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At least 775 records · Page 43

Compressor Stall Recovery Through Tip Injection Assessed

Aerodynamic stability is a fundamental limit in the compressor design process. The development of robust techniques for increasing stability has several benefits: enabling higher loading and fewer blades, increasing safety throughout a mission, increasing tolerance to stage mismatch during part-speed operation and speed transients, and providing an opportunity to match stages at the compressor maximum efficiency point, thus reducing fuel burn. Mass injection upstream of the tip of a high-speed axial compressor rotor is a stability enhancement approach known to be effective in suppressing stall in tip-critical rotors if the injection is activated before stall occurs. This approach to stall suppression requires that a reliable stall warning system be available. Tests have recently been performed to assess whether steady injection can also be used to recover from fully developed stall. If mass injection is effective in recovering from stall quickly enough to avoid structural damage or loss of engine power, then a stall warning system may not be required. The stall recovery tests were performed on a transonic compressor rotor at its design tip speed of 1475 ft/sec using four injectors evenly spaced around the compressor case upstream of the rotor. The injectors were connected to an external air source. In an actual engine application, the injected air would be supplied with compressor bleed air. The injectors were isolated from the air source by a fast-acting butterfly valve. With the injectors turned off, the compressor was throttled into stall. Air injection was then activated with no change in throttle setting by opening the butterfly valve. The compressor recovered from stall at a fixed throttle setting with the aid of tip injection. The unsteady operating characteristic of the rotor was measured during these tests using high-response pressure sensors located upstream and downstream of the rotor. The figure shows the results, where the unsteady pressure and mass flow are superimposed on the steady operating characteristic. The total injected mass flow was equal to 1.3 percent of the compressor flow. The solid line with no solid squares on it denotes the operating point during the beginning of throttle closure and the initial drop into stall. The gray traces denote the operating point during an additional throttle closure that occurred over the next 1200 rotor revolutions (4 sec). The dashed line denotes the recovery from stall that occurred during 90 rotor revolutions (0.3 sec) after the injectors were activated with no change in throttle setting. Tip injection not only recovers the compressor from stall, but also restores the compressor to its pre-stall level of pressure rise. In contrast, standard stall recovery schemes such as compressor bleed, stator vane actuation, or engine throttle modulation result in a loss of pressure rise across the compressor, which results in a loss of engine power.

Suder, Ken L.↗

Precious metal recovery from electronic waste by a porous porphyrin polymer

Significance Electronic waste, also called e-waste, is rapidly becoming a major industrial hazard because of the increased use of circuits and screens. With the right technology, however, this waste could become a sustainable source for precious metals. Such a solution requires selectivity toward the precious metals, as this characteristic is even more important than capacity. A porphyrin-based porous polymer with selective binding shows remarkable selectivity and a reductive mechanism, a combination which makes for record-high recycling of precious metals––particularly gold––from e-waste.

Hong, Yeongran↗

ORNL Campus Sustainability and Decarbonization using Waste Heat Recovery from the Oak Ridge Leadership Computing Facility’s High-Performance Computing Data Center

Heat pumps are a clean and efficient technology that can be powered by renewable electricity to transfer heat using a refrigerant from one place to another by different heat sources, making buildings clean and environmentally friendly. With the support of the ORNL Laboratory Modernization Division, this project explored and evaluated an innovative solution that uses water-water cost-effective midtemperature heat pump (MTHP) technology to leverage the low-grade waste heat from ORNL Frontier and the data center to deliver 85°C hot water, which replaces hot steam generated using natural gas combustion boilers for water heating or space heating in the buildings of ORNL campus. Two scenarios were studied. In the first scenario, which considered the 5600-5700-5800 complex only, Carrier’s commercial 1,000 kW MTHP technology achieves more than 6,640 MWh/year energy savings, an emission reduction of 858 TCO2e/year CO2, and a payback time of 4.85 years. In the second scenario, which considered the 5600-5700-5800 complex and Buildings 5100, 5200, and 5300, the CO2 emission reduction is 1,483 TCO2e/year, the operating cost savings are $0.21 million annually, and the payback time is 3.74 years. Additionally, a comprehensive HP ShowCase Tool was developed for evaluating the optimal solution to improve sustainability and decarbonization of the buildings on the ORNL campus. The tool is an Excel-based tool integrated with VBA (Visual Basic for Applications) coding. The tool includes collected ORNL campus building information and an MTHP library, which comprises collected commercial and ORNL-defined MTHPs. The tool was used to evaluate the sustainability and decarbonization of the ORNL campus. The tool can be widely used or referenced for heat pump solutions and building decarbonization renovation strategies to modernize ORNL facilities and energy use–intensive equipment to enable efficient, sustainable, and resilient operations in the future.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Source Term Modeling for Evaluating the Potential Impacts to Groundwater of Fluids Escaping from a Depleted Oil Reservoir Used for Carbon Sequestration

