that is 30 vol % SBS and 70% styrene (φ SBS = 30%) exhibits a lamellar morphology, and in situ SAXS measurements reveal an unexpected deformation mechanism. During deformation, there are two simultaneous processes: significant lamellar domain rearrangement to preferentially orient the lamellae planes parallel to the stretch direction and crazing. The samples whiten at high strains as expected for crazing, which corresponds with the emergence of features in the 2D SAXS pattern during stretching consistent with fibril-like structures that bridge the voids in crazes. The significant domain rearrangement in the grafted copolymers is attributed to the new junctions formed across multiple PS domains by the grafting of a single chain. In conclusion, the in situ SAXS measurements provide insights into the enhanced mechanical properties of grafted copolymers that arise through improved physical cross-linking that leads to nanostructure domain reorientation for self-reinforcement and craze formation where fibrils help to strengthen the polymer.

36 MATERIALS SCIENCE↗
NASA NTRS2024

Three-Dimensional Atmospheric Dynamics of Jupiter from Ground-Based Doppler Imaging Spectroscopy in the Visible

We present three-dimensional (3D) maps of Jupiter’s atmospheric circulation at cloud-top level from Doppler-imaging data obtained in the visible domain with JIVE, the second node of the JOVIAL network, which is mounted on the Dunn Solar Telescope at Sunspot, New Mexico. We report on 12 nights of observations between May 4 and May 30, 2018, representing a total of about 80 hours. Firstly, the average zonal wind profile derived from our data is compatible with that derived from cloud-tracking measurements performed on Hubble Space Telescope images obtained in April 2018 from the Outer Planet Atmospheres Legacy (OPAL) program. Secondly, we present the first ever two-dimensional maps of Jupiter’s atmospheric circulation from Doppler measurements. The zonal velocity map highlights well-known atmospheric features, such as the equatorial hot spots and the Great Red Spot (GRS). In addition to zonal winds, we derive meridional and vertical velocity fields from the Doppler data. The motions attributed to vertical flows are mainly located at the boundary between the equatorial belts and tropical zones, which could indicate active motion in these regions. Qualitatively, these results compare well to recent Juno data that have unveiled the three-dimensional structure of Jupiter’s wind field. To the contrary, the motions attributed to meridional circulation are very different from what is obtained by cloud tracking, except at the GRS. Because of limitations with data resolution and processing techniques, we acknowledge that our measurement of vertical or meridional flows of Jupiter are still to be confirmed.

Francois-Xavier Schmider↗
NASA NTRSDate not supplied

A comparison between CERES TOA Radiative Fluxes and Airborne Radiative Flux Measurements from ARISE

Uncertainty in top-of-atmosphere (TOA) radiation fluxes observations are larger in the Arctic than in other regions. These uncertainties are due to the low sun angles and the highly reflective, anisotropic, and heterogeneous surface conditions. Quantifying, attributing, and reducing Arctic TOA radiative flux uncertainty enables a better understanding of the rapidly changing Arctic. To advance this goal, we compare the Cloud and Earth’s Radiant Energy System (CERES) TOA radiative fluxes with Arctic Radiation-IceBridge Sea and Ice Experiment (ARISE) campaign measurements collected in September 2014. We compare CERES TOA and aircraft radiative flux measurements using two complementary approaches: grid box average fluxes and instantaneously matched footprints. The grid box mean flux comparison indicates an agreement between CERES and aircraft measurements within 2σ uncertainty (calibration and inversion) in the longwave for all five grid boxes and for four-of-five grid boxes in the shortwave; shortwave and longwave mean differences are -7.9 and +2.3 Wm 2, respectively. The comparison of 36 40 instantaneously matched footprints with aircraft measurements reveals mean differences of -120.25 and -1.00.4 Wm 2 in the shortwave and longwave, respectively. To further explore the persistent negative difference in the shortwave, Wwe further quantify the effects of temporal and spatial sampling differences, angular distribution models, and scene identification to CERES-aircraft differences. Our analysis indicates that sampling differences (including scene evolution) account for an additional 1.8 and 1.7% uncertainty in the shortwave and longwave, respectively and , but indicates no bias. After accounting for this sampling uncertainty, all CERES-aircraft grid box mean fluxes agree within 2σ uncertainty. Scene identification errors due to sea ice concentration data set differences exhibit no bias in the shortwave flux difference and indicate the possibility of substantial differences in the CERES fluxes in specific cases with large spatial heterogeneity. Considering the instantaneously matched footprints, we find that the angular distribution models account may account for up to 7.3 Wm-2 of the persistent CERES-aircraft shortwave flux difference due to systematic differences in the anisotropy for sea ice partly cloudy scenes. Additional analysis using a special programmable scan model with the CERES FM2 instrument suggests a significant view zenith angle dependence of the CERES fluxes for sea ice partly cloudy scenes where shortwave fluxes systematically decrease with increasing view zenith angle; no dependence is found for other scene types. We conclude that (1) spatial heterogeneity and scene temporal evolution substantially limit our ability to use aircraft measurements to place strong constraints on CERES TOA fluxes and (2) that the representation of anisotropy in sea ice partly cloudy scenes is likely a significant factor contributing to the persistent negative CERES-aircraft shortwave flux difference in this comparison and require additional data to analysis fully quantify the potential bias.

