Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “REACTIVITY”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 775 records · Page 43

Countermeasures to microgravity

Biological systems ranging from the most simple to the most complex generally survive exposure to microgravity. Changes in many characteristics of biological systems are well documented as a consequence of space flight. Attempts to devise countermeasures to microgravity may have direct pragmatic consequences for crew protection and may provide additional insights into the nature of microgravity influences on biological systems. Some of the most well documented changes occur in humans who have experienced space flight. Changes appear to be transient. Space adaption syndrome occurs relatively briefly whereas bone deterioration may require months of postflight time for restoration. It seems critical to recognize that these changes and others may derive from rather passive, active or even reactive changes in the biological systems that are hosts to them. For example, hydrostatic fluid redistributions may be quite passive occurrences that are realized through extensive fluid channels. Changes occur in cell metabolism because of fluid, nutrient and gas redistributions. Equally important are the misconstrued messages likely to be carried by fluid redistributions. These reactive events can trigger, for example, loss of fluids and electrolytes through altered kidney function. Each of these considerations must be evaluated in regard to the biological site affected. Countermeasures to the vast range of biological changes and sites are difficult to envision. The most obvious countermeasure is the restoration of gravity-like influences. Some options are discussed. Recent work has focussed on the use of magnetic fields. Pulsed electromagnetic fields (PEMF) are shown to alleviate bone deterioration produced in rodents exposed to tail suspension. Methods of PEMF exposure are consistent with human use in space. Related methods may provide muscular and neural benefits.

Luttges, Marvin W.↗

Isotope exchange in oxide-containing catalyst

A method of exchanging rare-isotope oxygen for common-isotope oxygen in the top several layers of an oxide-containing catalyst is disclosed. A sample of an oxide-containing catalyst is exposed to a flowing stream of reducing gas in an inert carrier gas at a temperature suitable for the removal of the reactive common-isotope oxygen atoms from the surface layer or layers of the catalyst without damaging the catalyst structure. The reduction temperature must be higher than any at which the catalyst will subsequently operate. Sufficient reducing gas is used to allow removal of all the reactive common-isotope oxygen atoms in the top several layers of the catalyst. The catalyst is then reoxidized with the desired rare-isotope oxygen in sufficient quantity to replace all of the common-isotope oxygen that was removed.

Robert V Hess↗

Study to identify future cryogen payload elements/users for space shuttle launch during period 1990 to 2000

This study provides a summary of future cryogenic space payload users, their currently projected needs and reported planning for space operations over the next decade. At present, few users with payloads consisting of reactive cryogens, or any cryogen in significant quantities, are contemplating the use of the Space Shuttle. Some members of the cryogenic payload community indicated an interest in flying their future planned payloads on the orbiter, versus an expendable launch vehicle (ELV), but are awaiting the outcome of a Rockwell study to define what orbiter mods and payloads requirements are needed to safely fly chemically reactive cryogen payloads, and the resultant cost, schedule, and operational impacts. Should NASA management decide in early 1990 to so modify orbiter(s), based on the Rockwell study and/or changes in national defense payloads launch requirements, then at least some cryo payload customers will reportedly plan on using the Shuttle orbiter vehicle in preference to an ELV. This study concludes that the most potential for possible future cryogenic space payloads for the Space Transportation System Orbiter fleet lies within the scientific research and defense communities.

Elim, Frank M.↗

The indexed time table approach for planning and acting

A representation is discussed of symbolic temporal relations, called IxTeT, that is both powerful enough at the reasoning level for tasks such as plan generation, refinement and modification, and efficient enough for dealing with real time constraints in action monitoring and reactive planning. Such representation for dealing with time is needed in a teleoperated space robot. After a brief survey of known approaches, the proposed representation shows its computational efficiency for managing a large data base of temporal relations. Reactive planning with IxTeT is described and exemplified through the problem of mission planning and modification for a simple surveying satellite.

