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At least 775 records · Page 43

Materials Data on Tm3(In2Co)2 by Materials Project

Tm3(CoIn2)2 crystallizes in the hexagonal P-6 space group. The structure is three-dimensional. Tm is bonded in a 2-coordinate geometry to three Co and eight In atoms. There are two shorter (2.79 Å) and one longer (3.16 Å) Tm–Co bond lengths. There are a spread of Tm–In bond distances ranging from 3.15–3.43 Å. There are two inequivalent Co sites. In the first Co site, Co is bonded in a 9-coordinate geometry to three equivalent Tm and six equivalent In atoms. All Co–In bond lengths are 2.70 Å. In the second Co site, Co is bonded in a 6-coordinate geometry to six equivalent Tm and three equivalent In atoms. All Co–In bond lengths are 3.01 Å. There are two inequivalent In sites. In the first In site, In is bonded in a 10-coordinate geometry to six equivalent Tm, three Co, and one In atom. The In–In bond length is 2.97 Å. In the second In site, In is bonded in a 9-coordinate geometry to six equivalent Tm and three equivalent In atoms.

36 MATERIALS SCIENCE↗

Materials Data on TmGa4Ni by Materials Project

TmNiGa4 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Tm is bonded in a 1-coordinate geometry to two equivalent Ni and thirteen Ga atoms. Both Tm–Ni bond lengths are 3.11 Å. There are a spread of Tm–Ga bond distances ranging from 2.88–3.38 Å. Ni is bonded in a 9-coordinate geometry to two equivalent Tm and seven Ga atoms. There are a spread of Ni–Ga bond distances ranging from 2.34–2.51 Å. There are three inequivalent Ga sites. In the first Ga site, Ga is bonded in a distorted q6 geometry to four equivalent Tm and six Ga atoms. There are two shorter (2.82 Å) and four longer (2.84 Å) Ga–Ga bond lengths. In the second Ga site, Ga is bonded in a distorted linear geometry to three equivalent Tm, one Ni, and eight Ga atoms. All Ga–Ga bond lengths are 2.99 Å. In the third Ga site, Ga is bonded in a 12-coordinate geometry to three equivalent Tm, three equivalent Ni, and six Ga atoms. There are one shorter (2.62 Å) and two longer (2.92 Å) Ga–Ga bond lengths.

36 MATERIALS SCIENCE↗

Materials Data on TmMg3 by Materials Project

Mg3Tm is Uranium Silicide structured and crystallizes in the orthorhombic Pmmm space group. The structure is three-dimensional. there are three inequivalent Mg sites. In the first Mg site, Mg is bonded to eight Mg and four equivalent Tm atoms to form MgTm4Mg8 cuboctahedra that share corners with twelve equivalent MgTm4Mg8 cuboctahedra, edges with eight equivalent TmMg12 cuboctahedra, faces with four equivalent TmMg12 cuboctahedra, and faces with six equivalent MgTm4Mg8 cuboctahedra. There are four shorter (3.20 Å) and four longer (3.21 Å) Mg–Mg bond lengths. All Mg–Tm bond lengths are 3.51 Å. In the second Mg site, Mg is bonded in a distorted body-centered cubic geometry to four equivalent Mg and four equivalent Tm atoms. All Mg–Tm bond lengths are 3.20 Å. In the third Mg site, Mg is bonded in a distorted body-centered cubic geometry to four equivalent Mg and four equivalent Tm atoms. All Mg–Tm bond lengths are 3.21 Å. Tm is bonded to twelve Mg atoms to form distorted TmMg12 cuboctahedra that share corners with twelve equivalent TmMg12 cuboctahedra, edges with eight equivalent MgTm4Mg8 cuboctahedra, faces with four equivalent MgTm4Mg8 cuboctahedra, and faces with six equivalent TmMg12 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on TmAlNi by Materials Project

Tm(NiAl) crystallizes in the hexagonal P-62m space group. The structure is three-dimensional. Tm is bonded in a 11-coordinate geometry to five Ni and six equivalent Al atoms. There are four shorter (2.82 Å) and one longer (2.88 Å) Tm–Ni bond lengths. There are two shorter (3.05 Å) and four longer (3.14 Å) Tm–Al bond lengths. There are two inequivalent Ni sites. In the first Ni site, Ni is bonded in a 9-coordinate geometry to three equivalent Tm and six equivalent Al atoms. All Ni–Al bond lengths are 2.52 Å. In the second Ni site, Ni is bonded in a 9-coordinate geometry to six equivalent Tm and three equivalent Al atoms. All Ni–Al bond lengths are 2.69 Å. Al is bonded in a 12-coordinate geometry to six equivalent Tm, four Ni, and two equivalent Al atoms. Both Al–Al bond lengths are 2.89 Å.