In recent years depleted oil reservoirs have received special interest as carbon storage reservoirs because of their potential to offset costs through collaboration with enhanced oil recovery projects. Modeling is currently being conducted to evaluate potential risks to groundwater associated with leakage of fluids from depleted oil reservoirs used for storage of CO2. Modeling results reported here focused on understanding how toxic organic compounds found in oil will distribute between the various phases within a storage reservoir after introduction of CO2, understanding the migration potential of these compounds, and assessing potential groundwater impacts should leakage occur. Two model scenarios were conducted to evaluate how organic components in oil will distribute among the phases of interest (oil, CO2, and brine). The first case consisted of 50 wt.% oil and 50 wt.% water; the second case was 90 wt.% CO2 and 10 wt.% oil. Several key organic compounds were selected for special attention in this study based upon their occurrence in oil at significant concentrations, relative toxicity, or because they can serve as surrogate compounds for other more highly toxic compounds for which required input data are not available. The organic contaminants of interest (COI) selected for this study were benzene, toluene, naphthalene, phenanthrene, and anthracene. Partitioning of organic compounds between crude oil and supercritical CO2 was modeled using the Peng-Robinson equation of state over temperature and pressure conditions that represent the entire subsurface system (from those relevant to deep geologic carbon storage environments to near surface conditions). Results indicate that for a typical set of oil reservoir conditions (75°C, and 21,520 kPa) negligible amounts of the COI dissolve into the aqueous phase. When CO2 is introduced into the reservoir such that the final composition of the reservoir is 90 wt.% CO2 and 10 wt.% oil, a significant fraction of the oil dissolves into the vapor phase. As the vapor phase moves up through the stratigraphic column, pressures and temperatures decrease, resulting in significant condensation of oil components. The heaviest organic components condense early in this process (at higher pressures and temperatures), while the lighter components tend to remain in the vapor phase until much lower pressures and temperatures are reached. Based on the model assumptions, the final concentrations of COI to reach an aquifer at 1,520 kPa and 25°C were quite significant for benzene and toluene, whereas the concentrations of polynuclear aromatic hydrocarbons that reach the aquifer were very small. This work demonstrates a methodology that can provide COI source term concentrations in CO2 leaking from a reservoir and entering an overlying aquifer for use in risk assessments.

carbon sequestration, scCO2, crude oil, benzene, B↗

Characterizing Pore-Scale Geochemical Alterations in Eagle Ford and Barnett Shale from Exposure to Hydraulic Fracturing Fluid and CO 2 /H 2 O

As demand increases for an affordable energy source that is tied to an environmental obligation to reduce greenhouse gas emissions and water usage, there is a growing consideration in shale production utilizing processes such as 1) enhancing hydrocarbon recovery via carbon dioxide (CO 2 ) flooding, 2) using CO 2 as a fracturing agent to minimize water use, and 3) storing CO 2 in depleted shale formations to mitigate emissions to the atmosphere. Understanding the geochemical reactions and alterations that occur as shale is exposed to fluids and CO 2 is necessary to develop and optimize each of these processes for field applications. While the majority of shale formations are stimulated using traditional fracturing fluid, some may be fractured using CO 2 or other non-traditional means. We examine the effect fracturing fluid has on shale and how it behaves with secondary exposure to dry CO 2 or CO 2 -saturated water using in situ Fourier Transform infrared spectroscopy (FTIR), feature relocation scanning electron microscopy (SEM), and surface area and pore size analysis using volumetric gas sorption. These techniques were performed on Eagle Ford and Barnett shale samples that were exposed to fracturing fluid and unexposed (as received). Shales that have been exposed to traditional fracturing fluid experienced two reaction fronts. The first reaction front was formed during exposure to the fracturing fluid (pH of ~1.4). A secondary reaction front was formed as a result of CO 2 -saturated fluid exposure in the form of carbonic acid (pH ~5.6). These two different reaction mechanisms drove multiple dissolution and precipitation cycles which altered petrophysical properties of the shale and could lead to a significant impact on flow pathways. FTIR showed that equilibration of carbonate dissolution and precipitation cycles could take as long as 35 days. Samples exposed to fracturing fluid showed significantly less carbonate reactivity compared to those exposed to water. Pore size analysis results indicate exposure to fracturing fluid blocked small nanopores (10-15 nm) reducing BET surface area and total pore volume. SEM results show barite precipitated heavily during exposure to fracturing fluid. It appeared that carbonic acid was able to extract sulfur from organic matter to form gypsum evaporites. The mineralogical (barite precipitation and calcite dissolution/precipitation) and pore-scale alterations observed in these samples may lead to enhancement of flow pathways for injected CO 2 or produced hydrocarbons.