Patrick C. Taylor↗
DOE OSTI2021

Toward Optimizing Electrospun Nanofiber Fuel Cell Catalyst Layers: Microstructure and Pt Accessibility

This work investigates how local ionomer/platinum (Pt) interactions and ionomer distribution in electrospun Pt/Vulcan nanofiber electrodes impact ionomer coverage, proton accessibility, and oxygen reduction reaction (ORR) performance in proton-exchange membrane fuel cells. Insights from various in situ electrochemical diagnostics were utilized in conjunction with ex situ microscopic characterization to understand how the electrode microstructure—both at the aggregate level and near the ionomer/platinum interface—is affected by electrospinning in comparison to ultrasonic spraying. The effect of the carrier polymer poly(acrylic acid) (PAA) concentration from 5–20 wt % (with respect to total ink solids) on the resulting nanofiber morphology is discussed. Electron microscopy observations and CO displacement measurements indicated that Pt/Vulcan nanofibers prepared with a higher PAA concentration (15 wt %) were conformally coated with a film of ionomer on the exterior of the fiber, which resulted in an overall lower ionomer coverage on both Pt and carbon throughout the fiber diameter. In contrast, 10 wt % PAA leads to a uniform intrafiber distribution of the ionomer within the fibers, increasing the overall ionomer coverage and proton accessibility under both wet and dry conditions. These differences in the local ionomer coverage on Pt between 10 and 15 wt % PAA were also attributed to differences in the adsorption/interaction affinities between PAA and the ionomer onto the catalyst surface in the ink using zeta potential measurements. Additional fuel cell electrochemical tests on the electrospun electrodes show improvements in ORR kinetics and high-current-density H 2 /air performance compared to the ultrasonically sprayed electrodes.

25 ENERGY STORAGE↗
NASA NTRS1990

Operational testing of a figure of merit for overall task performance

An overall indicator or figure of merit (FOM), for the quality of pilot performance is needed to define optimal workload levels, predict system failure, measure the impact of new automation in the cockpit, and define the relative contributions of subtasks to overall task performance. A normative FOM was developed based on the calculation of a standard score for each component of a complex task. It reflected some effects, detailed in an earlier study, of the introduction of new data link technology into the cockpit. Since the technique showed promise, further testing was done. A new set of data was obtained using the recently developed Multi-Attribute Task Battery. This is a complex battery consisting of four tasks which can be varied in task demand, and on which performance measures can be obtained. This battery was presented to 12 subjects in a 20 minute trial at each of three levels of workload or task demand, and performance measures collected on all four tasks. The NASA-TLX workload rating scale was presented at minutes 6, 12, and 18, of each trial. A figure of merit was then obtained for each run of the battery by calculating a mean, SD, and standard score for each task. Each task contributed its own proportion to the overall FOM, and relative contributions changed with increasing workload. Thus, the FOM shows the effect of task changes, not only on the individual task that is changed, but also on the performance of other tasks and of the whole task. The cost to other tasks of maintaining constant performance on an individual task can be quantified.

Lemay, Moira↗
DOE OSTI2025

Short-Term Energy and Meteorological Impacts on Thanksgiving CO2 in Salt Lake City

Abstract Long-term, high-frequency atmospheric CO2 measurements at multiple sites in the Salt Lake City (SLC), Utah, reveal that annual and monthly CO2 variability aligns with a priori estimates of emissions from anthropogenic and biological sources. In this study, we investigate whether short-term fluctuations in anthropogenic emissions, as captured in the Vulcan3 dataset for the United States, can be detected in atmospheric CO2 observations. Specifically, we focus on Thanksgiving holidays, when traffic and energy usage patterns differ from the rest of November. Onroad CO2 emissions exhibit a double peak during weekday morning and evening rush hours but remain relatively low on weekends and Thanksgiving. Interestingly, CO2 mole fractions during Thanksgiving were higher than the rest of November at all SLC monitoring sites, particularly from 2008 to 2013. This increase is partially attributed to elevated energy-related emissions — especially residential sources — and meteorological factors such as weak wind speeds, cold temperature, and a low planetary boundary layer height (PBLH).&#xD;&#xD; While CO₂ emissions and mole fraction patterns align over time, notable spatial differences exist. For instance, the near-highway site in Murray shows the highest CO₂ mole fractions despite low local emissions, suggesting pollution transport via highways and wind advection. Random Forest model-based SHapley Additive exPlanations (SHAP) analysis reveals that onroad emissions dominate CO2 contributions on weekdays and weekends, while energy-related emissions play a larger role during Thanksgiving, alongside meteorological drivers such as wind speed and PBLH. Across six urban cities, CO2 emissions display a consistent pattern: residential and commercial (onroad) emissions peak during Thanksgiving (weekday) with substantial (minimal) year-to-year variability. These findings highlight that urban CO₂ variability is driven by the combined influence of emissions and meteorology, underscoring the need for integrated mitigation strategies. Additionally, multi-site measurements are essential for accurate source attribution and the development of effective policy interventions. &#xD;

Ryoo, Ju-Mee (ORCID:0000000234256296)↗
DOE OSTI2024

Defining Golden Batches in Biomanufacturing Processes From Internal Metabolic Activity to Detect Process Changes That May Affect Product Quality

ABSTRACT Cellular metabolism plays a role in the observed variability of a drug substance's Critical Quality Attributes (CQAs) made by biomanufacturing processes. Therefore, here we describe a new approach for monitoring biomanufacturing processes that measures a set of metabolic reaction rates (named Critical Metabolic Parameters (CMP) in addition to the macroscopic process conditions currently being used as Critical Process Parameters (CPP) for biomanufacturing. Constraint‐based systems biology models like Flux Balance Analysis (FBA) are used to estimate metabolic reaction rates, and metabolic rates are used as inputs for multivariate Batch Evolution Models (BEM). Metabolic activity was reproducible among batches and could be monitored to detect a deliberately induced macroscopic process shift (i.e., temperature change). The CMP approach has the potential to enable “golden batches” in biomanufacturing processes to be defined from the internal metabolic activity and to aid in detecting process changes that may impact the quality of the product. Overall, the data suggested that monitoring of metabolic activity has promise for biomanufacturing process control.

Biotechnology & Applied Microbiology↗