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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 775 records · Page 43
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Porous Ti 3 AlC 2 MAX phase enables efficient synthesis of Ti 3 C 2 T x MXene

Abstract MXenes, a large family of two‐dimensional carbides and/or nitrides, are among the most studied materials worldwide due to their great diversity of structures and compositions. Their unique properties find use in several applications. Typically, they are manufactured by selective wet‐chemical etching of layered MAX phase ceramics, which are produced nowadays primarily for MXene synthesis. However, the synthesis of MAX phases has not been changed since the time of their use in structural and high‐temperature applications, and it has not been optimized for MXene manufacturing. The main purpose of this study is to develop a porous Ti 3 AlC 2 MAX phase that can be easily ground into individual grains without time‐consuming, harsh, and tedious crushing and milling steps. Moreover, we also demonstrate the synthesis of highly porous Ti 3 AlC 2 from an inexpensive titanium sponge instead of a highly pure titanium powder and explain the mechanisms of reaction sintering and formation of porous MAX phase. MXene obtained from this MAX phase, Ti 3 C 2 Tx, shows larger flake size and higher electrical conductivity in thin films, compared to the materials produced from the costly fine titanium powder. The proposed approach may apply to the synthesis of other MAX phases as well.

Materials Science↗
DOE OSTI2022

Transcription Factors Controlling the Rhizobium–Legume Symbiosis: Integrating Infection, Organogenesis and the Abiotic Environment

Abstract Legume roots engage in a symbiotic relationship with rhizobia, leading to the development of nitrogen-fixing nodules. Nodule development is a sophisticated process and is under the tight regulation of the plant. The symbiosis initiates with a signal exchange between the two partners, followed by the development of a new organ colonized by rhizobia. Over two decades of study have shed light on the transcriptional regulation of rhizobium–legume symbiosis. A large number of transcription factors (TFs) have been implicated in one or more stages of this symbiosis. Legumes must monitor nodule development amidst a dynamic physical environment. Some environmental factors are conducive to nodulation, whereas others are stressful. The modulation of rhizobium–legume symbiosis by the abiotic environment adds another layer of complexity and is also transcriptionally regulated. Several symbiotic TFs act as integrators between symbiosis and the response to the abiotic environment. In this review, we trace the role of various TFs involved in rhizobium–legume symbiosis along its developmental route and highlight the ones that also act as communicators between this symbiosis and the response to the abiotic environment. Finally, we discuss contemporary approaches to study TF-target interactions in plants and probe their potential utility in the field of rhizobium–legume symbiosis.

Cell Biology↗
DOE OSTI2023

Incorporating Potassium Citrate to Improve the Performance of Tin‐Lead Perovskite Solar Cells

Abstract Easy‐to‐form tin vacancies at the buried interface of tin‐lead perovskites hinder the performance of low‐bandgap perovskite solar cells (PSCs). Here, a synergistic strategy by incorporating potassium citrate (PC) into the poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) hole‐transport layer to passivate the buried interface of Sn‐Pb PSCs is reported. PC neutralizes the acidity of PEDOT:PSS and stabilizes the perovskite front surface, enhancing device stability. Citrate moieties coordinate with Sn 2+ on the buried perovskite surface, preventing Sn 2+ oxidation and suppressing defect formation. Additionally, potassium cations incorporate into Sn‐Pb perovskites, enhancing crystallinity and passivating halide defects. The combined benefits enable efficient low‐bandgap Sn‐Pb PSCs with a power conversion efficiency of 22.7% and a high open‐circuit voltage of 0.894 V. Using this method, 26.1% efficiency for all‐perovskite tandem solar cells is demonstrated. These results emphasize the significance of buried interface passivation in developing efficient and stable Sn‐Pb PSCs and all‐perovskite tandem solar cells.

14 SOLAR ENERGY↗
DOE OSTI2021

Demons in the North Atlantic: Variability of Deep Ocean Ventilation

Abstract Translation of atmospheric forcing variability into the ocean interior via ocean ventilation is an important aspect of transient climate change. On a seasonal timescale in the subtropics, this translation is mediated by a so‐called “Demon” that prevents access to all except late‐winter mixed‐layer water. Here, we use an eddy‐permitting numerical circulation model to investigate a similar process operating on longer (interannual) timescales in the subpolar North Atlantic. We find that variations in atmospheric forcing are mediated in their translation to the ocean interior, with year‐to‐year changes in the late‐winter mixed layer depth being the critical factor. The signature of persistent strong atmospheric forcing driving deep mixed layers is preferentially ventilated to the interior when the forcing is ceased. Susceptibility to this effect depends on the location and density of subduction—with the rate at which newly ventilated water escapes its region of subduction being the crucial factor.