Ghallab, Malik↗

Cellular structure of lean hydrogen flames in microgravity

Detailed, time-dependent, two-dimensional numerical simulations of premixed laminar flames have been used to study the initiation and subsequent development of cellular structures in lean hydrogen-air flames. The model includes detailed hydrogen-oxygen combustion with 24 elementary reactions of eight reactive species and a nitrogen diluent, molecular diffusion of all species, thermal conduction, viscosity, and convection. This model has been used to study the nonlinear evolution of cellular flame structure and shows that cell splitting, as observed in experiments, can be predicted numerically for sufficiently reactive mixtures. The structures that evolved also resembled the cellular structures observed in experiments. The present study shows that the 'cell-split limit' postulated from experimental observations is an intrinsic property of the mixture and that external factors such as heat losses are not necessary to cause this limit.

Patnaik, G.↗

Loss of ozone in the Arctic vortex for the winter of 1989

Measurements of ClO (Brune et al., 1990) acquired during the Airborne Arctic Stratospheric Expedition are used to infer concentrations of reactive chlorine (ClO + 2 x Cl2O2). Observed fields of potential temperature and potential vorticity are used to extrapolate in situ data to larger regions of the vortex. Calculated values of the loss rate of O3, based on estimates of reactive chlorine and measurements of BrO (Toohey et al., 1990), suggest that the loss of O3 was abut 12 pct for levels of the atmosphere with potential temperatures between 440 and 470 K over the 39 day duration of the ER-2 flights into the polar vortex. Calculated loss rates agree with observed rates of removal of O3, although significant uncertainties exist for each.

Salawitch, Ross J.↗

High-speed fiber-optic links for distribution of satellite traffic

Low-loss fiberoptic links are designed for distribution of data and the frequency reference in large-aperture phased-array antennas based on the transmit/receive-level data mixing architecture. In particular, design aspects of a fiberoptic link satisfying the distribution requirements of satellite data traffic are presented. The design is addressed in terms of reactively matched optical transmitter and receiver modules. Analog and digital characterization of a 50-m fiberoptic link realized using these modules indicates the applicability of this architecture as the only viable alternative for distribution of data signals inside a satellite at present. It is demonstrated that the design of a reactive matching modules enhances the link performance. A dynamic range of 88 dB/MHz was measured for analog data over a 500-1000-MHz bandwidth.

Daryoush, Afshin S.↗

Functionalized poly(arylene ethers) as toughness modifiers for bismaleimides

A family of novel, low molecular weight functionalized poly(arylene ether) resins has been investigated to ascertain its members' toughness-imparting contribution to neat bismaleimide (BMI) resin and BMI-matrix laminate composite properties. Attention is given to the contribution of the reactive poly(arylene ether)'s backbone chemistry to fracture toughness, as well as to the comparative influence of high and low molecular weight reactive poly(arylene ether) types on the modified BMI resin systems. The modified BMIs possess a polyphase morphology, with good adhesion between the thermoplastic nodules and the host thermoset systems.

Stenzenberger, H. D.↗

Near-limit flame structures at low Lewis number

The characteristics of premixed gas flames in mixtures with low Lewis numbers near flammability limits were studied experimentally using a low-gravity environment to reduce buoyant convection. The behavior of such flames was found to be dominated by diffusive-thermal instabilities. For sufficiently reactive mixtures, cellular structures resulting from these instabilities were observed and found to spawn new cells in regular patterns. For less reactive mixtures, cells formed shortly after ignition but did not spawn new cells; instead these cells evolved into a flame structure composed of stationary, apparently stable spherical flamelets. Experimental observations are found to be in qualitative agreement with elementary analytical models based on the interaction of heat release due to chemical reaction, differential diffusion of thermal energy and mass, flame front curvature, and volumetric heat losses due to gas and/or soot radiation.