04 OIL SHALES AND TAR SANDS↗

Estimating Critical Customer Outages Resulting from Extreme Hurricanes

US power outage data has been collected by organizations such as Oak Ridge National Laboratory (ORNL) through Environment for Analysis Geo-Located Energy Infrastructure (EAGLE-I: freely available) and poweroutage.us (commercial data: available to purchase). However, these sources do not provide information specific to outages of critical customers. Critical customers include entities, facilities, and individuals whose continuous access to electricity is essential for public safety, emergency response, disaster recovery, the well-being of vulnerable populations, public safety and order, and public utilities such as natural gas, communications, water and sanitation. Identification and geolocation of critical customers is crucial for understanding and addressing the effects of power outages on essential services and ensuring that necessary measures are taken to maintain their operations during power disruptions. This work is a first step towards estimating the occurrences of critical customer outages and developing a critical customer power outage data repository. This work estimates outage incidents of critical customers through spatiotemporal mapping of power outage data, weather data, building data, and critical infrastructure network data. Our results show that critical customer effects vary across different counties. We provide appropriate mathematical explanations and simplifications to define and systematize the proposed approach.

Bhusal, Narayan [ORNL] (ORCID:0000000222752145)↗

First Horizontal Test Results of the HZB SRF Photoinjector for BERLinPro

The BERLinPro project, a small superconducting RF (SRF) c.w. energy recovery linac (ERL) is being built at Helmholtz-Zentrum Berlin in order to develop the technology required for operation of a high current, 100 mA, 50 MeV ERL. The electron source for the accelerator is a 1.4 cell SRF photoinjector fitted with a multi-alkali photocathode. As part of the HZB photoinjector development program three different SRF photoinjectors will be fabricated and tested. The photoinjector described herein is the second cavity that has been fabricated, and the first photoinjector designed for use with a multi-alkali photocathode. The photoinjector has been built and tested at JLab and subsequently shipped to HZB for testing in the horizontal test cryostat HoBiCaT prior to installation in the photoinjector cryomodule. This cryomodule will be used to measure the photocathode operation in a dedicated experiment called GunLab, the precursor to installation in the BERLinPro hall. This paper will report on the final results of the cavity installed in the helium vessel in the vertical testing dewar at Jefferson Lab as well as the first horizontal test in HoBiCaT

Burrill, A.↗

Testing and Performance Analysis of a 650 Mbps QPPM Modem for Free-space Laser Communications

The testing and performance of a prototype modem developed at NASA Lewis Research Center for high-speed free-space direct detection optical communications is described. The testing was performed under laboratory conditions using computer control with specially developed test equipment that simulates free-space link conditions. The modem employs quaternary pulse position modulation (QPPM) at 325 Megabits per second (Mbps) on two optical channels, which are multiplexed to transmit a single 650 Mbps data stream. The measured results indicate that the receiver's automatic gain control (AGC), phased-locked-loop slot clock recovery, digital symbol clock recovery, matched filtering, and maximum likelihood data recovery circuits were found to have only 1.5 dB combined implementation loss during bit-error-rate (BER) performance measurements. Pseudo random bit sequences and real-time high quality video sources were used to supply 650 Mbps and 325 Mbps data streams to the modem. Additional testing revealed that Doppler frequency shifting can be easily tracked by the receiver, that simulated pointing errors are readily compensated for by the AGC circuits, and that channel timing skew affects the BER performance in an expected manner. Overall, the needed technologies for a high-speed laser communications modem were demonstrated.