MacGilchrist, G. A.↗
DOE OSTI2024

Thermodynamics and electronic structure of adsorbed and intercalated plumbene in graphene/hexagonal SiC heterostructures

Abstract Graphene-covered hexagonal SiC substrates have been frequently discussed to be appropriate starting points for epitaxial overlayers of Xenes, such as plumbene, or even their deposition as intercalates between graphene and SiC. Here, we investigate, within density functional theory, the plumbene deposition for various layer orderings and substrate terminations. By means of total energy studies we demonstrate the favorization of the intercalation versus the epitaxy for both C-terminated and Si-terminated 4H-SiC substrates. These results are explained in terms of chemical bonding and by means of layer-resolved projected band structures. Our results are compared with available experimental findings.

Science & Technology - Other Topics↗
DOE OSTI2022

Triggering of tearing instability by impurity radiation through resistive interchange reversal in a tokamak

Abstract Recent MHD simulations find that the reversal of the local resistive interchange parameter D R from negative to positive due to impurity radiation cooling is able to linearly destabilize the resistive tearing mode (TM) growth in a tokamak above a threshold in impurity level. A layer of perturbed Pfirsch–Schlüter current density and resistivity are also induced by the impurity radiation, which further govern the TM growth and saturation in the nonlinear stage. The impurity threshold and the TM growth strongly depend on the parallel thermal conductivity, and such a dependence derives from the impact on D R of the fast parallel thermal equilibration along the helical magnetic field lines.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Reducing the Barrier Height in Organic Transistors

Abstract Reducing the Schottky barrier height and Fermi level de‐pinning in metal‐organic semiconductor contacts are crucial for enhancing the performance of organic transistors. The reduction of the Schottky barrier height in bottom‐contact top‐gate organic transistors is demonstrated by adding 1 nm thick atomic layer deposited Al 2 O 3 on the source and drain contacts. By using two different donor‐acceptor copolymers, both p‐ and n‐ type transistors are investigated. Temperature‐dependent current–voltage measurements from non‐treated, self‐assembled monolayer treated, and Al 2 O 3 treated Au source‐drain contact field‐effect transistors with varying channel lengths are carried out. The drain current versus drain voltage near zero gate voltage, which may be described by the thermionic emission model at temperatures above 150 K, allows the estimation of the Schottky barrier height ( φ B ). The Al 2 O 3 contact‐treated transistors show more than 40% lower φ B compared with the non‐treated contacts in the p ‐type transistor. Similarly, an isoindigo‐based transistor, with n ‐type transport, shows a reduction in φ B with Al 2 O 3 treated contacts suggesting that such ultrathin oxide layers provide a universal method for reducing the barrier height.

Ghobadi, Arash↗
DOE OSTI2023

Why Increased CdSeTe Charge Carrier Lifetimes and Radiative Efficiencies did not Result in Voltage Boost for CdTe Solar Cells

After a focused effort over the last decade, order-of-magnitude improvements in doping and electro-optical characteristics (radiative efficiency, carrier lifetime, and passivation) have been reported for polycrystalline CdSeTe solar cells. Surprisingly, this did not result in higher solar cell voltages regardless of device contacting layers, absorber grading profiles, and other changes in device architecture. From detailed evaluation of radiative emission and carrier dynamics in CdSeTe heterostructures and devices, it is shown that the complexity introduced to the absorber to achieve lifetime and passivation metrics resulted in charge carrier trapping, which now negatively affects CdSeTe absorbers.

CdTe↗
DOE OSTI2023

Uncovering acoustic signatures of pore formation in laser powder bed fusion

Abstract We present a machine learning workflow to discover signatures in acoustic measurements that can be utilized to create a low-dimensional model to accurately predict the location of keyhole pores formed during additive manufacturing processes. Acoustic measurements were sampled at 100 kHz during single-layer laser powder bed fusion (LPBF) experiments, and spatio-temporal registration of pore locations was obtained from post-build radiography. Power spectral density (PSD) estimates of the acoustic data were then decomposed using non-negative matrix factorization with custom $$\varvec{k}$$ k -means clustering (NMF $$\varvec{k}$$ k ) to learn the underlying spectral patterns associated with pore formation. NMF $$\varvec{k}$$ k returned a library of basis signals and matching coefficients to blindly construct a feature space based on the PSD estimates in an optimized fashion. Moreover, the NMF $$\varvec{k}$$ k decomposition led to the development of computationally inexpensive machine learning models which are capable of quickly and accurately identifying pore formation with classification accuracy of supervised and unsupervised label learning greater than 95% and 90%, respectively. The intrinsic data compression of NMF k , the relatively light computational cost of the machine learning workflow, and the high classification accuracy makes the proposed workflow an attractive candidate for edge computing toward in-situ keyhole pore prediction in LPBF.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Electronic Melting of Silicon in Nanostructures using X-ray Forbidden Bragg Reflections