Ronney, Paul D.↗

Gas and dust emission from comets and life spans of active areas on their rotating nuclei

Outgassing and dust emission from discrete regions on the nuclei of comets are investigated with regard to the processes of activation, dormancy, reactivation, and extinction. With regard to P/Halley, P/Encke, P/Tempel 2, P/Machholz, P/Takamizawa, Bowell and some other new comets, the evolution of one active region of the nucleus surface appears to be independent of the evolution of another active region. The traditional concept of deactivation as a slow and monolithic process needs to be replaced with a more dynamic concept of intermittent periods of dormancy and reactivation of individual vents, varying in size. Life spans of discrete sources of activity are estimated to be at a few hundred revolutions about the sun for comets with perihelia at heliocentric distances of less than 2 AU, if the bulk density is very low.

Sekanina, Z.↗

Copper-Exchanged Zeolite L Traps Oxygen

Brief series of simple chemical treatments found to enhance ability of zeolite to remove oxygen from mixture of gases. Thermally stable up to 700 degrees C and has high specific surface area which provides high capacity for adsorption of gases. To increase ability to adsorb oxygen selectively, copper added by ion exchange, and copper-exchanged zeolite reduced with hydrogen. As result, copper dispersed atomically on inner surfaces of zeolite, making it highly reactive to oxygen, even at room temperature. Reactivity to oxygen even greater at higher temperatures.

Sharma, Pramod K.↗

Ramifications of the recent FAA rule for windshear systems on the development of forward-looking systems

The recent Federal Aviation Administration (FAA) rule requiring windshear systems with flight guidance may have severe ramifications for the development of infrared and other forward-looking systems. The industry needs to have and can have a more cost effective option through the use of a forward-looking system with a reactive backup instead of a reactive system with flight guidance. However, because of the short time for compliance with the new FAA rule, it is possible that existing transport aircraft will be in full compliance before a comprehensive investigation of all forward-looking systems can be completed. If this occurs, it is possible that the market for forward-looking systems will be severely reduced, thereby eliminating the economic incentive to develop these much needed systems. Thus, to assure that this option is available for the airlines, it beehoves the industry to immediately support an in-service evaluation of all available forward-looking systems.

Adamson, H. Patrick↗

CLASS: Coherent Lidar Airborne Shear Sensor. Windshear avoidance

The coherent lidar airborne shear sensor (CLASS) is an airborne CO2 lidar system being designed and developed by Lockheed Missiles and Space Company, Inc. (LMSC) under contract to NASA Langley Research Center. The goal of this program is to develop a system with a 2- to 4-kilometer range that will provide a warning time of 20 to 40 seconds, so that the pilot can avoid the hazards of low-altitude wind shear under all weather conditions. It is a predictive system which will warn the pilot about a hazard that the aircraft will experience at some later time. The ability of the system to provide predictive warnings of clear air turbulence will also be evaluated. A one-year flight evaluation program will measure the line-of-sight wind velocity from a wide variety of wind fields obtained by an airborne radar, an accelerometer-based reactive wind-sensing system, and a ground-based Doppler radar. The success of the airborne lidar system will be determined by its correlation with the windfield as indicated by the onboard reactive system, which indicates the winds actually experienced by the NASA Boeing 737 aircraft.

Targ, Russell↗

The chemistry and mineralogy of Mars soil and dust

A single geological unit consisting of fine, apparently weathered soil material is covering large portions of the surface of Mars. This soil material has been thoroughly homogenized by global dust storms and it is plausible to assume that Mars dust is strongly correlated with it. The chemical-elemental composition of the soil was directly measured by the Viking Landers. Positive detection of Si, Al, Fe, Mg, Ca, Ti, S, Cl, and Br was achieved. Analyses of the SNC meteorites, a group of meteorites that has been suggested to be ejected Martian rocks, supply additional elemental-concentration data, broadening considerably the chemical data-base on the surface materials. A composition model for Mars soil, giving selected average elemental concentrations of major and trace elements, was recently suggested. It was constructed by combining the Viking Lander data, the SNC meteorite analyses, and other analyses. The mineralogy of the surface materials on Mars has not been directly measured yet. By use of various indirect approaches, including chemical correspondence to the surface analyses, spectral analogies, simulations of Viking Lander experiments, analyses of the SNC meteorites and various modeling efforts, the mineralogical composition was constrained to some extent. No direct analyses of soil reactivity have been done yet. Indirect evidence, mostly from the Viking biology experimental results, suggests that the soil probably has a slightly acidic reaction and is generally oxidized. Unambiguous identification of the Mars soil minerals by direct mineralogical analyses, and non-disturbed or in-situ measurements of the soil's reactivity, are of primary importance in future Mars research.