Mortensen, Dale J.↗

Adsorption Modeling at the Front and Back Ends of the Nuclear Fuel Cycle

Adsorption is a diverse and complex physicochemical process that has many different applications in chemical, environmental, and nuclear sciences. For example, adsorption can be found at both the front and back ends of the nuclear fuel cycle for (i) capturing uranium from seawater to use as a new source of nuclear fuel and (ii) treatment of the off-gases produced when reprocessing used nuclear fuel. Accurate modeling of these processes is important for the design of efficient capture, recovery, and removal systems for the particular aqueous or gaseous species of interest. A set of algorithms and methods designed for flexibility and portability will greatly improve the ability to rigorously model such a complex set of systems. This approach allows more specific models to be built upon the more generic methods, which gives the overall modeling effort larger breadth and greater usability. Due to the complexity of adsorption processes, it is necessary to develop relatively complex mechanistic models to accurately predict the behavior of engineered adsorption systems. Capture and recovery systems designed for nuclear energy need to have a high level of accuracy to reduce uncertainties and aid in the implementation of separations technologies for efficient nuclear energy systems. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The Potential for Electrons to Molecules Using Solar Energy

Solar photovoltaics (PV) do and will continue to play an important role in the electric power sector and can potentially support other sectors that are in need of decarbonized energy sources. Chemicals such as hydrogen, ammonia, and hydrocarbons including ethylene are currently produced from natural gas and crude oil. Thus, processes to produce them emit carbon dioxide and other greenhouse gases both directly and in upstream feedstock recovery processes. Electrons-to-molecules (E2M) technologies are being developed to convert carbon dioxide, water, and atmospheric nitrogen to desired chemical products and they are large electricity loads. Thus, they are emerging as a potential applications for PV. In its essence, they can act as electrochemical energy storage, thereby providing a means to further utilize the energy generated from PV and store it in molecular form. E2M systems offer an array of potential products and system designs that can be tailored to different end-uses and applications. It involves electrochemical conversion which uses electricity to break molecular bonds and produce new molecules. Various electrochemical conversion technologies split water into hydrogen and oxygen, reduce carbon dioxide into other hydrocarbon molecules, and several other possible combinations. While this Chapter does not attempt to provide an exhaustive summary or analysis of the potential products from E2M systems, it does provide an initial overview of the potential opportunities and challenges for PV and E2M systems in this space. This Chapter considers the potential for E2M to produce key chemicals and fuels that currently rely on hydrocarbons for production, either as a reactant or a source of high-grade heat.

14 SOLAR ENERGY↗

Californium Electrodepositions at Oak Ridge National Laboratory

Electrodepositions of californium isotopes were successfully performed at Oak Ridge National Laboratory (ORNL) during the past year involving two different types of deposition solutions, ammonium acetate (NH 4 C 2 H 3 O 2 ) and isobutanol ((CH 3 ) 2 CHCH 2 OH). A californium product that was decay enriched in 251 Cf was recovered for use in super-heavy element (SHE) research. This neutron-rich isotope, 251 Cf, provides target material for SHE research for the potential discovery of heavier isotopes of Z=118. The californium material was recovered from aged 252 Cf neutron sources in storage at ORNL. These sources have decayed for over 30 years, thus providing material with a very high 251 Cf-to- 252 Cf ratio. After the source capsules were opened, the californium was purified and then electrodeposited using the isobutanol method onto thin titanium foils for use in an accelerator at the Joint Institute for Nuclear Research in Dubna, Russia. Another deposition method, ammonium acetate, was used to produce a deposition containing 1.7 0.1 Ci of 252 Cf onto a stainless steel substrate. This was the largest single electrodeposition of 252 Cf ever prepared. The 252 Cf material was initially purified using traditional ion exchange media, such as AG50-AHIB and AG50-HCl, and further purified using a TEVA-NH 4 SCN system to remove any lanthanides, resulting in the recovery of 3.6 0.1 mg of purified 252 Cf. The ammonium acetate deposition was run with a current of 1.0 amp, resulting in a 91.5% deposition yield. Purification and handling of the highly radioactive californium material created additional challenges in the production of these sources.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Dynamic NBTI effects in HfSiON.