Abstract We carried out a short beamtime at the Pohang Accelerator Laboratory x-ray Free Electron Laser to perform a pump-probe (PP) laser excitation diffraction experiment on the silicon (222) forbidden Bragg peak. To limit the x-ray penetration, we used a “device layer” silicon film wafer bonded to a silicon substrate. The sample, specially fabricated by MEMC Electronic Materials, had a Si(100) substrate bonded to a 170 nm Si(100) film rotated at 45° for crystallographic isolation. A second sample was reactive-ion-etched down to 52 nm thickness. In the silicon lattice, the covalent bonds are seen exclusively at the 222 reflection. Upon laser excitation, these electrons are expected to be excited to the valence band on femtosecond electronic time scales. The Si(222) reflection is therefore expected to be extinguished on this fast time scale, while the electron–phonon coupled acoustic response is determined by the lattice dynamics. The latter is determined by the speed of sound over the device thickness, which is in the mid-picosecond range.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2022

Cloud Morphology Evolution in Arctic Cold‐Air Outbreak: Two Cases During COMBLE Period

Abstract Cloud feedbacks play an important role in Arctic warming. Cloud morphology, for example, cloud size and spatial distributions, is among key factors that directly impact their radiative effects. In this work, we use two cases observed during the Cold‐air Outbreak (CAO) in the Marine Boundary Layer Experiment (COMBLE) to study the evolution of cloud size distributions as an air mass is advected from the Arctic over a comparatively warm ocean and cloud mesoscale organization changes from rolls to cells. Cloud objects are identified from Moderate Resolution Imaging Spectroradiometer (MODIS) reflectance images through an object segmentation procedure and roll breakup is identified by homogeneities in cloud water path (CWP). Roll breakup is found to be accompanied by a local minimum in wind shear and local maxima in cloud size and marine cold air outbreak index. The mean cloud horizontal aspect ratio has weak fetch dependency and is around 2 in roll, transition, and cell regimes. Regardless of distance from the ice edge, smaller clouds (<10 km 2 ) dominate the population number but not cloud cover. Cloud size distributions show bimodality in transition and cell regimes. For clouds with comparable sizes, mean nearest neighbor distances normalized by equivalent cloud radius converge to a single value for all regimes and for all but the smallest clouds, suggesting that clouds of comparable sizes in CAOs are separated by distance proportional to their sizes. The presented statistical results pave the way to evaluating model simulated cloud organizations during CAO events.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Flat band carrier confinement in magic-angle twisted bilayer graphene

Abstract Magic-angle twisted bilayer graphene has emerged as a powerful platform for studying strongly correlated electron physics, owing to its almost dispersionless low-energy bands and the ability to tune the band filling by electrostatic gating. Techniques to control the twist angle between graphene layers have led to rapid experimental progress but improving sample quality is essential for separating the delicate correlated electron physics from disorder effects. Owing to the 2D nature of the system and the relatively low carrier density, the samples are highly susceptible to small doping inhomogeneity which can drastically modify the local potential landscape. This potential disorder is distinct from the twist angle variation which has been studied elsewhere. Here, by using low temperature scanning tunneling spectroscopy and planar tunneling junction measurements, we demonstrate that flat bands in twisted bilayer graphene can amplify small doping inhomogeneity that surprisingly leads to carrier confinement, which in graphene could previously only be realized in the presence of a strong magnetic field.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Mixing Pathways in Simple Box Models

Abstract Tracer variance budgets can be used to estimate bulk mixing in a control volume. For example, simple, analytical, bulk formulations of salt mixing, defined here as the destruction of salinity variance, can be found for estuaries with a riverine source of freshwater and a two-layer exchange flow at the mouth using salinity as a representative tracer. For a steady case, the bulk salt mixing M can be calculated as , where S in and S out are the representative salinities in the estuarine exchange flow, and Q R and Q in are the river and landward volume fluxes, respectively. The bulk salt mixing M can be considered as the sum of mixing pathways, where each pathway has a mixing of Q (Δ S ) 2 , where Q is the volume transport and Δ S is the salinity difference across the pathway. For the estuary case, one mixing path is associated with the river inflow, and the other is associated with the inflow of salty, oceanic water. This concept of linking mixing to input–output pathways is extended, in simple box models, from estuaries to scenarios with multiple inputs/outputs, as might be found in a complex estuarine/fjord network, in a region on a continental shelf, or any other control volume with multiple exchanges. This approach allows for the estimation of the relative contributions of each input–output pathway to the total mixing within a control volume.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Local correlation-based transition models for high-Reynolds-number wind-turbine airfoils