36 MATERIALS SCIENCE↗

Vacancy‐Enabled O3 Phase Stabilization for Manganese‐Rich Layered Sodium Cathodes

Abstract Manganese‐rich layered oxide materials hold great potential as low‐cost and high‐capacity cathodes for Na‐ion batteries. However, they usually form a P2 phase and suffer from fast capacity fade. In this work, an O3 phase sodium cathode has been developed out of a Li and Mn‐rich layered material by leveraging the creation of transition metal (TM) and oxygen vacancies and the electrochemical exchange of Na and Li. The Mn‐rich layered cathode material remains primarily O3 phase during sodiation/desodiation and can have a full sodiation capacity of ca. 220 mAh g −1 . It delivers ca. 160 mAh g −1 specific capacity between 2–3.8 V with >86 % retention over 250 cycles. The TM and oxygen vacancies pre‐formed in the sodiated material enables a reversible migration of TMs from the TM layer to the tetrahedral sites in the Na layer upon de‐sodiation and sodiation. The migration creates metastable states, leading to increased kinetic barrier that prohibits a complete O3‐P3 phase transition.

Xiao, Biwei↗

Revisiting the assignment of atomic charges in metal oxides based on core-level x-ray photoelectron spectra: The case of Ti in SrTiO3(001)

We demonstrate that assigning formal charges to transition metal (TM) cations based on core-level (CL) x-ray photoemission binding energies in oxides leads to physically inconsistent pictures of electronic structure. O 2p–TM 3d hybridization is well known to result in significant covalency in TM–O bonds, thereby reducing TM cation charges from their fully ionic values. However, the ionic bonding model remains the working paradigm for assigning TM CL features, and the resulting cation charges are often taken to be representative of the material under study. Here, we show that a more physically meaningful way to assign charges is to extract information about charge distributions utilizing Dirac–Hartree–Fock theory to calculate CL spectra from first principles and then use the resulting wave functions to determine charges based on orbital occupancies. TM cation charges can also be determined using density functional theory and Bader population analysis. We illustrate these two methods using the Ti 2p spectrum for SrTiO3(001) and show that the agreement between them is excellent. Significantly, the resulting Ti charge is considerably lower than the formal charge. The high degree of similarity between the Ti 2p spectrum for SrTiO3 and those for the rutile and anatase polymorphs of TiO2 suggests that the charge densities surrounding Ti in the latter materials are similar to that in SrTiO3. Taking a broader perspective, oxides containing other first-row transition metals also exhibit covalent character, leading to TM cation charges lower than the analogous fully ionic values in these materials as well.

Chambers, Scott A. (ORCID:000000025415043X)↗

Analysis of the quality of image data acquired by the LANDSAT-4 Thematic Mapper and Multispectral Scanners

The geometric quality of TM film and digital products is evaluated by making selective photomeasurements and by measuring the coordinates of known features on both the TM products and map products. These paired observations are related using a standard linear least squares regression approach. Using regression equations and coefficients developed from 225 (TM film product) and 20 (TM digital product) control points, map coordinates of test points are predicted. The residual error vectors and analysis of variance (ANOVA) were performed on the east and north residual using nine image segments (blocks) as treatments. Based on the root mean square error of the 223 (TM film product) and 22 (TM digital product) test points, users of TM data expect the planimetric accuracy of mapped points to be within 91 meters and within 117 meters for the film products, and to be within 12 meters and within 14 meters for the digital products.