Negative bias temperature instability is an issue of critical importance as the space electronics industry evolves because it may dominate the reliability lifetime. Understanding its physical origin is therefore essential in determining how best to search for methods of mitigation. It has been suggested that the magnitude of the effect is strongly dependent on circuit operation conditions (static or dynamic modes). In the present work, we examine the time constants related to the charging and recovery of trapped charged induced by NBTI in HfSiON gate dielectric devices. In previous work, we avoided the issue of charge relaxation during acquisition of the I{sub ds}(V{sub gs}) curve by invoking a continuous stressing technique whereby {Delta}V{sub th} was extracted from a series of single point I{sub ds} measurements. This method relied heavily on determination of the initial value of the source-drain current (I{sub ds}{sup o}) prior to application of gate-source stress. In the present work we have used a new pulsed measurement system (Keithley SCS 4200-PIV) which not only removes this uncertainty but also permits dynamic measurements in which devices are AC stressed (Fig. 1a) or subjected to cycles of continued DC stresses followed by relaxation (Fig. 1b). We can now examine the charging and recovery characteristics of NBTI with higher precision than previously possible. We have performed NBTI stress experiments at room temperature on p-channel MOSFETs made with HfSiON gate dielectrics. In all cases the devices were stressed in the linear regime with V{sub ds}=-0.1V. We have defined two separate waveforms/pulse trains as illustrated in Fig 1. These were applied to the gate of the MOSFET. Firstly we examined the charging characteristics by applying an AC stress at 2.5MHz or 10Hz for different times. For a 50% duty cycle this corresponded to V{sub gs} = - 2V pulses for 200ns or 500ms followed by V{sub gs} = 0V pulses for 200ns or 500ms recovery respectively. In between 'bursts' of AC stress cycles, the I{sub ds}(V{sub gs}) characteristic in the range (-0.6V, -1.3V) was measured in 10.2 {micro}s. V{sub th} was extracted directly from this curve, or from a single I{sub ds} point normalized to the initial I{sub ds}{sup o} using our previous method. The resulting I{sub ds}/I{sub ds}{sup o} curves are compared; in Fig 2, the continuous stress results are included. In the second method, we examined the recovery dynamic by holding V{sub gs} = 0V for a finite amount of time (range 100 ns to 100 ms) following stress at V{sub gs} = - 2V for various times. In Fig 3 we compare |{Delta}V{sub th}(t)| results for recovery times of 100ms, 1ms, 100{micro}s, 50{micro}s, 25{micro}s, 10{micro}s, 100ns, and DC (i.e. no recovery) The data in Fig 2 shows that with a high frequency stress (2.5MHz) devices undergo significantly less (but finite) current degradation than devices stressed at 10Hz. This appears to be limited by charging and not by recovery. Fig 3 supports this hypothesis since for 100ns recovery periods, only a small percentage of the trapped charge relaxes. Detailed explanation of these experiments will be presented at the conference.

36 MATERIALS SCIENCE↗

Wildfire Produces Transient Minerals: Speciation, Reactivity, and Fate of Iron and Manganese in Surface Soils Post Wildfire

Wildfire leads to the deposition of an ash layer at the land surface. This material typically has alkaline properties, abundant pyrogenic carbon, and elevated metal concentrations compared to surface soils. Here, we compare ash and surface soils collected three weeks and two years after the Glass Fire (St. Helena, California, USA) to determine how wildfire affects the speciation and reactivity of iron (Fe) and manganese (Mn), two micronutrients that influence many soil processes. Synchrotron-based analyses revealed that wildfire generated stable Fe oxides like maghemite (γ-Fe 2 O 3 ) and hematite (α-Fe 2 O 3 ) that likely derived from surface soil or mineral dust rather than the vegetation, and Mn oxides such as hausmannite (Mn 3 O 4 ) and bixbyite (Mn 2 O 3 ) that derived primarily from aboveground biomass. However, these pyrogenic minerals were absent in soils collected two years after the fire. Their loss from the soil surface may result from a combination of erosion, translocation to deeper soil layers, and chemical weathering. The latter hypothesis is supported by the enhanced mobilization of Fe and Mn from ash upon the addition of pyoverdine, a model biogenic ligand. The increased mobility of micronutrients from fire-derived minerals in ash in response to microbial and root exudation may facilitate postfire soil and vegetation recovery.

bixbyite↗

Foundation Heat Exchanger Final Report: Demonstration, Measured Performance, and Validated Model and Design Tool