Banin, A.↗

Ion Beam Sputtered Coatings of Bioglass

The ion beam sputtering technique available at the NASA-Lewis was used to apply coatings of bioglass to ceramic, metallic, and polymeric substrates. Experiments in vivo and in vitro described investigate these coatings. Some degree of substrate masking was obtained in all samples although stability and reactivity equivalent to bulk bioglass was not observed in all coated samples. Some degree of stability was seen in all coated samples that were reacted in vitro. Both metallic and ceramic substrates coated in this manner failed to show significantly improved coatings over those obtained with existing techniques. Implantation of the coated ceramic substrate samples in bone gave no definite bonding as seen with bulk glass; however, partial and patchy bonding was seen. Polymeric substrates in these studies showed promise of success. The coatings applied were sufficient to mask the underlying reactive test surface and tissue adhesion of collagen to bioglass was seen. Hydrophilic, hydrophobic, charged, and uncharged polymeric surfaces were successfully coated.

Hench, Larry L.↗

Ignition of nonmetallic materials by impact of high-pressure oxygen. II - Evaluation of repeatability of pneumatic impact test

The gaseous oxygen pneumatic impact test is used to evaluate the suitability of nonmetallic materials for use in high-pressure oxygen systems. The test was evaluated by testing the reactivity of four materials over a range of impact pressures. The evaluation also investigated the effect of valve opening time and other test variables on the frequency of reaction. The variability of the data obtained for each test material was too large for the test method to be capable of distinguishing other than gross differences in the reactivity of materials. No relation was found between this variability and changes in valve opening time and other test variables. The materials studied were found to be unacceptable for use as reference standards. Because of the high variability of the test data, it is recommended that new methods be developed for evaluating the suitability of materials for use in high-pressure oxygen systems.

Schmidt, Naomi↗

The potential for ozone depletion in the Arctic polar stratosphere

The nature of the Arctic polar stratosphere is observed to be similar in many respects to that of the Antarctic polar stratosphere, where an ozone hole has been identified. Most of the available chlorine (CHl and ClONO2) was converted by reactions on polar stratospheric clouds to reactive ClO and Cl2O2 thoroughout the Arctic polar vortex before midwinter. Reactive nitrogen was converted to HNO3, and some, with spatial inhomogeneity, fell out of the stratosphere. These chemical changes ensured characteristic ozone losses of 10 to 15 percent at altitudes inside the polar vortex where polar stratospheric clouds had occurred. These local losses can translate into 5 to 8 percent losses in the vertical column abundance of ozone. As the amount of stratospheric chlorine inevitably increases by 50 percent over the next two decades, ozone losses recognizable as an ozone hole may well appear.

Brune, W. H.↗

Sputtered Ta-Si-N diffusion barriers in Cu metallizations for Si

Electrical measurements on shallow Si n+-p junction diodes with a 30-nm TiSi2 contacting layer demonstrate that an 80-nm-thick amorphous Ta36Si14N50 film prepared by reactive RF sputtering of a Ta5Si3 target in an Ar/N2 plasma very effectively prevents the interaction between the Si substrate with the TiSi2 contacting layer and a 500-nm Cu overlayer. The Ta36Si14N50 diffusion barrier maintains the integrity of the I-V characteristics up to 900 C for 30-min annealing in vacuum. It is concluded that the amorphous Ta36Si14N50 alloy is not only a material with a very low reactivity for copper, titanium, and silicon, but must have a small diffusivity for copper as well.

Kolawa, E.↗