Colwell, R. N.↗

Landsat-4 Thematic Mapper scene characteristics of a suburban and rural area

The Thematic Mapper (TM) sensor, which is carried by the Landsat-4 and Landsat-5 satellites, represents the latest generation of an earth resource scanner system. TM applications range from determining the extent and changes of land cover to estimating agricultural yields. The TM has improvements over the Multispectral Scanner (MSS) with respect to spatial resolution, spectral regions, and radiometry. The present paper is concerned with two major objectives related to the analysis of the Landsat TM. One of these objectives is related to an evaluation of the utility of TM in the discrimination of surface cover. In connection with the second objective, an evaluation was conducted of the utility of selected image processing procedures to enhance the capability of Landsat TM to map land cover. It was found that TM data may be used for discriminating smaller targets, such as agricultural fields and city blocks, than previously obtainable with MSS data.

Toll, D. L.↗

Interim report on Landsat national archive activities

The Department of the Interior (DOI) has the responsibility to preserve and to distribute most Landsat Thematic Mapper (TM) and Multispectral Scanner (MSS) data that have been acquired by the five Landsat satellites operational since July 1972. Data that are still covered by exclusive marketing rights, which were granted by the U.S. Government to the commercial Landsat operator, cannot be distributed by the DOI. As the designated national archive for Landsat data, the U.S. Geological Survey's EROS Data Center (EDC) has initiated two new programs to protect and make available any of the 625,000 MSS scenes currently archived and the 200,000 TM scenes to be archived at EDC by 1995. A specially configured system has begun converting Landsat MSS data from obsolete high density tapes (HDT's) to more dense digital cassette tapes. After transcription, continuous satellite swaths are (1) divided into standard scenes defined by a world reference system, (2) geographically located by latitude and longitude, and (3) assessed for overall quality. Digital browse images are created by subsampling the full-resolution swaths. Conversion of the TM HDT's will begin in the fourth quarter of 1992 and will be conducted concurrently with MSS conversion. Although the TM archive is three times larger than the entire MSS archive, conversion of data from both sensor systems and consolidation of the entire Landsat archive at EDC will be completed by the end of 1994. Some MSS HDT's have deteriorated, primarily as a result of hydrolysis of the pigment binder. Based on a small sample of the 11 terabytes of post-1978 MSS data and the 41 terabytes of TM data to be converted, it appears that to date, less than 2 percent of the data have been lost. The data loss occurs within small portions of some scenes; few scenes are lost entirely. Approximately 10,000 pre-1979 MSS HDT's have deteriorated to such an extent, as a result of hydrolysis, that the data cannot be recovered without special treatment of the tapes. An independent consulting division of a major tape manufacturer has analyzed affected tapes and is confident that restorative procedures can be applied to the HDT's to permit one pass to reproduce the data on another recording media. A system to distribute minimally processed Landsat data will be procured in 1992 and will be operational by mid-1994. Any TM or MSS data in the national archive that are not restricted by exclusive marketing rights will be reproduced directly from the archive media onto user specified computer-compatible media. TM data will be produced either at a raw level (radiometrically and geometrically uncorrected) or at an intermediate level (radiometrically corrected and geometrically indexed). MSS data will be produced to an intermediate level or to a fully corrected level (radiometrically corrected and geometrically transformed to an Oblique Mercator projection). The system will be capable of providing ordered scenes within 48 hours of receipt of order.

Boyd, John E.↗

A One-Piece Lunar Regolith-Bag Garage Prototype

Shelter structures on the moon, even in early phases of exploration, should incorporate lunar materials as much as possible. We designed and constructed a prototype for a one-piece regolith-bag unpressurized garage concept, and, in parallel, we conducted a materials testing program to investigate six candidate fabrics to learn how they might perform in the lunar environment. In our concept, a lightweight fabric form is launched from Earth to be landed on the lunar surface and robotically filled with raw lunar regolith. In the materials testing program, regolith-bag fabric candidates included: Vectran(TM), Nextel(TM), Gore PTFE Fabric(TM), Zylon(TM), Twaron(TM), and Nomex(TM). Tensile (including post radiation exposure), fold, abrasion, and hypervelocity impact testing were performed under ambient conditions, and, within our current means, we also performed these tests under cold and elevated temperatures. In some cases, lunar simulant (JSC-1) was used in conjunction with testing. Our ambition is to continuously refine our testing to reach lunar environmental conditions to the extent possible. A series of preliminary structures were constructed during design of the final prototype. Design is based on the principles of the classic masonry arch. The prototype was constructed of Kevlar(TM) and filled with vermiculite (fairly close to the weight of lunar regolith on the moon). The structure is free-standing, but has not yet been load tested. Our plan for the future would be to construct higher fidelity mockups with each iteration, and to conduct appropriate tests of the structure.