Geothermal heat pumps, sometimes called ground-source heat pumps (GSHPs), have been proven capable of significantly reducing energy use and peak demand in buildings. Conventional equipment for controlling the temperature and humidity of a building, or supplying hot water and fresh outdoor air, must exchange energy (or heat) with the building's outdoor environment. Equipment using the ground as a heat source and heat sink consumes less non-renewable energy (electricity and fossil fuels) because the earth is cooler than outdoor air in summer and warmer in winter. The most important barrier to rapid growth of the GSHP industry is high first cost of GSHP systems to consumers. The most common GSHP system utilizes a closed-loop ground heat exchanger. This type of GSHP system can be used almost anywhere. There is reason to believe that reducing the cost of closed-loop systems is the strategy that would achieve the greatest energy savings with GSHP technology. The cost premium of closed-loop GSHP systems over conventional space conditioning and water heating systems is primarily associated with drilling boreholes or excavating trenches, installing vertical or horizontal ground heat exchangers, and backfilling the excavations. This project investigates reducing the cost of horizontal closed-loop ground heat exchangers by installing them in the construction excavations, augmented when necessary with additional trenches. This approach applies only to new construction of residential and light commercial buildings or additions to such buildings. In the business-as-usual scenario, construction excavations are not used for the horizontal ground heat exchanger (HGHX); instead the HGHX is installed entirely in trenches dug specifically for that purpose. The potential cost savings comes from using the construction excavations for the installation of ground heat exchangers, thereby minimizing the need and expense of digging additional trenches. The term foundation heat exchanger (FHX) has been coined to refer exclusively to ground heat exchangers installed in the overcut around the basement walls. The primary technical challenge undertaken by this project was the development and validation of energy performance models and design tools for FHX. In terms of performance modeling and design, ground heat exchangers in other construction excavations (e.g., utility trenches) are no different from conventional HGHX, and models and design tools for HGHX already exist. This project successfully developed and validated energy performance models and design tools so that FHX or hybrid FHX/HGHX systems can be engineered with confidence, enabling this technology to be applied in residential and light commercial buildings. The validated energy performance model also addresses and solves another problem, the longstanding inadequacy in the way ground-building thermal interaction is represented in building energy models, whether or not there is a ground heat exchanger nearby. Two side-by-side, three-level, unoccupied research houses with walkout basements, identical 3,700 ft{sup 2} floor plans, and hybrid FHX/HGHX systems were constructed to provide validation data sets for the energy performance model and design tool. The envelopes of both houses are very energy efficient and airtight, and the HERS ratings of the homes are 44 and 45 respectively. Both houses are mechanically ventilated with energy recovery ventilators, with space conditioning provided by water-to-air heat pumps with 2 ton nominal capacities. Separate water-to-water heat pumps with 1.5 ton nominal capacities were used for water heating. In these unoccupied research houses, human impact on energy use (hot water draw, etc.) is simulated to match the national average. At House 1 the hybrid FHX/HGHX system was installed in 300 linear feet of excavation, and 60% of that was construction excavation (needed to construct the home). At House 2 the hybrid FHX/HGHX system was installed in 360 feet of excavation, 50% of which was construction excavation. There are six pipes in all excavations (three parallel circuits - out and back), and the multiple instances of FHX and/or HGHX are all connected in series. The working fluid is 20% by weight propylene glycol in water. Model and design tool development was undertaken in parallel with constructing the houses, installing instrumentation, and monitoring performance for a year. Several detailed numerical models for FHX were developed as part of the project. Essentially the project team was searching for an energy performance model accurate enough to achieve project objectives while also having sufficient computational efficiency for practical use in EnergyPlus. A 3-dimensional, dual-coordinate-system, finite-volume model satisfied these criteria and was included in the October 2011 EnergyPlus Version 7 public release after being validated against measured data.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Solar Photovoltaics in Severe Weather: Cost Considerations for Storm Hardening PV Systems for Resilience

Solar photovoltaic (PV) power has many advantages as a resilient power source, including the ability to provide power after a natural disaster. While solar arrays often survive severe weather events, systems are occasionally compromised and left unable to provide power. For PV systems to act as resilient power providers, they must remain operational. Building a system that is more likely to survive a storm comes at a cost, though. Previous efforts have identified various system measures and practices that can increase the likelihood of a PV system surviving a severe weather event. But what is the cost premium for a storm hardened PV system? This report provides initial estimates for the up-front cost premiums for various methods of storm hardening PV systems.