Abstract. Modern wind-turbine airfoil design requires robust performance predictions for varying thicknesses, shapes, and appropriate Reynolds numbers. The airfoils of current large offshore wind turbines operate with chord-based Reynolds numbers in the range of 3–15 million. Turbulence transition in the airfoil boundary layer is known to play an important role in the aerodynamics of these airfoils near the design operating point. While the lack of prediction of lift stall through Reynolds-averaged Navier–Stokes (RANS) computational fluid dynamics (CFD) is well known, airfoil design using CFD requires the accurate prediction of the glide ratio (L/D) in the linear portion of the lift polar. The prediction of the drag bucket and the glide ratio is greatly affected by the choice of the transition model in RANS CFD of airfoils. We present the performance of two existing local correlation-based transition models – one-equation model (γ− SA) and two-equation model (γ-Reθt‾- SA) coupled with the Spalart–Allmaras (SA) RANS turbulence model – for offshore wind-turbine airfoils operating at a high Reynolds number. We compare the predictions of the two transition models with available experimental and CFD data in the literature in the Reynolds number range of 3–15 million including the AVATAR project measurements of the DU00-W-212 airfoil. Both transition models predict a larger L/D compared to fully turbulent results at all Reynolds numbers. The two models exhibit similar behavior at Reynolds numbers around 3 million. However, at higher Reynolds numbers, the one-equation model fails to predict the natural transition behavior due to early transition onset. The two-equation transition model predicts the aerodynamic coefficients for airfoils of various thickness at higher Reynolds numbers up to 15 million more accurately compared to the one-equation model. As a result, the two-equation model predictions are more comparable to the predictions from eN transition model. However, a limitation of this model is observed at very high Reynolds numbers of around 12–15 million where the predictions are very sensitive to the inflow turbulent intensity. The combination of the two-equation transition model coupled with the Spalart–Allmaras (SA) RANS turbulence model is a good method for performance prediction of modern wind-turbine airfoils using CFD.

17 WIND ENERGY↗
NASA NTRS2001

Tomography of Accretion Flows in Binary Stars and Active Galactic Nuclei

Under this project, a variety of accretion problems have been studied, with two in particular. In the first, astrophysical jets are observed in many objects ranging from young stars to Active Galactic Nuclei. A major unsolved problem is how do these jets originate from accretion disks. In a series of works, I have examined the launching of outflows from magnetized disks, the extraction of energy from black holes, and the formation of jets in systems like Cataclysmic Variables and supermassive accreting black holes. The results of these works were published in a number of papers. In the second, I examined the potential role of vortices in accretion disks around Young Stellar Objects, for the formation of planets and for angular momentum transport. I showed that vortices are surprisingly stable, and that they are able to concentrate dust in their cores. I also examined the development of spiral shocks in disks. Finally, I studied the evolution of magnetically layered protoplanetary disks, and showed that they exhibit outbursts which could 'pump' the jets that are observed in Herbig-Haro objects. The results of these works were published in a number of papers as well. Additional information on the published papers is contained in the original abstract.

Livio, Mario↗
NASA NTRS2010

Detailed Analysis of the Intra-Ejecta Dark Plains of Caloris Basin, Mercury

The Caloris basin on Mercury is floored by light-toned plains and surrounded by an annulus of dark-toned material interpreted to be ejecta blocks and smooth, dark, ridged plains. Strangely, preliminary crater counts indicate that these intra-ejecta dark plains are younger than the light-toned plains within the Caloris basin. This would imply a second, younger plains emplacement event, possibly involving lower albedo material volcanics, which resurfaced the original ejecta deposit. On the other hand, the dark plains may be pre-Caloris light plains covered by a thin layer of dark ejecta. Another alternative to the hypothesis of young, dark volcanism is the possibility that previous crater counts have not thoroughly distinguished between superposed craters (fresh) and partly-buried craters (old) and therefore have not accurately determined the ages of the Caloris units. This abstract outlines the tasks associated with a new mapping project of the Caloris basin, intended to improve our knowledge of the geology and geologic history of the basin, and thus facilitate an understanding of the thermal evolution of this region of Mercury.

Buczkowski, Debra L.↗
NASA NTRS1995

(abstract) An Assessment of Electric Propulsion Research, Development, and Application in the United States

This paper will discuss the development of Electric Propulsion technology in the U.S. from the 1960's to the present. It will summarize the various activities related to arcjets, resistojets, pulsed plasma thrustors, magneto-plasma-dynamic thrustors, ion engines, and more recently the evaluation of Hall effect thrustors of the SPT or Anode Layer type developed in Russia. Also, demonstration test flight and actual mission applications will be summarized. Finally, the future application of electric propulsion to near-term commercial communications satellites and planetary missions will be projected. This history is rich in diversity, and has involved a succession of types of thrustors, propellants, and electric power sources. With the recent use of arcjets on commercial communication satellites and the flight tests of ion engines for this application, it appears that electric propulsion is finally on the verge of wide spread application.

ion engines electric propulsion arcjets resistojet↗