Smithers, Gweneth A.↗

A One-Piece Lunar Regolith Bag Garage Prototype

Shelter structures on the moon, even in early phases of exploration, should incorporate lunar materials as much as possible. This Technical Memorandum details the design and construction of a prototype for a one-piece regolith bag unpressurized garage concept and a materials testing program to investigate six candidate fabrics to learn how they might perform in the lunar environment. The conceptualization was that a lightweight fabric form be launched from Earth and landed on the lunar surface to be robotically filled with raw lunar regolith. Regolith bag fabric candidates included: Vectran(TM), Nextel(TM), Gore PTFE Fabric(TM), Zylon(TM), Twaron(TM), and Nomex(TM). Tensile (including post radiation exposure), fold, abrasion, and hypervelocity impact testing were performed under ambient conditions, and also performed under cold and elevated temperatures. In some cases, Johnson Space Center lunar simulant (JSC-1) was used in conjunction with testing. A series of preliminary structures was constructed during final prototype design based on the principles of the classic masonry arch. The prototype was constructed of Kevlar(TM) and filled with vermiculite. The structure is free-standing, but has not yet been load tested. Future plans would be to construct higher fidelity prototypes and to conduct appropriate tests of the structure.

Smithers, G. A.↗

Forty-Year Calibrated Record of Earth-Surface Reflected Radiance from Landsat: A Review

Sensors on Landsat satellites have been collecting images of the Earth's surface for nearly 40 years. These images have been invaluable for characterizing and detecting changes in the land cover and land use of the world. Although initially conceived as primarily picture generating sensors, even the early sensors were radiometrically calibrated and spectrally characterized prior to launch and incorporated some capabilities to monitor their radiometric calibration once on orbit. Recently, as the focus of studies has shifted to monitoring Earth surface parameters over significant periods of time, serious attention has been focused toward bringing the data from all these sensors onto a common radiometric scale over this 40-year period. This effort started with the most recent systems and then was extended back in time. Landsat-7 ETM+, the best-characterized sensor of the series prior to launch and once on orbit, and the most stable system to date, was chosen to serve as the reference. The Landsat-7 project was the first of the series to build an image assessment system into its ground system, allowing systematic characterization of its sensors and data. Second, the Landsat-5 TM (still operating at the time of the Landsat-7 launch and continues to operate) calibration history was reconstructed based on its internal calibrator, vicarious calibrations, pseudo-invariant sites and a tie to Landsat-7 ETM+ at the time of the commissioning of Landsat-7. This process was performed in two iterations: the earlier one relied primarily on the TM internal calibrator. When this was found to have some deficiencies, a revised calibration was based more on pseudo-invariant sites, though the internal calibrator was still used to establish the short-term variations in response due to icing build up on the cold focal plane. As time progressed, a capability to monitor the Landsat-5 TM was added to the image assessment system. The Landsat-4 TM, which operated from 1982-1992, was the third system to which the radiometric scale was extended. The limited and broken use of the Landsat-4 TM made this analysis more difficult. Eight-day separated image pairs from Landsat-5 combined with analysis of pseudo invariant sites established this history. The fourth and most challenging effort was making the Landsat-1 to -5 MSS sensors' data internally radiometrically consistent. This effort was particularly complicated by the age of the MSS data, varying formats and processing levels in the archive, limited datasets, and limited documentation available. Ultimately, pseudo-invariant sites were identified in North America and used for this effort. Note that most of the Landsat-MSS archived data had already been calibrated using the MSS internal calibrators, so this processing was imbedded in the result. The final effort was developing an absolute scale for Landsat MSS similar to what was already established for the "TM" sensors. This was accomplished by using simultaneous data from Landsat-5 MSS and Landsat-5 TM, accounting for spectral differences between the sensors using EO-1 Hyperion data. The recalibrated history of the Landsat data and implications to users are discussed. The key result from this work is a consistently calibrated Landsat data archive that spans nearly 40 years with total uncertainties on the order of 10% or less for most sensors and bands.