14 SOLAR ENERGY↗

Thickness dependent self limiting 1-D tin oxide nanowire arrays by nanosecond pulsed laser irradiation

Fast, sensitive and discriminating detection of hydrogen at room temperature is crucial for storage, transportation, and distribution of hydrogen as an energy source. One dimensional nanowires of SnO2 are potential candidates for improved H2 sensor performance. The single directional conducting continuous nanowires can decrease electrical noise, and their large active surface area could improve the response and recovery time of the sensor. In this work we discuss synthesis and characterization of nanowire arrays made using nanosecond ultraviolet wavelength (266 nm) laser interference processing of ultrathin SnO2 films on SiO2 substrates. The laser energy was chosen to be above the melting point of the films. The results show that the final nanowire formation is dominated by preferential evaporation as compared to thermocapillary flow. The nanowire height (and hence wire aspect ratio) increased with increasing initial film thickness ho and with increasing laser energy density Eo. Furthermore, a self-limiting effect was observed where-in the wire formation ceased at a specific final remaining thickness of SnO2 that was almost independent of ho for a given Eo. To understand these effects, finite element modeling of the nanoscale laser heating was performed. This showed that the temperature rise under laser heating was a strong non-monotonic function of film thickness. As a result, the preferential evaporation rate varies as wire formation occurs, eventually leading to a shut-off of evaporation at a characteristic thickness. This results in the stoppage of wire formation. This combination of nanosecond pulsed laser experiments and thermal modeling shows that several unique synthesis approaches can be utilized to control the nanowire characteristics.

08 HYDROGEN↗

Liberation and release of rare earth minerals from Middle Kittanning, Fire Clay, and West Kentucky No. 13 coal sources

Here, a laboratory REE release test procedure was designed to better understand the association and liberation characteristics of rare earth elements (REEs) from coal-based material, such as coal middlings and refuse. For this particular study, three samples of mixed-phase, middling material was collected from three coal preparation plants operating in three different coal basins and coal seams, namely Fire Clay, Middle Kittanning, and West Kentucky #13. In these release tests, the mixed-phase material was first ground in a laboratory ball mill for a designated amount of time and subsequently decarbonized using staged flotation. The REE content of the high ash tailings and low ash concentrate was determined, and the process was repeated for various target grind sizes down to the micron range. The results indicate that smaller grind sizes produce increased REE concentrations in the high ash tailings, and this result is predominantly driven by the increased ash content in the decarbonized tailings. The grinding characteristics of the Fire Clay coal source showed that more energy is needed to achieve the desired particle size reduction; however further size reduction of this sample resulted in a significantly higher ash and REE content in the tailings material due to improved liberation. For the Middle Kittanning and West Kentucky #13 sources, the grinding and release data indicates that the mineral matter is liberated at a coarser particle size, and micronizing the coals only produces marginal improvements in rare earth mineral liberation and recovery.

01 COAL, LIGNITE, AND PEAT↗

Accounting for Sustainability and Performance: Contrasting Effects of PET-Derived Modifiers on Asphalt Durability

The valorization of waste plastics in roadway infrastructure requires careful balance between sustainability and performance, as ineffective modifiers may incur both environmental and financial costs. This study shows that two modifiers derived from the same waste plastic source (PET)-DOTP (N1,N4-(dioctyl)terephthalamide) and HETP (N1,N4-Bis(2-hydroxyethyl)terephthalamide)-exhibit opposite effects on asphalt properties, despite having nearly the same carbon footprint. DOTP improves elastic recovery in multiple creep recovery tests (MCRT), while HETP increases strain accumulation and reduces elasticity. Density functional theory (DFT) shows that DOTP's molecular structure can disperse well in bitumen mixtures by binding to both polar and non-polar components. In contrast, HETP binds only to the binder's polar sites, lacking adequate dispersion. This increases the risk of aggregation of polar compounds in the bitumen mixture, resulting in a more deformation-prone binder. A techno-economic analysis highlights trade-offs between sustainability and performance in industrial-scale synthesis. This study advocates for applying first-principles thinking in material design, coupled with experimental validation, to engineer plastic waste-derived additives that achieve both performance and sustainability goals.

36 MATERIALS SCIENCE↗