Markham, Brian↗

Materials Data on TmCd2 by Materials Project

TmCd2 crystallizes in the hexagonal P6/mmm space group. The structure is three-dimensional. Tm is bonded to two equivalent Tm and twelve equivalent Cd atoms to form a mixture of distorted face, edge, and corner-sharing TmTm2Cd12 cuboctahedra. Both Tm–Tm bond lengths are 3.41 Å. All Tm–Cd bond lengths are 3.33 Å. Cd is bonded in a 11-coordinate geometry to six equivalent Tm and five equivalent Cd atoms. There are three shorter (2.86 Å) and two longer (3.41 Å) Cd–Cd bond lengths.

36 MATERIALS SCIENCE↗

Materials Data on Tm2NiAs2 by Materials Project

Tm2NiAs2 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Tm is bonded in a 9-coordinate geometry to three equivalent Ni and six As atoms. All Tm–Ni bond lengths are 2.99 Å. There are three shorter (2.87 Å) and three longer (2.99 Å) Tm–As bond lengths. Ni is bonded in a 3-coordinate geometry to six equivalent Tm and three equivalent As atoms. All Ni–As bond lengths are 2.35 Å. There are two inequivalent As sites. In the first As site, As is bonded to six equivalent Tm atoms to form edge-sharing AsTm6 octahedra. In the second As site, As is bonded in a 3-coordinate geometry to six equivalent Tm and three equivalent Ni atoms.

36 MATERIALS SCIENCE↗

Materials Data on TmSnRh by Materials Project

TmRhSn crystallizes in the hexagonal P-62m space group. The structure is three-dimensional. Tm is bonded in a 11-coordinate geometry to five Rh and six equivalent Sn atoms. There are four shorter (2.97 Å) and one longer (3.06 Å) Tm–Rh bond lengths. There are two shorter (3.13 Å) and four longer (3.28 Å) Tm–Sn bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh is bonded in a 9-coordinate geometry to three equivalent Tm and six equivalent Sn atoms. All Rh–Sn bond lengths are 2.75 Å. In the second Rh site, Rh is bonded in a 9-coordinate geometry to six equivalent Tm and three equivalent Sn atoms. All Rh–Sn bond lengths are 2.82 Å. Sn is bonded in a 10-coordinate geometry to six equivalent Tm and four Rh atoms.

36 MATERIALS SCIENCE↗

Materials Data on Tm2Al3Si2 by Materials Project

Tm2Al3Si2 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Tm is bonded in a 12-coordinate geometry to six Al and five equivalent Si atoms. There are a spread of Tm–Al bond distances ranging from 3.00–3.22 Å. There are a spread of Tm–Si bond distances ranging from 2.85–2.98 Å. There are two inequivalent Al sites. In the first Al site, Al is bonded in a distorted water-like geometry to four equivalent Tm and two equivalent Si atoms. Both Al–Si bond lengths are 2.60 Å. In the second Al site, Al is bonded in a 12-coordinate geometry to four equivalent Tm and two equivalent Si atoms. Both Al–Si bond lengths are 2.71 Å. Si is bonded in a 9-coordinate geometry to five equivalent Tm, three Al, and one Si atom. The Si–Si bond length is 2.38 Å.

36 MATERIALS SCIENCE↗

Materials Data on TmGa3Ru by Materials Project

TmRuGa3 crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tm is bonded in a 8-coordinate geometry to four equivalent Ru and ten Ga atoms. All Tm–Ru bond lengths are 3.20 Å. There are eight shorter (2.93 Å) and two longer (3.20 Å) Tm–Ga bond lengths. Ru is bonded to four equivalent Tm and eight equivalent Ga atoms to form distorted RuTm4Ga8 cuboctahedra that share corners with four equivalent RuTm4Ga8 cuboctahedra, edges with four equivalent GaTm6 octahedra, and faces with eight equivalent RuTm4Ga8 cuboctahedra. All Ru–Ga bond lengths are 2.66 Å. There are two inequivalent Ga sites. In the first Ga site, Ga is bonded to six equivalent Tm atoms to form GaTm6 octahedra that share corners with six equivalent GaTm6 octahedra and edges with twelve equivalent RuTm4Ga8 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. In the second Ga site, Ga is bonded in a 6-coordinate geometry to three equivalent Tm and three equivalent Ru atoms.

36 MATERIALS SCIENCE↗